Professor Lee Cronin

  • Regius Chair of Chemistry (School of Chemistry)

telephone: 01413306650
email: Lee.Cronin@glasgow.ac.uk

Level 5, Room 571, Chemistry, Advanced Research Centre, Glasgow, G11 6EW

Import to contacts

ORCID iDhttps://orcid.org/0000-0001-8035-5757

Research interests

Research Interests

Research in the Cronin Group is focussed on the potential of complex chemical systems derived from non-biological building blocks to have a major impact on our fundamental understanding of the interplay of chemical systems and to revolutionise modern technologies. To this end the Cronin group works within three major research "themes" of Synthesis and Self Assembly, Molecular Devices and Complex Chemical Systems. The Cronin Group believes in a synergistic approach to research with research themes and projects reinforcing each other to enable fundamental advances to be made.

This research feeds into a number of major applications being investigated in the Cronin group with the intention of realising the real-world benefits of the fundamental science being conducted. These applications range from developing materials for solar fuel devices to producing potential drug and drug delivery candidates.

This Research would not be possible without the wide range of state of the art research equipment routinely used by the Cronin Group. Having recently moved into a purpose built facility within the School of Chemistry at Glasgow university the Cronin Group is at the forefront of developing cutting edge synthetic and analytical techniques for the study of complex inorganic Chemical systems. These advances include the use of low temperature (cryospray) ESI MS techniques to observe chemical transformations and highly reactive intermediate reaction structures and using purpose built flow reactors to study the self-assembly of polyoxometalate systems.

polyoxometalate 

Publication Highlights

 

  • D. Long, E. Burkholder, and L. Cronin (2007). Chem. Soc. Rev. 36, 105-121. "Polyoxometalate Clusters, Nanostructures and Materials: From Self Assembly to Designer Materials and Devices"
  • Y. F. Song, D. L. Long, L. Cronin (2007). Angew. Chem. Int. Ed. 46, 3900-39004 "Noncovalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate-pyrene hybrid"
  • G. T. Cooper, G. N. Newton, P. Kogerler, D. L. Long, L. Engelhardt, M. Luban, L. Cronin (2007). Angew Chem. Int. Ed. 46, 1340-1344. "Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry"
  • A. D. C. Parenty, Y. F. Song, C. J. Richmond, L. Cronin (2007). Org. Letts., 9, 2253-2256. "A general and efficient five-step one-pot procedure leading to nitrogen-bridgehead heterocycles containing an imidazole ring"
  • N. McMillan, L. V. Smith, J. M. de la Fuente, A. D. C. Parenty (2007). Chem. Commun., 2581-2583. "Incorporation of N-heterocyclic cations into proteins with a highly directed chemical modification"

Research groups

Publications

Selected publications

Zhan, C. et al. (2017) A metamorphic inorganic framework that can be switched between eight single-crystalline states. Nature Communications, 8, 14185. (doi: 10.1038/ncomms14185) (PMID:28194009) (PMCID:PMC5316803)

Dragone, V., Sans, V., Henson, A. B. , Granda, J. M. and Cronin, L. (2017) An autonomous organic reaction search engine for chemical reactivity. Nature Communications, 8, 15733. (doi: 10.1038/ncomms15733) (PMID:28598440) (PMCID:PMC5472751)

Xuan, W., Pow, R., Long, D.-L. and Cronin, L. (2017) Exploring the molecular growth of two gigantic half-closed polyoxometalate clusters {Mo180} and {Mo130Ce6}. Angewandte Chemie (International Edition), 56(33), pp. 9727-9731. (doi: 10.1002/ange.201702957) (PMID:28508585) (PMCID:PMC5600119)

Boyd, T., Mitchell, S. G., Gabb, D., Long, D.-L. , Song, Y.-F. and Cronin, L. (2017) POMzites: a family of zeolitic polyoxometalate frameworks from a minimal building block library. Journal of the American Chemical Society, 139(16), pp. 5930-5938. (doi: 10.1021/jacs.7b01807) (PMID:28368582) (PMCID:PMC5423706)

All publications

List by: Type | Date

Jump to: 2024 | 2023 | 2022 | 2021 | 2020 | 2019 | 2018 | 2017 | 2016 | 2015 | 2014 | 2013 | 2012 | 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001
Number of items: 433.

2024

Parrilla-Gutiérrez, J. M. , Granda, J. M., Ayme, J.-F., Bajczyk, M. D., Wilbraham, L. and Cronin, L. (2024) Electron density-based GPT for optimization and suggestion of host–guest binders. Nature Computational Science, (doi: 10.1038/s43588-024-00602-x) (Early Online Publication)

Asche, S., Pow, R. W., Mehr, H. M. , Cooper, G. J. T. , Sharma, A. and Cronin, L. (2024) Evidence of selection in mineral mediated polymerization reactions executed in a robotic Chemputer system. ChemSystemsChem, e202400006. (doi: 10.1002/syst.202400006) (Early Online Publication)

Sharma, A. , Ng, M. T.-K., Parrilla Gutierrez, J. M. , Jiang, Y. and Cronin, L. (2024) A programmable hybrid digital chemical information processor based on the Belousov-Zhabotinsky reaction. Nature Communications, 15, 1984. (doi: 10.1038/s41467-024-45896-7) (PMID:38443339) (PMCID:PMC10915172)

Matysiak, B. M., Thomas, D. and Cronin, L. (2024) Reaction kinetics using a Chemputable framework for data collection and analysis. Angewandte Chemie (International Edition), 63(9), e202315207. (doi: 10.1002/anie.202315207) (PMID:38155102)

Leonov, A. I. et al. (2024) An integrated self-optimizing programmable chemical synthesis and reaction engine. Nature Communications, 15, 1240. (doi: 10.1038/s41467-024-45444-3) (PMID:38336880) (PMCID:PMC10858227)

Bell, N. L. , Boser, F., Bubliauskas, A., Willcox, D. R., Sandoval Luna, V. E. and Cronin, L. (2024) Autonomous execution of highly reactive chemical transformations in the Schlenkputer. Nature Chemical Engineering, 1, pp. 180-189. (doi: 10.1038/s44286-023-00024-y)

2023

Sharma, A. , Czégel, D., Lachmann, M., Kempes, C. P., Walker, S. I. and Cronin, L. (2023) Assembly theory explains and quantifies selection and evolution. Nature, 622(7982), pp. 321-328. (doi: 10.1038/s41586-023-06600-9) (PMID:37794189) (PMCID:PMC10567559)

Wang, H., Manzano, J. S., Kitson, P. J., Mullin, M., Lin, C.-G., Slowing, I. I. and Cronin, L. (2023) Digitizing protocols into single reactors for the one-pot synthesis of nanomaterials. Matter, 6(7), pp. 2383-2394. (doi: 10.1016/j.matt.2023.05.029)

Krasecki, V. K. et al. (2023) The role of experimental noise in a hybrid classical-molecular computer to solve combinatorial optimization problems. ACS Central Science, 9(7), 1453–1465. (doi: 10.1021/acscentsci.3c00515) (PMID:37521801)

Zhao, T., Bell, N. L. , Chisholm, G. , Kandasamy, B., Long, D.-L. and Cronin, L. (2023) Aqueous solutions of super reduced polyoxotungstates as electron storage systems. Energy and Environmental Science, 16(6), pp. 2603-2610. (doi: 10.1039/D3EE00569K) (PMID:37323468) (PMCID:PMC10265398)

Jiang, Y., Sharma, A. and Cronin, L. (2023) An accelerated method for investigating spectral properties of dynamically evolving nanostructures. Journal of Physical Chemistry Letters, 14(16), pp. 3929-3938. (doi: 10.1021/acs.jpclett.3c00395) (PMID:37078273) (PMCID:PMC10150391)

M. Mehr, S. H. , Caramelli, D. and Cronin, L. (2023) Digitizing chemical discovery with a Bayesian explorer for interpreting reactivity data. Proceedings of the National Academy of Sciences of the United States of America, 120(17), e2220045120. (doi: 10.1073/pnas.2220045120) (PMID:37068251)

Jiang, Z.-G., Zeng, H.-M., Zhang, X., Tan, Y., Lan, Y.-Z., Wang, Y., Long, D.-L. , Cronin, L. and Zhan, C.-H. (2023) A synergistic {Cu2-W12O40} catalyst with high conversion for homo-coupling of terminal alkynes. Inorganic Chemistry Frontiers, 10(4), pp. 1255-1261. (doi: 10.1039/D2QI02368G)

Kowalski, D. J., MacGregor, C. M., Long, D.-L. , Bell, N. L. and Cronin, L. (2023) Automated library generation and serendipity quantification enables diverse discovery in coordination chemistry. Journal of the American Chemical Society, 145(4), pp. 2332-2341. (doi: 10.1021/jacs.2c11066) (PMID:36649125)

Sinclair, Z. L., Bell, N. L. , Bame, J. R., Long, D.-L. and Cronin, L. (2023) A water-soluble self-assembled {Pd84}ᴬᶜ polyoxopalladate nano-wheel as a supramolecular host. Angewandte Chemie (International Edition), 62(1), e202214203. (doi: 10.1002/anie.202214203) (PMID:36336660)

2022

Restuccia, S. , Gibson, G. M. , Cronin, L. and Padgett, M. J. (2022) Measuring optical activity with unpolarized light: ghost polarimetry. Physical Review A: Atomic, Molecular and Optical Physics, 106(6), 062601. (doi: 10.1103/PhysRevA.106.062601)

Manzano, J. S., Hou, W., Zalesskiy, S. S., Frei, P., Wang, H., Kitson, P. J. and Cronin, L. (2022) An autonomous portable platform for universal chemical synthesis. Nature Chemistry, 14(11), pp. 1311-1318. (doi: 10.1038/s41557-022-01016-w) (PMID:36202987)

She, S., Bell, N. L. , Zheng, D., Mathieson, J. S., Castro, M. D., Long, D.-L. , Koehnke, J. and Cronin, L. (2022) Robotic synthesis of peptides containing metal-oxide-based amino acids. Chem, 8(10), pp. 2734-2748. (doi: 10.1016/j.chempr.2022.07.007)

Jiang, Y., Salley, D., Sharma, A. , Keenan, G., Mullen, M. and Cronin, L. (2022) An artificial intelligence enabled chemical synthesis robot for exploration and optimization of nanomaterials. Science Advances, 8(40), eabo2626. (doi: 10.1126/sciadv.abo2626) (PMID:36206340) (PMCID:PMC9544322)

Rohrbach, S. et al. (2022) Digitization and validation of a chemical synthesis literature database in the ChemPU. Science, 377(6602), pp. 172-180. (doi: 10.1126/science.abo0058)

Marshall, S. M., Moore, D. G., Murray, A. R.G., Walker, S. I. and Cronin, L. (2022) Formalising the pathways to life using assembly spaces. Entropy, 24(7), 884. (doi: 10.3390/e24070884) (PMID:35885107) (PMCID:PMC9323097)

Bubliauskas, A., Blair, D. J., Powell-Davies, H., Kitson, P. J., Burke, M. and Cronin, L. (2022) A practical approach to combine modular reactions and reactionware for the digitization of chemical synthesis. Angewandte Chemie (International Edition), 61(24), e202116108. (doi: 10.1002/anie.202116108) (PMID:35257447)

Chen, J.-J. et al. (2022) Effective storage of electrons in water by the formation of highly reduced polyoxometalate clusters. Journal of the American Chemical Society, 144(20), pp. 8951-8960. (doi: 10.1021/jacs.1c10584) (PMID:35536652)

Ribó, E. G., Bell, N. L. , Long, D.-l. and Cronin, L. (2022) Engineering highly reduced molybdenum polyoxometalates via the incorporation of d and f block metal ions. Angewandte Chemie (International Edition), 61(21), e202201672. (doi: 10.1002/anie.202201672) (PMID:35257462)

Dearle, A. E. et al. (2022) An [Fe ᴵᴵᴵ₃₀] molecular metal oxide. Chemical Communications, 58(1), pp. 52-55. (doi: 10.1039/D1CC06224G) (PMID:34807967)

Lockey, D., Mathis, C., Miras, H. N. and Cronin, L. (2022) Investigating the autocatalytically driven formation of Keggin-based polyoxometalate clusters. Matter, 5(1), pp. 302-313. (doi: 10.1016/j.matt.2021.11.030)

2021

Tze-Kiat Ng, M., Bell, N. L. , Long, D.-L. and Cronin, L. (2021) Facile and reproducible electrochemical synthesis of the giant polyoxomolybdates. Journal of the American Chemical Society, 143(48), pp. 20059-20063. (doi: 10.1021/jacs.1c10198) (PMID:34812622)

Cronin, L. (2021) Exploring the hidden constraints that control the self-assembly of nanomolecular inorganic clusters. Bulletin of Japan Society of Coordination Chemistry, 78, pp. 11-17. (doi: 10.4019/bjscc.78.11)

Caramelli, D., Granda, J. M., Mehr, S. H. M. , Cambie, D. , Henson, A. B. and Cronin, L. (2021) Discovering new chemistry with an autonomous robotic platform driven by a reactivity-seeking neural network. ACS Central Science, 7(11), pp. 1821-1830. (doi: 10.1021/acscentsci.1c00435)

Hammer, A. J.S., Leonov, A. I., Bell, N. L. and Cronin, L. (2021) Chemputation and the standardization of chemical informatics. JACS Au, 1(10), pp. 1572-1587. (doi: 10.1021/jacsau.1c00303) (PMCID:PMC8549037)

Bornemann-Pfeiffer, M., Wolf, J., Meyer, K., Kern, S., Angelone, D., Leonov, A., Cronin, L. and Emmerling, F. L. (2021) Standardization and control of Grignard reactions in a universal chemical synthesis machine using online NMR. Angewandte Chemie (International Edition), 60(43), pp. 23202-23206. (doi: 10.1002/anie.202106323) (PMID:34278673)

Restuccia, S. , Gibson, G. M. , Cronin, L. and Padgett, M. J. (2021) Bell inequality in chiral liquids. In: Proceedings SPIE 11881, Quantum Technology: Driving Commercialisation of an Enabling Science II (SPIE Photonex), Glasgow, Scotland, United Kingdom, 28 September - 1 October 2021, p. 1188112. (doi: 10.1117/12.2601516)

Kandasamy, B., Lee, E. , Long, D.-L. , Bell, N. and Cronin, L. (2021) Exploring the geometric space of metal-organic polyhedrons (MOPs) of metal-oxo clusters. Inorganic Chemistry, 60(19), pp. 14772-14778. (doi: 10.1021/acs.inorgchem.1c01987) (PMID:34549944) (PMCID:PMC8493551)

Long, D.-L. and Cronin, L. (2021) Advances in gigantic polyoxomolybdate chemistry. In: Hubbard, C. D. and van Eldik, R. (eds.) Advances in Inorganic Chemistry: Recent Highlights I. Series: Advances in inorganic chemistry (78). Elsevier Academic Press: Cambridge, MA, pp. 227-267. ISBN 9780323851152 (doi: 10.1016/bs.adioch.2021.06.003)

Bell, N. L. , Kupper, M. and Cronin, L. (2021) Design of experiments for optimization of polyoxometalate syntheses. Chemistry of Materials, 33(18), pp. 7263-7271. (doi: 10.1021/acs.chemmater.1c01401)

Cutler, D. J., Singh, M. K., Nichol, G. S., Evangelisti, M., Schnack, J., Cronin, L. and Brechin, E. K. (2021) [Fe15]: a frustrated, centred tetrakis hexahedron. Chemical Communications, 57(71), pp. 8925-8928. (doi: 10.1039/D1CC03919A) (PMID:34396373)

Liu, Y. , Mathis, C., Marshall, S., Bajczyk, M. D., Wilbraham, L. and Cronin, L. (2021) Exploring and mapping chemical space with molecular assembly trees. Science Advances, 7(39), eabj2465. (doi: 10.1126/sciadv.abj2465) (PMID:34559562)

Pow, R. W., Sinclair, Z. L., Bell, N. L. , Watfa, N., Abul-Haija, Y. M. , Long, D.-L. and Cronin, L. (2021) Enantioselective recognition of racemic amino alcohols in aqueous solution by chiral metal-oxide keplerate {Mo132} cluster capsules. Chemistry: A European Journal, 27(48), pp. 12327-12334. (doi: 10.1002/chem.202100899) (PMID:34196438)

Minato, T., Salley, D., Mizuno, N., Yamaguchi, K., Cronin, L. and Suzuki, K. (2021) Robotic stepwise synthesis of hetero-multinuclear metal oxo clusters as single-molecule magnets. Journal of the American Chemical Society, 143(32), pp. 12809-12816. (doi: 10.1021/jacs.1c06047) (PMID:34358427)

Asche, S., Cooper, G. J.T. , Keenan, G., Mathis, C. and Cronin, L. (2021) A robotic prebiotic chemist probes long term reactions of complexifying mixtures. Nature Communications, 12, 3547. (doi: 10.1038/s41467-021-23828-z) (PMID:34112788) (PMCID:PMC8192940)

Marshall, S. M. et al. (2021) Identifying molecules as biosignatures with assembly theory and mass spectrometry. Nature Communications, 12, 3033. (doi: 10.1038/s41467-021-23258-x) (PMID:34031398) (PMCID:PMC8144626)

Chou, L. et al. (2021) Towards a more universal life detection strategy. Bulletin of the American Astronomical Society, 53(4), 181. (doi: 10.3847/25c2cfeb.53a24171)

Hou, W., Bubliauskas, A., Kitson, P. J., Francoia, J.-P., Powell-Davies, H., Parrilla Gutierrez, J. M. , Frei, P., Manzano, J. S. and Cronin, L. (2021) Automatic generation of 3D-printed reactionware for chemical synthesis digitization using ChemSCAD. ACS Central Science, 7(2), pp. 212-218. (doi: 10.1021/acscentsci.0c01354) (PMCID:PMC7908023)

Lin, C.-G., Hutin, M., Busche, C. , Bell, N. L. , Long, D.-L. and Cronin, L. (2021) Elucidating the paramagnetic interactions of an inorganic–organic hybrid radical-functionalized Mn-Anderson cluster. Dalton Transactions, 50(7), pp. 2350-2353. (doi: 10.1039/D0DT04149A) (PMID:33564815)

Lapham, P., Vilà-Nadal, L. , Cronin, L. and Georgiev, V. P. (2021) Influence of the contact geometry and counterions on the current flow and charge transfer in polyoxometalate molecular junctions: a density functional theory study. Journal of Physical Chemistry C, 125(6), pp. 3599-3610. (doi: 10.1021/acs.jpcc.0c11038) (PMID:33633816) (PMCID:PMC7899180)

Cronin, L. (2021) Modelling Emergent Phenomenon Using Chemically Encoded Computations. In: 25th Solvay Conference on Chemistry, Brussels, Belgium, 19-19 Oct 2019, pp. 75-79. ISBN 9789811228209 (doi: 10.1142/9789811228216_0008)

Wilbraham, L. , Mehr, S. H. M. and Cronin, L. (2021) Digitizing chemistry using the chemical processing unit: from synthesis to discovery. Accounts of Chemical Research, 54(2), pp. 253-262. (doi: 10.1021/acs.accounts.0c00674) (PMID:33370095)

Angelone, D., Hammer, A., Rohrbach, S. , Krambeck, S., Granda, J. M., Wolf, J., Zalesskiy, S., Chisholm, G. and Cronin, L. (2021) Convergence of multiple synthetic paradigms in a universally programmable chemical synthesis machine. Nature Chemistry, 13(1), pp. 63-69. (doi: 10.1038/s41557-020-00596-9) (PMID:33353971)

She, S., Xuan, W., Bell, N. L. , Pow, R. , Ribo, E. G., Sinclair, Z., Long, D.-L. and Cronin, L. (2021) Peptide sequence mediated self-assembly of molybdenum blue nanowheel superstructures. Chemical Science, 12(7), pp. 2427-2432. (doi: 10.1039/D0SC06098D)

2020

Traustason, H., Bell, N. L. , Caranto, K., Auld, D. C., Lockey, D. T., Kokot, A., Szymanowski, J. E.S., Cronin, L. and Burns, P. C. (2020) Reactivity, formation, and solubility of polyoxometalates pprobed by calorimetry. Journal of the American Chemical Society, 142(48), pp. 20463-20469. (doi: 10.1021/jacs.0c10133) (PMID:33203207)

Garrido Ribó, E., Bell, N. L. , Xuan, W., Luo, J., Long, D.-L. , Liu, T. and Cronin, L. (2020) Synthesis, assembly, and sizing of neutral, lanthanide substituted molybdenum blue wheels {Mo90Ln10}. Journal of the American Chemical Society, 142(41), pp. 17508-17514. (doi: 10.1021/jacs.0c07146) (PMID:32965108)

Mehr, S. H. M. , Craven, M., Leonov, A. I., Keenan, G. and Cronin, L. (2020) A universal system for digitization and automatic execution of the chemical synthesis literature. Science, 370(6512), pp. 101-108. (doi: 10.1126/science.abc2986) (PMID:33004517)

Salley, D. S., Keenan, G. A., Long, D.-L. , Bell, N. L. and Cronin, L. (2020) A modular programmable inorganic cluster discovery robot for the discovery and synthesis of polyoxometalates. ACS Central Science, 6(9), pp. 1587-1593. (doi: 10.1021/acscentsci.0c00415) (PMID:32999934) (PMCID:32999934)

Cardoso, S. S.S. et al. (2020) Chemobrionics: from self-assembled material architectures to the origin of life. Artificial Life, 26(3), pp. 315-326. (doi: 10.1162/artl_a_00323) (PMID:32697160)

Porwol, L., Kowalski, D. J., Henson, A. , Long, D.-L. , Bell, N. L. and Cronin, L. (2020) An autonomous chemical robot discovers the rules of supramolecular chemistry without prior knowledge. Angewandte Chemie (International Edition), 59(28), pp. 11256-11261. (doi: 10.1002/anie.202000329) (PMID:32419277) (PMCID:PMC7384156)

Salley, D., Keenan, G., Grizou, J. , Sharma, A. , Martín, S. and Cronin, L. (2020) A nanomaterials discovery robot for the Darwinian evolution of shape programmable gold nanoparticles. Nature Communications, 11, 2771. (doi: 10.1038/s41467-020-16501-4) (PMID:32488034) (PMCID:PMC7265452)

Miras, H. N. , Mathis, C., Xuan, W., Long, D. , Pow, R. and Cronin, L. (2020) Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters. Proceedings of the National Academy of Sciences of the United States of America, 117(20), pp. 10699-10705. (doi: 10.1073/pnas.1921536117) (PMID:32371490) (PMCID:PMC7245103)

Parrilla Gutierrez, J. M. , Sharma, A. , Tsuda, S., Cooper, G. J.T. , Aragon Camarasa, G. , Donkers, K. and Cronin, L. (2020) A programmable chemical computer with memory and pattern recognition. Nature Communications, 11, 1442. (doi: 10.1038/s41467-020-15190-3) (PMID:32188858) (PMCID:PMC7080730)

Pow, R. W., Xuan, W., Long, D.-L. , Bell, N. L. and Cronin, L. (2020) Embedding alkenes within an icosahedral inorganic fullerene {(NH4)42[Mo132O372(L)30(H2O)72]} for trapping volatile organics. Chemical Science, 11(9), pp. 2388-2393. (doi: 10.1039/C9SC06217C)

Lee, E. C. , Parrilla-Gutierrez, J. M. , Henson, A. , Brechin, E. K. and Cronin, L. (2020) A crystallization robot for generating true random numbers based on stochastic chemical processes. Matter, 2(3), pp. 649-657. (doi: 10.1016/j.matt.2020.01.024)

Grizou, J. , Points, L. J., Sharma, A. and Cronin, L. (2020) A curious formulation robot enables the discovery of a novel proto-cell behaviour. Science Advances, 6(5), eaay4237. (doi: 10.1126/sciadv.aay4237) (PMID:32064348) (PMCID:PMC6994213)

Chisholm, G. , Cronin, L. and Symes, M. D. (2020) Decoupled electrolysis using a silicotungstic acid electron-coupled-proton buffer in a proton exchange membrane cell. Electrochimica Acta, 331, 135255. (doi: 10.1016/j.electacta.2019.135255)

Gromski, P. S., Granda, J. M. and Cronin, L. (2020) Universal chemical synthesis and discovery with 'The Chemputer'. Trends in Chemistry, 2(1), pp. 4-12. (doi: 10.1016/j.trechm.2019.07.004)

Cavell, A. C. et al. (2020) Optical monitoring of polymerizations in droplets with high temporal dynamic range. Chemical Science, 11(10), pp. 2647-2656. (doi: 10.1039/c9sc05559b) (PMID:34084323) (PMCID:PMC8157680)

2019

Zhan, C.-H., Zheng, Q., Long, D.-L. , Vilà‐Nadal, L. and Cronin, L. (2019) Controlling the reactivity of the [P8W48O184]40– inorganic ring and its assembly into POMZite inorganic frameworks with silver ions. Angewandte Chemie (International Edition), 131(48), pp. 17442-6. (doi: 10.1002/anie.201911170) (PMID:31538679) (PMCID:PMC6900112)

Dearle, A. E. et al. (2019) An [Feᴵᴵᴵ₃₄] molecular metal oxide. Angewandte Chemie (International Edition), 58(47), pp. 16903-16906. (doi: 10.1002/anie.201911003) (PMID:31535459) (PMCID:PMC7186828)

Lie, J., Yang, J.-J., Liu, T., Yuan, R.-M., Deng, D.-R., Zheng, M.-S., Chen, J.-J., Cronin, L. and Dong, Q.-F. (2019) Tuning redox active polyoxometalates for efficient electron‐coupled proton buffer mediated water splitting. Chemistry: A European Journal, 25(49), pp. 11432-11436. (doi: 10.1002/chem.201903142) (PMID:31309625) (PMCID:PMC6851869)

Colón-Santos, S., Cooper, G. J.T. and Cronin, L. (2019) Taming combinatorial explosion of the formose reaction via recursion within mineral environments. ChemSystemsChem, 1(3), e1900014. (doi: 10.1002/syst.201900014)

Doran, D., Abul-Haija, Y. M. and Cronin, L. (2019) Emergence of function and selection from recursively programmed polymerisation reactions in mineral environments. Angewandte Chemie (International Edition), 58(33), pp. 11253-11256. (doi: 10.1002/anie.201902287) (PMID:31206983) (PMCID:PMC6772075)

Xuan, W., Pow, R., Zheng, Q., Watfa, N., Long, D.-L. and Cronin, L. (2019) Ligand-directed template assembly for the construction of gigantic molybdenum blue wheels. Angewandte Chemie (International Edition), 58(32), pp. 10867-10872. (doi: 10.1002/anie.201901818) (PMID:31155800) (PMCID:PMC6771582)

Zheng, Q., Kupper, M., Xuan, W., Oki, H., Tsunashima, R., Long, D.-L. and Cronin, L. (2019) Anisotropic polyoxometalate cages assembled via layers of heteroanion templates. Journal of the American Chemical Society, 141(34), pp. 13479-13486. (doi: 10.1021/jacs.9b04533) (PMID:31295408) (PMCID:PMC6716119)

Duros, V., Grizou, J. , Sharma, A. , Mehr, S. H. M., Bubliauskas, A., Frei, P., Miras, H. N. and Cronin, L. (2019) Intuition-enabled machine learning beats the competition when joint human-robot teams perform inorganic chemical experiments. Journal of Chemical Information and Modeling, 59(6), pp. 2664-2671. (doi: 10.1021/acs.jcim.9b00304) (PMID:31025861) (PMCID:PMC6593393)

Janusson, E. , de Kler, N., Vilà-Nadal, L. , Long, D.-L. and Cronin, L. (2019) Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection. Chemical Communications, 55(41), pp. 5797-5800. (doi: 10.1039/C9CC02361E) (PMID:31041957)

Rosnes, M. H., Mathieson, J. S., Törnroos, K. W., Johnsen, R. E., Cronin, L. and Dietzel, P. D.C. (2019) Electrospray mass spectrometry investigation into the formation of CPO-27. Crystal Growth and Design, 19(4), pp. 2089-2096. (doi: 10.1021/acs.cgd.8b01657)

Martín, S., Takashima, Y., Lin, C.-G., Song, Y.-F., Miras, H. N. and Cronin, L. (2019) Integrated synthesis of gold nanoparticles coated with polyoxometalate clusters. Inorganic Chemistry, 58(7), pp. 4110-4116. (doi: 10.1021/acs.inorgchem.8b03013) (PMID:30869513)

Surman, A. J. , Rodriguez Garcia, M., Abul-Haija, Y. M. , Cooper, G. J.T. , Gromski, P. S., Turk-MacLeod, R., Mullin, M., Mathis, C., Walker, S. I. and Cronin, L. (2019) Environmental control programs the emergence of distinct functional ensembles from unconstrained chemical reactions. Proceedings of the National Academy of Sciences of the United States of America, 116(12), pp. 5387-5392. (doi: 10.1073/pnas.1813987116) (PMID:30842280) (PMCID:PMC6431231)

Suárez-Marina, I., Abul-Haija, Y. M. , Turk-MacLeod, R., Gromski, P. S., Cooper, G. J.T. , Olivé Olivé, A., Colón-Santos, S. and Cronin, L. (2019) Integrated synthesis of nucleotide and nucleosides influenced by amino acids. Communications Chemistry, 2, 28. (doi: 10.1038/s42004-019-0130-7)

Gromski, P. S., Henson, A. B. , Granda, J. M. and Cronin, L. (2019) How to explore chemical space using algorithms and automation. Nature Reviews Chemistry, 3(2), pp. 119-128. (doi: 10.1038/s41570-018-0066-y)

Luo, J., Zhang, B., Yvon, C., Hutin, M., Gerislioglu, S., Wesdemiotis, C., Cronin, L. and Liu, T. (2019) Self-assembly of polyoxometalate-peptide hybrids in solution: elucidating the contributions of multiple possible driving forces. European Journal of Inorganic Chemistry, 2019(3-4), pp. 380-386. (doi: 10.1002/ejic.201800158) (PMID:31007577) (PMCID:PMC6472639)

Sans, V., Dragone, V. and Cronin, L. (2019) Applications of 3D printing in synthetic process and analytical chemistry. In: Anastas, P. T. (ed.) Handbook of Green Chemistry. Wiley, pp. 215-256. ISBN 9783527628698 (doi: 10.1002/9783527628698.hgc141)

Xuan, W., Pow, R., Watfa, N., Zheng, Q., Surman, A. J. , Long, D.-L. and Cronin, L. (2019) Stereoselective assembly of gigantic chiral molybdenum blue wheels using lanthanide ions and amino acids. Journal of the American Chemical Society, 141(3), pp. 1242-1250. (doi: 10.1021/jacs.8b09750) (PMID:30495944) (PMCID:PMC6351008)

Steiner, S. et al. (2019) Organic synthesis in a modular robotic system driven by a chemical programming language. Science, 363(6423), eaav2211. (doi: 10.1126/science.aav2211) (PMID:30498165)

Mathew, P. T., Fang, F., Vila-Nadal, L. , Cronin, L. and Georgiev, V. (2019) First Principle Simulations of Current Flow in Inorganic Molecules: Polyoxometalates (POMs). In: 2019 Joint International EUROSOI Workshop and International Conference on Ultimate Integration on Silicon (EUROSOI-ULIS), Grenoble, France, 01-03 Apr 2019, ISBN 9781728116587 (doi: 10.1109/EUROSOI-ULIS45800.2019.9041869)

Zalesskiy, S. S., Kitson, P. J., Frei, P., Bubliauskas, A. and Cronin, L. (2019) 3D designed and printed chemical generators for on demand reagent synthesis. Nature Communications, 10, 5496. (doi: 10.1038/s41467-019-13328-6) (PMID:31792220) (PMCID:PMC6889270)

2018

Lin, C.-G., Zhou, W., Xiong, X.-T., Xuan, W., Kitson, P. J., Long, D.-L. , Chen, W., Song, Y.-F. and Cronin, L. (2018) Digital control of multistep hydrothermal synthesis by using 3D printed reactionware for the synthesis of metal–organic frameworks. Angewandte Chemie (International Edition), 57(51), pp. 16716-16720. (doi: 10.1002/anie.201810095) (PMID:30370977) (PMCID:PMC6391986)

Nakanishi, K., Cooper, G. J.T. , Points, L. J., Bloor, L. G., Ohba, M. and Cronin, L. (2018) Development of a minimal photosystem for hydrogen production in inorganic chemical cells. Angewandte Chemie (International Edition), 57(40), pp. 13066-13070. (doi: 10.1002/anie.201805584) (PMID:30105766) (PMCID:PMC6348376)

Chen, J.-J., Symes, M. D. and Cronin, L. (2018) Highly reduced and protonated aqueous solutions of [P2W18O62]6− for on-demand hydrogen generation and energy storage. Nature Chemistry, 10(10), pp. 1042-1047. (doi: 10.1038/s41557-018-0109-5) (PMID:30104721)

Miras, H. N. , Vilà-Nadal, L. and Cronin, L. (2018) Correction: Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 47(17), p. 6890. (doi: 10.1039/c8cs90091d) (PMID:30067251)

Caramelli, D., Henson, A. , Aragon Camarasa, G. , Sharabi, S., Keenan, G. and Cronin, L. (2018) Networking chemical robots for reaction multitasking. Nature Communications, 9, 3406. (doi: 10.1038/s41467-018-05828-8) (PMID:30143646) (PMCID:PMC6109044)

Christie, L. G. , Asche, S., Mathieson, J. S., Vila-Nadal, L. and Cronin, L. (2018) Investigating the formation of giant {Pd72}Prop and {Pd84}Gly macrocycles using NMR, HPLC and mass spectrometry. Journal of the American Chemical Society, 140(30), pp. 9379-9382. (doi: 10.1021/jacs.8b05059) (PMID:30005574)

Cronin, L. , Mehr, S.H.M. and Granda, J. (2018) Catalyst: the metaphysics of chemical reactivity. Chem, 4(8), pp. 1759-1761. (doi: 10.1016/j.chempr.2018.07.008)

Henson, A. B. , Gromski, P. S. and Cronin, L. (2018) Designing algorithms to aid discovery by chemical robots. ACS Central Science, 4(7), pp. 793-804. (doi: 10.1021/acscentsci.8b00176) (PMID:30062108) (PMCID:PMC6062836)

