Professor Haralampos Moiras

Professor of Inorganic and Supramolecular Chemistry (School of Chemistry)

telephone: 0141 330 4375
email: Charalampos.Moiras@glasgow.ac.uk

A4-42 Level A4, School of Chemistry, Joseph Black Building, Glasgow, G12 8QQ

Research interests

Highly motivated and ambitious candidates are invited to apply for a fully-funded PhD studentship in the Miras Group. The PhD scholar will exploit a timely opportunity to implement new methodologies developed in Miras group to tailor electronic and catalytic properties of molecular and 2D materials using directed self-assembly approaches for accessing a host of artificial heterostructures with potential applications ranging from electronic devices to hydrogen evolution catalysts. This research incorporates aspects from across chemistry, involving synthesis, characterization and analysis. Opportunities will also be available for travel to national and international conferences to present research results as well opportunities to cross the disciplinary boundaries by working together with physicists and engineers.

More details about this position is available by following the link.

Research Interests

My research interests are primarily focused on the development of metal oxide/chalcogenide molecule based materials for energy applications. The current research is focused on the discovery of simple preparation routes to chalcoxide-based composite functional materials as well as the understanding of fundamental processes in the self-assembly of supramolecular clusters and molecular nanomaterials with modular magnetic, redox, electronic, conductive and catalytic properties.

A synergistic research strand which is being developed in parallel, involves the fundamental understanding, control and design of self-assembled chemical systems. I am interested in exploiting novel methodologies for the discovery and design of functional molecular devices. Other recent research projects have investigated the discovery of intermediate reaction structures in an effort to understand the underlying chemistry in the self-assembly of polyoxometalate systems and extraction of crucial mechanistic information utilizing high resolution ESI-MS techniques.

Publication Highlights

H. N. Miras, C. Mathis, W. Xuan, D.-L. Long,R. Pow, L. Cronin, Proc. Nat. Acad. Sci., 2020, 117, 10699-10705. "Spontaneous formation of autocatalytic sets with self-replicating metal oxide clusters."
J. McAllister, N. A. G. Bandeira, J. C. McGlynn, A. Y. Ganin, Y.-F. Song, C. Bo, H. N. Miras*, Nature Commun. 2019,10, 370. "Tuning and mechanistic insights of metal chalcogenide molecular catalysts for the hydrogen-evolution reaction."
T. Li, Z. Wang, W. Chen, H. N. Miras,* Y.-F. Song, Chem. A Eur. J., 2017,23, 1069-1077.“Rational design of a polyoxometalate intercalated layered double hydroxide: highly efficient catalytic epoxidation of allylic alcohols under mildand solvent-free conditions”.
H.-Y. Zang, J.-J. Chen, D. L. Long, L. Cronin, H. N. Miras* Chem. Sci. 2016, 7, 3798-3804. “Assembly of inorganic [Mo₂S₂O₂]²⁺ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters.”
Y. Chen, Z. Yao, H. N. Miras,* Y.-F. Song, Chem. Eur. J. 2015, 21, 10812 – 10820 ‘Modular Polyoxometalate-Layered Double Hydroxide Composites as Efficient Oxidative Catalysts’.
C. Busche, L. Vilá-Nadal, J. Yan, H. N. Miras, D.-L. Long, V. P. Georgiev, A. Asenov, R. H. Pedersen, N. Gadegaard, M. M. Mirza, D. J. Paul, J. M. Poblet, L. Cronin, Nature 2014, 515, 545-549 ‘Design and fabrication of memory devices based on nanoscale polyoxometalate clusters’.
H. N. Miras,* Chem. Eur. J. 2014, 20, 10554 – 10560 ‘Molecular Chalcoxides (ChalcoPolyoxometalates): A Family of Functional Materials with Emergent Properties’.
H.-Y. Zang, J.-J. Chen, D.-L. Long, L. Cronin, H. N. Miras,* Adv. Mater. 2013, 25, 6245–6249 "Assembly of thiometalate-based composite clusters combining [Mo₂O₂S₂]²⁺ cations and selenite anions"
H. N. Miras,* J. Yan, D.-L. Long, L. Cronin, Chem. Soc. Rev., 2012, 41, 7403–7430. "Engineering polyoxometalates with emergent properties"
H. N. Miras, C. J. Richmond, D-L. Long, L. Cronin, J. Am. Chem. Soc., 2012, 134, 3816−3824. “Solution Phase Monitoring of the Structural Evolution of a Molybdenum Blue Nano-ring”
E. F. Wilson, H. N. Miras, M. H. Rosnes, L. Cronin, Angew. Chem. Int. Ed., 2011, 50, 3720 –3724. “Real-Time Observation of the Self-Assembly of Hybrid Polyoxometalates Using Mass Spectrometry”
H. N. Miras, G. J. T. Cooper, D-L. Long, H. Bögge, A. Müller, C. Streb, L. Cronin, Science, 2010, 327, 72-74. “Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel”