Granda, J. M., Donina, L., Dragone, V., Long, D.-L. and Cronin, L. (2018) Controlling an organic synthesis robot with machine learning to search for new reactivity. Nature, 559(7714), pp. 377-381. (doi: 10.1038/s41586-018-0307-8) (PMID:30022133) (PMCID:PMC6223543)

Walker, S. I. et al. (2018) Exoplanet biosignatures: future directions. Astrobiology, 18(6), pp. 779-824. (doi: 10.1089/ast.2017.1738) (PMID:29938538) (PMCID:PMC6016573)

Turk-MacLeod, R., Henson, A. , Rodriguez-Garcia, M., Gibson, G. M. , Aragon Camarasa, G. , Caramelli, D., Padgett, M. J. and Cronin, L. (2018) Approach to classify, separate, and enrich objects in groups using ensemble sorting. Proceedings of the National Academy of Sciences of the United States of America, 115(22), pp. 5681-5685. (doi: 10.1073/pnas.1721929115) (PMID:29760051) (PMCID:PMC5984510)

Georgiev, V. P. , Vila-Nadal, L. , Cronin, L. and Asenov, A. (2018) Molecular Based Flash Cell for Low Power Flash Application: Optimization and Variability Evaluation. In: IEEE 12th Nanotechnology Materials and Devices Conference (NMDC 2017), Singapore, 2-4 Oct 2017, pp. 64-65. ISBN 9781538627723 (doi: 10.1109/NMDC.2017.8350505)

Purcell, J. W., Long, D.-L. , Lee, E. C. , Cronin, L. and Miras, H. N. (2018) Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates. Dalton Transactions, 47(18), pp. 6283-6287. (doi: 10.1039/C8DT00832A) (PMID:29667663) (PMCID:PMC5944425)

Miras, H. N. , Sartzi, H., Long, D.-L. , Sproules, S. and Cronin, L. (2018) Directed self-assembly, symmetry breaking, and electronic modulation of metal oxide clusters by pyramidal heteroanions. Chemistry: A European Journal, 24(17), pp. 4399-4411. (doi: 10.1002/chem.201705711) (PMID:29315925)

Yoshida, M. , Hinkley, T., Tsuda, S., Abul-Haija, Y. , Mcburney, R. T., Kulikov, V., Mathieson, J., Galinanes Reyes, S., Castro Spencer, M. D. and Cronin, L. (2018) Using evolutionary algorithms and machine learning to explore sequence space for the discovery of antimicrobial peptides. Chem, 4(3), pp. 533-543. (doi: 10.1016/j.chempr.2018.01.005)

Martin-Sabi, M., Soriano-López, J., Winter, R. S., Chen, J.-J., Vilà-Nadal, L. , Long, D.-L. , Galán-Mascarós, J. R. and Cronin, L. (2018) Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction. Nature Catalysis, 1(3), pp. 208-213. (doi: 10.1038/s41929-018-0037-1) (PMID:30079397) (PMCID:PMC6075698)

Szymański, J. K., Abul-Haija, Y. M. and Cronin, L. (2018) Exploring strategies to bias sequence in natural and synthetic oligomers and polymers. Accounts of Chemical Research, 51(3), pp. 649-658. (doi: 10.1021/acs.accounts.7b00495) (PMID:29493212)

Ye, J. C., Chen, J. J., Yuan, R. M., Deng, D. R., Zheng, M. S., Cronin, L. and Dong, Q. F. (2018) Strategies to explore and develop reversible redox reactions of Li-S in electrode architectures using silver-polyoxometalate clusters. Journal of the American Chemical Society, 140(8), pp. 3134-3138. (doi: 10.1021/jacs.8b00411) (PMID:29425034)

Zheng, Q., Vilà-Nadal, L. , Lang, Z., Chen, J.-j., Long, D.-L. , Mathieson, J. S., Poblet, J. M. and Cronin, L. (2018) Self-sorting of heteroanions in the assembly of cross-shaped polyoxometalate clusters. Journal of the American Chemical Society, 140(7), pp. 2595-2601. (doi: 10.1021/jacs.7b11982) (PMID:29359931) (PMCID:PMC6075695)

Chen, J.-J., Ye, J.-C., Zhang, X.-G., Symes, M. D. , Fan, S.-C., Long, D.-L. , Zheng, M.-S., Wu, D.-Y., Cronin, L. and Dong, Q.-F. (2018) Design and performance of rechargeable sodium ion batteries, and symmetrical li-ion batteries with supercapacitor-like power density based upon polyoxovanadates. Advanced Energy Materials, 8(6), 1701021. (doi: 10.1002/aenm.201701021)

Kirkaldy, N. , Chisholm, G. , Chen, J.-J. and Cronin, L. (2018) A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities. Chemical Science, 9(6), pp. 1621-1626. (doi: 10.1039/C7SC05388F) (PMID:29675207) (PMCID:PMC5887965)

Points, L. J., Taylor, J. W., Grizou, J. , Donkers, K. and Cronin, L. (2018) Artificial intelligence exploration of unstable protocells leads to predictable properties and discovery of collective behavior. Proceedings of the National Academy of Sciences of the United States of America, 115(5), pp. 885-890. (doi: 10.1073/pnas.1711089115) (PMID:29339510) (PMCID:PMC5798325)

Macdonald, L., Rausch, B., Symes, M. D. and Cronin, L. (2018) Selective hydrogenation of nitroarenes using an electrogenerated polyoxometalate redox mediator. Chemical Communications, 54(9), pp. 1093-1096. (doi: 10.1039/C7CC09036F) (PMID:29333558)

Kitson, P. J., Marie, G., Francoia, J.-P., Zalesskiy, S. S., Sigerson, R. C., Mathieson, J. S. and Cronin, L. (2018) Digitization of multistep organic synthesis in reactionware for on-demand pharmaceuticals. Science, 359(6373), pp. 314-319. (doi: 10.1126/science.aao3466) (PMID:29348235)

2017

Marshall, S. M., Murray, A. R.G. and Cronin, L. (2017) A probabilistic framework for identifying biosignatures using Pathway Complexity. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 375(2109), 20160342. (doi: 10.1098/rsta.2016.0342) (PMID:29133442) (PMCID:PMC5686400)

Parrilla Gutierrez, J. M. , Tsuda, S., Grizou, J. , Taylor, J., Henson, A. and Cronin, L. (2017) Adaptive artificial evolution of droplet protocells in a 3D-printed fluidic chemorobotic platform with configurable environments. Nature Communications, 8, 1144. (doi: 10.1038/s41467-017-01161-8) (PMID:29074987) (PMCID:PMC5658334)

Symes, M. , Cogdell, R. , Macdonald, L., McGlynn, J., Irvine, N., Alshibane, I., Bloor, L., Rausch, B., Hargreaves, J. S.J. and Cronin, L. (2017) Using earth abundant materials for the catalytic evolution of hydrogen from electron-coupled proton buffers. Sustainable Energy and Fuels, 1(8), pp. 1782-1787. (doi: 10.1039/C7SE00334J)

Points, L. J., Grizou, J. , Parrilla Gutierrez, J. M. , Taylor, J. W. and Cronin, L. (2017) The Evolution of Active Droplets in Chemorobotic Platforms. In: 14th European Conference on Artificial Life (ECAL 2017), Lyon, France, 04-08 Sep 2017, pp. 356-357. ISBN 9780262346337 (doi: 10.7551/ecal_a_059)

Vilà-Nadal, L. and Cronin, L. (2017) Design and synthesis of polyoxometalate-framework materials from cluster precursors. Nature Reviews Materials, 2, 17054. (doi: 10.1038/natrevmats.2017.54)

Duros, V., Grizou, J. , Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human versus robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie (International Edition), 56(36), pp. 10815-10820. (doi: 10.1002/anie.201705721) (PMID:28649740) (PMCID:PMC5577512)

Doran, D., Rodriguez-Garcia, M., Turk-MacLeod, R., Cooper, G. J.T. and Cronin, L. (2017) A recursive microfluidic platform to explore the emergence of chemical evolution. Beilstein Journal of Organic Chemistry, 13, pp. 1702-1709. (doi: 10.3762/bjoc.13.164) (PMID:28904613) (PMCID:PMC5564272)

Taylor, J.W., Eghtesadi, S.A., Points, L.J., Liu, T. and Cronin, L. (2017) Autonomous model protocell division driven by molecular replication. Nature Communications, 8, 237. (doi: 10.1038/s41467-017-00177-4) (PMID:28798300) (PMCID:PMC5552811)

Vila-Nadal, L. and Cronin, L. (2017) Self-assembly of molecular metal oxide nanoclusters. In: Dronskowski, R., Kikkawa, S. and Stein, A. (eds.) Handbook of Solid State Chemistry. Wiley: Weinheim. ISBN 9783527325870 (doi: 10.1002/9783527691036.hsscvol4003)

Xuan, W., Pow, R., Long, D.-L. and Cronin, L. (2017) Exploring the molecular growth of two gigantic half-closed polyoxometalate clusters {Mo180} and {Mo130Ce6}. Angewandte Chemie (International Edition), 56(33), pp. 9727-9731. (doi: 10.1002/ange.201702957) (PMID:28508585) (PMCID:PMC5600119)

Zang, H.-Y., Purcell, J. W., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}. Chemical Communications, 53(61), pp. 8585-8587. (doi: 10.1039/c7cc04398h) (PMID:28718479)

Surman, A. J. , Rodriguez-Garcia, M., Abul-Haija, Y. , Cooper, G. J.T. , Donkers, K., Planchat i Barbarà, J. M., Kube, J., Mullin, M., Hezwani, M. and Cronin, L. (2017) Can a Reaction's Environment Program its Outcome, and Does it Matter? In: XVIIIth International Conference on the Origin of Life (LPI Contribution No. 1967), San Diego, CA, USA, 16-21 Jul 2017, p. 4006.

Purcell, J. W., Miras, H. , Long, D.-L. , Markopoulou, P. and Cronin, L. (2017) Tellurite-squarate driven assembly of a new family of nanoscale clusters based on (Mo2O2S2)2+. Chemistry: A European Journal, 23(40), pp. 9683-9689. (doi: 10.1002/chem.201701920) (PMID:28548217) (PMCID:PMC5575479)

Zhan, C., Busche, C. , Long, D.-L. , Molina, P. I., Winter, R. S. and Cronin, L. (2017) Encapsulation of a {Cu16} cluster containing four [Cu4O4] cubanes within an isopolyoxometalate {W44} cluster. Chemical Communications, 53(52), pp. 7076-7079. (doi: 10.1039/c7cc03544f) (PMID:28627534)

Cooper, G. J.T. , Surman, A. J. , McIver, J. , Colón-Santos, S. M., Gromski, P. S., Buchwald, S., Suárez Marina, I. and Cronin, L. (2017) Miller–Urey spark-discharge experiments in the deuterium world. Angewandte Chemie (International Edition), 56(28), pp. 8079-8082. (doi: 10.1002/anie.201610837) (PMID:28474773) (PMCID:PMC5499724)

Dragone, V., Sans, V., Henson, A. B. , Granda, J. M. and Cronin, L. (2017) An autonomous organic reaction search engine for chemical reactivity. Nature Communications, 8, 15733. (doi: 10.1038/ncomms15733) (PMID:28598440) (PMCID:PMC5472751)

Yoshida, M. , Galiñanes Reyes, S. G., Tsuda, S., Horinouchi, T., Furusawa, C. and Cronin, L. (2017) Time-programmable drug dosing allows the manipulation, suppression and reversal of antibiotic drug resistance in vitro. Nature Communications, 8, 15589. (doi: 10.1038/ncomms15589) (PMID:28593940) (PMCID:PMC5472167)

Cronin, L. (2017) Reaction: a new genesis for origins research? Chem, 2(5), pp. 601-603. (doi: 10.1016/j.chempr.2017.04.014)

Ruiz de la Oliva, A., Sans, V., Miras, H. , Long, D. L. and Cronin, L. (2017) Coding the assembly of polyoxotungstates with a programmable reaction system. Inorganic Chemistry, 56(9), pp. 5089-5095. (doi: 10.1021/acs.inorgchem.7b00206) (PMID:28414229) (PMCID:PMC5423703)

Boyd, T., Mitchell, S. G., Gabb, D., Long, D.-L. , Song, Y.-F. and Cronin, L. (2017) POMzites: a family of zeolitic polyoxometalate frameworks from a minimal building block library. Journal of the American Chemical Society, 139(16), pp. 5930-5938. (doi: 10.1021/jacs.7b01807) (PMID:28368582) (PMCID:PMC5423706)

Zhan, C. et al. (2017) A metamorphic inorganic framework that can be switched between eight single-crystalline states. Nature Communications, 8, 14185. (doi: 10.1038/ncomms14185) (PMID:28194009) (PMCID:PMC5316803)

van Eldik, R. and Cronin, L. (Eds.) (2017) Polyoxometalate Chemistry. Series: Advances in inorganic chemistry. Academic Press: Burlington. ISBN 9780128111055

Kulikov, V., Johnson, N. A.B., Surman, A. J. , Hutin, M., Kelly, S. K. , Hezwani, M., Long, D.-L. , Meyer, G. and Cronin, L. (2017) Spontaneous assembly of an organic-inorganic nucleic acid Z-DNA double-helix structure. Angewandte Chemie (International Edition), 56(4), pp. 1141-1145. (doi: 10.1002/anie.201606658) (PMID:27900812) (PMCID:PMC6057607)

Giagkoulovits, C. , Al-Rawhani, M. A., Cheah, B. C. , Martin, C., Busche, C. , Cronin, L. and Cumming, D. R.S. (2017) Hybrid Amperometric and Potentiometric Sensing Based on a CMOS ISFET Array. In: IEEE Sensors 2017, Glasgow, UK, 30 Oct - 01 Nov 2017, ISBN 9781509010127 (doi: 10.1109/ICSENS.2017.8234249)

Miras, H.N. , Long, D.-L. and Cronin, L. (2017) Exploring self-assembly and the self-organization of nanoscale inorganic polyoxometalate clusters. In: van Eldik, R. and Cronin, L. (eds.) Polyoxometalate Chemistry. Series: Advances in inorganic chemistry, 69. Academic Press: Burlington, pp. 1-28. ISBN 9780128111055 (doi: 10.1016/bs.adioch.2016.12.001)

2016

Kitson, P. J., Glatzel, S. and Cronin, L. (2016) The digital code driven autonomous synthesis of ibuprofen automated in a 3D-printer-based robot. Beilstein Journal of Organic Chemistry, 12, pp. 2776-2783. (doi: 10.3762/bjoc.12.276) (PMID:28144350) (PMCID:PMC5238580)

Christie, L. G. , Surman, A. J. , Scullion, R. A., Xu, F., Long, D.-L. and Cronin, L. (2016) Overcoming the crystallization bottleneck: a family of gigantic inorganic {Pdx}L(x=84, 72) palladium macrocycles discovered using solution techniques. Angewandte Chemie (International Edition), 55(41), pp. 12741-12745. (doi: 10.1002/anie.201606005) (PMID:27634480) (PMCID:PMC5113701)

Xuan, W., Surman, A. J. , Zheng, Q., Long, D.-L. and Cronin, L. (2016) Self-templating and in situ assembly of a cubic cluster-of-clusters architecture based on a {Mo24Fe12} inorganic macrocycle. Angewandte Chemie (International Edition), 55(41), pp. 12703-12707. (doi: 10.1002/anie.201603298) (PMID:27358195) (PMCID:PMC5396355)

Fujibayashi, M., Song, Y.-F., Cronin, L. and Tsunashima, R. (2016) Exploring the solvent mediated assembly and redox activity of a POM–organic hybrid [Na(SO3)2(PhPO3)4MoV4MoVI14O49]5−. New Journal of Chemistry, 40(10), pp. 8488-8492. (doi: 10.1039/C6NJ01774F) (PMID:30078986) (PMCID:PMC6075703)

Zhang, G., Liu, C., Long, D.-L. , Cronin, L. , Tung, C.-H. and Wang, Y. (2016) Water-soluble pentagonal-prismatic titanium-oxo clusters. Journal of the American Chemical Society, 138(35), pp. 11097-11100. (doi: 10.1021/jacs.6b06290) (PMID:27525444)

Points, L., Grizou, J. and Cronin, L. (2016) Robotic chemistry sets for the classroom. Education in Chemistry, 53(5), pp. 22-25.

Zang, H., Surman, A. , Long, D. L. , Cronin, L. and Miras, H. N. (2016) Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks. Chemical Communications, 52(58), pp. 9109-9112. (doi: 10.1039/C6CC01041E) (PMID:26982102)

Cameron, J. M., Vilà-Nadal, L. , Winter, R. S., Iijima, F., Murillo, J. C., Rodríguez-Fortea, A., Oshio, H., Poblet, J. M. and Cronin, L. (2016) Investigating the transformations of polyoxoanions using mass spectrometry and molecular dynamics. Journal of the American Chemical Society, 138(28), pp. 8765-8773. (doi: 10.1021/jacs.6b02245) (PMID:27321042)

Scharf, C. and Cronin, L. (2016) Quantifying the origins of life on a planetary scale. Proceedings of the National Academy of Sciences of the United States of America, 113(29), pp. 8127-8132. (doi: 10.1073/pnas.1523233113) (PMID:27382156) (PMCID:PMC4961144)

Porwol, L., Henson, A. , Kitson, P. J., Long, D. L. and Cronin, L. (2016) On the fly multi-modal observation of ligand synthesis and complexation of Cu complexes in flow with ‘benchtop’ NMR and mass spectrometry. Inorganic Chemistry Frontiers, 3(7), pp. 919-923. (doi: 10.1039/C6QI00079G)

Takashima, Y., Miras, H. N. , Glatzel, S. and Cronin, L. (2016) Shrink wrapping redox-active crystals of polyoxometalate open frameworks with organic polymers via crystal induced polymerisation. Chemical Communications, 52(50), pp. 7794-7797. (doi: 10.1039/C6CC03031A) (PMID:27203804) (PMCID:PMC6055993)

Cronin, L. and Walker, S. I. (2016) Beyond prebiotic chemistry. Science, 352(6290), pp. 1174-1175. (doi: 10.1126/science.aaf6310) (PMID:27257242)

Zang, H.-Y., Chen, J.-J., Long, D. L. , Cronin, L. and Miras, H. N. (2016) Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters. Chemical Science, 7(6), pp. 3798-3804. (doi: 10.1039/c5sc04944j)

Kitson, P. J., Glatzel, S., Chen, W., Lin, C.-G., Song, Y.-F. and Cronin, L. (2016) 3D printing of versatile reactionware for chemical synthesis. Nature Protocols, 11(5), pp. 920-936. (doi: 10.1038/nprot.2016.041) (PMID:27077333)

Sans Sangorrin, V. and Cronin, L. (2016) Towards dial-a-molecule by integrating continuous flow, analytics and self-optimisation. Chemical Society Reviews, 45(8), pp. 2032-2043. (doi: 10.1039/C5CS00793C) (PMID:26815081) (PMCID:PMC6057606)

Points, L. J., Cooper, G. J.T. , Dolbecq, A., Mialane, P. and Cronin, L. (2016) An all-inorganic polyoxometalate–polyoxocation chemical garden. Chemical Communications, 52(9), pp. 1911-1914. (doi: 10.1039/c5cc09536k) (PMID:26681204)

Martin-Sabi, M., Winter, R. S., Lydon, C., Cameron, J. M., Long, D.-L. and Cronin, L. (2016) Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters. Chemical Communications, 52(5), pp. 919-921. (doi: 10.1039/C5CC08486E) (PMID:26581307)

Bloor, L. G., Solarska, R., Bienkowski, K., Kulesza, P. J., Augustynski, J., Symes, M. D. and Cronin, L. (2016) Solar-driven water oxidation and decoupled hydrogen production mediated by an electron-coupled-proton buffer. Journal of the American Chemical Society, 138(21), pp. 6707-6710. (doi: 10.1021/jacs.6b03187) (PMID:27159121) (PMCID:PMC5033397)

Glatzel, S., Hezwani, M., Kitson, P. J., Gromski, P. S., Schürer, S. and Cronin, L. (2016) A portable 3D printer system for the diagnosis and treatment of multidrug-resistant bacteria. Chem, 1(3), pp. 494-504. (doi: 10.1016/j.chempr.2016.08.008)

Surman, A. J. , Robbins, P. J., Ujma, J., Zheng, Q., Barran, P. E. and Cronin, L. (2016) Sizing and discovery of nanosized polyoxometalate clusters by mass spectrometry. Journal of the American Chemical Society, 138(11), pp. 3824-3830. (doi: 10.1021/jacs.6b00070) (PMID:26906879) (PMCID:PMC5033399)

2015

Sartzi, H., Miras, H. N. , Vila-Nadal, L. , Long, D. L. and Cronin, L. (2015) Trapping the δ isomer of the polyoxometalate-based Keggin cluster with a tripodal ligand. Angewandte Chemie (International Edition), 54(51), pp. 15488-15492. (doi: 10.1002/anie.201505377) (PMID:26511859)

Anamimoghadam, O., Symes, M. D. , Long, D. L. , Sproules, S. , Cronin, L. and Bucher, G. (2015) Electronically stabilized nonplanar phenalenyl radical and its planar isomer. Journal of the American Chemical Society, 137(47), pp. 14944-14951. (doi: 10.1021/jacs.5b07959) (PMID:26526672)

Zhan, C.-H., Winter, R. S., Zheng, Q., Yan, J., Cameron, J. M., Long, D.-L. and Cronin, L. (2015) Assembly of tungsten-oxide-based pentagonal motifs in solution leads to nanoscale {W48}, {W56}, and {W92} polyoxometalate clusters. Angewandte Chemie (International Edition), 54(48), pp. 14308-14312. (doi: 10.1002/anie.201506170) (PMID:26449850)

Tsuda, S., Jaffery, H., Doran, D., Hezwani, M., Robbins, P. J., Yoshida, M. and Cronin, L. (2015) Customizable 3D printed 'Plug and Play' millifluidic devices for programmable fluidics. PLoS ONE, 10(11), e0141640. (doi: 10.1371/journal.pone.0141640) (PMID:26558389) (PMCID:PMC4641590)

Barge, L. M. et al. (2015) From chemical gardens to chemobrionics. Chemical Reviews, 115(16), pp. 8652-8703. (doi: 10.1021/acs.chemrev.5b00014) (PMID:26176351)

Chen, J.-J., Symes, M. D. , Fan, S.-C., Zheng, M.-S., Miras, H. N. , Dong, Q.-F. and Cronin, L. (2015) High performance polyoxometalate-based cathode materials for rechargeable lithium ion batteries. Advanced Materials, 27(31), pp. 4649-4654. (doi: 10.1002/adma.201501088) (PMID:26177828)

Henson, A. , Parrilla Gutierrez, J. M. , Hinkley, T., Tsuda, S. and Cronin, L. (2015) Towards heterotic computing with droplets in a fully automated droplet-maker platform. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 373(2046), 20140221. (doi: 10.1098/rsta.2014.0221) (PMID:26078348)

Parrilla Gutierrez, J. M. and Cronin, L. (2015) Embodied Evolution of Artificial Cells in a Hybrid Wet/Hard-ware Platform. In: ECAL 2015: The Thirteenth European Conference on Artificial Life, York, UK, 20-24 Jul 2015, p. 215. ISBN 9780262330275 (doi: 10.7551/978-0-262-33027-5-ch042)

Zheng, Q., Vila-Nadal, L. , Busche, C. , Mathieson, J. S., Long, D.-L. and Cronin, L. (2015) Following the reaction of heteroanions inside a {W18O56} polyoxometalate nanocage by NMR spectroscopy and mass spectrometry. Angewandte Chemie (International Edition), 127(27), pp. 8006-8010. (doi: 10.1002/ange.201502295)

Zhang, B., Pradeep, C. P., Cronin, L. and Liu, T. (2015) Self-assembly of triangular polyoxometalate–organic hybrid macroions in mixed solvents. Chemical Communications, 51(41), pp. 8630-8633. (doi: 10.1039/C5CC02003D) (PMID:25900154)

MacDonell, A., JOHNSON, N. A.B., Surman, A. J. and Cronin, L. (2015) Configurable nanosized metal oxide oligomers via precise “click” coupling control of hybrid polyoxometalates. Journal of the American Chemical Society, 137(17), pp. 5662-5665. (doi: 10.1021/jacs.5b02466) (PMID:25846763)

Nakamura, I., Miras, H. N. , Fujiwara, A., Fujibayashi, M., Song, Y.-F., Cronin, L. and Tsunashima, R. (2015) Investigating the formation of 'Molybdenum Blues' with gel electrophoresis and mass spectrometry. Journal of the American Chemical Society, 137(20), pp. 6524-6530. (doi: 10.1021/ja512758j) (PMID:25897816)

Wu, B., Li, S., Lei, Y., Hu, H., de Sousa Amadeu, N., Janiak, C., Mathieson, J. S., Long, D.-L. , Cronin, L. and Yang, X.-J. (2015) The effect of the spacer of Bis(biurea) ligands on the structure of A2L3-type (A=anion) phosphate complexes. Chemistry: A European Journal, 21(6), pp. 2588-2593. (doi: 10.1002/chem.201405235) (PMID:25504744)

Georgiev, V. P. , Amoroso, S. M., Ali, T. M., Vila-Nadal, L. , Busche, C. , Cronin, L. and Asenov, A. (2015) Comparison between bulk and FDSOI POM flash cell: a multiscale simulation study. IEEE Transactions on Electron Devices, 62(2), pp. 680-684. (doi: 10.1109/TED.2014.2378378)

Lee, M. P., Cooper, G. J.T. , Hinkley, T., Gibson, G. M. , Padgett, M. J. and Cronin, L. (2015) Development of a 3D printer using scanning projection stereolithography. Scientific Reports, 5, 9875. (doi: 10.1038/srep09875) (PMID:25906401) (PMCID:PMC4407727)

Rodriguez-Garcia, M., Surman, A. J. , Cooper, G. J.T. , Suarez Marina, I., Hosni, Z., Lee, M. P. and Cronin, L. (2015) Formation of oligopeptides in high yield under simple programmable conditions. Nature Communications, 6, 8385. (doi: 10.1038/ncomms9385) (PMID:26442968) (PMCID:PMC4633627)

Sans Sangorrin, V., Porwol, L., Dragone, V. and Cronin, L. (2015) A self optimizing synthetic organic reactor system using real-time in-line NMR spectroscopy. Chemical Science, 6(2), pp. 1258-1264. (doi: 10.1039/C4SC03075C)

Winter, R. S., Long, D.-L. and Cronin, L. (2015) Synthesis and characterization of a series of [M2(β-SiW8O31)2]n− clusters and mechanistic insight into the reorganization of {β-SiW8O31} into {α-SiW9O34}. Inorganic Chemistry, 54(8), pp. 4151-4155. (doi: 10.1021/acs.inorgchem.5b00405)

2014

Parrilla Gutierrez, J. M. , Hinkley, T., Taylor, J. W. and Cronin, L. (2014) Evolution of oil droplets in a chemorobotic platform. Nature Communications, 5, 5571. (doi: 10.1038/ncomms6571) (PMID:25482304) (PMCID:PMC4268700)

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi: 10.1038/nature13951) (PMID:25409147)

Kitson, P. J., Marshall, R. J., Long, D. , Forgan, R. S. and Cronin, L. (2014) 3D printed high-throughput hydrothermal reactionware for discovery, optimization, and scale-up. Angewandte Chemie (International Edition), 53(47), pp. 12723-12728. (doi: 10.1002/anie.201402654)

Xuan, W., Surman, A. J. , Miras, H. N., Long, D. L. and Cronin, L. (2014) Controlling the ring curvature, solution assembly, and reactivity of gigantic molybdenum blue wheels. Journal of the American Chemical Society, 136(40), pp. 14114-14120. (doi: 10.1021/ja5062483)

Zhan, C., Cameron, J. M., Gao, J., Purcell, J. W., Long, D. L. and Cronin, L. (2014) Time-resolved assembly of cluster-in-cluster {Ag12}-in-{W76} polyoxometalates under supramolecular control. Angewandte Chemie (International Edition), 53(39), pp. 10362-10366. (doi: 10.1002/anie.201402932) (PMID:25087861)

Scullion, R. A., Surman, A. J. , Xu, F., Mathieson, J. S., Long, D. L. , Haso, F., Liu, T. and Cronin, L. (2014) Exploring the symmetry, structure, and self-assembly mechanism of a gigantic seven-fold symmetric {Pd84} wheel. Angewandte Chemie (International Edition), 53(38), pp. 10032-10037. (doi: 10.1002/anie.201404621) (PMID:25044792)

Rausch, B., Symes, M. D. , Chisholm, G. and Cronin, L. (2014) Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting. Science, 345(6202), pp. 1326-1330. (doi: 10.1126/science.1257443)

Winter, R. S., Cameron, J. M. and Cronin, L. (2014) Controlling the minimal self assembly of "complex" polyoxometalate clusters. Journal of the American Chemical Society, 136(36), pp. 12753-12761. (doi: 10.1021/ja5067916)

Miras, H. N. , Vilà-Nadal, L. and Cronin, L. (2014) Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 43(16), pp. 5679-5699. (doi: 10.1039/c4cs00097h) (PMID:25005364)

Bagchi, V. et al. (2014) A versatile tripodal Cu(I) reagent for C–N bond construction via nitrene-transfer chemistry: catalytic perspectives and mechanistic insights on C–H aminations/amidinations and olefin aziridinations. Journal of the American Chemical Society, 136(32), pp. 11362-11381. (doi: 10.1021/ja503869j)

Lin, C.-G., Chen, W., Long, D. L. , Cronin, L. and Song, Y.-F. (2014) Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates. Dalton Transactions, 43(23), pp. 8587-8590. (doi: 10.1039/c4dt00033a) (PMID:24695647)

Kitson, P. J., Macdonell, A., Tsuda, S., Zang, H., Long, D.-L. and Cronin, L. (2014) Bringing crystal structures to reality by three-dimensional printing. Crystal Growth and Design, 14(6), pp. 2720-2724. (doi: 10.1021/cg5003012)

Georgiev, V. P. , Markov, S., Vila-Nadal, L. , Busche, C. , Cronin, L. and Asenov, A. (2014) Optimization and evaluation of variability in the programming window of a flash cell with molecular metal-oxide storage. IEEE Transactions on Electron Devices, 61(6), pp. 2019-2026. (doi: 10.1109/TED.2014.2315520)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2014) Assembly and core transformation properties of two tetrahedral clusters:([FeIII13P8W60O227(OH)15(H2O)2]30− and [FeIII13P8W60O224(OH)12(PO4)4]33−. Dalton Transactions, 43(13), pp. 5190-5199. (doi: 10.1039/c3dt53382d)

Yvon, C., Surman, A. J. , Hutin, M., Alex, J., Smith, B. O. , Long, D. L. and Cronin, L. (2014) Polyoxometalate clusters integrated into peptide chains and as inorganic amino acids: solution- and solid-phase approaches. Angewandte Chemie (International Edition), 53(13), pp. 3336-3341. (doi: 10.1002/anie.201311135)

Takashima, Y., Long, D.-L. and Cronin, L. (2014) Towards imaging electron density inside metal–organic framework structures. Chemical Communications, 50(18), pp. 2271-2274. (doi: 10.1039/c3cc48586b)

Cereda, A., Hitchcock, A., Symes, M. D. , Cronin, L. , Bibby, T. S. and Jones, A. K. (2014) A bioelectrochemical approach to characterize extracellular electron transfer by Synechocystis sp. PCC6803. PLoS ONE, 9(3), e91484. (doi: 10.1371/journal.pone.0091484) (PMID:24637387) (PMCID:PMC3956611)

Cameron, J. M., Gao, J., Vila-Nadal, L. , Long, D.-L. and Cronin, L. (2014) Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles. Chemical Communications, 50(17), pp. 2155-2157. (doi: 10.1039/C3CC49293A)

Cameron, J. M., Gao, J., Long, D. L. and Cronin, L. (2014) Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates. Inorganic Chemistry Frontiers, 1(2), pp. 178-185. (doi: 10.1039/c3qi00075c)

Bloor, L.G., Molina-Sanchez, P.I., Symes, M. and Cronin, L. (2014) Low pH electrolytic water splitting using earth abundant metastable catalysts that self-assemble in situ. Journal of the American Chemical Society, 136(8), pp. 3304-3311. (doi: 10.1021/ja5003197)

Chisholm, G. , Kitson, P. J., Kirkaldy, N. D., Bloor, L. G. and Cronin, L. (2014) 3D printed flow plates for the electrolysis of water: an economic and adaptable approach to device manufacture. Energy and Environmental Science, 7(9), pp. 3026-3032. (doi: 10.1039/C4EE01426J)

Georgiev, V. P. , Amoroso, S. M., Vila-Nadal, L. , Busche, C. , Cronin, L. and Asenov, A. (2014) FDSOI Molecular Flash Cell with Reduced Variability for Low Power Flash Applications. In: 44th European Solid-State Device Research Conference (ESSDERC), Venice, Italy, 22-26 Sep 2014, pp. 353-356. ISBN 9781479943760 (doi: 10.1109/ESSDERC.2014.6948833)

Mathieson, J. S., Cooper, G. J.T. , Symes, M. and Cronin, L. (2014) Quantification of ion binding using electrospray mass spectrometry. Inorganic Chemistry Frontiers, 1, pp. 49-52. (doi: 10.1039/C3QI00037K)

Sans, V., Glatzel, S., Douglas, F. J., MacLaren, D. A. , Lapkin, A. and Cronin, L. (2014) Non-equilibrium dynamic control of gold nanoparticle and hyper-branched nanogold assemblies. Chemical Science, 5(3), pp. 1153-1157. (doi: 10.1039/C3SC53223B)

Zang, H.-Y., Ruiz de la Oliva, A., Miras, H. N. , Long, D.-L. , McBurney, R. T. and Cronin, L. (2014) Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine. Nature Communications, 5, pp. 1-8. (doi: 10.1038/ncomms4715)

2013

Vilà-Nadal, L. , Mitchell, S. G., Markov, S., Busche, C. , Georgiev, V. , Asenov, A. and Cronin, L. (2013) Towards polyoxometalate-cluster-based nano-electronics. Chemistry: A European Journal, 19(49), pp. 16502-16511. (doi: 10.1002/chem.201301631)

Zang, H., Chen, J.-J., Long, D.-L. , Cronin, L. and Miras, H. N. (2013) Assembly of thiometalate-based [Mo16] and [Mo36] composite clusters combining [Mo2O2S2],2+ cations and selenite anions. Advanced Materials, 25(43), pp. 6245-6249. (doi: 10.1002/adma.201302565)

Yvon, C., Macdonell, A., Buchwald, S., Surman, A. , Follet, N., Alex, J., Long, D.L. and Cronin, L. (2013) A collection of robust methodologies for the preparation of asymmetric hybrid Mn–Anderson polyoxometalates for multifunctional materials. Chemical Science, 4(10), pp. 3810-3817. (doi: 10.1039/C3SC51618K)

Chen, W., Ma, D., Yan, J., Boyd, T., Cronin, L. , Long, D.-L. and Song, Y.-F. (2013) 0D to 1D switching of hybrid polyoxometalate assemblies at the nanoscale by using molecular control. ChemPlusChem, 78(10), pp. 1226-1229. (doi: 10.1002/cplu.201300244)

Long, D.L. , Yan, J., Ruiz De La Oliva, A., Busche, C. , Miras, H.N. , Errington, R.J. and Cronin, L. (2013) A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage. Chemical Communications, 49(84), pp. 9731-9733. (doi: 10.1039/c3cc45659e)

Yin, P., Li, T., Forgan, R.S. , Lydon, C., Zuo, X., Zheng, Z.N., Lee, B., Long, D. , Cronin, L. and Liu, T. (2013) Exploring the programmable assembly of a polyoxometalate− organic hybrid via metal ion coordination. Journal of the American Chemical Society, 135(36), pp. 13425-13432. (doi: 10.1021/ja404777g)

Vilà-Nadal, L. , Peuntinger, K., Busche, C. , Yan, J., Lüders, D., Long, D. , Poblet, J.M., Guldi, D.M. and Cronin, L. (2013) Polyoxometalate {W18O56XO6} clusters with embedded redox-active main-group templates as localized inner-cluster radicals. Angewandte Chemie (International Edition), 52(37), pp. 9695-9699. (doi: 10.1002/anie.201303126)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) Exploring time assembly of supramolecular polyoxometalate triangular morphologies with johnson solid cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19−. Inorganic Chemistry, 52(16), pp. 9284-9289. (doi: 10.1021/ic400542x)

Cogdell, R.J. , Gardiner, A.T., Molina-Sanchez, P.I. and Cronin, L. (2013) The use and misuse of photosynthesis in the quest for novel methods to harness solar energy to make fuel. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 371(1996), p. 20110603. (doi: 10.1098/rsta.2011.0603)

Symes, M.D. , Cogdell, R.J. and Cronin, L. (2013) Designing artificial photosynthetic devices using hybrid organic-inorganic modules based on polyoxometalates. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 371(1996), p. 20110411. (doi: 10.1098/rsta.2011.0411)

Kitson, P. J., Symes, M. D. , Dragone, V. and Cronin, L. (2013) Combining 3D printing and liquid handling to produce user-friendly reactionware for chemical synthesis and purification. Chemical Science, 4(8), pp. 3099-3103. (doi: 10.1039/C3SC51253C)

Kato, C., Nishihara, S., Tsunashima, R., Tatewaki, Y., Okada, S., Ren, X.M., Inoue, K., Long, D. and Cronin, L. (2013) Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents. Dalton Transactions, 42, pp. 11363-11366. (doi: 10.1039/c3dt51120k)

Rosnes, M. H., Musumeci, C., Yvon, C., MacDonell, A., Pradeep, C. P., Sartorio, C., Long, D.-L. , Pignataro, B. and Cronin, L. (2013) Exploring the interplay between ligand derivatisation and cation type in the assembly of hybrid polyoxometalate Mn-Andersons. Small, 9(13), pp. 2316-2324. (doi: 10.1002/smll.201202510)

Zang, H.-Y., Miras, H. N. , Long, D. L. , Rausch, B. and Cronin, L. (2013) Template-directed assembly of polyoxothiometalate scaffolds into nanomolecular architectures. Angewandte Chemie (International Edition), 52(27), pp. 6903-6906. (doi: 10.1002/anie.201300578)

Anamimoghadam, O., Symes, M. D. , Busche, C. , Long, D.-L. , Caldwell, S. T. , Flors, C., Nonell, S., Cronin, L. and Bucher, G. (2013) Naphthoxanthenyl, a new stable phenalenyl type radical stabilized by electronic effects. Organic Letters, 15(12), pp. 2970-2973. (doi: 10.1021/ol401117g)

Dragone, V., Sans, V., Rosnes, M. H., Kitson, P. J. and Cronin, L. (2013) 3D-printed devices for continuous-flow organic chemistry. Beilstein Journal of Organic Chemistry, 9, pp. 951-959. (doi: 10.3762/bjoc.9.109) (PMID:23766811) (PMCID:PMC3678713)

Mathieson, J. S., Rosnes, M. H., Sans, V., Kitson, P. J. and Cronin, L. (2013) Continuous parallel ESI-MS analysis of reactions carried out in a bespoke 3D printed device. Beilstein Journal of Nanotechnology, 4, pp. 285-291. (doi: 10.3762/bjnano.4.31) (PMID:23766951) (PMCID:PMC3678396)

Miras, H. N. , Chilas, G. I., Cronin, L. and Kabanos, T. A. (2013) Sulfite anions as structure-directing templates for the engineering of modular polyoxometalates. European Journal of Inorganic Chemistry, 2013(10-11), pp. 1620-1630. (doi: 10.1002/ejic.201201065)

Gabb, D., Pradeep, C. P., Boyd, T., Mitchell, S. G., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) A general route for the transfer of large, highly-charged polyoxometalates from aqueous to organic phase. Polyhedron, 52, pp. 159-164. (doi: 10.1016/j.poly.2012.10.015)

Winter, R.S., Yan, J., Busche, C. , Mathieson, J.S., Prescimone, A., Brechin, E.K., Long, D.L. and Cronin, L. (2013) Nanoscale control of polyoxometalate assembly: a {Mn8W4} cluster within a {W36Si4Mn10} cluster showing a new type of isomerism. Chemistry: A European Journal, 19(9), pp. 2976-2981. (doi: 10.1002/chem.201204345)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2013) One-pot versus sequential reactions in the self-assembly of gigantic nanoscale polyoxotungstates. Journal of the American Chemical Society, 135(5), pp. 1796-1805. (doi: 10.1021/ja309237x)

Cameron, J., Newton, G.N., Busche, C. , Long, D.L. , Oshio, H. and Cronin, L. (2013) Synthesis and characterisation of a lanthanide-capped dodecavanadate cage. Chemical Communications, 49, pp. 3395-3397. (doi: 10.1039/c3cc40912k)

Georgiev, V. P. , Markov, S., Vilà-Nadal, L. , Asenov, A. and Cronin, L. (2013) Molecular-Metal-Oxide-nanoelectronicS (M-MOS): Achieving the Molecular Limit. In: 16th International Workshop on Computational Electronics, Nara, Japan, 4-7 June 2013, ISBN 9783901578267

Georgiev, V. P. , Markov, S., Vila-Nadal, L. , Busche, C., Cronin, L. and Asenov, A. (2013) Multi-scale computational framework for the evaluation of variability in the programing window of a flash cell with molecular storage. In: 2013 Proceedings of the European Solid-State Device Research Conference (ESSDERC), Bucharest, Romania, 16-20 Sep 2013, pp. 230-233. (doi: 10.1109/ESSDERC.2013.6818861)

Hutin, M., Yan, J., Yvon, C., MacDonell, A., Long, D.L. and Cronin, L. (2013) Programming the assembly of carboxylic acid-functionalised hybrid polyoxometalates. CrystEngComm, 15(22), pp. 4422-4430. (doi: 10.1039/c3ce26816k)

Rausch, B., Symes, M.D. and Cronin, L. (2013) A bio-inspired, small molecule electron-coupled-proton buffer for decoupling the half-reactions of electrolytic water splitting. Journal of the American Chemical Society, 135(37), pp. 13656-13659. (doi: 10.1021/ja4071893)

Robbins, P.J., Surman, A.J. , Thiel, J., Long, D.L. and Cronin, L. (2013) Use of ion-mobility mass spectrometry (IMS-MS) to map polyoxometalate keplerate clusters and their supramolecular assemblies. Chemical Communications, 49, pp. 1909-1911. (doi: 10.1039/c3cc38615e)

2012

Corella-Ochoa, M.N., Miras, N., Long, D.L. and Cronin, L. (2012) Controlling the self-assembly of a mixed-metal Mo/V-selenite family of polyoxometalates. Chemistry: A European Journal, 18(43), pp. 13743-13754. (doi: 10.1002/chem.201200912)

Xu, F., Miras, H.N. , Scullion, R.A., Long, D.L. , Thiel, J. and Cronin, L. (2012) Correlating the magic numbers of inorganic nanomolecular assemblies with a {Pd84} molecular-ring Rosetta Stone. Proceedings of the National Academy of Sciences of the United States of America, 109(29), pp. 11609-11612. (doi: 10.1073/pnas.1202981109)

Boulay, A. G., Cooper, G. J.T. and Cronin, L. (2012) Morphogenesis of polyoxometalate cluster-based materials to microtubular network architectures. Chemical Communications, 48(42), pp. 5088-5090. (doi: 10.1039/c2cc31194a) (PMID:22513869)

Nemeth, B., Busche, C. , Tsuda, S., Cronin, L. and Cumming, D. R.S. (2012) Imaging the Belousov–Zhabotinsky reaction in real time using an ion sensitive array. Chemical Communications, 48(42), pp. 5085-5087. (doi: 10.1039/C2CC30811H) (PMID:22517276)

Symes, M.D. and Cronin, L. (2012) Patterned metal oxide films for solar energy. Nano Energy, 1(3), pp. 340-341. (doi: 10.1016/j.nanoen.2012.02.002)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2012) Assembly of molecular "layered" heteropolyoxometalate architectures. Angewandte Chemie (International Edition), 51(14), pp. 3373-3376. (doi: 10.1002/anie.201108428)

Miras, H. and Cronin, L. (2012) Electrospray and cryospray mass spectrometry: from serendipity to designed synthesis of supramolecular coordination and polyoxometalate clusters. In: Pignataro, B. (ed.) New Strategies in Chemical Synthesis and Catalysis. Wiley-VCH Verlag: Weinheim, pp. 3-32. ISBN 9783527330904

Nemeth, B., Symes, M. D. , Boulay, A. G., Busche, C. , Cooper, G. J. T. , Cumming, D. R. S. and Cronin, L. (2012) Real-time ion-flux imaging in the growth of micrometer-scale structures and membranes. Advanced Materials, 24(9), pp. 1238-1242. (doi: 10.1002/adma.201104345)

Lydon, C., Busche, C. , Miras, H.N. , Delf, A., Long, D.-L. , Yellowlees, L. and Cronin, L. (2012) Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates. Angewandte Chemie (International Edition), 51(9), pp. 2115-2118. (doi: 10.1002/anie.201105829)

Nemeth, B., Tsuda, S., Busche, C. , Cronin, L. and Cumming, D.R.S. (2012) An ISFET sensor system for real-time detection of extracellular pH oscillations in slime mould. Electronics Letters, 48(3), pp. 144-146. (doi: 10.1049/el.2011.3951)

Quesada Cabrera, R., Firth, S., Blackman, C.S., Long, D.L. , Cronin, L. and McMillan, P.F. (2012) Spectroscopic studies of sulfite-based polyoxometalates at high temperature and high pressure. Journal of Solid State Chemistry, 186, pp. 171-176. (doi: 10.1016/j.jssc.2011.12.005)

Cogdell, R.J. , Gardiner, A.T. and Cronin, L. (2012) Learning from photosynthesis: how to use solar energy to make fuels. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 370(1972), pp. 3819-3826. (doi: 10.1098/rsta.2011.0422)

Cooper, G.J.T. , Bowman, R.W., Magennis, E.P., Fernandez-Trillo, F., Alexander, C., Padgett, M.J. and Cronin, L. (2012) Directed assembly of inorganic polyoxometalate-based micrometer-scale tubular architectures by using optical control. Angewandte Chemie (International Edition), 51(51), pp. 12754-12758. (doi: 10.1002/anie.201204405)

de la Oliva, A.R., Sans Sangorrin, V., Miras, H.N. , Yan, J., Zang, H., Richmond, C.J., Long, D.L. and Cronin, L. (2012) Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system. Angewandte Chemie (International Edition), 51(51), pp. 12759-12762. (doi: 10.1002/anie.201206572)

Fielden, J., Long, D.-L. , Speldrich, M., Kögerler, P. and Cronin, L. (2012) [CoxCu1−x(DDOP)(OH2)(NO3)](NO3): hydrogen bond-driven distortion of cobalt(II) by solid solution ‘network mismatch’. Dalton Transactions, 41(16), pp. 4927-4934. (doi: 10.1039/c2dt11055e)

Gabb, D., Pradeep, C.P., Miras, H.N. , Mitchell, S.G., Long, D.L. and Cronin, L. (2012) Organic-soluble lacunary {M-2(P2W15)(2)} polyoxometalate sandwiches showing a previously unseen alpha beta beta alpha isomerism. Dalton Transactions, 41(33), pp. 10000-10005. (doi: 10.1039/C2DT30616F)

Kitson, P. J., Rosnes, M. H., Sans, V., Dragone, V. and Cronin, L. (2012) Configurable 3D-printed millifluidic and microfluidic ‘lab on a chip’ reactionware devices. Lab on a Chip, 12(18), pp. 3267-3271. (doi: 10.1039/C2LC40761B) (PMID:22875258)

Li, F., Long, D.L. , Cameron, J.M., Miras, H.N. , Pradeep, C., Xu, L. and Cronin, L. (2012) Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV). Dalton Transactions, 41(33), pp. 9859-9862. (doi: 10.1039/C2DT30627A)

Long, D.L. and Cronin, L. (2012) Pushing the frontiers in polyoxometalate and metal oxide cluster science. Dalton Transactions, 41(33), pp. 9815-9816. (doi: 10.1039/c2dt90121h)

Lydon, C., Sabi, M.M., Symes, M.D. , Long, D.L. , Murrie, M. , Yoshii, S., Nojiri, H. and Cronin, L. (2012) Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates. Chemical Communications, 48(79), pp. 9819-9821. (doi: 10.1039/c2cc34865a)

McGlone, T., Thiel, J., Streb, C., Long, D.L. and Cronin, L. (2012) An unprecedented silver-decavanadate dimer investigated using ion-mobility mass spectrometry. Chemical Communications, 48(3), pp. 359-361. (doi: 10.1039/c1cc15879a)

Miras, H.N. , Richmond, C.J., Long, D.-L. and Cronin, L. (2012) Solution-phase monitoring of the structural evolution of a molybdenum blue nanoring. Journal of the American Chemical Society, 134(8), pp. 3816-3824. (doi: 10.1021/ja210206z)

Miras, H.N. , Sorus, M., Hawkett, J., Sells, D.O., McInnes, E.L. and Cronin, L. (2012) Oscillatory template exchange in polyoxometalate capsules: a ligand-triggered, redox-powered, chemically damped oscillation. Journal of the American Chemical Society, 134(16), pp. 6980-6983. (doi: 10.1021/ja302861z)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Engineering polyoxometalates with emergent properties. Chemical Society Reviews, 41(22), pp. 7403-7430. (doi: 10.1039/C2CS35190K)

Richmond, C.J. et al. (2012) A flow-system array for the discovery and scale up of inorganic clusters. Nature Chemistry, 4(12), pp. 1038-1044. (doi: 10.1038/nchem.1489)

Rosnes, M.H., Yvon, C., Long, D.L. and Cronin, L. (2012) Mapping the synthesis of low nuclearity polyoxometalates from octamolybdates to Mn-Anderson clusters. Dalton Transactions, 41, pp. 10071-10079. (doi: 10.1039/c2dt31008b)

Symes, M.D. , Kitson, P.J., Yan, J., Richmond, C., Cooper, G.J.T. , Bowman, R.W., Vilbrandt, T. and Cronin, L. (2012) Integrated 3D-printed reactionware for chemical synthesis and analysis. Nature Chemistry, 4, pp. 349-354. (doi: 10.1038/nchem.1313)

Symes, M.D., Kitson, P.J., Yan, J., Richmond, C.J., Cooper, G.J.T., Bowman, R.W., Vilbrandt, T. and Cronin, L. (2012) Integrated 3D-printed reactionware for chemical synthesis and analysis. Nature Chemistry, 4, pp. 349-354. (doi: 10.1038/nchem.1313)

Symes, M. D. and Cronin, L. (2012) Materials for water splitting. In: Letcher, T. M. and Scott, J. L. (eds.) Materials for a Sustainable Future. Royal Society of Chemistry: Cambridge, pp. 592-616. ISBN 9781849734073

Thiel, J., Molina-Sanchez, P.I., Symes, M.D. and Cronin, L. (2012) Insights into the self-assembly mechanism of the modular polyoxometalate "Keggin-Net" family of framework materials and their electronic properties. Crystal Growth and Design, 12(2), pp. 902-908. (doi: 10.1021/cg201342z)

Vilá-Nadal, L. , Mitchell, S.G., Long, D.L. , Rodríguez-Fortea, A., López, X., Poblet, J.M. and Cronin, L. (2012) Exploring the rotational isomerism in non-classical Wells–Dawson anions {W18X}:: a combined theoretical and mass spectrometry study. Dalton Transactions, 41(8), pp. 2264-2271. (doi: 10.1039/c2dt11919f)

Zang, H., Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Assembly and autochirogenesis of a chiral inorganic polythioanion Mobius strip via symmetry breaking. Journal of the American Chemical Society, 134(28), pp. 11376-11379. (doi: 10.1021/ja304371j)

2011

Miras, H.N. , Zang, H.Y., Long, D.L. and Cronin, L. (2011) Direct synthesis and mass spectroscopic observation of the {M40} polyoxothiometalate wheel. European Journal of Inorganic Chemistry, 2011(33), pp. 5105-5111. (doi: 10.1002/ejic.201100833)

Cooper, G.J.T. , Kitson, P.J., Winter, R., Zagnoni, M., Long, D.L. and Cronin, L. (2011) Modular redox-active inorganic chemical cells: iCHELLs. Angewandte Chemie (International Edition), 50(44), pp. 10373-10376. (doi: 10.1002/anie.201105068)

Boyd, T., Mitchell, S.G., Gabb, D., Long, D.L. and Cronin, L. (2011) Investigating cation binding in the polyoxometalate-super-crown [P8W48O184]40−. Chemistry: A European Journal, 17(43), pp. 12010-12014. (doi: 10.1002/chem.201101666)

Prat, I., Mathieson, J.S., Güell, M., Ribas, X., Luis, J.M., Cronin, L. and Costas, M. (2011) Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions. Nature Chemistry, 3(10), pp. 788-793. (doi: 10.1038/NCHEM.1132)

Mitchell, S. G. et al. (2011) A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands. Angewandte Chemie (International Edition), 50(39), pp. 9154-9157. (doi: 10.1002/anie.201102727)

Corella-Ochoa, M.N., Miras, H.N. , Kidd, A., Long, D.L. and Cronin, L. (2011) Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}. Chemical Communications, 47(31), pp. 8799-8801. (doi: 10.1002/chin.201143020)

Misdrahi, M.F., Wang, M.H., Pradeep, C.P., Li, F.Y., Lydon, C., Xu, L., Cronin, L. and Liu, T.B. (2011) Amphiphilic properties of dumbbell-shaped inorganic–organic–inorganic molecular hybrid materials in solution and at an interface. Langmuir, 27(15), pp. 9193-9202. (doi: 10.1021/la2013914)

Akutagawa, T., Kudo, F., Tsunashima, R., Noro, S., Cronin, L. and Nakamura, T. (2011) Hydrogen-bonded assemblies of two-electron reduced mixed-valence [XMo12O40] (X = P and Si) with p-phenylenediamines. Inorganic Chemistry, 50(14), pp. 6711-6718. (doi: 10.1021/ic200683e)

Song, Y.-F., Long, D.-L. , Ritchie, C. and Cronin, L. (2011) Nanoscale polyoxometalate-based inorganic/organic hybrids. Chemical Record, 11(3), pp. 158-171. (doi: 10.1002/tcr.201100002) (PMID:21594969)

Wilson, E.F., Miras, H.N. , Rosnes, M.H. and Cronin, L. (2011) Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry. Angewandte Chemie (International Edition), 50(16), pp. 3720-3724. (doi: 10.1002/anie.201006938)

Cronin, L. (2011) Defining new architectural design principles with 'living' inorganic materials. Architectural Design, 81(2), pp. 34-43. (doi: 10.1002/ad.1210)

Walsh, J.J., Long, D.L. , Cronin, L. , Bond, A.M., Forster, R.J. and Keyes, T.E. (2011) Electronic and photophysical properties of adducts of [Ru(bpy)3]2+ and Dawson-type sulfite polyoxomolybdates α/β-[Mo18O54(SO3)2]4−. Dalton Transactions, 40(9), pp. 2038-2045. (doi: 10.1039/C0DT01540G)

Mitchell, S.G., Boyd, T., Miras, H.N. , Long, D.L. and Cronin, L. (2011) Extended polyoxometalate framework solids: two MnII-linked {P8W48} network arrays. Inorganic Chemistry, 50(1), pp. 136-143. (doi: 10.1021/ic101472s)

Cooper, G.T.J. , Boulay, A.G., Kitson, P.J., Ritchie, C., Richmond, C.J., Thiel, J., Gabb, D., Eadie, R., Long, D.L. and Cronin, L. (2011) Osmotically driven crystal morphogenesis: a general approach to the fabrication of micrometer-scale tubular architectures based on polyoxometalates. Journal of the American Chemical Society, 133(15), pp. 5947-5954. (doi: 10.1021/ja111011j)

Cronin, L. , Kitson, P. and Wilson, C.C. (2011) Process understanding – crystallization. In: Houson, I. (ed.) Process Understanding for Scale-up and Manufacture of Active Ingredients. Wiley. ISBN 9783527637140

Cronin, L. , Molina, P.I. and Miras, H.N. (2011) Polyoxometalate-based solar cells for water splitting. Proceedings of the SPIE: The International Society for Optical Engineering, 8109, 81090C. (doi: 10.1117/12.895296)

Gao, J., Yan, J., Mitchell, S.G., Miras, H.N. , Boulay, A.G., Long, D.L. and Cronin, L. (2011) Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties. Chemical Science, 2(8), pp. 1502-1508. (doi: 10.1039/C1SC00150G)

Hutin, M., Long, D.L. and Cronin, L. (2011) Controlling the molecular assembly of polyoxometalates from the nano to the micron scale: molecules to materials. Israel Journal of Chemistry, 51(2), pp. 205-214. (doi: 10.1002/ijch.201100008)

McGlone, T., Streb, C., Busquets-Fite, M., Yan, J., Gabb, D., Long, D.L. and Cronin, L. (2011) Silver linked polyoxometalate open frameworks (Ag-POMOFs) for the directed fabrication of silver nanomaterials. Crystal Growth and Design, 11(6), pp. 2471-2478. (doi: 10.1021/cg2002496)

Miras, H.N. , Stone, D., Long, D.L. , McInnes, E.J.L., Kögerler, P. and Cronin, L. (2011) Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorganic Chemistry, 50(17), pp. 8384-8391. (doi: 10.1021/ic200943s)

Musumeci, C., Luzio, A., Pradeep, C.P., Miras, H.N. , Rosnes, M.H., Song, Y.-F., Long, D.L. , Cronin, L. and Pignataro, B. (2011) Programmable surface architectures derived from hybrid polyoxometalate-based clusters. Journal of Physical Chemistry C, 115(11), pp. 4446-4455. (doi: 10.1021/jp109916e)

Musumeci, C., Rosnes, M.H., Giannazzo, F., Symes, M.D. , Cronin, L. and Pignataro, B. (2011) Smart high-κ nanodielectrics using solid supported polyoxometalate-rich nanostructures. ACS Nano, 5(12), pp. 9992-9999. (doi: 10.1021/nn2037797)

Pradeep, C.P., Li, F.-Y., Lydon, C., Miras, H.N. , Long, D.L. , Xu, L. and Cronin, L. (2011) Design and synthesis of "dumb-bell" and "triangular" inorganic-organic hybrid nanopolyoxometalate clusters and their characterisation through ESI-MS analyses. Chemistry: A European Journal, 17(27), pp. 7472-7479. (doi: 10.1002/chem.201100257)

Symes, M.D. and Cronin, L. (2011) The crystal computer - computing with inorganic cellular frameworks and nets. International Journal of Nanotechnology and Molecular Computation, 3(1), pp. 24-34. (doi: 10.4018/jnmc.2011010103)

Thiel, J., Yang, D., Rosnes, M.H., Liu, X., Yvon, C., Kelly, S.E., Song, Y.F., Long, D.L. and Cronin, L. (2011) Observing the hierarchical self-assembly and architectural bistability of hybrid molecular metal oxides using ion-mobility mass spectrometry. Angewandte Chemie (International Edition), 50(38), pp. 8871-8875. (doi: 10.1002/anie.201102340)

Vila-Nadal, L. , Wilson, E.F., Miras, H.N. , Rodriguez-Fortea, A., Cronin, L. and Poblet, J.M. (2011) Combined theoretical and mass spectrometry study of the formation-fragmentation of small polyoxomolybdates. Inorganic Chemistry, 50(16), pp. 7811-7819. (doi: 10.1021/ic200969h)

Vilà-Nadal, L. , Mitchell, S.G., Rodríguez-Fortea, A., Miras, H.N. , Cronin, L. and Poblet, J.M. (2011) Connecting theory with experiment to understand the initial nucleation steps of heteropolyoxometalate clusters. Physical Chemistry Chemical Physics, 13(45), pp. 20136-20145. (doi: 10.1039/c1cp21209e)

Xu, F., Scullion, R.A., Yan, J., Miras, H.N. , Busche, C. , Scandurra, A., Pignataro, B., Long, D.-L. and Cronin, L. (2011) A supramolecular heteropolyoxopalladate {Pd15} cluster host encapsulating a {Pd2} dinuclear guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−. Journal of the American Chemical Society, 133(13), pp. 4684-4686. (doi: 10.1021/ja1105514)

2010

Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core. Inorganica Chimica Acta, 363(15), pp. 4240-4246. (doi: 10.1016/j.ica.2010.07.020)

Pradeep, C. P., Long, D.-L. and Cronin, L. (2010) Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly. Dalton Transactions, 39(40), p. 9443. (doi: 10.1039/C0DT00325E) (PMID:20721370)

Rosnes, M.H., Musumeci, C., Pradeep, C.P., Mathieson, J.S., Long, D.L. , Song, Y.-F., Pignataro, B., Cogdell, R.J. and Cronin, L. (2010) Assembly of modular asymmetric organic-inorganic polyoxometalate hybrids into anisotropic nanostructures. Journal of the American Chemical Society, 132(44), pp. 15490-15492. (doi: 10.1021/ja1066338)

Ivanov, N.B., Schnack, J., Schnalle, R., Richter, J., Kogerler, P., Newton, G., Cronin, L. , Oshima, Y. and Nojiri, H. (2010) Heat capacity reveals the physics of a frustrated spin tube. Physical Review Letters, 105(3), 037206. (doi: 10.1103/PhysRevLett.105.037206)

Long, D.-L., Tsunashima, R. and Cronin, L. (2010) Polyoxometalates: building blocks for functional nanoscale systems. Angewandte Chemie (International Edition), 49(10), pp. 1736-1758. (doi: 10.1002/anie.200902483)

Miras, H.N. , Cooper, G.J.T., Long, D.-L., Bogge, H., Muller, A., Streb, C. and Cronin, L. (2010) Unveiling the transient template in the self-assembly of a molecular oxide nanowheel. Science, 327(5961), pp. 72-74. (doi: 10.1126/science.1181735)

Boyd, T., Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) Understanding and mapping the assembly of a family of trimeric polyoxometalates: transition metal mediated Wells-Dawson (M-18)-trimers. Dalton Transactions, 39(28), pp. 6460-6465. (doi: 10.1039/C002633F)

Cabrera, R.Q., Long, D.-L. , Cronin, L. and McMillan, P.F. (2010) In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions. CrystEngComm, 12(9), pp. 2568-2572. (doi: 10.1039/C003388J)

Cogdell, R.J. , Brotosudarmo, T.H.P., Gardiner, A.T., Sanchez, P.M. and Cronin, L. (2010) Artificial photosynthesis – solar fuels: current status and future prospects. Biofuels, 1(6), pp. 861-876. (doi: 10.4155/bfs.10.62)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2010) Assembly of Pure Silver-Tungsten-Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component. Advanced Materials, 22(38), pp. 4275-4279. (doi: 10.1002/adma.201001398)

McGlone, T., Vilà-Nadal, L. , Miras, H.N. , Long, D.L. , Poblet, J.M. and Cronin, L. (2010) Assembly of titanium embedded polyoxometalates with unprecedented structural features. Dalton Transactions, 39(48), pp. 11599-11604. (doi: 10.1039/c0dt01327g)

Miras, H.N. , Ochoa, M.N.C., Long, D.L. and Cronin, L. (2010) Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}. Chemical Communications, 46(43), pp. 8148-8150. (doi: 10.1039/C0CC02849E)

Mitchell, S.G., Streb, C., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2010) Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture. Nature Chemistry, 2(4), pp. 308-312. (doi: 10.1038/NCHEM.581)

Ochoa, M.N.C., Cooper, G.J.T. , Newton, G.N., Long, D.L. , Seeber, G. and Cronin, L. (2010) Supramolecular Architectures of Copper(II) Perchlorate Complexes of cis,trans-1,3,5-Triaminocyclohexane Assembled Exploiting the Delicate Balance Between Weak and Strong Interactions. Zeitschrift für Naturforschung B - A Journal of Chemical Sciences, 65(3), pp. 304-310.