Research groups

Complex Chemistry

Publications

Selected publications

Miras, H.N. , Long, D.-L. and Cronin, L. (2017) Exploring self-assembly and the self-organization of nanoscale inorganic polyoxometalate clusters. In: van Eldik, R. and Cronin, L. (eds.) Polyoxometalate Chemistry. Series: Advances in inorganic chemistry, 69. Academic Press: Burlington, pp. 1-28. ISBN 9780128111055 (doi: 10.1016/bs.adioch.2016.12.001)

Li, T., Wang, Z., Chen, W., Miras, H. N. and Song, Y.-F. (2017) Rational design of a polyoxometalate intercalated layered double hydroxide: highly efficient catalytic epoxidation of allylic alcohols under mild and solvent-free conditions. Chemistry: A European Journal, 23(5), pp. 1069-1077. (doi: 10.1002/chem.201604180) (PMID:27748545)

Zang, H.-Y., Chen, J.-J., Long, D. L. , Cronin, L. and Miras, H. N. (2016) Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters. Chemical Science, 7(6), pp. 3798-3804. (doi: 10.1039/c5sc04944j)

Sartzi, H., Miras, H. N. , Vila-Nadal, L. , Long, D. L. and Cronin, L. (2015) Trapping the δ isomer of the polyoxometalate-based Keggin cluster with a tripodal ligand. Angewandte Chemie (International Edition), 54(51), pp. 15488-15492. (doi: 10.1002/anie.201505377) (PMID:26511859)

Wilson, E.F., Miras, H.N. , Rosnes, M.H. and Cronin, L. (2011) Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry. Angewandte Chemie (International Edition), 50(16), pp. 3720-3724. (doi: 10.1002/anie.201006938)

Miras, H.N. , Cooper, G.J.T., Long, D.-L., Bogge, H., Muller, A., Streb, C. and Cronin, L. (2010) Unveiling the transient template in the self-assembly of a molecular oxide nanowheel. Science, 327(5961), pp. 72-74. (doi: 10.1126/science.1181735)

All publications

List by: Type | Date

Jump to: 2023 | 2022 | 2021 | 2020 | 2019 | 2018 | 2017 | 2016 | 2015 | 2014 | 2013 | 2012 | 2011 | 2010 | 2009 | 2008 | 2005 | 2003

Number of items: 136.

2023

Ojo, O. S. , Steel, H. J. and Miras, H. N. (2023) Expeditious access to cis-β-aryl, γ-alkyl disubstituted (±)-γ-butyrolactones via nickel-hydride catalysis. Organic and Biomolecular Chemistry, 21(33), pp. 6738-6742. (doi: 10.1039/D3OB00895A) (PMID:37551644)

Elliott, A., McAllister, J. , Long, D.-L. , Song, Y.-F. and Miras, H. N. (2023) Pore “softening” and emergence of breathability effects of new keplerate nano-containers. Angewandte Chemie (International Edition), 62(20), e202218897. (doi: 10.1002/anie.202218897) (PMID:36812050)

He, W., Lin, T., Song, Z., Cheng, Y., Zheng, R., Chen, W., Miras, H. N. and Song, Y.-F. (2023) Fabrication of epitaxially grown Mg₂Al-LDH-modified nanofiber membranes for efficient and sustainable separation of water-in-oil emulsion. ACS Applied Materials and Interfaces, 15(3), pp. 4755-4763. (doi: 10.1021/acsami.2c19015) (PMID:36629917)