Pasparakis, G., Krasnogor, N., Cronin, L. , Davis, B. G. and Alexander, C. (2010) Controlled polymer synthesis-from biomimicry towards synthetic biology. Chemical Society Reviews, 39(1), pp. 286-300. (doi: 10.1039/b809333b)

Seeber, G., Cooper, G. J. T. , Newton, G. N., Rosnes, M. H., Long, D. L. , Kariuki, B. M., Kogerler, P. and Cronin, L. (2010) Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry. Chemical Science, 1(1), pp. 62-67. (doi: 10.1039/c0sc00264j)

Shiga, T., Newton, G. N., Mathieson, J. S., Tetsuka, T., Nihei, M., Cronin, L. and Oshio, H. (2010) Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages. Dalton Transactions, 39(20), pp. 4730-4733. (doi: 10.1039/b925399h)

Song, Y. -F., Long, D. L. and Cronin, L. (2010) Hybrid polyoxometalate clusters with appended aromatic platforms. CrystEngComm, 12(1), pp. 109-115. (doi: 10.1039/b910434h)

Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi: 10.1002/anie.201002672)

Tsunashima, R., Long, D.L. , Miras, H.N. , Gabb, D., Pradeep, C.P. and Cronin, L. (2010) The construction of high-nuclearity isopolyoxoniobates with pentagonal building blocks: [HNb27O76](16-) and [H10Nb31O93(CO3)](23-). Angewandte Chemie (International Edition), 49(1), pp. 113-116. (doi: 10.1002/anie.200903970)

Yan, J., Gao, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Self-assembly of a nanosized, saddle-shaped, solution-stable polyoxometalate anion built from pentagonal building blocks: [H34W119Se8Fe2O420](54-). Journal of the American Chemical Society, 132(33), pp. 11410-11411. (doi: 10.1021/ja104043s)

Yan, J., Long, D. L. and Cronin, L. (2010) Development of a Building Block Strategy To Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO32- as a Template Linker. Angewandte Chemie (International Edition), 49(24), pp. 4117-4120. (doi: 10.1002/anie.201000076)

Yan, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Cation controlled assembly and transformation of mono- and bi-sulfite templated dawson-type polyoxotungstates. Inorganic Chemistry, 49(4), pp. 1819-1825. (doi: 10.1021/ic9021646)

Zhang, J., Song, Y.-F., Cronin, L. and Liu, T. (2010) Reverse-Vesicle Formation of Organic-Inorganic Polyoxometalate-Containing Hybrid Surfactants with Tunable Sizes. Chemistry: A European Journal, 16(37), pp. 11320-11324. (doi: 10.1002/chem.201000794)

2009

Pradeep, P.C., Misdrahi, M.F., Li, F.Y., Zhang, J., Xu, L., Long, D.L. , Liu, T. and Cronin, L. (2009) Synthesis of modular “inorganic-organic-inorganic” polyoxometalates and their assembly into vesicles. Angewandte Chemie (International Edition), 48(44), pp. 8309-8313. (doi: 10.1002/anie.200903070)

Streb, C., Tsunashima, R., MacLaren, D.A. , McGlone, T., Akutagawa, T., Nakamura, T., Scandurra, A., Pignataro, B., Gadegaard, N. and Cronin, L. (2009) Supramolecular silver polyoxometalate architectures direct the growth of composite semiconducting nanostructures. Angewandte Chemie (International Edition), 48(35), pp. 6490-6493. (doi: 10.1002/anie.200901650)

Kitson, P. J., Parenty, A. D. C., Richmond, C. J., Long, D. L. and Cronin, L. (2009) A new C-C bond forming annulation reaction leading to pH switchable heterocycles. Chemical Communications(27), pp. 4067-4069. (doi: 10.1039/b905383b)

Mitchell, S.G., Khanra, S., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2009) The trinity of polyoxometalates: connecting {M-12} Keggin and {M-18} Dawson clusters to triangles. Chemical Communications(19), pp. 2712-2714. (doi: 10.1039/b903206a)

Thiel, J., Ritchie, C., Streb, C., Long, D. L. and Cronin, L. (2009) Heteroatom-controlled kinetics of switchable polyoxometalate frameworks. Journal of the American Chemical Society, 131(12), pp. 4180-4181. (doi: 10.1021/ja809422k)

Miras, H.N. , Wilson, E.F. and Cronin, L. (2009) Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry. Chemical Communications(11), pp. 1297-1311. (doi: 10.1039/b819534j)

Brechin, E. K. and Cronin, L. (2009) The Marriage of Inorganic and Organic Building Blocks for the Assembly of Rotaxanes. Angewandte Chemie (International Edition), 48(38), pp. 6948-6949. (doi: 10.1002/anie.200902228)

Cooper, G. J. T. and Cronin, L. (2009) How to sweet-talk bacteria. Nature Chemistry, 1(5), pp. 342-343. (doi: 10.1038/nchem.306)

Cooper, G. J. T. and Cronin, L. (2009) Real-time direction control of self fabricating polyoxometalate-based microtubes. Journal of the American Chemical Society, 131(24), pp. 8368-8369. (doi: 10.1021/ja902684b)

Cooper, G. J.T. , Newton, G. N., Long, D.-L. , Kogerler, P., Rosnes, M. H., Keller, M. and Cronin, L. (2009) Exploring a series of isostructural dodecanuclear mixed ni:co clusters: toward the control of elemental composition using ph and stoichiometry. Inorganic Chemistry, 48(3), pp. 1097-1104. (doi: 10.1021/ic802197u)

Fielden, J., Long, D. L. , Cronin, L. and Kogerler, P. (2009) Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. Polyhedron, 28(13), pp. 2803-2807. (doi: 10.1016/j.poly.2009.05.058)

Goral, M., McCormac, T., Dempsey, E., Long, D. L. , Cronin, L. and Bond, A. M. (2009) Voltammetry of [R4N](4)[M18O54(SO3)(2)] and [Ru(bpy)(3)](2)[M18O54(SO3)(2)] (M = Mo, W) as microcrystals adhered to a glassy carbon electrode surface in contact with ionic liquid media. Dalton Transactions(34), pp. 6727-6735. (doi: 10.1039/b822167g)

Imai, H., Akutagawa, T., Kudo, F., Ito, M., Toyoda, K., Noro, S., Cronin, L. and Nakamura, T. (2009) Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo-176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)(80)]Cl-27 center dot 450H(2)O. Journal of the American Chemical Society, 131(38), 13578-+. (doi: 10.1021/ja9048042)

Mathieson, J.S., Cooper, G.J.T. , Pickering, A.L., Keller, M., Long, D.L. , Newton, G.N. and Cronin, L. (2009) Monitoring the Formation of Coordination Complexes Using Electrospray Mass Spectrometry. Chemistry: An Asian Journal, 4(5), pp. 681-687. (doi: 10.1002/asia.200900007)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2009) Guest-Directed Supramolecular Architectures of {W-36} Polyoxometalate Crowns. Chemistry: An Asian Journal, 4(10), pp. 1612-1618. (doi: 10.1002/asia.200900242)

Mitchell, S. G., Gabb, D., Ritchie, C., Hazel, N., Long, D. L. and Cronin, L. (2009) Controlling nucleation of the cyclic heteropolyanion {P8W48}: a cobalt-substituted phosphotungstate chain and network. CrystEngComm, 11(1), pp. 36-39. (doi: 10.1039/b813066c)

Newton, G. N., Cooper, G. J. T. , Schuch, D., Shiga, T., Khanra, S., Long, D. L. , Oshio, H. and Cronin, L. (2009) cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe-III and Pd-II coordination clusters. Dalton Transactions(9), pp. 1549-1553. (doi: 10.1039/b815200d)

Noro, S., Tsunashima, R., Kamiya, Y., Uemura, K., Kita, H., Cronin, L. , Akutagawa, T. and Nakamura, T. (2009) Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster. Angewandte Chemie (International Edition), 48(46), pp. 8703-8706. (doi: 10.1002/anie.200903142)

Richmond, C. J., Eadie, R. M., Parenty, A. D. C. and Cronin, L. (2009) Fine Tuning Reactivity: Synthesis and Isolation of 1,2,3,12b-Tetrahydroimidazo[1,2-f]phenanthridines. Journal of Organic Chemistry, 74(21), pp. 8196-8202. (doi: 10.1021/jo901622e)

Ritchie, C., Boyd, T., Long, D. L. , Ditzel, E. and Cronin, L. (2009) Grafting ligands to direct the self-assembly of Co/Ni2+ substituted polyoxometalate clusters. Dalton Transactions(9), pp. 1587-1592. (doi: 10.1039/b814076f)

Ritchie, C., Cooper, G.J.T. , Song, Y.F., Streb, C., Yin, H.B. , Parenty, A.D.C., MacLaren, D.A. and Cronin, L. (2009) Spontaneous assembly and real-time growth of micrometre-scale tubular structures from polyoxometalate-based inorganic solids. Nature Chemistry, 1(1), pp. 47-52. (doi: 10.1038/nchem.113)

Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L. , Xu, L. and Cronin, L. (2009) A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)(2)Co2Na2(H2O)(2)](18-). Dalton Transactions(33), pp. 6483-6486. (doi: 10.1039/b907410d)

Song, Y.F., McMillan, N., Long, D.L. , Kane, S., Malm, J., Riehle, M. , Pradeep, C.P., Gadegaard, N. and Cronin, L. (2009) Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-Hybrid Clusters Lead to Selective Cell Adhesion. Journal of the American Chemical Society, 131(4), pp. 1340-1341. (doi: 10.1021/ja807091v)

Vilá-Nadal, L. , Rodriguez-Fortea, A., Yan, L.K., Wilson, E.F., Cronin, L. and Poblet, J.M. (2009) Nucleation mechanisms of molecular oxides: a study of the assembly-dissassembly of [W6O19]2- by theory and mass spectrometry. Angewandte Chemie (International Edition), 48(30), pp. 5452-5456. (doi: 10.1002/anie.200901348)

Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi: 10.1002/anie.200806343)

2008

Zhang, J., Song, Y.-F., Cronin, L. and Liu, T. (2008) Self-Assembly of Organic-Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups. Journal of the American Chemical Society, 130(44), p. 14408. (doi: 10.1021/ja805644a)

Fleming, C., Long, D. L. , McMillan, N., Johnston, J., Bovet, N., Dhanak, V., Gadegaard, N. , Kogerler, P., Cronin, L. and Kadodwala, M. (2008) Reversible electron-transfer reactions within a nanoscale metal oxide cage mediated by metallic substrates. Nature Nanotechnology, 3(4), pp. 229-233. (doi: 10.1038/nnano.2008.66)

Song, Y.-F., McMillan, N., Long, D.-L. , Thiel, J., Ding, Y., Chen, H., Gadegaard, N. and Cronin, L. (2008) Design of hydrophobic polyoxometalate hybrid assemblies beyond surfactant encapsulation. Chemistry: A European Journal, 14(8), pp. 2349-2354. (doi: 10.1002/chem.200701629)

Miras, H. and Cronin, L. (2008) Polyoxometalate nanocapsules: from structure to function. In: Atwood, J. L. and Steed, J. W. (eds.) Organic Nanostructures. Wiley-VCH Verlag: Weinheim, pp. 277-291. ISBN 9783527318360

Abbas, H., Streb, C., Pickering, A. L., Neil, A. R., Long, D. L. and Cronin, L. (2008) Molecular growth of polyoxometalate Architectures based on [-Ag{Mo-8}Ag-] synthons: Toward designed cluster assemblies. Crystal Growth and Design, 8(2), pp. 635-642. (doi: 10.1021/cg700736v)

Akutagawa, T., Endo, D., Kudo, F., Noro, S. I., Takeda, S., Cronin, L. and Nakamura, T. (2008) A solid-state supramolecular rotator assembled front a Cs-crown ether polyoxometalate hybrid: (Cs+)(3)([18]crown-6)(3)(H+)(2)[PMo12O40]. Crystal Growth and Design, 8(3), pp. 812-816. (doi: 10.1021/cg060951+)

Akutagawa, T., Jin, R., Tunashima, R., Noro, S., Cronin, L. and Nakamura, T. (2008) Nanoscale assemblies of gigantic molecular {Mo-154}-rings: (Dimethyldioctadecylammonium)(20)[Mo154O462H8(H2O)(70)]. Langmuir, 24(1), pp. 231-238. (doi: 10.1021/la701364k)

Kitson, P. J., Song, Y. -F., Gamez, P., de Hoog, P., Long, D. L. , Parenty, A. D. C., Reedijk, J. and Cronin, L. (2008) Metal-mediated transformation of a triazinephenanthridinium ligand leading to a {Pd-5} coordination complex observed crystallographically and by cryospray mass Spectrometry. Inorganic Chemistry, 47(6), pp. 1883-1885. (doi: 10.1021/ic7022192)

Long, D.L. , Song, Y.-F., Wilson, E.F., Kogerler, P., Guo, S.X., Bond, A.M., Hargreaves, J.S.J. and Cronin, L. (2008) Capture of periodate in a {W18O54} cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)](6-) embedded with high-valent iodine. Angewandte Chemie (International Edition), 47(23), pp. 4384-4387. (doi: 10.1002/anie.200800041)

Long, D.L. , Streb, C., Song, Y.-F., Mitchell, S. and Cronin, L. (2008) Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion. Journal of the American Chemical Society, 130(6), 1830-+. (doi: 10.1021/ja075940z)

Miras, H.N. , Long, D.L. , Kogerler, P. and Cronin, L. (2008) Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties. Dalton Transactions(2), pp. 214-221. (doi: 10.1039/b714285d)

Miras, H.N. , Stone, D.J., McInnes, E.J.L., Raptis, R.G., Baran, P., Chilas, G.I., Sigalas, M.P., Kabanos, T.A. and Cronin, L. (2008) Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-). Chemical Communications(39), pp. 4703-4705. (doi: 10.1039/B811279G)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2008) Structural evolution of "S"-shaped [H4W22O74](12-) and ""-shaped [H10W34O116](18-) isopolyoxotungstate clusters. Angewandte Chemie (International Edition), 47(44), pp. 8420-8423. (doi: 10.1002/anie.200802109)

Mitchell, S. G., Ritchie, C., Long, D.L. and Cronin, L. (2008) Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control. Dalton Transactions(11), pp. 1415-1417. (doi: 10.1039/b715885h)

Newton, G.N., Cooper, G.J.T. , Kogerler, P., Long, D.L. and Cronin, L. (2008) Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters. Journal of the American Chemical Society, 130(3), pp. 790-791. (doi: 10.1021/ja0768183)

Parenty, A. D. C. and Cronin, L. (2008) One-pot synthesis of dihydroimidazo- and imidazophenanthridinium salts. Synthesis(1), pp. 155-160. (doi: 10.1055/s-2007-983895)

Parenty, A. D. C. and Cronin, L. (2008) One-pot synthesis of imidazopyridine derivatives. Synthesis(9), pp. 1479-1485. (doi: 10.1055/s-2007-1000936)

Pradeep, C. P., Long, D. L. , Newton, G. N., Song, Y. -F. and Cronin, L. (2008) Supramolecular metal oxides: Programmed hierarchical assembly of a protein-sized 21 kDa [(C16H36N)(19){H2NC(CH2O)(3)P2V3W15O59}(4)](5-) polyoxometalate assembly. Angewandte Chemie (International Edition), 47(23), pp. 4388-4391. (doi: 10.1002/anie.200800431)

Pradeep, C. P., Long, D. L. , Streb, C. and Cronin, L. (2008) "Bottom-Up" Meets "Top-Down" Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P4W52O178](24-) and Disassembly to [P3W39O134](19-). Journal of the American Chemical Society, 130(45), p. 14946. (doi: 10.1021/ja806596j)

Rancan, M., Newton, G. N., Muryn, C. A., Pritchard, R. G., Timco, G. A., Cronin, L. and Winpenny, R. E. P. (2008) Chemistry and supramolecular chemistry of chromium horseshoes. Chemical Communications(13), pp. 1560-1562. (doi: 10.1039/b718282a)

Richmond, C. J., Parenty, A. D. C., Song, Y. -F., Cooke, G. and Cronin, L. (2008) Realization of a "Lockable" molecular switch via pH- and redox-modulated cyclization. Journal of the American Chemical Society, 130(39), pp. 13059-13065. (doi: 10.1021/ja803338m)

Ritchie, C. et al. (2008) Polyoxometalate-mediated self-assembly of single-molecule magnets: {[XW9O34](2)[(Mn4Mn2O4)-Mn-III-O-II(H2O)(4)]}(12-). Angewandte Chemie (International Edition), 47(30), pp. 5609-5612. (doi: 10.1002/anie.200801281)

Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N. , Long, D.L. , Boyd, T., Peacock, R.D., McGlone, T. and Cronin, L. (2008) Reversible redox reactions in an extended polyoxometalate framework solid. Angewandte Chemie (International Edition), 47(36), pp. 6881-6884. (doi: 10.1002/anie.200802594)

Song, Y. -F., Long, D. L. , Kelly, S. E. and Cronin, L. (2008) Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry. Inorganic Chemistry, 47(20), pp. 9137-9139. (doi: 10.1021/ic801366r)

Song, Y.-F. and Cronin, L. (2008) Postsynthetic covalent modification of metal-organic framework (MOF) materials. Angewandte Chemie (International Edition), 47(25), pp. 4635-4637. (doi: 10.1002/anie.200801631)

Song, Y.F., Kitson, P.J., Long, D.L. , Parenty, A.D.C., Thatcher, R.J. and Cronin, L. (2008) Supramolecular self-assembly and anion-dependence of copper(II) complexes with cationic dihydro-imidazo phenanthridinium (DIP)-containing ligands. CrystEngComm, 10(9), pp. 1243-1251. (doi: 10.1039/b802541j)

Streb, C., McGlone, T., Brucher, O., Long, D. L. and Cronin, L. (2008) Hybrid Host-Guest Complexes: Directing the Supramolecular Structure through Secondary Host-Guest Interactions. Chemistry: A European Journal, 14(29), pp. 8861-8868. (doi: 10.1002/chem.200801247)

Wilson, E. F., Abbas, H., Duncombe, B. J., Streb, C., Long, D. L. and Cronin, L. (2008) Probing the self-assembly of inorganic cluster architectures in solution with cryospray mass spectrometry: Growth of polyoxomolybdate clusters and polymers mediated by silver(I) ions. Journal of the American Chemical Society, 130(42), pp. 13876-13884. (doi: 10.1021/ja802514q)

2007

Akutagawa, T., Endo, D., Noro, S.I., Cronin, L. and Nakamura, T. (2007) Directing organic–inorganic hybrid molecular-assemblies of polyoxometalate crown-ether complexes with supramolecular cations. Coordination Chemistry Reviews, 251(21-24), pp. 2547-2561. (doi: 10.1016/j.ccr.2007.08.015)

Streb, C., Ritchie, C., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported AgIAgI interactions. Angewandte Chemie (International Edition), 46(40), pp. 7579-7582. (doi: 10.1002/anie.200702698)

Parenty, A.D.C., Song, Y.-F., Richmond, C.J. and Cronin, L. (2007) A general and efficient five-step one-pot procedure leading to nitrogen-bridgehead heterocycles containing an imidazole ring. Organic Letters, 9(12), pp. 2253-2256. (doi: 10.1021/ol070263z)

Long, D.L. , Burkholder, E. and Cronin, L. (2007) Polyoxometalate clusters, nanostructures and materials: from self-assembly to designer materials and devices. ChemInform, 38(15), (doi: 10.1002/chin.200715223)

Song, Y.F., Long, D.L. and Cronin, L. (2007) Noncovalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate-pyrene hybrid. Angewandte Chemie (International Edition), 46(21), pp. 3900-3904. (doi: 10.1002/anie.200604734)

Fay, N., Bond, A.M., Baffert, C., Boas, J.F., Pilbrow, J.R., Long, D.-L. and Cronin, L. (2007) Structural, electrochemical, and spectroscopic characterization of a redox pair of sulfite-based polyoxotungstates: α-[W18O54(SO3)2]4- and α-[W18O54(SO3)2]5-. Inorganic Chemistry, 46(9), pp. 3502-3510. (doi: 10.1021/ic062067e)

Guthrie, K.M., Parenty, A.D.C., Smith, L.V., Cronin, L. and Cooper, A. (2007) Microcalorimetry of interaction of dihydro-imidazo-phenanthridinium (DIP)-based compounds with duplex DNA. Biophysical Chemistry, 126(1-3), pp. 117-123. (doi: 10.1016/j.bpc.2006.05.006)

Akutagawa, T., Endo, D., Noro, S. I., Cronin, L. and Nakamura, T. (2007) Directing organic-inorganic hybrid molecular-assemblies of polyoxometalate crown-ether complexes with supramolecular cations. Coordination Chemistry Reviews, 251(21-24), pp. 2547-2561. (doi: 10.1016/j.ccr.2007.08.015)

Baffert, C., Feldberg, S.W., Bond, A.M., Long, D.L. and Cronin, L. (2007) pH-Dependence of the aqueous electrochemistry of the two-electron reduced alpha-[Mo18O54(SO3)] sulfite Dawson-like polyoxometalate anion derived from its triethanolammonium salt. Dalton Transactions, pp. 4599-4607. (doi: 10.1039/b705991d)

Cooper, G.J.T. , Newton, G.N., Kogerler, P., Long, D.L. , Engelhardt, L., Luban, M. and Cronin, L. (2007) Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry. Angewandte Chemie (International Edition), 46(8), pp. 1340-1344. (doi: 10.1002/anie.200603870)

Fielden, J., Long, D.L. , Slawin, A.M.Z., Kogerler, P. and Cronin, L. (2007) Ligand and counterion control of Ag(I) architectures: Assembly of a {Ag-8} ring cluster mediated by hydrophobic and Ag center dot center dot center dot Ag interactions. Inorganic Chemistry, 46, pp. 9090-9097. (doi: 10.1021/ic700872b)

Long, D., Burkholder, E. and Cronin, L. (2007) Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices. Chemical Society Reviews, 36, pp. 105-121. (doi: 10.1039/b502666k)

McMillan, N., Smith, L.V., de la Fuente, J.M., Parenty, A.D.C., Gadegaard, N. , Pitt, A.R., Thomson, K., MacKenzie, C., Kelly, S. and Cronin, L. (2007) Incorporation of N-heterocyclic cations into proteins with a highly directed chemical modification. Chemical Communications, 25, pp. 2581-2583. (doi: 10.1039/b702575k)

Pradeep, C.P., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Controlled assembly and solution observation of a 2.6 nm polyoxometalate super tetrahedron cluster: [KFe12(OH)18(-1,2,3-P2W15O56)4]29–. Chemical Communications, 41, pp. 4254-4256. (doi: 10.1039/b707202c)

Ritchie, C., Burkholder, E.M., Long, D.-L. , Adam, D., Kögerler, P. and Cronin, L. (2007) Exploiting the multifunctionality of organocations in the assembly of hybrid polyoxometalate clusters and networks. Chemical Communications, 38(17), pp. 468-470. (doi: 10.1039/b612741j)

Song, Y.-F., Abbas, H., Ritchie, C., McMillian, N., Long, D.-L. , Gadegaard, N. and Cronin, L. (2007) From polyoxometalate building blocks to polymers and materials: the silver connection. Journal of Materials Chemistry, 17, pp. 1903-1908. (doi: 10.1039/b617830h)

Streb, C., Ritchie, C., Long, D.L. , Kogerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported Ag-I center dot center dot center dot Ag-I interactions". Angewandte Chemie (International Edition), 46, pp. 7579-7582. (doi: 10.1002/anie.200702698)

2006

Fielden, J., Gunning, P.T., Long, D.-L. , Nutley, M., Ellern, A., Kögerler, P. and Cronin, L. (2006) Anion control of isomerism, crystal packing and binding properties in a mononuclear zinc complex. Polyhedron, 25(18), pp. 3474-3480. (doi: 10.1016/j.poly.2006.06.044)

Akutagawa, T., Endo, D., Imai, H., Noro, S., Cronin, L. and Nakamura, T. (2006) Formation of p-Phenylenediamine-Crown Ether-[PMo12O40]4- Salts. Inorganic Chemistry, 45(21), pp. 8628-8637. (doi: 10.1021/ic060857i)

Baffert, C., Boas, J.F., Bond, A.M., Kögerler, P., Long, D.-L. , Pilbrow, J.R. and Cronin, L. (2006) Experimental and theoretical investigations of the sulfite-based polyoxometalate cluster redox series: α - and β-[Mo18O54(SO3)2]4-/5-/6-. Chemistry: A European Journal, 12(33), pp. 8472-8483. (doi: 10.1002/chem.200501450)

Newton, G. N., Cooper, G. J.T. , Long, D.-L. , Kogerler, P. and Cronin, L. (2006) Synthetic, structural and magnetic characterisation of a one-dimensional nickel chain constructed using cis,trans-1,3,5-triaminocyclohexane as a building block. Journal of Molecular Structure, 796, pp. 23-27. (doi: 10.1016/j.molstruc.2006.03.087)

Fielden, J., Long, D.L. , Evans, C. and Cronin, L. (2006) Metal-dependent formation of mononuclear complexes and M2L2 mesocates with Schiff-base ligands. European Journal of Inorganic Chemistry, 2006(19), pp. 3930-3935. (doi: 10.1002/ejic.200600367)

Long, D.L. , Kögerler, P., Farrugia, L.J. and Cronin, L. (2006) Linking chiral clusters with molybdate building blocks: from homochiral helical supramolecular arrays to coordination helices. Chemistry: An Asian Journal, 1(3), pp. 352-357. (doi: 10.1002/asia.200600069)

Long, D.L. , Kogerler, P., Parenty, A.D.C., Fielden, J. and Cronin, L. (2006) Discovery of a family of isopolyoxotungstates [H4W19O62]6- encapsulating a {WO6} moiety within a {W18} Dawson-like cluster cage. Angewandte Chemie (International Edition), 45(29), pp. 4798-4803. (doi: 10.1002/anie.200504600)

Cronin, L. (2006) Supramolecular coordination chemistry. Annual Reports on the Progress of Chemistry Section A: Inorganic Chemistry, 101, pp. 348-374. (doi: 10.1039/b410477n)

Fielden, J., Malaestean, Y.L., Ellern, A., García-Serres, R., Cronin, L. and Kögerler, P. (2006) Inducing molecular growth in an {Mo57Fe6}-type nanocluster: synthesis, structure, and properties of {Mo57}(Mo)2Fe6III}. Journal of Cluster Science, 17(2), pp. 291-302. (doi: 10.1007/s10876-006-0053-1)

Long, D.-L. , Streb, C., Kögerler, P. and Cronin, L. (2006) Observation and theoretical analysis of the “sensitive coordination sites” in the isopolyoxomolybdate cluster [Mo36O112(H2O)14]8-. Journal of Cluster Science, 17(2), pp. 257-266. (doi: 10.1007/s10876-006-0058-9)

Long, D.-L. and Cronin, L. (2006) Towards polyoxometalate-integrated nanosystems. Chemistry: A European Journal, 12(14), pp. 3698-3706. (doi: 10.1002/chem.200501002)

Fielden, J., Sprott, J., Long, D.-L. , Kögerler, P. and Cronin, L. (2006) Controlling aggregation of copper(II)-based coordination compounds: from mononuclear to dinuclear, tetranuclear, and polymeric copper complexes. Inorganic Chemistry, 45(7), pp. 2886-2895. (doi: 10.1021/ic051647t)

Akutagawa, T., Endo, D., Imai, H., Noro, S., Cronin, L. and Nakamura, T. (2006) Formation of p-phenylenediamine-crown ether-[PMo12O40](4-) salts. Inorganic Chemistry, 45, pp. 8628-8637. (doi: 10.1021/ic060857i)

Cronin, L. (2006) Inorganic molecular capsules: From structure to function. Angewandte Chemie (International Edition), 45, pp. 3576-3578. (doi: 10.1002/anie.200600090)

Cronin, L. et al. (2006) The imitation game - a computational chemical approach to recognizing life. Nature Biotechnology, 24, pp. 1203-1206. (doi: 10.1038/nbt1006-1203)

Fielden, J., Long, D., Evans, C. and Cronin, L. (2006) Metal-dependent formation of mononuclear complexes and M2L2 mesocates with Schiff-base ligands. European Journal of Inorganic Chemistry, pp. 3930-3935. (doi: 10.1002/ejic.200600367)

Fielden, J., Malaestean, Y., Ellern, A., Garcia-Serres, R., Cronin, L. and Kogerler, P. (2006) Inducing molecular growth in an {Mo57Fe6}-type nanocluster: Synthesis, structure, and properties of {Mo-57(Mo)(2)Fe-6(III). Journal of Cluster Science, 17, pp. 291-302. (doi: 10.1007/s10876-006-0053-1)

Long, D.-L. , Brücher, O., Streb, C. and Cronin, L. (2006) Inorganic crown: the host–guest chemistry of a high nuclearity 'Celtic-ring' isopolyoxotungstate [H12W36O120]12–. Dalton Transactions(23), pp. 2852-2860. (doi: 10.1039/b515935k)

Parenty, A.D.C., Guthrie, K.M., Song, Y.-F., Smith, L.V., Burkholder, E. and Cronin, L. (2006) Discovery of an imidazo-phenanthridine synthon produced in a 'five-step one-pot reaction' leading to a new family of heterocycles with novel physical properties. Chemical Communications, 2006, pp. 1194-1196. (doi: 10.1039/b517117b)

Ritchie, C., Burkholder, E., Kogerler, P. and Cronin, L. (2006) Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species. Dalton Transactions, pp. 1712-1714. (doi: 10.1039/b518316b)

Ritchie, C., Burkholder, E., Kögerler, P. and Cronin, . (2006) Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species. Dalton Transactions, pp. 1712-1714. (doi: 10.1039/b518316b)

Smith, L., Parenty, A., Guthrie, K., Plumb, J., Brown, R. and Cronin, L. (2006) Dihydroimidazophenanthridinium (DIP)-based DNA binding agents with tuneable structures and biological activity. ChemBioChem, 7, pp. 1757-1763. (doi: 10.1002/cbic.200600205)

Streb, C., Long, D.-L. and Cronin, L. (2006) Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks. CrystEngComm, 8, pp. 629-634. (doi: 10.1039/b605285a)

2005

Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2005) A novel copper (II) metallacycle as a building block for the assembly of an extended supramolecular array containing channels and helical chains. Inorganic Chemistry Communications, 8(8), pp. 737-739. (doi: 10.1016/j.inoche.2005.05.005)

Parenty, A.D.C., Smith, L.V. and Cronin, L. (2005) An unusual substitution reaction directed by an intramolecular re-arrangement. Tetrahedron, 61(35), pp. 8410-8418. (doi: 10.1016/j.tet.2005.06.074)

de la Fuente, J.M., Fandel, M., Berry, C.C. , Riehle, M. , Cronin, L. , Aitchison, G. and Curtis, A.S.G. (2005) Quantum dots protected with tiopronin: a new fluorescence system for cell-biology studies. ChemBioChem, 6(6), pp. 989-991. (doi: 10.1002/cbic.200500071)

Parenty, A.D.C., Smith, L.V., Guthrie, K.M., Long, D.-L. , Plumb, J., Brown, R. and Cronin, L. (2005) Highly stable phenanthridinium frameworks as a new class of tunable DNA binding agents with cytotoxic properties. Journal of Medicinal Chemistry, 48(14), pp. 4504-4506. (doi: 10.1021/jm050320z)

Long, D.-L. , Abbas, H., Kogerler, P. and Cronin, L. (2005) Confined electron-transfer reactions within a molecular metal oxide "Trojan horse". Angewandte Chemie (International Edition), 44(22), pp. 3415-3419. (doi: 10.1002/anie.200500541)

Abbas, H., Pickering, A.L., Long, D.-L. , Kögerler, P. and Cronin, L. (2005) Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers. Chemistry: A European Journal, 11(4), pp. 1071-1078. (doi: 10.1002/chem.200401088)

Kögerler, P. and Cronin, L. (2005) Polyoxometalate nanostructures, superclusters, and colloids: from functional clusters to chemical aesthetics. Angewandte Chemie (International Edition), 44(6), pp. 844-846. (doi: 10.1002/anie.200462662)

Fielden, J., Sprott, J. and Cronin, L. (2005) Design and sterospecific synthesis of modular ligands based upon cis-1,3-trans-5-substituted cyclohexanes. New Journal of Chemistry, 29, pp. 1152-1158. (doi: 10.1039/b503606b)

Long, D.L. , Kogerler, P., Farrugia, L.J. and Cronin, L. (2005) Reactions of a {Mo-16}-type polyoxometalate cluster with electrophiles: a synthetic, theoretical and magnetic investigation. Dalton Transactions, pp. 1372-1380. (doi: 10.1039/b419301f)

Pickering, A.L., Seeber, G., Long, D.L. and Cronin, L. (2005) The importance of pi-pi, pi-CH and N-CH interactions in the crystal packing of Schiff-base derivatives of cis,cis- and cis,trans-1,3,5-triaminocyclohexane. CrystEngComm, 7, pp. 504-510. (doi: 10.1039/b506718a)

Seeber, G., Kariuki, B., Cronin, L. and Kogerler, P. (2005) Synthesis, structure and magnetism of a linear Cu-Cl-Cu entity found in [(Cu(tachH)(tach))(2)(mu-Cl)](5+). Polyhedron, 24, pp. 1651-1655. (doi: 10.1016/j.poly.2005.05.008)

Smith, L.V., de la Fuente, J.M., Guthrie, K.M., Parenty, A.D.C. and Cronin, L. (2005) Does it bind? An instant binding assay for DNA oligonucleotide interactive small molecules. New Journal of Chemistry, 29, pp. 1118-1120. (doi: 10.1039/b507037f)

2004

Cronin, L. , McGregor, P.A., Parsons, S., Teat, S., Gould, R., White, V.A., Long, N.J. and Robertson, N. (2004) Synthesis, structure, and complexation of a large 28-mer macrocycle containing two binding sites for either anions or metal ions. Inorganic Chemistry, 43(25), pp. 8023-8029. (doi: 10.1021/ic049190v)

Schnack, J., Nojiri, H., Kogerler, P., Cooper, G. J.T. and Cronin, L. (2004) Magnetic characterization of the frustrated three-leg ladder compound [(CuCl2tachH)3Cl]Cl2. Physical Review B, 70(17), 174420. (doi: 10.1103/PhysRevB.70.174420)

Cooper, G.J.T. , Abbas, H., Kögerler, P., Long, D.-L. and Cronin, L. (2004) Pentadecadentate chelating ligands as building blocks for a {Fe6} cage with 12 exo-coordinated sodium cations. Inorganic Chemistry, 43(23), pp. 7266-7268. (doi: 10.1021/ic049068w)

Parenty, A.D.C., Smith, L.V., Pickering, A.L., Long, D.-L. and Cronin, L. (2004) General one-pot, three-step methodology leading to an extended class of N-heterocyclic cations: spontaneous nucleophilic addition, cyclization, and hydride loss. Journal of Organic Chemistry, 69(18), pp. 5934-5946. (doi: 10.1021/jo0495440)

Pickering, A.L., Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2004) Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers. Polyhedron, 23(12), pp. 2075-2079. (doi: 10.1016/j.poly.2004.06.002)

Pickering, A.L., Long, D.-L. and Cronin, L. (2004) Coordination networks through the dimensions: from discrete clusters to 1D, 2D, and 3D silver(I) coordination polymers with rigid aliphatic amino ligands. Inorganic Chemistry, 43(16), pp. 4953-4961. (doi: 10.1021/ic049786i)

Long, D.-L. , Kögerler, P. and Cronin, L. (2004) Old clusters with new tricks: engineering S...S interactions and novel physical properties in sulfite-based Dawson clusters. Angewandte Chemie (International Edition), 43(14), pp. 1817-1820. (doi: 10.1002/anie.200352896)

Cronin, L. (2004) Macrocyclic and supramolecular coordination chemistry. Annual Reports on the Progress of Chemistry Section A: Inorganic Chemistry, 100, pp. 323-383. (doi: 10.1039/b311796k)

Fielden, J., Long, D.-L. and Cronin, L. (2004) Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes. Chemical Communications(19), pp. 2156-2157. (doi: 10.1039/b407229d)

Long, D.L. , Abbas, H., Kogerler, P. and Cronin, L. (2004) A high-nuclearity "Celtic-Ring" isopolyoxotungstate, [H12W36O120] that captures trace potassium ions. Journal of the American Chemical Society, 126, pp. 13880-13881. (doi: 10.1021/ja046410v)

Pickering, A.L., Seeber, G., Long, D.-L. and Cronin, L. (2004) Polymeric silver(I) coordination tubes. Chemical Communications, 2004, pp. 136-137. (doi: 10.1039/b312876h)

Seeber, G., Kogerler, P., Kariuki, B. and Cronin, L. (2004) Supramolecular assembly of ligand-directed triangular {(Cu3Cl)-Cl-II} clusters with spin frustration and spin-chain behaviour. Chemical Communications, pp. 1580-1581. (doi: 10.1039/b402487g)

Seeber, G., Kögerler, P., Kariuki, B.M. and Cronin, L. (2004) Supramolecular assembly of ligand-directed triangular {CuII3Cl} clusters with spin frustration and spin-chain behaviour. Chemical Communications, 2004, pp. 1580-1581. (doi: 10.1039/b402487g)

2003

Long, D.-L. , Kögerler, P., Farrugia, L. and Cronin, L. (2003) Restraining symmetry in the formation of small polyoxomolybdates: building blocks of unprecedented topology resulting from "shrink-wrapping" [H2Mo16O52]10--type clusters. Angewandte Chemie (International Edition), 42(35), pp. 4180-4183. (doi: 10.1002/anie.200351615)

Long, D.-L. , Orr, D., Seeber, G., Kögerler, P., Farrugia, L.J. and Cronin, L. (2003) The missing link in low nuclearity pure polyoxovanadate clusters: preliminary synthesis and structural analysis of a new {V16} cluster and related products: dedicated to professor Achim Müller. Journal of Cluster Science, 14(3), pp. 313-324. (doi: 10.1023/B:JOCL.0000005066.92182.90)

Seeber, G., Long, D.L. , Kariuki, B.M. and Cronin, L. (2003) Palladium(II)-based cis,trans-1,3,5-triaminocyclohexane complexes demonstrating a variety of coordination modes and architectures. Dalton Transactions, pp. 4498-4504. (doi: 10.1039/b307616d)

Seeber, G., Pickering, A.L., Long, D.L. and Cronin, L. (2003) Controlling dimensionality of silver(I) coordination networks with rigid aliphatic amino ligands: from a 2D to a 3D network of unprecedented topology comprising helical channels. Chemical Communications, pp. 2002-2003. (doi: 10.1039/b305188a)

2002

Robertson, N. and Cronin, L. (2002) Metal bis-1,2-dithiolene complexes in conducting or magnetic crystalline assemblies. Coordination Chemistry Reviews, 227, pp. 93-127.