2022

Zhao, W.-L., Liu, Y., Yang, Y., Chen, W., Miras, H. N. and Song, Y.-F. (2022) Modular polyoxometalate-intercalated layered double hydroxide membranes for molecular sieving and in situ regeneration. Cell Reports Physical Science, 3(12), 101189. (doi: 10.1016/j.xcrp.2022.101189)

Passadis, S. S., Hadjithoma, S., Fairbairn, N. J., Hedley, G. J., Bandeira, N. A.G., Tsipis, A. C., Miras, H. N. , Keramidas, A. D. and Kabanos, T. A. (2022) Hafnium(IV) chemistry with imide-dioxime and catecholate-oxime ligands: unique {Hf₅} and metalloaromatic {Hf₆}-oxo clusters exhibiting fluorescence. Inorganic Chemistry, 61(50), pp. 20253-20267. (doi: 10.1021/acs.inorgchem.2c01768) (PMID:36461927)

Papanikolaou, M. G., Simaioforidou, A. V., Drouza, C., Tsipis, A. C., Miras, H. N. , Keramidas, A. D., Louloudi, M. and Kabanos, T. A. (2022) A combined experimental and theoretical investigation of oxidation catalysis by cis-[VIV(O)(Cl/F)(N4)]+ species mimicking the active center of metal-enzymes. Inorganic Chemistry, 61(46), pp. 18434-18449. (doi: 10.1021/acs.inorgchem.2c02526) (PMID:36357045)

Elliott, A. and Miras, H.N. (2022) Recent advances in polyoxothiometalate chemistry. Journal of Coordination Chemistry, 75(11-14), pp. 1467-1493. (doi: 10.1080/00958972.2022.2086049)

Elliott, A., McAllister, J. , Masaityte, L., Segado Centellas, M., Long, D.-L. , Ganin, A. , Song, Y.-F., Bo, C. and Miras, H. N. (2022) Mechanistic insights of molecular metal polyselenides for catalytic hydrogen generation. Chemical Communications, 58(49), pp. 6906-6909. (doi: 10.1039/D2CC01226J) (PMID:35642784)

Zheng, R., Cheng, Y., Jiang, X., Lin, T., Chen, W., Deng, G., Miras, H. N. and Song, Y.-F. (2022) Fiber templated epitaxially grown composite membranes: from thermal insulation to infrared stealth. ACS Applied Materials and Interfaces, 14(23), pp. 27214-27221. (doi: 10.1021/acsami.2c05906) (PMID:35653141)

Passadis, S. S., Hadjithoma, S., Papanikolaou, M. G., Keramidas, A. D., Miras, H. N. and Kabanos, T. A. (2022) Acid/base responsive assembly/dis-assembly of a family of zirconium(iv) clusters with a cyclic imide-dioxime ligand. Dalton Transactions, 51(5), pp. 1806-1818. (doi: 10.1039/d1dt03641f) (PMID:35018917)

Lockey, D., Mathis, C., Miras, H. N. and Cronin, L. (2022) Investigating the autocatalytically driven formation of Keggin-based polyoxometalate clusters. Matter, 5(1), pp. 302-313. (doi: 10.1016/j.matt.2021.11.030)

Draoui, Y., Radi, S., Tanan, A., Oulmidi, A., Miras, H. N. , Benabbes, R., Ouahhoudo, S., Mamri, S., Rotaru, A. and Garcia, Y. (2022) Novel family of bis-pyrazole coordination complexes as potent antibacterial and antifungal agents. RSC Advances, 12, pp. 17755-17764. (doi: 10.1039/D2RA03414J)

2021

Passadis, S. S., Hadjithoma, S., Siafarika, P., Kalampounias, A. G., Keramidas, A. D., Miras, H. N. and Kabanos, T. A. (2021) Synthesis, structural and physicochemical characterization of a titanium(IV) compound with the hydroxamate ligand N,2-dihydroxybenzamide. Molecules, 26(18), 5588. (doi: 10.3390/molecules26185588)