Seeber, G., Kariuki, B. and Cronin, L. (2002) Self-assembly of a twelve-component hexanuclear metallomacrocycle constructed with a novel tri-amino ligand. Chemical Communications, pp. 2912-2913. (doi: 10.1039/b209493m)

Shivaiah, V., Reddy, P.V.N., Cronin, L. and Das, S.K. (2002) A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)(7)Al(OH)(6)Mo6O18](n)center dot 4nH(2)O. Journal of the Chemical Society: Dalton Transactions, pp. 3781-3782. (doi: 10.1039/b207149e)

2001

Cronin, L. , Clark, S.J., Parsons, S., Nakamura, T. and Robertson, N. (2001) Unique structural topologies involving metal-metal and metal-sulfur interactions: salts of [Ni(C3S5)(2)](x-) with cis-anti-cis-dicyclohexyl-18-crown-6 complexed counter ions. Journal of the Chemical Society: Dalton Transactions, pp. 1347-1351. (doi: 10.1039/b008299f)

This list was generated on Wed Apr 24 07:43:19 2024 BST.
Number of items: 433.

Articles

Parrilla-Gutiérrez, J. M. , Granda, J. M., Ayme, J.-F., Bajczyk, M. D., Wilbraham, L. and Cronin, L. (2024) Electron density-based GPT for optimization and suggestion of host–guest binders. Nature Computational Science, (doi: 10.1038/s43588-024-00602-x) (Early Online Publication)

Asche, S., Pow, R. W., Mehr, H. M. , Cooper, G. J. T. , Sharma, A. and Cronin, L. (2024) Evidence of selection in mineral mediated polymerization reactions executed in a robotic Chemputer system. ChemSystemsChem, e202400006. (doi: 10.1002/syst.202400006) (Early Online Publication)

Sharma, A. , Ng, M. T.-K., Parrilla Gutierrez, J. M. , Jiang, Y. and Cronin, L. (2024) A programmable hybrid digital chemical information processor based on the Belousov-Zhabotinsky reaction. Nature Communications, 15, 1984. (doi: 10.1038/s41467-024-45896-7) (PMID:38443339) (PMCID:PMC10915172)

Matysiak, B. M., Thomas, D. and Cronin, L. (2024) Reaction kinetics using a Chemputable framework for data collection and analysis. Angewandte Chemie (International Edition), 63(9), e202315207. (doi: 10.1002/anie.202315207) (PMID:38155102)

Leonov, A. I. et al. (2024) An integrated self-optimizing programmable chemical synthesis and reaction engine. Nature Communications, 15, 1240. (doi: 10.1038/s41467-024-45444-3) (PMID:38336880) (PMCID:PMC10858227)

Bell, N. L. , Boser, F., Bubliauskas, A., Willcox, D. R., Sandoval Luna, V. E. and Cronin, L. (2024) Autonomous execution of highly reactive chemical transformations in the Schlenkputer. Nature Chemical Engineering, 1, pp. 180-189. (doi: 10.1038/s44286-023-00024-y)

Sharma, A. , Czégel, D., Lachmann, M., Kempes, C. P., Walker, S. I. and Cronin, L. (2023) Assembly theory explains and quantifies selection and evolution. Nature, 622(7982), pp. 321-328. (doi: 10.1038/s41586-023-06600-9) (PMID:37794189) (PMCID:PMC10567559)

Wang, H., Manzano, J. S., Kitson, P. J., Mullin, M., Lin, C.-G., Slowing, I. I. and Cronin, L. (2023) Digitizing protocols into single reactors for the one-pot synthesis of nanomaterials. Matter, 6(7), pp. 2383-2394. (doi: 10.1016/j.matt.2023.05.029)

Krasecki, V. K. et al. (2023) The role of experimental noise in a hybrid classical-molecular computer to solve combinatorial optimization problems. ACS Central Science, 9(7), 1453–1465. (doi: 10.1021/acscentsci.3c00515) (PMID:37521801)

Zhao, T., Bell, N. L. , Chisholm, G. , Kandasamy, B., Long, D.-L. and Cronin, L. (2023) Aqueous solutions of super reduced polyoxotungstates as electron storage systems. Energy and Environmental Science, 16(6), pp. 2603-2610. (doi: 10.1039/D3EE00569K) (PMID:37323468) (PMCID:PMC10265398)

Jiang, Y., Sharma, A. and Cronin, L. (2023) An accelerated method for investigating spectral properties of dynamically evolving nanostructures. Journal of Physical Chemistry Letters, 14(16), pp. 3929-3938. (doi: 10.1021/acs.jpclett.3c00395) (PMID:37078273) (PMCID:PMC10150391)

M. Mehr, S. H. , Caramelli, D. and Cronin, L. (2023) Digitizing chemical discovery with a Bayesian explorer for interpreting reactivity data. Proceedings of the National Academy of Sciences of the United States of America, 120(17), e2220045120. (doi: 10.1073/pnas.2220045120) (PMID:37068251)

Jiang, Z.-G., Zeng, H.-M., Zhang, X., Tan, Y., Lan, Y.-Z., Wang, Y., Long, D.-L. , Cronin, L. and Zhan, C.-H. (2023) A synergistic {Cu2-W12O40} catalyst with high conversion for homo-coupling of terminal alkynes. Inorganic Chemistry Frontiers, 10(4), pp. 1255-1261. (doi: 10.1039/D2QI02368G)

Kowalski, D. J., MacGregor, C. M., Long, D.-L. , Bell, N. L. and Cronin, L. (2023) Automated library generation and serendipity quantification enables diverse discovery in coordination chemistry. Journal of the American Chemical Society, 145(4), pp. 2332-2341. (doi: 10.1021/jacs.2c11066) (PMID:36649125)

Sinclair, Z. L., Bell, N. L. , Bame, J. R., Long, D.-L. and Cronin, L. (2023) A water-soluble self-assembled {Pd84}ᴬᶜ polyoxopalladate nano-wheel as a supramolecular host. Angewandte Chemie (International Edition), 62(1), e202214203. (doi: 10.1002/anie.202214203) (PMID:36336660)

Restuccia, S. , Gibson, G. M. , Cronin, L. and Padgett, M. J. (2022) Measuring optical activity with unpolarized light: ghost polarimetry. Physical Review A: Atomic, Molecular and Optical Physics, 106(6), 062601. (doi: 10.1103/PhysRevA.106.062601)

Manzano, J. S., Hou, W., Zalesskiy, S. S., Frei, P., Wang, H., Kitson, P. J. and Cronin, L. (2022) An autonomous portable platform for universal chemical synthesis. Nature Chemistry, 14(11), pp. 1311-1318. (doi: 10.1038/s41557-022-01016-w) (PMID:36202987)

She, S., Bell, N. L. , Zheng, D., Mathieson, J. S., Castro, M. D., Long, D.-L. , Koehnke, J. and Cronin, L. (2022) Robotic synthesis of peptides containing metal-oxide-based amino acids. Chem, 8(10), pp. 2734-2748. (doi: 10.1016/j.chempr.2022.07.007)

Jiang, Y., Salley, D., Sharma, A. , Keenan, G., Mullen, M. and Cronin, L. (2022) An artificial intelligence enabled chemical synthesis robot for exploration and optimization of nanomaterials. Science Advances, 8(40), eabo2626. (doi: 10.1126/sciadv.abo2626) (PMID:36206340) (PMCID:PMC9544322)

Rohrbach, S. et al. (2022) Digitization and validation of a chemical synthesis literature database in the ChemPU. Science, 377(6602), pp. 172-180. (doi: 10.1126/science.abo0058)

Marshall, S. M., Moore, D. G., Murray, A. R.G., Walker, S. I. and Cronin, L. (2022) Formalising the pathways to life using assembly spaces. Entropy, 24(7), 884. (doi: 10.3390/e24070884) (PMID:35885107) (PMCID:PMC9323097)

Bubliauskas, A., Blair, D. J., Powell-Davies, H., Kitson, P. J., Burke, M. and Cronin, L. (2022) A practical approach to combine modular reactions and reactionware for the digitization of chemical synthesis. Angewandte Chemie (International Edition), 61(24), e202116108. (doi: 10.1002/anie.202116108) (PMID:35257447)

Chen, J.-J. et al. (2022) Effective storage of electrons in water by the formation of highly reduced polyoxometalate clusters. Journal of the American Chemical Society, 144(20), pp. 8951-8960. (doi: 10.1021/jacs.1c10584) (PMID:35536652)

Ribó, E. G., Bell, N. L. , Long, D.-l. and Cronin, L. (2022) Engineering highly reduced molybdenum polyoxometalates via the incorporation of d and f block metal ions. Angewandte Chemie (International Edition), 61(21), e202201672. (doi: 10.1002/anie.202201672) (PMID:35257462)

Dearle, A. E. et al. (2022) An [Fe ᴵᴵᴵ₃₀] molecular metal oxide. Chemical Communications, 58(1), pp. 52-55. (doi: 10.1039/D1CC06224G) (PMID:34807967)

Lockey, D., Mathis, C., Miras, H. N. and Cronin, L. (2022) Investigating the autocatalytically driven formation of Keggin-based polyoxometalate clusters. Matter, 5(1), pp. 302-313. (doi: 10.1016/j.matt.2021.11.030)

Tze-Kiat Ng, M., Bell, N. L. , Long, D.-L. and Cronin, L. (2021) Facile and reproducible electrochemical synthesis of the giant polyoxomolybdates. Journal of the American Chemical Society, 143(48), pp. 20059-20063. (doi: 10.1021/jacs.1c10198) (PMID:34812622)

Cronin, L. (2021) Exploring the hidden constraints that control the self-assembly of nanomolecular inorganic clusters. Bulletin of Japan Society of Coordination Chemistry, 78, pp. 11-17. (doi: 10.4019/bjscc.78.11)

Caramelli, D., Granda, J. M., Mehr, S. H. M. , Cambie, D. , Henson, A. B. and Cronin, L. (2021) Discovering new chemistry with an autonomous robotic platform driven by a reactivity-seeking neural network. ACS Central Science, 7(11), pp. 1821-1830. (doi: 10.1021/acscentsci.1c00435)

Hammer, A. J.S., Leonov, A. I., Bell, N. L. and Cronin, L. (2021) Chemputation and the standardization of chemical informatics. JACS Au, 1(10), pp. 1572-1587. (doi: 10.1021/jacsau.1c00303) (PMCID:PMC8549037)

Bornemann-Pfeiffer, M., Wolf, J., Meyer, K., Kern, S., Angelone, D., Leonov, A., Cronin, L. and Emmerling, F. L. (2021) Standardization and control of Grignard reactions in a universal chemical synthesis machine using online NMR. Angewandte Chemie (International Edition), 60(43), pp. 23202-23206. (doi: 10.1002/anie.202106323) (PMID:34278673)

Kandasamy, B., Lee, E. , Long, D.-L. , Bell, N. and Cronin, L. (2021) Exploring the geometric space of metal-organic polyhedrons (MOPs) of metal-oxo clusters. Inorganic Chemistry, 60(19), pp. 14772-14778. (doi: 10.1021/acs.inorgchem.1c01987) (PMID:34549944) (PMCID:PMC8493551)

Bell, N. L. , Kupper, M. and Cronin, L. (2021) Design of experiments for optimization of polyoxometalate syntheses. Chemistry of Materials, 33(18), pp. 7263-7271. (doi: 10.1021/acs.chemmater.1c01401)

Cutler, D. J., Singh, M. K., Nichol, G. S., Evangelisti, M., Schnack, J., Cronin, L. and Brechin, E. K. (2021) [Fe15]: a frustrated, centred tetrakis hexahedron. Chemical Communications, 57(71), pp. 8925-8928. (doi: 10.1039/D1CC03919A) (PMID:34396373)

Liu, Y. , Mathis, C., Marshall, S., Bajczyk, M. D., Wilbraham, L. and Cronin, L. (2021) Exploring and mapping chemical space with molecular assembly trees. Science Advances, 7(39), eabj2465. (doi: 10.1126/sciadv.abj2465) (PMID:34559562)

Pow, R. W., Sinclair, Z. L., Bell, N. L. , Watfa, N., Abul-Haija, Y. M. , Long, D.-L. and Cronin, L. (2021) Enantioselective recognition of racemic amino alcohols in aqueous solution by chiral metal-oxide keplerate {Mo132} cluster capsules. Chemistry: A European Journal, 27(48), pp. 12327-12334. (doi: 10.1002/chem.202100899) (PMID:34196438)

Minato, T., Salley, D., Mizuno, N., Yamaguchi, K., Cronin, L. and Suzuki, K. (2021) Robotic stepwise synthesis of hetero-multinuclear metal oxo clusters as single-molecule magnets. Journal of the American Chemical Society, 143(32), pp. 12809-12816. (doi: 10.1021/jacs.1c06047) (PMID:34358427)

Asche, S., Cooper, G. J.T. , Keenan, G., Mathis, C. and Cronin, L. (2021) A robotic prebiotic chemist probes long term reactions of complexifying mixtures. Nature Communications, 12, 3547. (doi: 10.1038/s41467-021-23828-z) (PMID:34112788) (PMCID:PMC8192940)

Marshall, S. M. et al. (2021) Identifying molecules as biosignatures with assembly theory and mass spectrometry. Nature Communications, 12, 3033. (doi: 10.1038/s41467-021-23258-x) (PMID:34031398) (PMCID:PMC8144626)

Chou, L. et al. (2021) Towards a more universal life detection strategy. Bulletin of the American Astronomical Society, 53(4), 181. (doi: 10.3847/25c2cfeb.53a24171)

Hou, W., Bubliauskas, A., Kitson, P. J., Francoia, J.-P., Powell-Davies, H., Parrilla Gutierrez, J. M. , Frei, P., Manzano, J. S. and Cronin, L. (2021) Automatic generation of 3D-printed reactionware for chemical synthesis digitization using ChemSCAD. ACS Central Science, 7(2), pp. 212-218. (doi: 10.1021/acscentsci.0c01354) (PMCID:PMC7908023)

Lin, C.-G., Hutin, M., Busche, C. , Bell, N. L. , Long, D.-L. and Cronin, L. (2021) Elucidating the paramagnetic interactions of an inorganic–organic hybrid radical-functionalized Mn-Anderson cluster. Dalton Transactions, 50(7), pp. 2350-2353. (doi: 10.1039/D0DT04149A) (PMID:33564815)

Lapham, P., Vilà-Nadal, L. , Cronin, L. and Georgiev, V. P. (2021) Influence of the contact geometry and counterions on the current flow and charge transfer in polyoxometalate molecular junctions: a density functional theory study. Journal of Physical Chemistry C, 125(6), pp. 3599-3610. (doi: 10.1021/acs.jpcc.0c11038) (PMID:33633816) (PMCID:PMC7899180)

Wilbraham, L. , Mehr, S. H. M. and Cronin, L. (2021) Digitizing chemistry using the chemical processing unit: from synthesis to discovery. Accounts of Chemical Research, 54(2), pp. 253-262. (doi: 10.1021/acs.accounts.0c00674) (PMID:33370095)

Angelone, D., Hammer, A., Rohrbach, S. , Krambeck, S., Granda, J. M., Wolf, J., Zalesskiy, S., Chisholm, G. and Cronin, L. (2021) Convergence of multiple synthetic paradigms in a universally programmable chemical synthesis machine. Nature Chemistry, 13(1), pp. 63-69. (doi: 10.1038/s41557-020-00596-9) (PMID:33353971)

She, S., Xuan, W., Bell, N. L. , Pow, R. , Ribo, E. G., Sinclair, Z., Long, D.-L. and Cronin, L. (2021) Peptide sequence mediated self-assembly of molybdenum blue nanowheel superstructures. Chemical Science, 12(7), pp. 2427-2432. (doi: 10.1039/D0SC06098D)

Traustason, H., Bell, N. L. , Caranto, K., Auld, D. C., Lockey, D. T., Kokot, A., Szymanowski, J. E.S., Cronin, L. and Burns, P. C. (2020) Reactivity, formation, and solubility of polyoxometalates pprobed by calorimetry. Journal of the American Chemical Society, 142(48), pp. 20463-20469. (doi: 10.1021/jacs.0c10133) (PMID:33203207)

Garrido Ribó, E., Bell, N. L. , Xuan, W., Luo, J., Long, D.-L. , Liu, T. and Cronin, L. (2020) Synthesis, assembly, and sizing of neutral, lanthanide substituted molybdenum blue wheels {Mo90Ln10}. Journal of the American Chemical Society, 142(41), pp. 17508-17514. (doi: 10.1021/jacs.0c07146) (PMID:32965108)

Mehr, S. H. M. , Craven, M., Leonov, A. I., Keenan, G. and Cronin, L. (2020) A universal system for digitization and automatic execution of the chemical synthesis literature. Science, 370(6512), pp. 101-108. (doi: 10.1126/science.abc2986) (PMID:33004517)

Salley, D. S., Keenan, G. A., Long, D.-L. , Bell, N. L. and Cronin, L. (2020) A modular programmable inorganic cluster discovery robot for the discovery and synthesis of polyoxometalates. ACS Central Science, 6(9), pp. 1587-1593. (doi: 10.1021/acscentsci.0c00415) (PMID:32999934) (PMCID:32999934)

Cardoso, S. S.S. et al. (2020) Chemobrionics: from self-assembled material architectures to the origin of life. Artificial Life, 26(3), pp. 315-326. (doi: 10.1162/artl_a_00323) (PMID:32697160)

Porwol, L., Kowalski, D. J., Henson, A. , Long, D.-L. , Bell, N. L. and Cronin, L. (2020) An autonomous chemical robot discovers the rules of supramolecular chemistry without prior knowledge. Angewandte Chemie (International Edition), 59(28), pp. 11256-11261. (doi: 10.1002/anie.202000329) (PMID:32419277) (PMCID:PMC7384156)

Salley, D., Keenan, G., Grizou, J. , Sharma, A. , Martín, S. and Cronin, L. (2020) A nanomaterials discovery robot for the Darwinian evolution of shape programmable gold nanoparticles. Nature Communications, 11, 2771. (doi: 10.1038/s41467-020-16501-4) (PMID:32488034) (PMCID:PMC7265452)

Miras, H. N. , Mathis, C., Xuan, W., Long, D. , Pow, R. and Cronin, L. (2020) Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters. Proceedings of the National Academy of Sciences of the United States of America, 117(20), pp. 10699-10705. (doi: 10.1073/pnas.1921536117) (PMID:32371490) (PMCID:PMC7245103)

Parrilla Gutierrez, J. M. , Sharma, A. , Tsuda, S., Cooper, G. J.T. , Aragon Camarasa, G. , Donkers, K. and Cronin, L. (2020) A programmable chemical computer with memory and pattern recognition. Nature Communications, 11, 1442. (doi: 10.1038/s41467-020-15190-3) (PMID:32188858) (PMCID:PMC7080730)

Pow, R. W., Xuan, W., Long, D.-L. , Bell, N. L. and Cronin, L. (2020) Embedding alkenes within an icosahedral inorganic fullerene {(NH4)42[Mo132O372(L)30(H2O)72]} for trapping volatile organics. Chemical Science, 11(9), pp. 2388-2393. (doi: 10.1039/C9SC06217C)

Lee, E. C. , Parrilla-Gutierrez, J. M. , Henson, A. , Brechin, E. K. and Cronin, L. (2020) A crystallization robot for generating true random numbers based on stochastic chemical processes. Matter, 2(3), pp. 649-657. (doi: 10.1016/j.matt.2020.01.024)

Grizou, J. , Points, L. J., Sharma, A. and Cronin, L. (2020) A curious formulation robot enables the discovery of a novel proto-cell behaviour. Science Advances, 6(5), eaay4237. (doi: 10.1126/sciadv.aay4237) (PMID:32064348) (PMCID:PMC6994213)

Chisholm, G. , Cronin, L. and Symes, M. D. (2020) Decoupled electrolysis using a silicotungstic acid electron-coupled-proton buffer in a proton exchange membrane cell. Electrochimica Acta, 331, 135255. (doi: 10.1016/j.electacta.2019.135255)

Gromski, P. S., Granda, J. M. and Cronin, L. (2020) Universal chemical synthesis and discovery with 'The Chemputer'. Trends in Chemistry, 2(1), pp. 4-12. (doi: 10.1016/j.trechm.2019.07.004)

Cavell, A. C. et al. (2020) Optical monitoring of polymerizations in droplets with high temporal dynamic range. Chemical Science, 11(10), pp. 2647-2656. (doi: 10.1039/c9sc05559b) (PMID:34084323) (PMCID:PMC8157680)

Zhan, C.-H., Zheng, Q., Long, D.-L. , Vilà‐Nadal, L. and Cronin, L. (2019) Controlling the reactivity of the [P8W48O184]40– inorganic ring and its assembly into POMZite inorganic frameworks with silver ions. Angewandte Chemie (International Edition), 131(48), pp. 17442-6. (doi: 10.1002/anie.201911170) (PMID:31538679) (PMCID:PMC6900112)

Dearle, A. E. et al. (2019) An [Feᴵᴵᴵ₃₄] molecular metal oxide. Angewandte Chemie (International Edition), 58(47), pp. 16903-16906. (doi: 10.1002/anie.201911003) (PMID:31535459) (PMCID:PMC7186828)

Lie, J., Yang, J.-J., Liu, T., Yuan, R.-M., Deng, D.-R., Zheng, M.-S., Chen, J.-J., Cronin, L. and Dong, Q.-F. (2019) Tuning redox active polyoxometalates for efficient electron‐coupled proton buffer mediated water splitting. Chemistry: A European Journal, 25(49), pp. 11432-11436. (doi: 10.1002/chem.201903142) (PMID:31309625) (PMCID:PMC6851869)

Colón-Santos, S., Cooper, G. J.T. and Cronin, L. (2019) Taming combinatorial explosion of the formose reaction via recursion within mineral environments. ChemSystemsChem, 1(3), e1900014. (doi: 10.1002/syst.201900014)

Doran, D., Abul-Haija, Y. M. and Cronin, L. (2019) Emergence of function and selection from recursively programmed polymerisation reactions in mineral environments. Angewandte Chemie (International Edition), 58(33), pp. 11253-11256. (doi: 10.1002/anie.201902287) (PMID:31206983) (PMCID:PMC6772075)

Xuan, W., Pow, R., Zheng, Q., Watfa, N., Long, D.-L. and Cronin, L. (2019) Ligand-directed template assembly for the construction of gigantic molybdenum blue wheels. Angewandte Chemie (International Edition), 58(32), pp. 10867-10872. (doi: 10.1002/anie.201901818) (PMID:31155800) (PMCID:PMC6771582)

Zheng, Q., Kupper, M., Xuan, W., Oki, H., Tsunashima, R., Long, D.-L. and Cronin, L. (2019) Anisotropic polyoxometalate cages assembled via layers of heteroanion templates. Journal of the American Chemical Society, 141(34), pp. 13479-13486. (doi: 10.1021/jacs.9b04533) (PMID:31295408) (PMCID:PMC6716119)

Duros, V., Grizou, J. , Sharma, A. , Mehr, S. H. M., Bubliauskas, A., Frei, P., Miras, H. N. and Cronin, L. (2019) Intuition-enabled machine learning beats the competition when joint human-robot teams perform inorganic chemical experiments. Journal of Chemical Information and Modeling, 59(6), pp. 2664-2671. (doi: 10.1021/acs.jcim.9b00304) (PMID:31025861) (PMCID:PMC6593393)

Janusson, E. , de Kler, N., Vilà-Nadal, L. , Long, D.-L. and Cronin, L. (2019) Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection. Chemical Communications, 55(41), pp. 5797-5800. (doi: 10.1039/C9CC02361E) (PMID:31041957)

Rosnes, M. H., Mathieson, J. S., Törnroos, K. W., Johnsen, R. E., Cronin, L. and Dietzel, P. D.C. (2019) Electrospray mass spectrometry investigation into the formation of CPO-27. Crystal Growth and Design, 19(4), pp. 2089-2096. (doi: 10.1021/acs.cgd.8b01657)

Martín, S., Takashima, Y., Lin, C.-G., Song, Y.-F., Miras, H. N. and Cronin, L. (2019) Integrated synthesis of gold nanoparticles coated with polyoxometalate clusters. Inorganic Chemistry, 58(7), pp. 4110-4116. (doi: 10.1021/acs.inorgchem.8b03013) (PMID:30869513)

Surman, A. J. , Rodriguez Garcia, M., Abul-Haija, Y. M. , Cooper, G. J.T. , Gromski, P. S., Turk-MacLeod, R., Mullin, M., Mathis, C., Walker, S. I. and Cronin, L. (2019) Environmental control programs the emergence of distinct functional ensembles from unconstrained chemical reactions. Proceedings of the National Academy of Sciences of the United States of America, 116(12), pp. 5387-5392. (doi: 10.1073/pnas.1813987116) (PMID:30842280) (PMCID:PMC6431231)

Suárez-Marina, I., Abul-Haija, Y. M. , Turk-MacLeod, R., Gromski, P. S., Cooper, G. J.T. , Olivé Olivé, A., Colón-Santos, S. and Cronin, L. (2019) Integrated synthesis of nucleotide and nucleosides influenced by amino acids. Communications Chemistry, 2, 28. (doi: 10.1038/s42004-019-0130-7)

Gromski, P. S., Henson, A. B. , Granda, J. M. and Cronin, L. (2019) How to explore chemical space using algorithms and automation. Nature Reviews Chemistry, 3(2), pp. 119-128. (doi: 10.1038/s41570-018-0066-y)

Luo, J., Zhang, B., Yvon, C., Hutin, M., Gerislioglu, S., Wesdemiotis, C., Cronin, L. and Liu, T. (2019) Self-assembly of polyoxometalate-peptide hybrids in solution: elucidating the contributions of multiple possible driving forces. European Journal of Inorganic Chemistry, 2019(3-4), pp. 380-386. (doi: 10.1002/ejic.201800158) (PMID:31007577) (PMCID:PMC6472639)

Xuan, W., Pow, R., Watfa, N., Zheng, Q., Surman, A. J. , Long, D.-L. and Cronin, L. (2019) Stereoselective assembly of gigantic chiral molybdenum blue wheels using lanthanide ions and amino acids. Journal of the American Chemical Society, 141(3), pp. 1242-1250. (doi: 10.1021/jacs.8b09750) (PMID:30495944) (PMCID:PMC6351008)

Steiner, S. et al. (2019) Organic synthesis in a modular robotic system driven by a chemical programming language. Science, 363(6423), eaav2211. (doi: 10.1126/science.aav2211) (PMID:30498165)

Zalesskiy, S. S., Kitson, P. J., Frei, P., Bubliauskas, A. and Cronin, L. (2019) 3D designed and printed chemical generators for on demand reagent synthesis. Nature Communications, 10, 5496. (doi: 10.1038/s41467-019-13328-6) (PMID:31792220) (PMCID:PMC6889270)

Lin, C.-G., Zhou, W., Xiong, X.-T., Xuan, W., Kitson, P. J., Long, D.-L. , Chen, W., Song, Y.-F. and Cronin, L. (2018) Digital control of multistep hydrothermal synthesis by using 3D printed reactionware for the synthesis of metal–organic frameworks. Angewandte Chemie (International Edition), 57(51), pp. 16716-16720. (doi: 10.1002/anie.201810095) (PMID:30370977) (PMCID:PMC6391986)

Nakanishi, K., Cooper, G. J.T. , Points, L. J., Bloor, L. G., Ohba, M. and Cronin, L. (2018) Development of a minimal photosystem for hydrogen production in inorganic chemical cells. Angewandte Chemie (International Edition), 57(40), pp. 13066-13070. (doi: 10.1002/anie.201805584) (PMID:30105766) (PMCID:PMC6348376)

Chen, J.-J., Symes, M. D. and Cronin, L. (2018) Highly reduced and protonated aqueous solutions of [P2W18O62]6− for on-demand hydrogen generation and energy storage. Nature Chemistry, 10(10), pp. 1042-1047. (doi: 10.1038/s41557-018-0109-5) (PMID:30104721)

Miras, H. N. , Vilà-Nadal, L. and Cronin, L. (2018) Correction: Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 47(17), p. 6890. (doi: 10.1039/c8cs90091d) (PMID:30067251)

Caramelli, D., Henson, A. , Aragon Camarasa, G. , Sharabi, S., Keenan, G. and Cronin, L. (2018) Networking chemical robots for reaction multitasking. Nature Communications, 9, 3406. (doi: 10.1038/s41467-018-05828-8) (PMID:30143646) (PMCID:PMC6109044)

Christie, L. G. , Asche, S., Mathieson, J. S., Vila-Nadal, L. and Cronin, L. (2018) Investigating the formation of giant {Pd72}Prop and {Pd84}Gly macrocycles using NMR, HPLC and mass spectrometry. Journal of the American Chemical Society, 140(30), pp. 9379-9382. (doi: 10.1021/jacs.8b05059) (PMID:30005574)

Cronin, L. , Mehr, S.H.M. and Granda, J. (2018) Catalyst: the metaphysics of chemical reactivity. Chem, 4(8), pp. 1759-1761. (doi: 10.1016/j.chempr.2018.07.008)

Henson, A. B. , Gromski, P. S. and Cronin, L. (2018) Designing algorithms to aid discovery by chemical robots. ACS Central Science, 4(7), pp. 793-804. (doi: 10.1021/acscentsci.8b00176) (PMID:30062108) (PMCID:PMC6062836)

Granda, J. M., Donina, L., Dragone, V., Long, D.-L. and Cronin, L. (2018) Controlling an organic synthesis robot with machine learning to search for new reactivity. Nature, 559(7714), pp. 377-381. (doi: 10.1038/s41586-018-0307-8) (PMID:30022133) (PMCID:PMC6223543)

Walker, S. I. et al. (2018) Exoplanet biosignatures: future directions. Astrobiology, 18(6), pp. 779-824. (doi: 10.1089/ast.2017.1738) (PMID:29938538) (PMCID:PMC6016573)

Turk-MacLeod, R., Henson, A. , Rodriguez-Garcia, M., Gibson, G. M. , Aragon Camarasa, G. , Caramelli, D., Padgett, M. J. and Cronin, L. (2018) Approach to classify, separate, and enrich objects in groups using ensemble sorting. Proceedings of the National Academy of Sciences of the United States of America, 115(22), pp. 5681-5685. (doi: 10.1073/pnas.1721929115) (PMID:29760051) (PMCID:PMC5984510)

Purcell, J. W., Long, D.-L. , Lee, E. C. , Cronin, L. and Miras, H. N. (2018) Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates. Dalton Transactions, 47(18), pp. 6283-6287. (doi: 10.1039/C8DT00832A) (PMID:29667663) (PMCID:PMC5944425)

Miras, H. N. , Sartzi, H., Long, D.-L. , Sproules, S. and Cronin, L. (2018) Directed self-assembly, symmetry breaking, and electronic modulation of metal oxide clusters by pyramidal heteroanions. Chemistry: A European Journal, 24(17), pp. 4399-4411. (doi: 10.1002/chem.201705711) (PMID:29315925)

Yoshida, M. , Hinkley, T., Tsuda, S., Abul-Haija, Y. , Mcburney, R. T., Kulikov, V., Mathieson, J., Galinanes Reyes, S., Castro Spencer, M. D. and Cronin, L. (2018) Using evolutionary algorithms and machine learning to explore sequence space for the discovery of antimicrobial peptides. Chem, 4(3), pp. 533-543. (doi: 10.1016/j.chempr.2018.01.005)

Martin-Sabi, M., Soriano-López, J., Winter, R. S., Chen, J.-J., Vilà-Nadal, L. , Long, D.-L. , Galán-Mascarós, J. R. and Cronin, L. (2018) Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction. Nature Catalysis, 1(3), pp. 208-213. (doi: 10.1038/s41929-018-0037-1) (PMID:30079397) (PMCID:PMC6075698)

Szymański, J. K., Abul-Haija, Y. M. and Cronin, L. (2018) Exploring strategies to bias sequence in natural and synthetic oligomers and polymers. Accounts of Chemical Research, 51(3), pp. 649-658. (doi: 10.1021/acs.accounts.7b00495) (PMID:29493212)

Ye, J. C., Chen, J. J., Yuan, R. M., Deng, D. R., Zheng, M. S., Cronin, L. and Dong, Q. F. (2018) Strategies to explore and develop reversible redox reactions of Li-S in electrode architectures using silver-polyoxometalate clusters. Journal of the American Chemical Society, 140(8), pp. 3134-3138. (doi: 10.1021/jacs.8b00411) (PMID:29425034)

Zheng, Q., Vilà-Nadal, L. , Lang, Z., Chen, J.-j., Long, D.-L. , Mathieson, J. S., Poblet, J. M. and Cronin, L. (2018) Self-sorting of heteroanions in the assembly of cross-shaped polyoxometalate clusters. Journal of the American Chemical Society, 140(7), pp. 2595-2601. (doi: 10.1021/jacs.7b11982) (PMID:29359931) (PMCID:PMC6075695)

Chen, J.-J., Ye, J.-C., Zhang, X.-G., Symes, M. D. , Fan, S.-C., Long, D.-L. , Zheng, M.-S., Wu, D.-Y., Cronin, L. and Dong, Q.-F. (2018) Design and performance of rechargeable sodium ion batteries, and symmetrical li-ion batteries with supercapacitor-like power density based upon polyoxovanadates. Advanced Energy Materials, 8(6), 1701021. (doi: 10.1002/aenm.201701021)

Kirkaldy, N. , Chisholm, G. , Chen, J.-J. and Cronin, L. (2018) A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities. Chemical Science, 9(6), pp. 1621-1626. (doi: 10.1039/C7SC05388F) (PMID:29675207) (PMCID:PMC5887965)

Points, L. J., Taylor, J. W., Grizou, J. , Donkers, K. and Cronin, L. (2018) Artificial intelligence exploration of unstable protocells leads to predictable properties and discovery of collective behavior. Proceedings of the National Academy of Sciences of the United States of America, 115(5), pp. 885-890. (doi: 10.1073/pnas.1711089115) (PMID:29339510) (PMCID:PMC5798325)

Macdonald, L., Rausch, B., Symes, M. D. and Cronin, L. (2018) Selective hydrogenation of nitroarenes using an electrogenerated polyoxometalate redox mediator. Chemical Communications, 54(9), pp. 1093-1096. (doi: 10.1039/C7CC09036F) (PMID:29333558)

Kitson, P. J., Marie, G., Francoia, J.-P., Zalesskiy, S. S., Sigerson, R. C., Mathieson, J. S. and Cronin, L. (2018) Digitization of multistep organic synthesis in reactionware for on-demand pharmaceuticals. Science, 359(6373), pp. 314-319. (doi: 10.1126/science.aao3466) (PMID:29348235)

Marshall, S. M., Murray, A. R.G. and Cronin, L. (2017) A probabilistic framework for identifying biosignatures using Pathway Complexity. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 375(2109), 20160342. (doi: 10.1098/rsta.2016.0342) (PMID:29133442) (PMCID:PMC5686400)

Parrilla Gutierrez, J. M. , Tsuda, S., Grizou, J. , Taylor, J., Henson, A. and Cronin, L. (2017) Adaptive artificial evolution of droplet protocells in a 3D-printed fluidic chemorobotic platform with configurable environments. Nature Communications, 8, 1144. (doi: 10.1038/s41467-017-01161-8) (PMID:29074987) (PMCID:PMC5658334)

Symes, M. , Cogdell, R. , Macdonald, L., McGlynn, J., Irvine, N., Alshibane, I., Bloor, L., Rausch, B., Hargreaves, J. S.J. and Cronin, L. (2017) Using earth abundant materials for the catalytic evolution of hydrogen from electron-coupled proton buffers. Sustainable Energy and Fuels, 1(8), pp. 1782-1787. (doi: 10.1039/C7SE00334J)

Vilà-Nadal, L. and Cronin, L. (2017) Design and synthesis of polyoxometalate-framework materials from cluster precursors. Nature Reviews Materials, 2, 17054. (doi: 10.1038/natrevmats.2017.54)

Duros, V., Grizou, J. , Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human versus robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie (International Edition), 56(36), pp. 10815-10820. (doi: 10.1002/anie.201705721) (PMID:28649740) (PMCID:PMC5577512)

Doran, D., Rodriguez-Garcia, M., Turk-MacLeod, R., Cooper, G. J.T. and Cronin, L. (2017) A recursive microfluidic platform to explore the emergence of chemical evolution. Beilstein Journal of Organic Chemistry, 13, pp. 1702-1709. (doi: 10.3762/bjoc.13.164) (PMID:28904613) (PMCID:PMC5564272)

Taylor, J.W., Eghtesadi, S.A., Points, L.J., Liu, T. and Cronin, L. (2017) Autonomous model protocell division driven by molecular replication. Nature Communications, 8, 237. (doi: 10.1038/s41467-017-00177-4) (PMID:28798300) (PMCID:PMC5552811)

Xuan, W., Pow, R., Long, D.-L. and Cronin, L. (2017) Exploring the molecular growth of two gigantic half-closed polyoxometalate clusters {Mo180} and {Mo130Ce6}. Angewandte Chemie (International Edition), 56(33), pp. 9727-9731. (doi: 10.1002/ange.201702957) (PMID:28508585) (PMCID:PMC5600119)

Zang, H.-Y., Purcell, J. W., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}. Chemical Communications, 53(61), pp. 8585-8587. (doi: 10.1039/c7cc04398h) (PMID:28718479)

Purcell, J. W., Miras, H. , Long, D.-L. , Markopoulou, P. and Cronin, L. (2017) Tellurite-squarate driven assembly of a new family of nanoscale clusters based on (Mo2O2S2)2+. Chemistry: A European Journal, 23(40), pp. 9683-9689. (doi: 10.1002/chem.201701920) (PMID:28548217) (PMCID:PMC5575479)

Zhan, C., Busche, C. , Long, D.-L. , Molina, P. I., Winter, R. S. and Cronin, L. (2017) Encapsulation of a {Cu16} cluster containing four [Cu4O4] cubanes within an isopolyoxometalate {W44} cluster. Chemical Communications, 53(52), pp. 7076-7079. (doi: 10.1039/c7cc03544f) (PMID:28627534)

Cooper, G. J.T. , Surman, A. J. , McIver, J. , Colón-Santos, S. M., Gromski, P. S., Buchwald, S., Suárez Marina, I. and Cronin, L. (2017) Miller–Urey spark-discharge experiments in the deuterium world. Angewandte Chemie (International Edition), 56(28), pp. 8079-8082. (doi: 10.1002/anie.201610837) (PMID:28474773) (PMCID:PMC5499724)

Dragone, V., Sans, V., Henson, A. B. , Granda, J. M. and Cronin, L. (2017) An autonomous organic reaction search engine for chemical reactivity. Nature Communications, 8, 15733. (doi: 10.1038/ncomms15733) (PMID:28598440) (PMCID:PMC5472751)

Yoshida, M. , Galiñanes Reyes, S. G., Tsuda, S., Horinouchi, T., Furusawa, C. and Cronin, L. (2017) Time-programmable drug dosing allows the manipulation, suppression and reversal of antibiotic drug resistance in vitro. Nature Communications, 8, 15589. (doi: 10.1038/ncomms15589) (PMID:28593940) (PMCID:PMC5472167)

Cronin, L. (2017) Reaction: a new genesis for origins research? Chem, 2(5), pp. 601-603. (doi: 10.1016/j.chempr.2017.04.014)

Ruiz de la Oliva, A., Sans, V., Miras, H. , Long, D. L. and Cronin, L. (2017) Coding the assembly of polyoxotungstates with a programmable reaction system. Inorganic Chemistry, 56(9), pp. 5089-5095. (doi: 10.1021/acs.inorgchem.7b00206) (PMID:28414229) (PMCID:PMC5423703)

Boyd, T., Mitchell, S. G., Gabb, D., Long, D.-L. , Song, Y.-F. and Cronin, L. (2017) POMzites: a family of zeolitic polyoxometalate frameworks from a minimal building block library. Journal of the American Chemical Society, 139(16), pp. 5930-5938. (doi: 10.1021/jacs.7b01807) (PMID:28368582) (PMCID:PMC5423706)

Zhan, C. et al. (2017) A metamorphic inorganic framework that can be switched between eight single-crystalline states. Nature Communications, 8, 14185. (doi: 10.1038/ncomms14185) (PMID:28194009) (PMCID:PMC5316803)

Kulikov, V., Johnson, N. A.B., Surman, A. J. , Hutin, M., Kelly, S. K. , Hezwani, M., Long, D.-L. , Meyer, G. and Cronin, L. (2017) Spontaneous assembly of an organic-inorganic nucleic acid Z-DNA double-helix structure. Angewandte Chemie (International Edition), 56(4), pp. 1141-1145. (doi: 10.1002/anie.201606658) (PMID:27900812) (PMCID:PMC6057607)

Kitson, P. J., Glatzel, S. and Cronin, L. (2016) The digital code driven autonomous synthesis of ibuprofen automated in a 3D-printer-based robot. Beilstein Journal of Organic Chemistry, 12, pp. 2776-2783. (doi: 10.3762/bjoc.12.276) (PMID:28144350) (PMCID:PMC5238580)

Christie, L. G. , Surman, A. J. , Scullion, R. A., Xu, F., Long, D.-L. and Cronin, L. (2016) Overcoming the crystallization bottleneck: a family of gigantic inorganic {Pdx}L(x=84, 72) palladium macrocycles discovered using solution techniques. Angewandte Chemie (International Edition), 55(41), pp. 12741-12745. (doi: 10.1002/anie.201606005) (PMID:27634480) (PMCID:PMC5113701)

Xuan, W., Surman, A. J. , Zheng, Q., Long, D.-L. and Cronin, L. (2016) Self-templating and in situ assembly of a cubic cluster-of-clusters architecture based on a {Mo24Fe12} inorganic macrocycle. Angewandte Chemie (International Edition), 55(41), pp. 12703-12707. (doi: 10.1002/anie.201603298) (PMID:27358195) (PMCID:PMC5396355)

Fujibayashi, M., Song, Y.-F., Cronin, L. and Tsunashima, R. (2016) Exploring the solvent mediated assembly and redox activity of a POM–organic hybrid [Na(SO3)2(PhPO3)4MoV4MoVI14O49]5−. New Journal of Chemistry, 40(10), pp. 8488-8492. (doi: 10.1039/C6NJ01774F) (PMID:30078986) (PMCID:PMC6075703)

Zhang, G., Liu, C., Long, D.-L. , Cronin, L. , Tung, C.-H. and Wang, Y. (2016) Water-soluble pentagonal-prismatic titanium-oxo clusters. Journal of the American Chemical Society, 138(35), pp. 11097-11100. (doi: 10.1021/jacs.6b06290) (PMID:27525444)

Points, L., Grizou, J. and Cronin, L. (2016) Robotic chemistry sets for the classroom. Education in Chemistry, 53(5), pp. 22-25.

Zang, H., Surman, A. , Long, D. L. , Cronin, L. and Miras, H. N. (2016) Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks. Chemical Communications, 52(58), pp. 9109-9112. (doi: 10.1039/C6CC01041E) (PMID:26982102)

Cameron, J. M., Vilà-Nadal, L. , Winter, R. S., Iijima, F., Murillo, J. C., Rodríguez-Fortea, A., Oshio, H., Poblet, J. M. and Cronin, L. (2016) Investigating the transformations of polyoxoanions using mass spectrometry and molecular dynamics. Journal of the American Chemical Society, 138(28), pp. 8765-8773. (doi: 10.1021/jacs.6b02245) (PMID:27321042)

Scharf, C. and Cronin, L. (2016) Quantifying the origins of life on a planetary scale. Proceedings of the National Academy of Sciences of the United States of America, 113(29), pp. 8127-8132. (doi: 10.1073/pnas.1523233113) (PMID:27382156) (PMCID:PMC4961144)

Porwol, L., Henson, A. , Kitson, P. J., Long, D. L. and Cronin, L. (2016) On the fly multi-modal observation of ligand synthesis and complexation of Cu complexes in flow with ‘benchtop’ NMR and mass spectrometry. Inorganic Chemistry Frontiers, 3(7), pp. 919-923. (doi: 10.1039/C6QI00079G)

Takashima, Y., Miras, H. N. , Glatzel, S. and Cronin, L. (2016) Shrink wrapping redox-active crystals of polyoxometalate open frameworks with organic polymers via crystal induced polymerisation. Chemical Communications, 52(50), pp. 7794-7797. (doi: 10.1039/C6CC03031A) (PMID:27203804) (PMCID:PMC6055993)

Cronin, L. and Walker, S. I. (2016) Beyond prebiotic chemistry. Science, 352(6290), pp. 1174-1175. (doi: 10.1126/science.aaf6310) (PMID:27257242)

Zang, H.-Y., Chen, J.-J., Long, D. L. , Cronin, L. and Miras, H. N. (2016) Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters. Chemical Science, 7(6), pp. 3798-3804. (doi: 10.1039/c5sc04944j)

Kitson, P. J., Glatzel, S., Chen, W., Lin, C.-G., Song, Y.-F. and Cronin, L. (2016) 3D printing of versatile reactionware for chemical synthesis. Nature Protocols, 11(5), pp. 920-936. (doi: 10.1038/nprot.2016.041) (PMID:27077333)

Sans Sangorrin, V. and Cronin, L. (2016) Towards dial-a-molecule by integrating continuous flow, analytics and self-optimisation. Chemical Society Reviews, 45(8), pp. 2032-2043. (doi: 10.1039/C5CS00793C) (PMID:26815081) (PMCID:PMC6057606)

Points, L. J., Cooper, G. J.T. , Dolbecq, A., Mialane, P. and Cronin, L. (2016) An all-inorganic polyoxometalate–polyoxocation chemical garden. Chemical Communications, 52(9), pp. 1911-1914. (doi: 10.1039/c5cc09536k) (PMID:26681204)

Martin-Sabi, M., Winter, R. S., Lydon, C., Cameron, J. M., Long, D.-L. and Cronin, L. (2016) Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters. Chemical Communications, 52(5), pp. 919-921. (doi: 10.1039/C5CC08486E) (PMID:26581307)

Bloor, L. G., Solarska, R., Bienkowski, K., Kulesza, P. J., Augustynski, J., Symes, M. D. and Cronin, L. (2016) Solar-driven water oxidation and decoupled hydrogen production mediated by an electron-coupled-proton buffer. Journal of the American Chemical Society, 138(21), pp. 6707-6710. (doi: 10.1021/jacs.6b03187) (PMID:27159121) (PMCID:PMC5033397)

Glatzel, S., Hezwani, M., Kitson, P. J., Gromski, P. S., Schürer, S. and Cronin, L. (2016) A portable 3D printer system for the diagnosis and treatment of multidrug-resistant bacteria. Chem, 1(3), pp. 494-504. (doi: 10.1016/j.chempr.2016.08.008)

Surman, A. J. , Robbins, P. J., Ujma, J., Zheng, Q., Barran, P. E. and Cronin, L. (2016) Sizing and discovery of nanosized polyoxometalate clusters by mass spectrometry. Journal of the American Chemical Society, 138(11), pp. 3824-3830. (doi: 10.1021/jacs.6b00070) (PMID:26906879) (PMCID:PMC5033399)

Sartzi, H., Miras, H. N. , Vila-Nadal, L. , Long, D. L. and Cronin, L. (2015) Trapping the δ isomer of the polyoxometalate-based Keggin cluster with a tripodal ligand. Angewandte Chemie (International Edition), 54(51), pp. 15488-15492. (doi: 10.1002/anie.201505377) (PMID:26511859)

Anamimoghadam, O., Symes, M. D. , Long, D. L. , Sproules, S. , Cronin, L. and Bucher, G. (2015) Electronically stabilized nonplanar phenalenyl radical and its planar isomer. Journal of the American Chemical Society, 137(47), pp. 14944-14951. (doi: 10.1021/jacs.5b07959) (PMID:26526672)

Zhan, C.-H., Winter, R. S., Zheng, Q., Yan, J., Cameron, J. M., Long, D.-L. and Cronin, L. (2015) Assembly of tungsten-oxide-based pentagonal motifs in solution leads to nanoscale {W48}, {W56}, and {W92} polyoxometalate clusters. Angewandte Chemie (International Edition), 54(48), pp. 14308-14312. (doi: 10.1002/anie.201506170) (PMID:26449850)

Tsuda, S., Jaffery, H., Doran, D., Hezwani, M., Robbins, P. J., Yoshida, M. and Cronin, L. (2015) Customizable 3D printed 'Plug and Play' millifluidic devices for programmable fluidics. PLoS ONE, 10(11), e0141640. (doi: 10.1371/journal.pone.0141640) (PMID:26558389) (PMCID:PMC4641590)

Barge, L. M. et al. (2015) From chemical gardens to chemobrionics. Chemical Reviews, 115(16), pp. 8652-8703. (doi: 10.1021/acs.chemrev.5b00014) (PMID:26176351)

Chen, J.-J., Symes, M. D. , Fan, S.-C., Zheng, M.-S., Miras, H. N. , Dong, Q.-F. and Cronin, L. (2015) High performance polyoxometalate-based cathode materials for rechargeable lithium ion batteries. Advanced Materials, 27(31), pp. 4649-4654. (doi: 10.1002/adma.201501088) (PMID:26177828)

Henson, A. , Parrilla Gutierrez, J. M. , Hinkley, T., Tsuda, S. and Cronin, L. (2015) Towards heterotic computing with droplets in a fully automated droplet-maker platform. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 373(2046), 20140221. (doi: 10.1098/rsta.2014.0221) (PMID:26078348)

Zheng, Q., Vila-Nadal, L. , Busche, C. , Mathieson, J. S., Long, D.-L. and Cronin, L. (2015) Following the reaction of heteroanions inside a {W18O56} polyoxometalate nanocage by NMR spectroscopy and mass spectrometry. Angewandte Chemie (International Edition), 127(27), pp. 8006-8010. (doi: 10.1002/ange.201502295)

Zhang, B., Pradeep, C. P., Cronin, L. and Liu, T. (2015) Self-assembly of triangular polyoxometalate–organic hybrid macroions in mixed solvents. Chemical Communications, 51(41), pp. 8630-8633. (doi: 10.1039/C5CC02003D) (PMID:25900154)

MacDonell, A., JOHNSON, N. A.B., Surman, A. J. and Cronin, L. (2015) Configurable nanosized metal oxide oligomers via precise “click” coupling control of hybrid polyoxometalates. Journal of the American Chemical Society, 137(17), pp. 5662-5665. (doi: 10.1021/jacs.5b02466) (PMID:25846763)

Nakamura, I., Miras, H. N. , Fujiwara, A., Fujibayashi, M., Song, Y.-F., Cronin, L. and Tsunashima, R. (2015) Investigating the formation of 'Molybdenum Blues' with gel electrophoresis and mass spectrometry. Journal of the American Chemical Society, 137(20), pp. 6524-6530. (doi: 10.1021/ja512758j) (PMID:25897816)

Wu, B., Li, S., Lei, Y., Hu, H., de Sousa Amadeu, N., Janiak, C., Mathieson, J. S., Long, D.-L. , Cronin, L. and Yang, X.-J. (2015) The effect of the spacer of Bis(biurea) ligands on the structure of A2L3-type (A=anion) phosphate complexes. Chemistry: A European Journal, 21(6), pp. 2588-2593. (doi: 10.1002/chem.201405235) (PMID:25504744)

Georgiev, V. P. , Amoroso, S. M., Ali, T. M., Vila-Nadal, L. , Busche, C. , Cronin, L. and Asenov, A. (2015) Comparison between bulk and FDSOI POM flash cell: a multiscale simulation study. IEEE Transactions on Electron Devices, 62(2), pp. 680-684. (doi: 10.1109/TED.2014.2378378)

Lee, M. P., Cooper, G. J.T. , Hinkley, T., Gibson, G. M. , Padgett, M. J. and Cronin, L. (2015) Development of a 3D printer using scanning projection stereolithography. Scientific Reports, 5, 9875. (doi: 10.1038/srep09875) (PMID:25906401) (PMCID:PMC4407727)

Rodriguez-Garcia, M., Surman, A. J. , Cooper, G. J.T. , Suarez Marina, I., Hosni, Z., Lee, M. P. and Cronin, L. (2015) Formation of oligopeptides in high yield under simple programmable conditions. Nature Communications, 6, 8385. (doi: 10.1038/ncomms9385) (PMID:26442968) (PMCID:PMC4633627)

Sans Sangorrin, V., Porwol, L., Dragone, V. and Cronin, L. (2015) A self optimizing synthetic organic reactor system using real-time in-line NMR spectroscopy. Chemical Science, 6(2), pp. 1258-1264. (doi: 10.1039/C4SC03075C)

Winter, R. S., Long, D.-L. and Cronin, L. (2015) Synthesis and characterization of a series of [M2(β-SiW8O31)2]n− clusters and mechanistic insight into the reorganization of {β-SiW8O31} into {α-SiW9O34}. Inorganic Chemistry, 54(8), pp. 4151-4155. (doi: 10.1021/acs.inorgchem.5b00405)

Parrilla Gutierrez, J. M. , Hinkley, T., Taylor, J. W. and Cronin, L. (2014) Evolution of oil droplets in a chemorobotic platform. Nature Communications, 5, 5571. (doi: 10.1038/ncomms6571) (PMID:25482304) (PMCID:PMC4268700)

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi: 10.1038/nature13951) (PMID:25409147)

Kitson, P. J., Marshall, R. J., Long, D. , Forgan, R. S. and Cronin, L. (2014) 3D printed high-throughput hydrothermal reactionware for discovery, optimization, and scale-up. Angewandte Chemie (International Edition), 53(47), pp. 12723-12728. (doi: 10.1002/anie.201402654)

Xuan, W., Surman, A. J. , Miras, H. N., Long, D. L. and Cronin, L. (2014) Controlling the ring curvature, solution assembly, and reactivity of gigantic molybdenum blue wheels. Journal of the American Chemical Society, 136(40), pp. 14114-14120. (doi: 10.1021/ja5062483)

Zhan, C., Cameron, J. M., Gao, J., Purcell, J. W., Long, D. L. and Cronin, L. (2014) Time-resolved assembly of cluster-in-cluster {Ag12}-in-{W76} polyoxometalates under supramolecular control. Angewandte Chemie (International Edition), 53(39), pp. 10362-10366. (doi: 10.1002/anie.201402932) (PMID:25087861)

Scullion, R. A., Surman, A. J. , Xu, F., Mathieson, J. S., Long, D. L. , Haso, F., Liu, T. and Cronin, L. (2014) Exploring the symmetry, structure, and self-assembly mechanism of a gigantic seven-fold symmetric {Pd84} wheel. Angewandte Chemie (International Edition), 53(38), pp. 10032-10037. (doi: 10.1002/anie.201404621) (PMID:25044792)

Rausch, B., Symes, M. D. , Chisholm, G. and Cronin, L. (2014) Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting. Science, 345(6202), pp. 1326-1330. (doi: 10.1126/science.1257443)

Winter, R. S., Cameron, J. M. and Cronin, L. (2014) Controlling the minimal self assembly of "complex" polyoxometalate clusters. Journal of the American Chemical Society, 136(36), pp. 12753-12761. (doi: 10.1021/ja5067916)

Miras, H. N. , Vilà-Nadal, L. and Cronin, L. (2014) Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 43(16), pp. 5679-5699. (doi: 10.1039/c4cs00097h) (PMID:25005364)

Bagchi, V. et al. (2014) A versatile tripodal Cu(I) reagent for C–N bond construction via nitrene-transfer chemistry: catalytic perspectives and mechanistic insights on C–H aminations/amidinations and olefin aziridinations. Journal of the American Chemical Society, 136(32), pp. 11362-11381. (doi: 10.1021/ja503869j)

Lin, C.-G., Chen, W., Long, D. L. , Cronin, L. and Song, Y.-F. (2014) Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates. Dalton Transactions, 43(23), pp. 8587-8590. (doi: 10.1039/c4dt00033a) (PMID:24695647)

Kitson, P. J., Macdonell, A., Tsuda, S., Zang, H., Long, D.-L. and Cronin, L. (2014) Bringing crystal structures to reality by three-dimensional printing. Crystal Growth and Design, 14(6), pp. 2720-2724. (doi: 10.1021/cg5003012)

Georgiev, V. P. , Markov, S., Vila-Nadal, L. , Busche, C. , Cronin, L. and Asenov, A. (2014) Optimization and evaluation of variability in the programming window of a flash cell with molecular metal-oxide storage. IEEE Transactions on Electron Devices, 61(6), pp. 2019-2026. (doi: 10.1109/TED.2014.2315520)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2014) Assembly and core transformation properties of two tetrahedral clusters:([FeIII13P8W60O227(OH)15(H2O)2]30− and [FeIII13P8W60O224(OH)12(PO4)4]33−. Dalton Transactions, 43(13), pp. 5190-5199. (doi: 10.1039/c3dt53382d)

Yvon, C., Surman, A. J. , Hutin, M., Alex, J., Smith, B. O. , Long, D. L. and Cronin, L. (2014) Polyoxometalate clusters integrated into peptide chains and as inorganic amino acids: solution- and solid-phase approaches. Angewandte Chemie (International Edition), 53(13), pp. 3336-3341. (doi: 10.1002/anie.201311135)

Takashima, Y., Long, D.-L. and Cronin, L. (2014) Towards imaging electron density inside metal–organic framework structures. Chemical Communications, 50(18), pp. 2271-2274. (doi: 10.1039/c3cc48586b)

Cereda, A., Hitchcock, A., Symes, M. D. , Cronin, L. , Bibby, T. S. and Jones, A. K. (2014) A bioelectrochemical approach to characterize extracellular electron transfer by Synechocystis sp. PCC6803. PLoS ONE, 9(3), e91484. (doi: 10.1371/journal.pone.0091484) (PMID:24637387) (PMCID:PMC3956611)

Cameron, J. M., Gao, J., Vila-Nadal, L. , Long, D.-L. and Cronin, L. (2014) Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles. Chemical Communications, 50(17), pp. 2155-2157. (doi: 10.1039/C3CC49293A)

Cameron, J. M., Gao, J., Long, D. L. and Cronin, L. (2014) Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates. Inorganic Chemistry Frontiers, 1(2), pp. 178-185. (doi: 10.1039/c3qi00075c)

Bloor, L.G., Molina-Sanchez, P.I., Symes, M. and Cronin, L. (2014) Low pH electrolytic water splitting using earth abundant metastable catalysts that self-assemble in situ. Journal of the American Chemical Society, 136(8), pp. 3304-3311. (doi: 10.1021/ja5003197)

Chisholm, G. , Kitson, P. J., Kirkaldy, N. D., Bloor, L. G. and Cronin, L. (2014) 3D printed flow plates for the electrolysis of water: an economic and adaptable approach to device manufacture. Energy and Environmental Science, 7(9), pp. 3026-3032. (doi: 10.1039/C4EE01426J)

Mathieson, J. S., Cooper, G. J.T. , Symes, M. and Cronin, L. (2014) Quantification of ion binding using electrospray mass spectrometry. Inorganic Chemistry Frontiers, 1, pp. 49-52. (doi: 10.1039/C3QI00037K)

Sans, V., Glatzel, S., Douglas, F. J., MacLaren, D. A. , Lapkin, A. and Cronin, L. (2014) Non-equilibrium dynamic control of gold nanoparticle and hyper-branched nanogold assemblies. Chemical Science, 5(3), pp. 1153-1157. (doi: 10.1039/C3SC53223B)

Zang, H.-Y., Ruiz de la Oliva, A., Miras, H. N. , Long, D.-L. , McBurney, R. T. and Cronin, L. (2014) Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine. Nature Communications, 5, pp. 1-8. (doi: 10.1038/ncomms4715)

Vilà-Nadal, L. , Mitchell, S. G., Markov, S., Busche, C. , Georgiev, V. , Asenov, A. and Cronin, L. (2013) Towards polyoxometalate-cluster-based nano-electronics. Chemistry: A European Journal, 19(49), pp. 16502-16511. (doi: 10.1002/chem.201301631)

Zang, H., Chen, J.-J., Long, D.-L. , Cronin, L. and Miras, H. N. (2013) Assembly of thiometalate-based [Mo16] and [Mo36] composite clusters combining [Mo2O2S2],2+ cations and selenite anions. Advanced Materials, 25(43), pp. 6245-6249. (doi: 10.1002/adma.201302565)

Yvon, C., Macdonell, A., Buchwald, S., Surman, A. , Follet, N., Alex, J., Long, D.L. and Cronin, L. (2013) A collection of robust methodologies for the preparation of asymmetric hybrid Mn–Anderson polyoxometalates for multifunctional materials. Chemical Science, 4(10), pp. 3810-3817. (doi: 10.1039/C3SC51618K)

Chen, W., Ma, D., Yan, J., Boyd, T., Cronin, L. , Long, D.-L. and Song, Y.-F. (2013) 0D to 1D switching of hybrid polyoxometalate assemblies at the nanoscale by using molecular control. ChemPlusChem, 78(10), pp. 1226-1229. (doi: 10.1002/cplu.201300244)

Long, D.L. , Yan, J., Ruiz De La Oliva, A., Busche, C. , Miras, H.N. , Errington, R.J. and Cronin, L. (2013) A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage. Chemical Communications, 49(84), pp. 9731-9733. (doi: 10.1039/c3cc45659e)

Yin, P., Li, T., Forgan, R.S. , Lydon, C., Zuo, X., Zheng, Z.N., Lee, B., Long, D. , Cronin, L. and Liu, T. (2013) Exploring the programmable assembly of a polyoxometalate− organic hybrid via metal ion coordination. Journal of the American Chemical Society, 135(36), pp. 13425-13432. (doi: 10.1021/ja404777g)

Vilà-Nadal, L. , Peuntinger, K., Busche, C. , Yan, J., Lüders, D., Long, D. , Poblet, J.M., Guldi, D.M. and Cronin, L. (2013) Polyoxometalate {W18O56XO6} clusters with embedded redox-active main-group templates as localized inner-cluster radicals. Angewandte Chemie (International Edition), 52(37), pp. 9695-9699. (doi: 10.1002/anie.201303126)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) Exploring time assembly of supramolecular polyoxometalate triangular morphologies with johnson solid cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19−. Inorganic Chemistry, 52(16), pp. 9284-9289. (doi: 10.1021/ic400542x)

Cogdell, R.J. , Gardiner, A.T., Molina-Sanchez, P.I. and Cronin, L. (2013) The use and misuse of photosynthesis in the quest for novel methods to harness solar energy to make fuel. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 371(1996), p. 20110603. (doi: 10.1098/rsta.2011.0603)

Symes, M.D. , Cogdell, R.J. and Cronin, L. (2013) Designing artificial photosynthetic devices using hybrid organic-inorganic modules based on polyoxometalates. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 371(1996), p. 20110411. (doi: 10.1098/rsta.2011.0411)

Kitson, P. J., Symes, M. D. , Dragone, V. and Cronin, L. (2013) Combining 3D printing and liquid handling to produce user-friendly reactionware for chemical synthesis and purification. Chemical Science, 4(8), pp. 3099-3103. (doi: 10.1039/C3SC51253C)

Kato, C., Nishihara, S., Tsunashima, R., Tatewaki, Y., Okada, S., Ren, X.M., Inoue, K., Long, D. and Cronin, L. (2013) Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents. Dalton Transactions, 42, pp. 11363-11366. (doi: 10.1039/c3dt51120k)

Rosnes, M. H., Musumeci, C., Yvon, C., MacDonell, A., Pradeep, C. P., Sartorio, C., Long, D.-L. , Pignataro, B. and Cronin, L. (2013) Exploring the interplay between ligand derivatisation and cation type in the assembly of hybrid polyoxometalate Mn-Andersons. Small, 9(13), pp. 2316-2324. (doi: 10.1002/smll.201202510)

Zang, H.-Y., Miras, H. N. , Long, D. L. , Rausch, B. and Cronin, L. (2013) Template-directed assembly of polyoxothiometalate scaffolds into nanomolecular architectures. Angewandte Chemie (International Edition), 52(27), pp. 6903-6906. (doi: 10.1002/anie.201300578)

Anamimoghadam, O., Symes, M. D. , Busche, C. , Long, D.-L. , Caldwell, S. T. , Flors, C., Nonell, S., Cronin, L. and Bucher, G. (2013) Naphthoxanthenyl, a new stable phenalenyl type radical stabilized by electronic effects. Organic Letters, 15(12), pp. 2970-2973. (doi: 10.1021/ol401117g)

Dragone, V., Sans, V., Rosnes, M. H., Kitson, P. J. and Cronin, L. (2013) 3D-printed devices for continuous-flow organic chemistry. Beilstein Journal of Organic Chemistry, 9, pp. 951-959. (doi: 10.3762/bjoc.9.109) (PMID:23766811) (PMCID:PMC3678713)

Mathieson, J. S., Rosnes, M. H., Sans, V., Kitson, P. J. and Cronin, L. (2013) Continuous parallel ESI-MS analysis of reactions carried out in a bespoke 3D printed device. Beilstein Journal of Nanotechnology, 4, pp. 285-291. (doi: 10.3762/bjnano.4.31) (PMID:23766951) (PMCID:PMC3678396)

Miras, H. N. , Chilas, G. I., Cronin, L. and Kabanos, T. A. (2013) Sulfite anions as structure-directing templates for the engineering of modular polyoxometalates. European Journal of Inorganic Chemistry, 2013(10-11), pp. 1620-1630. (doi: 10.1002/ejic.201201065)

Gabb, D., Pradeep, C. P., Boyd, T., Mitchell, S. G., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) A general route for the transfer of large, highly-charged polyoxometalates from aqueous to organic phase. Polyhedron, 52, pp. 159-164. (doi: 10.1016/j.poly.2012.10.015)

Winter, R.S., Yan, J., Busche, C. , Mathieson, J.S., Prescimone, A., Brechin, E.K., Long, D.L. and Cronin, L. (2013) Nanoscale control of polyoxometalate assembly: a {Mn8W4} cluster within a {W36Si4Mn10} cluster showing a new type of isomerism. Chemistry: A European Journal, 19(9), pp. 2976-2981. (doi: 10.1002/chem.201204345)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2013) One-pot versus sequential reactions in the self-assembly of gigantic nanoscale polyoxotungstates. Journal of the American Chemical Society, 135(5), pp. 1796-1805. (doi: 10.1021/ja309237x)

Cameron, J., Newton, G.N., Busche, C. , Long, D.L. , Oshio, H. and Cronin, L. (2013) Synthesis and characterisation of a lanthanide-capped dodecavanadate cage. Chemical Communications, 49, pp. 3395-3397. (doi: 10.1039/c3cc40912k)

Hutin, M., Yan, J., Yvon, C., MacDonell, A., Long, D.L. and Cronin, L. (2013) Programming the assembly of carboxylic acid-functionalised hybrid polyoxometalates. CrystEngComm, 15(22), pp. 4422-4430. (doi: 10.1039/c3ce26816k)

Rausch, B., Symes, M.D. and Cronin, L. (2013) A bio-inspired, small molecule electron-coupled-proton buffer for decoupling the half-reactions of electrolytic water splitting. Journal of the American Chemical Society, 135(37), pp. 13656-13659. (doi: 10.1021/ja4071893)

Robbins, P.J., Surman, A.J. , Thiel, J., Long, D.L. and Cronin, L. (2013) Use of ion-mobility mass spectrometry (IMS-MS) to map polyoxometalate keplerate clusters and their supramolecular assemblies. Chemical Communications, 49, pp. 1909-1911. (doi: 10.1039/c3cc38615e)

Corella-Ochoa, M.N., Miras, N., Long, D.L. and Cronin, L. (2012) Controlling the self-assembly of a mixed-metal Mo/V-selenite family of polyoxometalates. Chemistry: A European Journal, 18(43), pp. 13743-13754. (doi: 10.1002/chem.201200912)