Papanikolaou, M. G., Hadjithoma, S., Gallos, J. K., Miras, H. N. , Plakatouras, J. C., Keramidas, A. D. and Kabanos, T. A. (2021) Synthesis, structural and physicochemical properties of a series of manganese(II) complexes with a novel N5 tripodal-amidate ligand and their potential use as water oxidation catalysts. Polyhedron, 204, 115260. (doi: 10.1016/j.poly.2021.115260)

Martins, F. F., Sánchez‐González, Á., Lanuza, J., Miras, H. N. , Lopez, X., Bandeira, N. A. and Gil, A. (2021) Probing the catalytically active species in POM‐catalysed DNA‐model hydrolysis. Chemistry: A European Journal, 27(35), pp. 8977-8984. (doi: 10.1002/chem.202004989) (PMID:33885198)

Pavlidis, N., Kofinas, A., Papanikolaou, M. G., Miras, H. N. , Drouza, C., Kalampounias, A. G., Kabanos, T. A., Konstandi, M. and Leondaritis, G. (2021) Synthesis, characterization and pharmacological evaluation of quinoline derivatives and their complexes with copper(ΙΙ) in in vitro cell models of Alzheimer's disease. Journal of Inorganic Biochemistry, 217, 111393. (doi: 10.1016/j.jinorgbio.2021.111393)

Zhang, F.-D., Lin, C.-G., Diao, S.-J., Miras, H. N. and Song, Y.-F. (2021) Direct molecular confinement in layered double hydroxides: from fundamental to advanced photo-luminescent hybrid materials. Inorganic Chemistry Frontiers, 8(5), pp. 1324-1333. (doi: 10.1039/D0QI01349H)

Oulmidi, A., Radi, S., Miras, H. N. , Adarsh, N. N. and Garcia, Y. (2021) New bis-pyrazole-bis-acetate based coordination complexes: influence of counter-anions and metal ions on the supramolecular structures. Sustainability, 13(1), 288. (doi: 10.3390/su13010288)

2020

Papanikolaou, M. G., Elliott, A., McAllister, J. , Gallos, J. K., Keramidas, A. D., Kabanos, T. A., Sproules, S. and Miras, H. N. (2020) Electrocatalytic hydrogen production by dinuclear cobalt(ii) compounds containing redox-active diamidate ligands: a combined experimental and theoretical study. Dalton Transactions, 49(44), pp. 15718-15730. (doi: 10.1039/D0DT02617D) (PMID:33146215)

Lian, L., Chen, X., Yi, X., Liu, Y., Chen, W., Zheng, A., Miras, H. N. and Song, Y.-F. (2020) Modulation of self‐separating molecular catalysts for highly efficient biomass transformations. Chemistry: A European Journal, 26(51), pp. 11900-11908. (doi: 10.1002/chem.202001451) (PMID:32329538)

Damgaard-Møller, E., Krause, L., Lassen, H., Malaspina, L. A., Grabowsky, S., Bamberger, H., McGuire, J., Miras, H. N. , Sproules, S. and Overgaard, J. (2020) Investigating complex magnetic anisotropy in a Co(II) molecular compound: a charge density and correlated ab initio electronic structure study. Inorganic Chemistry, 59(18), pp. 13190-13200. (doi: 10.1021/acs.inorgchem.0c01489) (PMID:32869986)

Miras, H. N. , Mathis, C., Xuan, W., Long, D. , Pow, R. and Cronin, L. (2020) Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters. Proceedings of the National Academy of Sciences of the United States of America, 117(20), pp. 10699-10705. (doi: 10.1073/pnas.1921536117) (PMID:32371490) (PMCID:PMC7245103)

Zhang, H., Wu, L., Zhang, Y., An, S., Miras, H. N. and Song, Y.-F. (2020) Heteropolyacids and sulfonic acid-bifunctionalized organosilica spheres for efficient manufacture of cellulose acetate propionate with high viscosity. Cellulose, 27(5), pp. 2437-2453. (doi: 10.1007/s10570-019-02936-6)