Xu, F., Miras, H.N. , Scullion, R.A., Long, D.L. , Thiel, J. and Cronin, L. (2012) Correlating the magic numbers of inorganic nanomolecular assemblies with a {Pd84} molecular-ring Rosetta Stone. Proceedings of the National Academy of Sciences of the United States of America, 109(29), pp. 11609-11612. (doi: 10.1073/pnas.1202981109)

Boulay, A. G., Cooper, G. J.T. and Cronin, L. (2012) Morphogenesis of polyoxometalate cluster-based materials to microtubular network architectures. Chemical Communications, 48(42), pp. 5088-5090. (doi: 10.1039/c2cc31194a) (PMID:22513869)

Nemeth, B., Busche, C. , Tsuda, S., Cronin, L. and Cumming, D. R.S. (2012) Imaging the Belousov–Zhabotinsky reaction in real time using an ion sensitive array. Chemical Communications, 48(42), pp. 5085-5087. (doi: 10.1039/C2CC30811H) (PMID:22517276)

Symes, M.D. and Cronin, L. (2012) Patterned metal oxide films for solar energy. Nano Energy, 1(3), pp. 340-341. (doi: 10.1016/j.nanoen.2012.02.002)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2012) Assembly of molecular "layered" heteropolyoxometalate architectures. Angewandte Chemie (International Edition), 51(14), pp. 3373-3376. (doi: 10.1002/anie.201108428)

Nemeth, B., Symes, M. D. , Boulay, A. G., Busche, C. , Cooper, G. J. T. , Cumming, D. R. S. and Cronin, L. (2012) Real-time ion-flux imaging in the growth of micrometer-scale structures and membranes. Advanced Materials, 24(9), pp. 1238-1242. (doi: 10.1002/adma.201104345)

Lydon, C., Busche, C. , Miras, H.N. , Delf, A., Long, D.-L. , Yellowlees, L. and Cronin, L. (2012) Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates. Angewandte Chemie (International Edition), 51(9), pp. 2115-2118. (doi: 10.1002/anie.201105829)

Nemeth, B., Tsuda, S., Busche, C. , Cronin, L. and Cumming, D.R.S. (2012) An ISFET sensor system for real-time detection of extracellular pH oscillations in slime mould. Electronics Letters, 48(3), pp. 144-146. (doi: 10.1049/el.2011.3951)

Quesada Cabrera, R., Firth, S., Blackman, C.S., Long, D.L. , Cronin, L. and McMillan, P.F. (2012) Spectroscopic studies of sulfite-based polyoxometalates at high temperature and high pressure. Journal of Solid State Chemistry, 186, pp. 171-176. (doi: 10.1016/j.jssc.2011.12.005)

Cogdell, R.J. , Gardiner, A.T. and Cronin, L. (2012) Learning from photosynthesis: how to use solar energy to make fuels. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 370(1972), pp. 3819-3826. (doi: 10.1098/rsta.2011.0422)

Cooper, G.J.T. , Bowman, R.W., Magennis, E.P., Fernandez-Trillo, F., Alexander, C., Padgett, M.J. and Cronin, L. (2012) Directed assembly of inorganic polyoxometalate-based micrometer-scale tubular architectures by using optical control. Angewandte Chemie (International Edition), 51(51), pp. 12754-12758. (doi: 10.1002/anie.201204405)

de la Oliva, A.R., Sans Sangorrin, V., Miras, H.N. , Yan, J., Zang, H., Richmond, C.J., Long, D.L. and Cronin, L. (2012) Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system. Angewandte Chemie (International Edition), 51(51), pp. 12759-12762. (doi: 10.1002/anie.201206572)

Fielden, J., Long, D.-L. , Speldrich, M., Kögerler, P. and Cronin, L. (2012) [CoxCu1−x(DDOP)(OH2)(NO3)](NO3): hydrogen bond-driven distortion of cobalt(II) by solid solution ‘network mismatch’. Dalton Transactions, 41(16), pp. 4927-4934. (doi: 10.1039/c2dt11055e)

Gabb, D., Pradeep, C.P., Miras, H.N. , Mitchell, S.G., Long, D.L. and Cronin, L. (2012) Organic-soluble lacunary {M-2(P2W15)(2)} polyoxometalate sandwiches showing a previously unseen alpha beta beta alpha isomerism. Dalton Transactions, 41(33), pp. 10000-10005. (doi: 10.1039/C2DT30616F)

Kitson, P. J., Rosnes, M. H., Sans, V., Dragone, V. and Cronin, L. (2012) Configurable 3D-printed millifluidic and microfluidic ‘lab on a chip’ reactionware devices. Lab on a Chip, 12(18), pp. 3267-3271. (doi: 10.1039/C2LC40761B) (PMID:22875258)

Li, F., Long, D.L. , Cameron, J.M., Miras, H.N. , Pradeep, C., Xu, L. and Cronin, L. (2012) Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV). Dalton Transactions, 41(33), pp. 9859-9862. (doi: 10.1039/C2DT30627A)

Long, D.L. and Cronin, L. (2012) Pushing the frontiers in polyoxometalate and metal oxide cluster science. Dalton Transactions, 41(33), pp. 9815-9816. (doi: 10.1039/c2dt90121h)

Lydon, C., Sabi, M.M., Symes, M.D. , Long, D.L. , Murrie, M. , Yoshii, S., Nojiri, H. and Cronin, L. (2012) Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates. Chemical Communications, 48(79), pp. 9819-9821. (doi: 10.1039/c2cc34865a)

McGlone, T., Thiel, J., Streb, C., Long, D.L. and Cronin, L. (2012) An unprecedented silver-decavanadate dimer investigated using ion-mobility mass spectrometry. Chemical Communications, 48(3), pp. 359-361. (doi: 10.1039/c1cc15879a)

Miras, H.N. , Richmond, C.J., Long, D.-L. and Cronin, L. (2012) Solution-phase monitoring of the structural evolution of a molybdenum blue nanoring. Journal of the American Chemical Society, 134(8), pp. 3816-3824. (doi: 10.1021/ja210206z)

Miras, H.N. , Sorus, M., Hawkett, J., Sells, D.O., McInnes, E.L. and Cronin, L. (2012) Oscillatory template exchange in polyoxometalate capsules: a ligand-triggered, redox-powered, chemically damped oscillation. Journal of the American Chemical Society, 134(16), pp. 6980-6983. (doi: 10.1021/ja302861z)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Engineering polyoxometalates with emergent properties. Chemical Society Reviews, 41(22), pp. 7403-7430. (doi: 10.1039/C2CS35190K)

Richmond, C.J. et al. (2012) A flow-system array for the discovery and scale up of inorganic clusters. Nature Chemistry, 4(12), pp. 1038-1044. (doi: 10.1038/nchem.1489)

Rosnes, M.H., Yvon, C., Long, D.L. and Cronin, L. (2012) Mapping the synthesis of low nuclearity polyoxometalates from octamolybdates to Mn-Anderson clusters. Dalton Transactions, 41, pp. 10071-10079. (doi: 10.1039/c2dt31008b)

Symes, M.D. , Kitson, P.J., Yan, J., Richmond, C., Cooper, G.J.T. , Bowman, R.W., Vilbrandt, T. and Cronin, L. (2012) Integrated 3D-printed reactionware for chemical synthesis and analysis. Nature Chemistry, 4, pp. 349-354. (doi: 10.1038/nchem.1313)

Symes, M.D., Kitson, P.J., Yan, J., Richmond, C.J., Cooper, G.J.T., Bowman, R.W., Vilbrandt, T. and Cronin, L. (2012) Integrated 3D-printed reactionware for chemical synthesis and analysis. Nature Chemistry, 4, pp. 349-354. (doi: 10.1038/nchem.1313)

Thiel, J., Molina-Sanchez, P.I., Symes, M.D. and Cronin, L. (2012) Insights into the self-assembly mechanism of the modular polyoxometalate "Keggin-Net" family of framework materials and their electronic properties. Crystal Growth and Design, 12(2), pp. 902-908. (doi: 10.1021/cg201342z)

Vilá-Nadal, L. , Mitchell, S.G., Long, D.L. , Rodríguez-Fortea, A., López, X., Poblet, J.M. and Cronin, L. (2012) Exploring the rotational isomerism in non-classical Wells–Dawson anions {W18X}:: a combined theoretical and mass spectrometry study. Dalton Transactions, 41(8), pp. 2264-2271. (doi: 10.1039/c2dt11919f)

Zang, H., Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Assembly and autochirogenesis of a chiral inorganic polythioanion Mobius strip via symmetry breaking. Journal of the American Chemical Society, 134(28), pp. 11376-11379. (doi: 10.1021/ja304371j)

Miras, H.N. , Zang, H.Y., Long, D.L. and Cronin, L. (2011) Direct synthesis and mass spectroscopic observation of the {M40} polyoxothiometalate wheel. European Journal of Inorganic Chemistry, 2011(33), pp. 5105-5111. (doi: 10.1002/ejic.201100833)

Cooper, G.J.T. , Kitson, P.J., Winter, R., Zagnoni, M., Long, D.L. and Cronin, L. (2011) Modular redox-active inorganic chemical cells: iCHELLs. Angewandte Chemie (International Edition), 50(44), pp. 10373-10376. (doi: 10.1002/anie.201105068)

Boyd, T., Mitchell, S.G., Gabb, D., Long, D.L. and Cronin, L. (2011) Investigating cation binding in the polyoxometalate-super-crown [P8W48O184]40−. Chemistry: A European Journal, 17(43), pp. 12010-12014. (doi: 10.1002/chem.201101666)

Prat, I., Mathieson, J.S., Güell, M., Ribas, X., Luis, J.M., Cronin, L. and Costas, M. (2011) Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions. Nature Chemistry, 3(10), pp. 788-793. (doi: 10.1038/NCHEM.1132)

Mitchell, S. G. et al. (2011) A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands. Angewandte Chemie (International Edition), 50(39), pp. 9154-9157. (doi: 10.1002/anie.201102727)

Corella-Ochoa, M.N., Miras, H.N. , Kidd, A., Long, D.L. and Cronin, L. (2011) Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}. Chemical Communications, 47(31), pp. 8799-8801. (doi: 10.1002/chin.201143020)

Misdrahi, M.F., Wang, M.H., Pradeep, C.P., Li, F.Y., Lydon, C., Xu, L., Cronin, L. and Liu, T.B. (2011) Amphiphilic properties of dumbbell-shaped inorganic–organic–inorganic molecular hybrid materials in solution and at an interface. Langmuir, 27(15), pp. 9193-9202. (doi: 10.1021/la2013914)

Akutagawa, T., Kudo, F., Tsunashima, R., Noro, S., Cronin, L. and Nakamura, T. (2011) Hydrogen-bonded assemblies of two-electron reduced mixed-valence [XMo12O40] (X = P and Si) with p-phenylenediamines. Inorganic Chemistry, 50(14), pp. 6711-6718. (doi: 10.1021/ic200683e)

Song, Y.-F., Long, D.-L. , Ritchie, C. and Cronin, L. (2011) Nanoscale polyoxometalate-based inorganic/organic hybrids. Chemical Record, 11(3), pp. 158-171. (doi: 10.1002/tcr.201100002) (PMID:21594969)

Wilson, E.F., Miras, H.N. , Rosnes, M.H. and Cronin, L. (2011) Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry. Angewandte Chemie (International Edition), 50(16), pp. 3720-3724. (doi: 10.1002/anie.201006938)

Cronin, L. (2011) Defining new architectural design principles with 'living' inorganic materials. Architectural Design, 81(2), pp. 34-43. (doi: 10.1002/ad.1210)

Walsh, J.J., Long, D.L. , Cronin, L. , Bond, A.M., Forster, R.J. and Keyes, T.E. (2011) Electronic and photophysical properties of adducts of [Ru(bpy)3]2+ and Dawson-type sulfite polyoxomolybdates α/β-[Mo18O54(SO3)2]4−. Dalton Transactions, 40(9), pp. 2038-2045. (doi: 10.1039/C0DT01540G)

Mitchell, S.G., Boyd, T., Miras, H.N. , Long, D.L. and Cronin, L. (2011) Extended polyoxometalate framework solids: two MnII-linked {P8W48} network arrays. Inorganic Chemistry, 50(1), pp. 136-143. (doi: 10.1021/ic101472s)

Cooper, G.T.J. , Boulay, A.G., Kitson, P.J., Ritchie, C., Richmond, C.J., Thiel, J., Gabb, D., Eadie, R., Long, D.L. and Cronin, L. (2011) Osmotically driven crystal morphogenesis: a general approach to the fabrication of micrometer-scale tubular architectures based on polyoxometalates. Journal of the American Chemical Society, 133(15), pp. 5947-5954. (doi: 10.1021/ja111011j)

Cronin, L. , Molina, P.I. and Miras, H.N. (2011) Polyoxometalate-based solar cells for water splitting. Proceedings of the SPIE: The International Society for Optical Engineering, 8109, 81090C. (doi: 10.1117/12.895296)

Gao, J., Yan, J., Mitchell, S.G., Miras, H.N. , Boulay, A.G., Long, D.L. and Cronin, L. (2011) Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties. Chemical Science, 2(8), pp. 1502-1508. (doi: 10.1039/C1SC00150G)

Hutin, M., Long, D.L. and Cronin, L. (2011) Controlling the molecular assembly of polyoxometalates from the nano to the micron scale: molecules to materials. Israel Journal of Chemistry, 51(2), pp. 205-214. (doi: 10.1002/ijch.201100008)

McGlone, T., Streb, C., Busquets-Fite, M., Yan, J., Gabb, D., Long, D.L. and Cronin, L. (2011) Silver linked polyoxometalate open frameworks (Ag-POMOFs) for the directed fabrication of silver nanomaterials. Crystal Growth and Design, 11(6), pp. 2471-2478. (doi: 10.1021/cg2002496)

Miras, H.N. , Stone, D., Long, D.L. , McInnes, E.J.L., Kögerler, P. and Cronin, L. (2011) Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorganic Chemistry, 50(17), pp. 8384-8391. (doi: 10.1021/ic200943s)

Musumeci, C., Luzio, A., Pradeep, C.P., Miras, H.N. , Rosnes, M.H., Song, Y.-F., Long, D.L. , Cronin, L. and Pignataro, B. (2011) Programmable surface architectures derived from hybrid polyoxometalate-based clusters. Journal of Physical Chemistry C, 115(11), pp. 4446-4455. (doi: 10.1021/jp109916e)

Musumeci, C., Rosnes, M.H., Giannazzo, F., Symes, M.D. , Cronin, L. and Pignataro, B. (2011) Smart high-κ nanodielectrics using solid supported polyoxometalate-rich nanostructures. ACS Nano, 5(12), pp. 9992-9999. (doi: 10.1021/nn2037797)

Pradeep, C.P., Li, F.-Y., Lydon, C., Miras, H.N. , Long, D.L. , Xu, L. and Cronin, L. (2011) Design and synthesis of "dumb-bell" and "triangular" inorganic-organic hybrid nanopolyoxometalate clusters and their characterisation through ESI-MS analyses. Chemistry: A European Journal, 17(27), pp. 7472-7479. (doi: 10.1002/chem.201100257)

Symes, M.D. and Cronin, L. (2011) The crystal computer - computing with inorganic cellular frameworks and nets. International Journal of Nanotechnology and Molecular Computation, 3(1), pp. 24-34. (doi: 10.4018/jnmc.2011010103)

Thiel, J., Yang, D., Rosnes, M.H., Liu, X., Yvon, C., Kelly, S.E., Song, Y.F., Long, D.L. and Cronin, L. (2011) Observing the hierarchical self-assembly and architectural bistability of hybrid molecular metal oxides using ion-mobility mass spectrometry. Angewandte Chemie (International Edition), 50(38), pp. 8871-8875. (doi: 10.1002/anie.201102340)

Vila-Nadal, L. , Wilson, E.F., Miras, H.N. , Rodriguez-Fortea, A., Cronin, L. and Poblet, J.M. (2011) Combined theoretical and mass spectrometry study of the formation-fragmentation of small polyoxomolybdates. Inorganic Chemistry, 50(16), pp. 7811-7819. (doi: 10.1021/ic200969h)

Vilà-Nadal, L. , Mitchell, S.G., Rodríguez-Fortea, A., Miras, H.N. , Cronin, L. and Poblet, J.M. (2011) Connecting theory with experiment to understand the initial nucleation steps of heteropolyoxometalate clusters. Physical Chemistry Chemical Physics, 13(45), pp. 20136-20145. (doi: 10.1039/c1cp21209e)

Xu, F., Scullion, R.A., Yan, J., Miras, H.N. , Busche, C. , Scandurra, A., Pignataro, B., Long, D.-L. and Cronin, L. (2011) A supramolecular heteropolyoxopalladate {Pd15} cluster host encapsulating a {Pd2} dinuclear guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−. Journal of the American Chemical Society, 133(13), pp. 4684-4686. (doi: 10.1021/ja1105514)

Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core. Inorganica Chimica Acta, 363(15), pp. 4240-4246. (doi: 10.1016/j.ica.2010.07.020)

Pradeep, C. P., Long, D.-L. and Cronin, L. (2010) Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly. Dalton Transactions, 39(40), p. 9443. (doi: 10.1039/C0DT00325E) (PMID:20721370)

Rosnes, M.H., Musumeci, C., Pradeep, C.P., Mathieson, J.S., Long, D.L. , Song, Y.-F., Pignataro, B., Cogdell, R.J. and Cronin, L. (2010) Assembly of modular asymmetric organic-inorganic polyoxometalate hybrids into anisotropic nanostructures. Journal of the American Chemical Society, 132(44), pp. 15490-15492. (doi: 10.1021/ja1066338)

Ivanov, N.B., Schnack, J., Schnalle, R., Richter, J., Kogerler, P., Newton, G., Cronin, L. , Oshima, Y. and Nojiri, H. (2010) Heat capacity reveals the physics of a frustrated spin tube. Physical Review Letters, 105(3), 037206. (doi: 10.1103/PhysRevLett.105.037206)

Long, D.-L., Tsunashima, R. and Cronin, L. (2010) Polyoxometalates: building blocks for functional nanoscale systems. Angewandte Chemie (International Edition), 49(10), pp. 1736-1758. (doi: 10.1002/anie.200902483)

Miras, H.N. , Cooper, G.J.T., Long, D.-L., Bogge, H., Muller, A., Streb, C. and Cronin, L. (2010) Unveiling the transient template in the self-assembly of a molecular oxide nanowheel. Science, 327(5961), pp. 72-74. (doi: 10.1126/science.1181735)

Boyd, T., Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) Understanding and mapping the assembly of a family of trimeric polyoxometalates: transition metal mediated Wells-Dawson (M-18)-trimers. Dalton Transactions, 39(28), pp. 6460-6465. (doi: 10.1039/C002633F)

Cabrera, R.Q., Long, D.-L. , Cronin, L. and McMillan, P.F. (2010) In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions. CrystEngComm, 12(9), pp. 2568-2572. (doi: 10.1039/C003388J)

Cogdell, R.J. , Brotosudarmo, T.H.P., Gardiner, A.T., Sanchez, P.M. and Cronin, L. (2010) Artificial photosynthesis – solar fuels: current status and future prospects. Biofuels, 1(6), pp. 861-876. (doi: 10.4155/bfs.10.62)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2010) Assembly of Pure Silver-Tungsten-Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component. Advanced Materials, 22(38), pp. 4275-4279. (doi: 10.1002/adma.201001398)

McGlone, T., Vilà-Nadal, L. , Miras, H.N. , Long, D.L. , Poblet, J.M. and Cronin, L. (2010) Assembly of titanium embedded polyoxometalates with unprecedented structural features. Dalton Transactions, 39(48), pp. 11599-11604. (doi: 10.1039/c0dt01327g)

Miras, H.N. , Ochoa, M.N.C., Long, D.L. and Cronin, L. (2010) Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}. Chemical Communications, 46(43), pp. 8148-8150. (doi: 10.1039/C0CC02849E)

Mitchell, S.G., Streb, C., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2010) Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture. Nature Chemistry, 2(4), pp. 308-312. (doi: 10.1038/NCHEM.581)

Ochoa, M.N.C., Cooper, G.J.T. , Newton, G.N., Long, D.L. , Seeber, G. and Cronin, L. (2010) Supramolecular Architectures of Copper(II) Perchlorate Complexes of cis,trans-1,3,5-Triaminocyclohexane Assembled Exploiting the Delicate Balance Between Weak and Strong Interactions. Zeitschrift für Naturforschung B - A Journal of Chemical Sciences, 65(3), pp. 304-310.

Pasparakis, G., Krasnogor, N., Cronin, L. , Davis, B. G. and Alexander, C. (2010) Controlled polymer synthesis-from biomimicry towards synthetic biology. Chemical Society Reviews, 39(1), pp. 286-300. (doi: 10.1039/b809333b)

Seeber, G., Cooper, G. J. T. , Newton, G. N., Rosnes, M. H., Long, D. L. , Kariuki, B. M., Kogerler, P. and Cronin, L. (2010) Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry. Chemical Science, 1(1), pp. 62-67. (doi: 10.1039/c0sc00264j)

Shiga, T., Newton, G. N., Mathieson, J. S., Tetsuka, T., Nihei, M., Cronin, L. and Oshio, H. (2010) Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages. Dalton Transactions, 39(20), pp. 4730-4733. (doi: 10.1039/b925399h)

Song, Y. -F., Long, D. L. and Cronin, L. (2010) Hybrid polyoxometalate clusters with appended aromatic platforms. CrystEngComm, 12(1), pp. 109-115. (doi: 10.1039/b910434h)

Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi: 10.1002/anie.201002672)

Tsunashima, R., Long, D.L. , Miras, H.N. , Gabb, D., Pradeep, C.P. and Cronin, L. (2010) The construction of high-nuclearity isopolyoxoniobates with pentagonal building blocks: [HNb27O76](16-) and [H10Nb31O93(CO3)](23-). Angewandte Chemie (International Edition), 49(1), pp. 113-116. (doi: 10.1002/anie.200903970)

Yan, J., Gao, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Self-assembly of a nanosized, saddle-shaped, solution-stable polyoxometalate anion built from pentagonal building blocks: [H34W119Se8Fe2O420](54-). Journal of the American Chemical Society, 132(33), pp. 11410-11411. (doi: 10.1021/ja104043s)

Yan, J., Long, D. L. and Cronin, L. (2010) Development of a Building Block Strategy To Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO32- as a Template Linker. Angewandte Chemie (International Edition), 49(24), pp. 4117-4120. (doi: 10.1002/anie.201000076)

Yan, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Cation controlled assembly and transformation of mono- and bi-sulfite templated dawson-type polyoxotungstates. Inorganic Chemistry, 49(4), pp. 1819-1825. (doi: 10.1021/ic9021646)

Zhang, J., Song, Y.-F., Cronin, L. and Liu, T. (2010) Reverse-Vesicle Formation of Organic-Inorganic Polyoxometalate-Containing Hybrid Surfactants with Tunable Sizes. Chemistry: A European Journal, 16(37), pp. 11320-11324. (doi: 10.1002/chem.201000794)

Pradeep, P.C., Misdrahi, M.F., Li, F.Y., Zhang, J., Xu, L., Long, D.L. , Liu, T. and Cronin, L. (2009) Synthesis of modular “inorganic-organic-inorganic” polyoxometalates and their assembly into vesicles. Angewandte Chemie (International Edition), 48(44), pp. 8309-8313. (doi: 10.1002/anie.200903070)

Streb, C., Tsunashima, R., MacLaren, D.A. , McGlone, T., Akutagawa, T., Nakamura, T., Scandurra, A., Pignataro, B., Gadegaard, N. and Cronin, L. (2009) Supramolecular silver polyoxometalate architectures direct the growth of composite semiconducting nanostructures. Angewandte Chemie (International Edition), 48(35), pp. 6490-6493. (doi: 10.1002/anie.200901650)

Kitson, P. J., Parenty, A. D. C., Richmond, C. J., Long, D. L. and Cronin, L. (2009) A new C-C bond forming annulation reaction leading to pH switchable heterocycles. Chemical Communications(27), pp. 4067-4069. (doi: 10.1039/b905383b)

Mitchell, S.G., Khanra, S., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2009) The trinity of polyoxometalates: connecting {M-12} Keggin and {M-18} Dawson clusters to triangles. Chemical Communications(19), pp. 2712-2714. (doi: 10.1039/b903206a)

Thiel, J., Ritchie, C., Streb, C., Long, D. L. and Cronin, L. (2009) Heteroatom-controlled kinetics of switchable polyoxometalate frameworks. Journal of the American Chemical Society, 131(12), pp. 4180-4181. (doi: 10.1021/ja809422k)

Miras, H.N. , Wilson, E.F. and Cronin, L. (2009) Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry. Chemical Communications(11), pp. 1297-1311. (doi: 10.1039/b819534j)

Brechin, E. K. and Cronin, L. (2009) The Marriage of Inorganic and Organic Building Blocks for the Assembly of Rotaxanes. Angewandte Chemie (International Edition), 48(38), pp. 6948-6949. (doi: 10.1002/anie.200902228)

Cooper, G. J. T. and Cronin, L. (2009) How to sweet-talk bacteria. Nature Chemistry, 1(5), pp. 342-343. (doi: 10.1038/nchem.306)

Cooper, G. J. T. and Cronin, L. (2009) Real-time direction control of self fabricating polyoxometalate-based microtubes. Journal of the American Chemical Society, 131(24), pp. 8368-8369. (doi: 10.1021/ja902684b)

Cooper, G. J.T. , Newton, G. N., Long, D.-L. , Kogerler, P., Rosnes, M. H., Keller, M. and Cronin, L. (2009) Exploring a series of isostructural dodecanuclear mixed ni:co clusters: toward the control of elemental composition using ph and stoichiometry. Inorganic Chemistry, 48(3), pp. 1097-1104. (doi: 10.1021/ic802197u)

Fielden, J., Long, D. L. , Cronin, L. and Kogerler, P. (2009) Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. Polyhedron, 28(13), pp. 2803-2807. (doi: 10.1016/j.poly.2009.05.058)

Goral, M., McCormac, T., Dempsey, E., Long, D. L. , Cronin, L. and Bond, A. M. (2009) Voltammetry of [R4N](4)[M18O54(SO3)(2)] and [Ru(bpy)(3)](2)[M18O54(SO3)(2)] (M = Mo, W) as microcrystals adhered to a glassy carbon electrode surface in contact with ionic liquid media. Dalton Transactions(34), pp. 6727-6735. (doi: 10.1039/b822167g)

Imai, H., Akutagawa, T., Kudo, F., Ito, M., Toyoda, K., Noro, S., Cronin, L. and Nakamura, T. (2009) Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo-176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)(80)]Cl-27 center dot 450H(2)O. Journal of the American Chemical Society, 131(38), 13578-+. (doi: 10.1021/ja9048042)

Mathieson, J.S., Cooper, G.J.T. , Pickering, A.L., Keller, M., Long, D.L. , Newton, G.N. and Cronin, L. (2009) Monitoring the Formation of Coordination Complexes Using Electrospray Mass Spectrometry. Chemistry: An Asian Journal, 4(5), pp. 681-687. (doi: 10.1002/asia.200900007)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2009) Guest-Directed Supramolecular Architectures of {W-36} Polyoxometalate Crowns. Chemistry: An Asian Journal, 4(10), pp. 1612-1618. (doi: 10.1002/asia.200900242)

Mitchell, S. G., Gabb, D., Ritchie, C., Hazel, N., Long, D. L. and Cronin, L. (2009) Controlling nucleation of the cyclic heteropolyanion {P8W48}: a cobalt-substituted phosphotungstate chain and network. CrystEngComm, 11(1), pp. 36-39. (doi: 10.1039/b813066c)

Newton, G. N., Cooper, G. J. T. , Schuch, D., Shiga, T., Khanra, S., Long, D. L. , Oshio, H. and Cronin, L. (2009) cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe-III and Pd-II coordination clusters. Dalton Transactions(9), pp. 1549-1553. (doi: 10.1039/b815200d)

Noro, S., Tsunashima, R., Kamiya, Y., Uemura, K., Kita, H., Cronin, L. , Akutagawa, T. and Nakamura, T. (2009) Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster. Angewandte Chemie (International Edition), 48(46), pp. 8703-8706. (doi: 10.1002/anie.200903142)

Richmond, C. J., Eadie, R. M., Parenty, A. D. C. and Cronin, L. (2009) Fine Tuning Reactivity: Synthesis and Isolation of 1,2,3,12b-Tetrahydroimidazo[1,2-f]phenanthridines. Journal of Organic Chemistry, 74(21), pp. 8196-8202. (doi: 10.1021/jo901622e)

Ritchie, C., Boyd, T., Long, D. L. , Ditzel, E. and Cronin, L. (2009) Grafting ligands to direct the self-assembly of Co/Ni2+ substituted polyoxometalate clusters. Dalton Transactions(9), pp. 1587-1592. (doi: 10.1039/b814076f)

Ritchie, C., Cooper, G.J.T. , Song, Y.F., Streb, C., Yin, H.B. , Parenty, A.D.C., MacLaren, D.A. and Cronin, L. (2009) Spontaneous assembly and real-time growth of micrometre-scale tubular structures from polyoxometalate-based inorganic solids. Nature Chemistry, 1(1), pp. 47-52. (doi: 10.1038/nchem.113)

Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L. , Xu, L. and Cronin, L. (2009) A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)(2)Co2Na2(H2O)(2)](18-). Dalton Transactions(33), pp. 6483-6486. (doi: 10.1039/b907410d)

Song, Y.F., McMillan, N., Long, D.L. , Kane, S., Malm, J., Riehle, M. , Pradeep, C.P., Gadegaard, N. and Cronin, L. (2009) Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-Hybrid Clusters Lead to Selective Cell Adhesion. Journal of the American Chemical Society, 131(4), pp. 1340-1341. (doi: 10.1021/ja807091v)

Vilá-Nadal, L. , Rodriguez-Fortea, A., Yan, L.K., Wilson, E.F., Cronin, L. and Poblet, J.M. (2009) Nucleation mechanisms of molecular oxides: a study of the assembly-dissassembly of [W6O19]2- by theory and mass spectrometry. Angewandte Chemie (International Edition), 48(30), pp. 5452-5456. (doi: 10.1002/anie.200901348)

Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi: 10.1002/anie.200806343)

Zhang, J., Song, Y.-F., Cronin, L. and Liu, T. (2008) Self-Assembly of Organic-Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups. Journal of the American Chemical Society, 130(44), p. 14408. (doi: 10.1021/ja805644a)

Fleming, C., Long, D. L. , McMillan, N., Johnston, J., Bovet, N., Dhanak, V., Gadegaard, N. , Kogerler, P., Cronin, L. and Kadodwala, M. (2008) Reversible electron-transfer reactions within a nanoscale metal oxide cage mediated by metallic substrates. Nature Nanotechnology, 3(4), pp. 229-233. (doi: 10.1038/nnano.2008.66)

Song, Y.-F., McMillan, N., Long, D.-L. , Thiel, J., Ding, Y., Chen, H., Gadegaard, N. and Cronin, L. (2008) Design of hydrophobic polyoxometalate hybrid assemblies beyond surfactant encapsulation. Chemistry: A European Journal, 14(8), pp. 2349-2354. (doi: 10.1002/chem.200701629)

Abbas, H., Streb, C., Pickering, A. L., Neil, A. R., Long, D. L. and Cronin, L. (2008) Molecular growth of polyoxometalate Architectures based on [-Ag{Mo-8}Ag-] synthons: Toward designed cluster assemblies. Crystal Growth and Design, 8(2), pp. 635-642. (doi: 10.1021/cg700736v)

Akutagawa, T., Endo, D., Kudo, F., Noro, S. I., Takeda, S., Cronin, L. and Nakamura, T. (2008) A solid-state supramolecular rotator assembled front a Cs-crown ether polyoxometalate hybrid: (Cs+)(3)([18]crown-6)(3)(H+)(2)[PMo12O40]. Crystal Growth and Design, 8(3), pp. 812-816. (doi: 10.1021/cg060951+)

Akutagawa, T., Jin, R., Tunashima, R., Noro, S., Cronin, L. and Nakamura, T. (2008) Nanoscale assemblies of gigantic molecular {Mo-154}-rings: (Dimethyldioctadecylammonium)(20)[Mo154O462H8(H2O)(70)]. Langmuir, 24(1), pp. 231-238. (doi: 10.1021/la701364k)

Kitson, P. J., Song, Y. -F., Gamez, P., de Hoog, P., Long, D. L. , Parenty, A. D. C., Reedijk, J. and Cronin, L. (2008) Metal-mediated transformation of a triazinephenanthridinium ligand leading to a {Pd-5} coordination complex observed crystallographically and by cryospray mass Spectrometry. Inorganic Chemistry, 47(6), pp. 1883-1885. (doi: 10.1021/ic7022192)

Long, D.L. , Song, Y.-F., Wilson, E.F., Kogerler, P., Guo, S.X., Bond, A.M., Hargreaves, J.S.J. and Cronin, L. (2008) Capture of periodate in a {W18O54} cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)](6-) embedded with high-valent iodine. Angewandte Chemie (International Edition), 47(23), pp. 4384-4387. (doi: 10.1002/anie.200800041)

Long, D.L. , Streb, C., Song, Y.-F., Mitchell, S. and Cronin, L. (2008) Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion. Journal of the American Chemical Society, 130(6), 1830-+. (doi: 10.1021/ja075940z)

Miras, H.N. , Long, D.L. , Kogerler, P. and Cronin, L. (2008) Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties. Dalton Transactions(2), pp. 214-221. (doi: 10.1039/b714285d)

Miras, H.N. , Stone, D.J., McInnes, E.J.L., Raptis, R.G., Baran, P., Chilas, G.I., Sigalas, M.P., Kabanos, T.A. and Cronin, L. (2008) Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-). Chemical Communications(39), pp. 4703-4705. (doi: 10.1039/B811279G)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2008) Structural evolution of "S"-shaped [H4W22O74](12-) and ""-shaped [H10W34O116](18-) isopolyoxotungstate clusters. Angewandte Chemie (International Edition), 47(44), pp. 8420-8423. (doi: 10.1002/anie.200802109)

Mitchell, S. G., Ritchie, C., Long, D.L. and Cronin, L. (2008) Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control. Dalton Transactions(11), pp. 1415-1417. (doi: 10.1039/b715885h)

Newton, G.N., Cooper, G.J.T. , Kogerler, P., Long, D.L. and Cronin, L. (2008) Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters. Journal of the American Chemical Society, 130(3), pp. 790-791. (doi: 10.1021/ja0768183)

Parenty, A. D. C. and Cronin, L. (2008) One-pot synthesis of dihydroimidazo- and imidazophenanthridinium salts. Synthesis(1), pp. 155-160. (doi: 10.1055/s-2007-983895)

Parenty, A. D. C. and Cronin, L. (2008) One-pot synthesis of imidazopyridine derivatives. Synthesis(9), pp. 1479-1485. (doi: 10.1055/s-2007-1000936)

Pradeep, C. P., Long, D. L. , Newton, G. N., Song, Y. -F. and Cronin, L. (2008) Supramolecular metal oxides: Programmed hierarchical assembly of a protein-sized 21 kDa [(C16H36N)(19){H2NC(CH2O)(3)P2V3W15O59}(4)](5-) polyoxometalate assembly. Angewandte Chemie (International Edition), 47(23), pp. 4388-4391. (doi: 10.1002/anie.200800431)

Pradeep, C. P., Long, D. L. , Streb, C. and Cronin, L. (2008) "Bottom-Up" Meets "Top-Down" Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P4W52O178](24-) and Disassembly to [P3W39O134](19-). Journal of the American Chemical Society, 130(45), p. 14946. (doi: 10.1021/ja806596j)

Rancan, M., Newton, G. N., Muryn, C. A., Pritchard, R. G., Timco, G. A., Cronin, L. and Winpenny, R. E. P. (2008) Chemistry and supramolecular chemistry of chromium horseshoes. Chemical Communications(13), pp. 1560-1562. (doi: 10.1039/b718282a)

Richmond, C. J., Parenty, A. D. C., Song, Y. -F., Cooke, G. and Cronin, L. (2008) Realization of a "Lockable" molecular switch via pH- and redox-modulated cyclization. Journal of the American Chemical Society, 130(39), pp. 13059-13065. (doi: 10.1021/ja803338m)

Ritchie, C. et al. (2008) Polyoxometalate-mediated self-assembly of single-molecule magnets: {[XW9O34](2)[(Mn4Mn2O4)-Mn-III-O-II(H2O)(4)]}(12-). Angewandte Chemie (International Edition), 47(30), pp. 5609-5612. (doi: 10.1002/anie.200801281)

Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N. , Long, D.L. , Boyd, T., Peacock, R.D., McGlone, T. and Cronin, L. (2008) Reversible redox reactions in an extended polyoxometalate framework solid. Angewandte Chemie (International Edition), 47(36), pp. 6881-6884. (doi: 10.1002/anie.200802594)

Song, Y. -F., Long, D. L. , Kelly, S. E. and Cronin, L. (2008) Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry. Inorganic Chemistry, 47(20), pp. 9137-9139. (doi: 10.1021/ic801366r)

Song, Y.-F. and Cronin, L. (2008) Postsynthetic covalent modification of metal-organic framework (MOF) materials. Angewandte Chemie (International Edition), 47(25), pp. 4635-4637. (doi: 10.1002/anie.200801631)

Song, Y.F., Kitson, P.J., Long, D.L. , Parenty, A.D.C., Thatcher, R.J. and Cronin, L. (2008) Supramolecular self-assembly and anion-dependence of copper(II) complexes with cationic dihydro-imidazo phenanthridinium (DIP)-containing ligands. CrystEngComm, 10(9), pp. 1243-1251. (doi: 10.1039/b802541j)

Streb, C., McGlone, T., Brucher, O., Long, D. L. and Cronin, L. (2008) Hybrid Host-Guest Complexes: Directing the Supramolecular Structure through Secondary Host-Guest Interactions. Chemistry: A European Journal, 14(29), pp. 8861-8868. (doi: 10.1002/chem.200801247)

Wilson, E. F., Abbas, H., Duncombe, B. J., Streb, C., Long, D. L. and Cronin, L. (2008) Probing the self-assembly of inorganic cluster architectures in solution with cryospray mass spectrometry: Growth of polyoxomolybdate clusters and polymers mediated by silver(I) ions. Journal of the American Chemical Society, 130(42), pp. 13876-13884. (doi: 10.1021/ja802514q)

Akutagawa, T., Endo, D., Noro, S.I., Cronin, L. and Nakamura, T. (2007) Directing organic–inorganic hybrid molecular-assemblies of polyoxometalate crown-ether complexes with supramolecular cations. Coordination Chemistry Reviews, 251(21-24), pp. 2547-2561. (doi: 10.1016/j.ccr.2007.08.015)

Streb, C., Ritchie, C., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported AgIAgI interactions. Angewandte Chemie (International Edition), 46(40), pp. 7579-7582. (doi: 10.1002/anie.200702698)

Parenty, A.D.C., Song, Y.-F., Richmond, C.J. and Cronin, L. (2007) A general and efficient five-step one-pot procedure leading to nitrogen-bridgehead heterocycles containing an imidazole ring. Organic Letters, 9(12), pp. 2253-2256. (doi: 10.1021/ol070263z)

Long, D.L. , Burkholder, E. and Cronin, L. (2007) Polyoxometalate clusters, nanostructures and materials: from self-assembly to designer materials and devices. ChemInform, 38(15), (doi: 10.1002/chin.200715223)

Song, Y.F., Long, D.L. and Cronin, L. (2007) Noncovalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate-pyrene hybrid. Angewandte Chemie (International Edition), 46(21), pp. 3900-3904. (doi: 10.1002/anie.200604734)

Fay, N., Bond, A.M., Baffert, C., Boas, J.F., Pilbrow, J.R., Long, D.-L. and Cronin, L. (2007) Structural, electrochemical, and spectroscopic characterization of a redox pair of sulfite-based polyoxotungstates: α-[W18O54(SO3)2]4- and α-[W18O54(SO3)2]5-. Inorganic Chemistry, 46(9), pp. 3502-3510. (doi: 10.1021/ic062067e)

Guthrie, K.M., Parenty, A.D.C., Smith, L.V., Cronin, L. and Cooper, A. (2007) Microcalorimetry of interaction of dihydro-imidazo-phenanthridinium (DIP)-based compounds with duplex DNA. Biophysical Chemistry, 126(1-3), pp. 117-123. (doi: 10.1016/j.bpc.2006.05.006)

Akutagawa, T., Endo, D., Noro, S. I., Cronin, L. and Nakamura, T. (2007) Directing organic-inorganic hybrid molecular-assemblies of polyoxometalate crown-ether complexes with supramolecular cations. Coordination Chemistry Reviews, 251(21-24), pp. 2547-2561. (doi: 10.1016/j.ccr.2007.08.015)

Baffert, C., Feldberg, S.W., Bond, A.M., Long, D.L. and Cronin, L. (2007) pH-Dependence of the aqueous electrochemistry of the two-electron reduced alpha-[Mo18O54(SO3)] sulfite Dawson-like polyoxometalate anion derived from its triethanolammonium salt. Dalton Transactions, pp. 4599-4607. (doi: 10.1039/b705991d)

Cooper, G.J.T. , Newton, G.N., Kogerler, P., Long, D.L. , Engelhardt, L., Luban, M. and Cronin, L. (2007) Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry. Angewandte Chemie (International Edition), 46(8), pp. 1340-1344. (doi: 10.1002/anie.200603870)

Fielden, J., Long, D.L. , Slawin, A.M.Z., Kogerler, P. and Cronin, L. (2007) Ligand and counterion control of Ag(I) architectures: Assembly of a {Ag-8} ring cluster mediated by hydrophobic and Ag center dot center dot center dot Ag interactions. Inorganic Chemistry, 46, pp. 9090-9097. (doi: 10.1021/ic700872b)

Long, D., Burkholder, E. and Cronin, L. (2007) Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices. Chemical Society Reviews, 36, pp. 105-121. (doi: 10.1039/b502666k)

McMillan, N., Smith, L.V., de la Fuente, J.M., Parenty, A.D.C., Gadegaard, N. , Pitt, A.R., Thomson, K., MacKenzie, C., Kelly, S. and Cronin, L. (2007) Incorporation of N-heterocyclic cations into proteins with a highly directed chemical modification. Chemical Communications, 25, pp. 2581-2583. (doi: 10.1039/b702575k)

Pradeep, C.P., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Controlled assembly and solution observation of a 2.6 nm polyoxometalate super tetrahedron cluster: [KFe12(OH)18(-1,2,3-P2W15O56)4]29–. Chemical Communications, 41, pp. 4254-4256. (doi: 10.1039/b707202c)

Ritchie, C., Burkholder, E.M., Long, D.-L. , Adam, D., Kögerler, P. and Cronin, L. (2007) Exploiting the multifunctionality of organocations in the assembly of hybrid polyoxometalate clusters and networks. Chemical Communications, 38(17), pp. 468-470. (doi: 10.1039/b612741j)

Song, Y.-F., Abbas, H., Ritchie, C., McMillian, N., Long, D.-L. , Gadegaard, N. and Cronin, L. (2007) From polyoxometalate building blocks to polymers and materials: the silver connection. Journal of Materials Chemistry, 17, pp. 1903-1908. (doi: 10.1039/b617830h)

Streb, C., Ritchie, C., Long, D.L. , Kogerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported Ag-I center dot center dot center dot Ag-I interactions". Angewandte Chemie (International Edition), 46, pp. 7579-7582. (doi: 10.1002/anie.200702698)

Fielden, J., Gunning, P.T., Long, D.-L. , Nutley, M., Ellern, A., Kögerler, P. and Cronin, L. (2006) Anion control of isomerism, crystal packing and binding properties in a mononuclear zinc complex. Polyhedron, 25(18), pp. 3474-3480. (doi: 10.1016/j.poly.2006.06.044)

Akutagawa, T., Endo, D., Imai, H., Noro, S., Cronin, L. and Nakamura, T. (2006) Formation of p-Phenylenediamine-Crown Ether-[PMo12O40]4- Salts. Inorganic Chemistry, 45(21), pp. 8628-8637. (doi: 10.1021/ic060857i)

Baffert, C., Boas, J.F., Bond, A.M., Kögerler, P., Long, D.-L. , Pilbrow, J.R. and Cronin, L. (2006) Experimental and theoretical investigations of the sulfite-based polyoxometalate cluster redox series: α - and β-[Mo18O54(SO3)2]4-/5-/6-. Chemistry: A European Journal, 12(33), pp. 8472-8483. (doi: 10.1002/chem.200501450)

Newton, G. N., Cooper, G. J.T. , Long, D.-L. , Kogerler, P. and Cronin, L. (2006) Synthetic, structural and magnetic characterisation of a one-dimensional nickel chain constructed using cis,trans-1,3,5-triaminocyclohexane as a building block. Journal of Molecular Structure, 796, pp. 23-27. (doi: 10.1016/j.molstruc.2006.03.087)

Fielden, J., Long, D.L. , Evans, C. and Cronin, L. (2006) Metal-dependent formation of mononuclear complexes and M2L2 mesocates with Schiff-base ligands. European Journal of Inorganic Chemistry, 2006(19), pp. 3930-3935. (doi: 10.1002/ejic.200600367)

Long, D.L. , Kögerler, P., Farrugia, L.J. and Cronin, L. (2006) Linking chiral clusters with molybdate building blocks: from homochiral helical supramolecular arrays to coordination helices. Chemistry: An Asian Journal, 1(3), pp. 352-357. (doi: 10.1002/asia.200600069)

Long, D.L. , Kogerler, P., Parenty, A.D.C., Fielden, J. and Cronin, L. (2006) Discovery of a family of isopolyoxotungstates [H4W19O62]6- encapsulating a {WO6} moiety within a {W18} Dawson-like cluster cage. Angewandte Chemie (International Edition), 45(29), pp. 4798-4803. (doi: 10.1002/anie.200504600)

Cronin, L. (2006) Supramolecular coordination chemistry. Annual Reports on the Progress of Chemistry Section A: Inorganic Chemistry, 101, pp. 348-374. (doi: 10.1039/b410477n)

Fielden, J., Malaestean, Y.L., Ellern, A., García-Serres, R., Cronin, L. and Kögerler, P. (2006) Inducing molecular growth in an {Mo57Fe6}-type nanocluster: synthesis, structure, and properties of {Mo57}(Mo)2Fe6III}. Journal of Cluster Science, 17(2), pp. 291-302. (doi: 10.1007/s10876-006-0053-1)

Long, D.-L. , Streb, C., Kögerler, P. and Cronin, L. (2006) Observation and theoretical analysis of the “sensitive coordination sites” in the isopolyoxomolybdate cluster [Mo36O112(H2O)14]8-. Journal of Cluster Science, 17(2), pp. 257-266. (doi: 10.1007/s10876-006-0058-9)

Long, D.-L. and Cronin, L. (2006) Towards polyoxometalate-integrated nanosystems. Chemistry: A European Journal, 12(14), pp. 3698-3706. (doi: 10.1002/chem.200501002)

Fielden, J., Sprott, J., Long, D.-L. , Kögerler, P. and Cronin, L. (2006) Controlling aggregation of copper(II)-based coordination compounds: from mononuclear to dinuclear, tetranuclear, and polymeric copper complexes. Inorganic Chemistry, 45(7), pp. 2886-2895. (doi: 10.1021/ic051647t)

Akutagawa, T., Endo, D., Imai, H., Noro, S., Cronin, L. and Nakamura, T. (2006) Formation of p-phenylenediamine-crown ether-[PMo12O40](4-) salts. Inorganic Chemistry, 45, pp. 8628-8637. (doi: 10.1021/ic060857i)

Cronin, L. (2006) Inorganic molecular capsules: From structure to function. Angewandte Chemie (International Edition), 45, pp. 3576-3578. (doi: 10.1002/anie.200600090)

Cronin, L. et al. (2006) The imitation game - a computational chemical approach to recognizing life. Nature Biotechnology, 24, pp. 1203-1206. (doi: 10.1038/nbt1006-1203)

Fielden, J., Long, D., Evans, C. and Cronin, L. (2006) Metal-dependent formation of mononuclear complexes and M2L2 mesocates with Schiff-base ligands. European Journal of Inorganic Chemistry, pp. 3930-3935. (doi: 10.1002/ejic.200600367)

Fielden, J., Malaestean, Y., Ellern, A., Garcia-Serres, R., Cronin, L. and Kogerler, P. (2006) Inducing molecular growth in an {Mo57Fe6}-type nanocluster: Synthesis, structure, and properties of {Mo-57(Mo)(2)Fe-6(III). Journal of Cluster Science, 17, pp. 291-302. (doi: 10.1007/s10876-006-0053-1)

Long, D.-L. , Brücher, O., Streb, C. and Cronin, L. (2006) Inorganic crown: the host–guest chemistry of a high nuclearity 'Celtic-ring' isopolyoxotungstate [H12W36O120]12–. Dalton Transactions(23), pp. 2852-2860. (doi: 10.1039/b515935k)

Parenty, A.D.C., Guthrie, K.M., Song, Y.-F., Smith, L.V., Burkholder, E. and Cronin, L. (2006) Discovery of an imidazo-phenanthridine synthon produced in a 'five-step one-pot reaction' leading to a new family of heterocycles with novel physical properties. Chemical Communications, 2006, pp. 1194-1196. (doi: 10.1039/b517117b)

Ritchie, C., Burkholder, E., Kogerler, P. and Cronin, L. (2006) Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species. Dalton Transactions, pp. 1712-1714. (doi: 10.1039/b518316b)

Ritchie, C., Burkholder, E., Kögerler, P. and Cronin, . (2006) Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species. Dalton Transactions, pp. 1712-1714. (doi: 10.1039/b518316b)

Smith, L., Parenty, A., Guthrie, K., Plumb, J., Brown, R. and Cronin, L. (2006) Dihydroimidazophenanthridinium (DIP)-based DNA binding agents with tuneable structures and biological activity. ChemBioChem, 7, pp. 1757-1763. (doi: 10.1002/cbic.200600205)

Streb, C., Long, D.-L. and Cronin, L. (2006) Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks. CrystEngComm, 8, pp. 629-634. (doi: 10.1039/b605285a)

Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2005) A novel copper (II) metallacycle as a building block for the assembly of an extended supramolecular array containing channels and helical chains. Inorganic Chemistry Communications, 8(8), pp. 737-739. (doi: 10.1016/j.inoche.2005.05.005)

Parenty, A.D.C., Smith, L.V. and Cronin, L. (2005) An unusual substitution reaction directed by an intramolecular re-arrangement. Tetrahedron, 61(35), pp. 8410-8418. (doi: 10.1016/j.tet.2005.06.074)

de la Fuente, J.M., Fandel, M., Berry, C.C. , Riehle, M. , Cronin, L. , Aitchison, G. and Curtis, A.S.G. (2005) Quantum dots protected with tiopronin: a new fluorescence system for cell-biology studies. ChemBioChem, 6(6), pp. 989-991. (doi: 10.1002/cbic.200500071)

Parenty, A.D.C., Smith, L.V., Guthrie, K.M., Long, D.-L. , Plumb, J., Brown, R. and Cronin, L. (2005) Highly stable phenanthridinium frameworks as a new class of tunable DNA binding agents with cytotoxic properties. Journal of Medicinal Chemistry, 48(14), pp. 4504-4506. (doi: 10.1021/jm050320z)

Long, D.-L. , Abbas, H., Kogerler, P. and Cronin, L. (2005) Confined electron-transfer reactions within a molecular metal oxide "Trojan horse". Angewandte Chemie (International Edition), 44(22), pp. 3415-3419. (doi: 10.1002/anie.200500541)

Abbas, H., Pickering, A.L., Long, D.-L. , Kögerler, P. and Cronin, L. (2005) Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers. Chemistry: A European Journal, 11(4), pp. 1071-1078. (doi: 10.1002/chem.200401088)

Kögerler, P. and Cronin, L. (2005) Polyoxometalate nanostructures, superclusters, and colloids: from functional clusters to chemical aesthetics. Angewandte Chemie (International Edition), 44(6), pp. 844-846. (doi: 10.1002/anie.200462662)

Fielden, J., Sprott, J. and Cronin, L. (2005) Design and sterospecific synthesis of modular ligands based upon cis-1,3-trans-5-substituted cyclohexanes. New Journal of Chemistry, 29, pp. 1152-1158. (doi: 10.1039/b503606b)

Long, D.L. , Kogerler, P., Farrugia, L.J. and Cronin, L. (2005) Reactions of a {Mo-16}-type polyoxometalate cluster with electrophiles: a synthetic, theoretical and magnetic investigation. Dalton Transactions, pp. 1372-1380. (doi: 10.1039/b419301f)

Pickering, A.L., Seeber, G., Long, D.L. and Cronin, L. (2005) The importance of pi-pi, pi-CH and N-CH interactions in the crystal packing of Schiff-base derivatives of cis,cis- and cis,trans-1,3,5-triaminocyclohexane. CrystEngComm, 7, pp. 504-510. (doi: 10.1039/b506718a)

Seeber, G., Kariuki, B., Cronin, L. and Kogerler, P. (2005) Synthesis, structure and magnetism of a linear Cu-Cl-Cu entity found in [(Cu(tachH)(tach))(2)(mu-Cl)](5+). Polyhedron, 24, pp. 1651-1655. (doi: 10.1016/j.poly.2005.05.008)

Smith, L.V., de la Fuente, J.M., Guthrie, K.M., Parenty, A.D.C. and Cronin, L. (2005) Does it bind? An instant binding assay for DNA oligonucleotide interactive small molecules. New Journal of Chemistry, 29, pp. 1118-1120. (doi: 10.1039/b507037f)

Cronin, L. , McGregor, P.A., Parsons, S., Teat, S., Gould, R., White, V.A., Long, N.J. and Robertson, N. (2004) Synthesis, structure, and complexation of a large 28-mer macrocycle containing two binding sites for either anions or metal ions. Inorganic Chemistry, 43(25), pp. 8023-8029. (doi: 10.1021/ic049190v)

Schnack, J., Nojiri, H., Kogerler, P., Cooper, G. J.T. and Cronin, L. (2004) Magnetic characterization of the frustrated three-leg ladder compound [(CuCl2tachH)3Cl]Cl2. Physical Review B, 70(17), 174420. (doi: 10.1103/PhysRevB.70.174420)

Cooper, G.J.T. , Abbas, H., Kögerler, P., Long, D.-L. and Cronin, L. (2004) Pentadecadentate chelating ligands as building blocks for a {Fe6} cage with 12 exo-coordinated sodium cations. Inorganic Chemistry, 43(23), pp. 7266-7268. (doi: 10.1021/ic049068w)

Parenty, A.D.C., Smith, L.V., Pickering, A.L., Long, D.-L. and Cronin, L. (2004) General one-pot, three-step methodology leading to an extended class of N-heterocyclic cations: spontaneous nucleophilic addition, cyclization, and hydride loss. Journal of Organic Chemistry, 69(18), pp. 5934-5946. (doi: 10.1021/jo0495440)

Pickering, A.L., Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2004) Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers. Polyhedron, 23(12), pp. 2075-2079. (doi: 10.1016/j.poly.2004.06.002)

Pickering, A.L., Long, D.-L. and Cronin, L. (2004) Coordination networks through the dimensions: from discrete clusters to 1D, 2D, and 3D silver(I) coordination polymers with rigid aliphatic amino ligands. Inorganic Chemistry, 43(16), pp. 4953-4961. (doi: 10.1021/ic049786i)

Long, D.-L. , Kögerler, P. and Cronin, L. (2004) Old clusters with new tricks: engineering S...S interactions and novel physical properties in sulfite-based Dawson clusters. Angewandte Chemie (International Edition), 43(14), pp. 1817-1820. (doi: 10.1002/anie.200352896)

Cronin, L. (2004) Macrocyclic and supramolecular coordination chemistry. Annual Reports on the Progress of Chemistry Section A: Inorganic Chemistry, 100, pp. 323-383. (doi: 10.1039/b311796k)

Fielden, J., Long, D.-L. and Cronin, L. (2004) Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes. Chemical Communications(19), pp. 2156-2157. (doi: 10.1039/b407229d)

Long, D.L. , Abbas, H., Kogerler, P. and Cronin, L. (2004) A high-nuclearity "Celtic-Ring" isopolyoxotungstate, [H12W36O120] that captures trace potassium ions. Journal of the American Chemical Society, 126, pp. 13880-13881. (doi: 10.1021/ja046410v)

Pickering, A.L., Seeber, G., Long, D.-L. and Cronin, L. (2004) Polymeric silver(I) coordination tubes. Chemical Communications, 2004, pp. 136-137. (doi: 10.1039/b312876h)

Seeber, G., Kogerler, P., Kariuki, B. and Cronin, L. (2004) Supramolecular assembly of ligand-directed triangular {(Cu3Cl)-Cl-II} clusters with spin frustration and spin-chain behaviour. Chemical Communications, pp. 1580-1581. (doi: 10.1039/b402487g)

Seeber, G., Kögerler, P., Kariuki, B.M. and Cronin, L. (2004) Supramolecular assembly of ligand-directed triangular {CuII3Cl} clusters with spin frustration and spin-chain behaviour. Chemical Communications, 2004, pp. 1580-1581. (doi: 10.1039/b402487g)

Long, D.-L. , Kögerler, P., Farrugia, L. and Cronin, L. (2003) Restraining symmetry in the formation of small polyoxomolybdates: building blocks of unprecedented topology resulting from "shrink-wrapping" [H2Mo16O52]10--type clusters. Angewandte Chemie (International Edition), 42(35), pp. 4180-4183. (doi: 10.1002/anie.200351615)

Long, D.-L. , Orr, D., Seeber, G., Kögerler, P., Farrugia, L.J. and Cronin, L. (2003) The missing link in low nuclearity pure polyoxovanadate clusters: preliminary synthesis and structural analysis of a new {V16} cluster and related products: dedicated to professor Achim Müller. Journal of Cluster Science, 14(3), pp. 313-324. (doi: 10.1023/B:JOCL.0000005066.92182.90)

Seeber, G., Long, D.L. , Kariuki, B.M. and Cronin, L. (2003) Palladium(II)-based cis,trans-1,3,5-triaminocyclohexane complexes demonstrating a variety of coordination modes and architectures. Dalton Transactions, pp. 4498-4504. (doi: 10.1039/b307616d)

Seeber, G., Pickering, A.L., Long, D.L. and Cronin, L. (2003) Controlling dimensionality of silver(I) coordination networks with rigid aliphatic amino ligands: from a 2D to a 3D network of unprecedented topology comprising helical channels. Chemical Communications, pp. 2002-2003. (doi: 10.1039/b305188a)

Robertson, N. and Cronin, L. (2002) Metal bis-1,2-dithiolene complexes in conducting or magnetic crystalline assemblies. Coordination Chemistry Reviews, 227, pp. 93-127.

Seeber, G., Kariuki, B. and Cronin, L. (2002) Self-assembly of a twelve-component hexanuclear metallomacrocycle constructed with a novel tri-amino ligand. Chemical Communications, pp. 2912-2913. (doi: 10.1039/b209493m)

Shivaiah, V., Reddy, P.V.N., Cronin, L. and Das, S.K. (2002) A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)(7)Al(OH)(6)Mo6O18](n)center dot 4nH(2)O. Journal of the Chemical Society: Dalton Transactions, pp. 3781-3782. (doi: 10.1039/b207149e)

Cronin, L. , Clark, S.J., Parsons, S., Nakamura, T. and Robertson, N. (2001) Unique structural topologies involving metal-metal and metal-sulfur interactions: salts of [Ni(C3S5)(2)](x-) with cis-anti-cis-dicyclohexyl-18-crown-6 complexed counter ions. Journal of the Chemical Society: Dalton Transactions, pp. 1347-1351. (doi: 10.1039/b008299f)

Book Sections

Long, D.-L. and Cronin, L. (2021) Advances in gigantic polyoxomolybdate chemistry. In: Hubbard, C. D. and van Eldik, R. (eds.) Advances in Inorganic Chemistry: Recent Highlights I. Series: Advances in inorganic chemistry (78). Elsevier Academic Press: Cambridge, MA, pp. 227-267. ISBN 9780323851152 (doi: 10.1016/bs.adioch.2021.06.003)

Sans, V., Dragone, V. and Cronin, L. (2019) Applications of 3D printing in synthetic process and analytical chemistry. In: Anastas, P. T. (ed.) Handbook of Green Chemistry. Wiley, pp. 215-256. ISBN 9783527628698 (doi: 10.1002/9783527628698.hgc141)

Vila-Nadal, L. and Cronin, L. (2017) Self-assembly of molecular metal oxide nanoclusters. In: Dronskowski, R., Kikkawa, S. and Stein, A. (eds.) Handbook of Solid State Chemistry. Wiley: Weinheim. ISBN 9783527325870 (doi: 10.1002/9783527691036.hsscvol4003)

Miras, H.N. , Long, D.-L. and Cronin, L. (2017) Exploring self-assembly and the self-organization of nanoscale inorganic polyoxometalate clusters. In: van Eldik, R. and Cronin, L. (eds.) Polyoxometalate Chemistry. Series: Advances in inorganic chemistry, 69. Academic Press: Burlington, pp. 1-28. ISBN 9780128111055 (doi: 10.1016/bs.adioch.2016.12.001)

Miras, H. and Cronin, L. (2012) Electrospray and cryospray mass spectrometry: from serendipity to designed synthesis of supramolecular coordination and polyoxometalate clusters. In: Pignataro, B. (ed.) New Strategies in Chemical Synthesis and Catalysis. Wiley-VCH Verlag: Weinheim, pp. 3-32. ISBN 9783527330904

Symes, M. D. and Cronin, L. (2012) Materials for water splitting. In: Letcher, T. M. and Scott, J. L. (eds.) Materials for a Sustainable Future. Royal Society of Chemistry: Cambridge, pp. 592-616. ISBN 9781849734073

Cronin, L. , Kitson, P. and Wilson, C.C. (2011) Process understanding – crystallization. In: Houson, I. (ed.) Process Understanding for Scale-up and Manufacture of Active Ingredients. Wiley. ISBN 9783527637140

Miras, H. and Cronin, L. (2008) Polyoxometalate nanocapsules: from structure to function. In: Atwood, J. L. and Steed, J. W. (eds.) Organic Nanostructures. Wiley-VCH Verlag: Weinheim, pp. 277-291. ISBN 9783527318360

Edited Books

van Eldik, R. and Cronin, L. (Eds.) (2017) Polyoxometalate Chemistry. Series: Advances in inorganic chemistry. Academic Press: Burlington. ISBN 9780128111055

Conference Proceedings

Restuccia, S. , Gibson, G. M. , Cronin, L. and Padgett, M. J. (2021) Bell inequality in chiral liquids. In: Proceedings SPIE 11881, Quantum Technology: Driving Commercialisation of an Enabling Science II (SPIE Photonex), Glasgow, Scotland, United Kingdom, 28 September - 1 October 2021, p. 1188112. (doi: 10.1117/12.2601516)

Cronin, L. (2021) Modelling Emergent Phenomenon Using Chemically Encoded Computations. In: 25th Solvay Conference on Chemistry, Brussels, Belgium, 19-19 Oct 2019, pp. 75-79. ISBN 9789811228209 (doi: 10.1142/9789811228216_0008)

Mathew, P. T., Fang, F., Vila-Nadal, L. , Cronin, L. and Georgiev, V. (2019) First Principle Simulations of Current Flow in Inorganic Molecules: Polyoxometalates (POMs). In: 2019 Joint International EUROSOI Workshop and International Conference on Ultimate Integration on Silicon (EUROSOI-ULIS), Grenoble, France, 01-03 Apr 2019, ISBN 9781728116587 (doi: 10.1109/EUROSOI-ULIS45800.2019.9041869)

Georgiev, V. P. , Vila-Nadal, L. , Cronin, L. and Asenov, A. (2018) Molecular Based Flash Cell for Low Power Flash Application: Optimization and Variability Evaluation. In: IEEE 12th Nanotechnology Materials and Devices Conference (NMDC 2017), Singapore, 2-4 Oct 2017, pp. 64-65. ISBN 9781538627723 (doi: 10.1109/NMDC.2017.8350505)

Points, L. J., Grizou, J. , Parrilla Gutierrez, J. M. , Taylor, J. W. and Cronin, L. (2017) The Evolution of Active Droplets in Chemorobotic Platforms. In: 14th European Conference on Artificial Life (ECAL 2017), Lyon, France, 04-08 Sep 2017, pp. 356-357. ISBN 9780262346337 (doi: 10.7551/ecal_a_059)

Surman, A. J. , Rodriguez-Garcia, M., Abul-Haija, Y. , Cooper, G. J.T. , Donkers, K., Planchat i Barbarà, J. M., Kube, J., Mullin, M., Hezwani, M. and Cronin, L. (2017) Can a Reaction's Environment Program its Outcome, and Does it Matter? In: XVIIIth International Conference on the Origin of Life (LPI Contribution No. 1967), San Diego, CA, USA, 16-21 Jul 2017, p. 4006.

Giagkoulovits, C. , Al-Rawhani, M. A., Cheah, B. C. , Martin, C., Busche, C. , Cronin, L. and Cumming, D. R.S. (2017) Hybrid Amperometric and Potentiometric Sensing Based on a CMOS ISFET Array. In: IEEE Sensors 2017, Glasgow, UK, 30 Oct - 01 Nov 2017, ISBN 9781509010127 (doi: 10.1109/ICSENS.2017.8234249)

Parrilla Gutierrez, J. M. and Cronin, L. (2015) Embodied Evolution of Artificial Cells in a Hybrid Wet/Hard-ware Platform. In: ECAL 2015: The Thirteenth European Conference on Artificial Life, York, UK, 20-24 Jul 2015, p. 215. ISBN 9780262330275 (doi: 10.7551/978-0-262-33027-5-ch042)

Georgiev, V. P. , Amoroso, S. M., Vila-Nadal, L. , Busche, C. , Cronin, L. and Asenov, A. (2014) FDSOI Molecular Flash Cell with Reduced Variability for Low Power Flash Applications. In: 44th European Solid-State Device Research Conference (ESSDERC), Venice, Italy, 22-26 Sep 2014, pp. 353-356. ISBN 9781479943760 (doi: 10.1109/ESSDERC.2014.6948833)

Georgiev, V. P. , Markov, S., Vilà-Nadal, L. , Asenov, A. and Cronin, L. (2013) Molecular-Metal-Oxide-nanoelectronicS (M-MOS): Achieving the Molecular Limit. In: 16th International Workshop on Computational Electronics, Nara, Japan, 4-7 June 2013, ISBN 9783901578267

Georgiev, V. P. , Markov, S., Vila-Nadal, L. , Busche, C., Cronin, L. and Asenov, A. (2013) Multi-scale computational framework for the evaluation of variability in the programing window of a flash cell with molecular storage. In: 2013 Proceedings of the European Solid-State Device Research Conference (ESSDERC), Bucharest, Romania, 16-20 Sep 2013, pp. 230-233. (doi: 10.1109/ESSDERC.2013.6818861)

This list was generated on Wed Apr 24 07:43:19 2024 BST.

Teaching

Teaching

  • Level-3 Bioinorganic Chemistry
  • Level-4 Metals in Medicine
  • Level-4 Advanced Bioinorganic Chemistry and Biomaterials.

Additional information

Awards

DPhil (York)

Selected Recent Talks

  • "Engineering reversible electron transfer reactions within polyoxometalate nanoscale cages", Invited talk, 234th ACS Meeting in Boston, August 2007
  • "Synthesis of triangular magnetic tubes" Workshop on quantum spin tubes, IMR, Tohoku, July 2007
  • "From Polyoxometalate-based building blocks to Functional Nanoclusters and Frameworks", Invited lecture, Cost D40 Dublin, May 2007
  • "Molecular design approaches to self assembly: From ligand design to functional nanoclusters and frameworks". Invited lecture, Leiden, April 2007
  • "Design of novel N-heterocyclic frameworks, cations and superstructures as bio-actives and new materials". Invited lecture, Bayer Crop Science, March 2007

External Appointments & Positions

  • EPSRC Advanced Research Fellow (2006-2011)
  • Visiting Professor, University of Versailles (2006)