Passadis, S. S., Papanikolaou, M. G., Elliott, A., Tsiafoulis, C. G., Tsipis, A. C., Keramidas, A. D., Miras, H. N. and Kabanos, T. A. (2020) Synthesis, structural, and physicochemical characterization of a Ti6 and a unique type of Zr6 oxo clusters bearing an electron-rich unsymmetrical {OON} catecholate/oxime ligand and exhibiting metalloaromaticity. Inorganic Chemistry, 59(24), pp. 18345-18357. (doi: 10.1021/acs.inorgchem.0c02959) (PMID:33289378)

Vila-Nadal, L. and Miras, H. N. (2020) Coordination chemistry in polyoxometalates and metal clusters. In: Constable, E., Parkin, G. and Que, L. (eds.) Comprehensive Coordination Chemistry III. Series: Chemistry molecular sciences and engineering. Academic Press: Burlington. (Accepted for Publication)

2019

Song, Y.-F., Zhang, W., Wang, Z., Zhao, Y. and Miras, H. N. (2019) Precise control of the oriented layered double hydroxide nanosheets growth on graphene oxides leading to efficient catalysts for cascade reactions. ChemCatChem, 11(22), pp. 5466-5474. (doi: 10.1002/cctc.201901208)

McGlynn, J. C. et al. (2019) The rapid electrochemical activation of MoTe2 for the hydrogen evolution reaction. Nature Communications, 10, 4916. (doi: 10.1038/s41467-019-12831-0) (PMID:31664018) (PMCID:PMC6820771)

Duros, V., Grizou, J. , Sharma, A. , Mehr, S. H. M., Bubliauskas, A., Frei, P., Miras, H. N. and Cronin, L. (2019) Intuition-enabled machine learning beats the competition when joint human-robot teams perform inorganic chemical experiments. Journal of Chemical Information and Modeling, 59(6), pp. 2664-2671. (doi: 10.1021/acs.jcim.9b00304) (PMID:31025861) (PMCID:PMC6593393)

An, S., Wang, Z., Zhang, H., Miras, H. N. and Song, Y.-F. (2019) Self‐organization of ionic liquid‐modified organosilica hollow nanospheres and heteropolyacids: efficient preparation of 5‐HMF under mild conditions. ChemCatChem, 11(10), pp. 2526-2536. (doi: 10.1002/cctc.201900285)

Martín, S., Takashima, Y., Lin, C.-G., Song, Y.-F., Miras, H. N. and Cronin, L. (2019) Integrated synthesis of gold nanoparticles coated with polyoxometalate clusters. Inorganic Chemistry, 58(7), pp. 4110-4116. (doi: 10.1021/acs.inorgchem.8b03013) (PMID:30869513)

Zhang, Y., Chen, X., Li, L., Chen, W., Miras, H. N. and Song, Y.-F. (2019) Mesoporous polymer loading heteropolyacid catalysts: one-step strategy to manufacture high value-added cellulose acetate propionate. ACS Sustainable Chemistry and Engineering, 7(5), pp. 4975-4982. (doi: 10.1021/acssuschemeng.8b05627)

McGuire, J., Miras, H. N. , Richards, E. and Sproules, S. (2019) Enabling single qubit addressability in a molecular semiconductor comprising gold-supported organic radicals. Chemical Science, 10(5), pp. 1483-1491. (doi: 10.1039/C8SC04500C) (PMID:30809365) (PMCID:PMC6354843)

McAllister, J., Bandeira, N. A.G., McGlynn, J. C., Ganin, A. Y. , Song, Y.-F., Bo, C. and Miras, H. N. (2019) Tuning and mechanistic insights of metal chalcogenide molecular catalysts for the hydrogen-evolution reaction. Nature Communications, 10, 370. (doi: 10.1038/s41467-018-08208-4) (PMID:30670694) (PMCID:PMC6342911)

McGuire, J., Wilson, B., McAllister, J., Miras, H. N. , Wilson, C. , Sproules, S. and Farnaby, J. H. (2019) Molecular and electronic structure of the dithiooxalato radical ligand stabilised by rare earth coordination. Dalton Transactions, 48, pp. 5491-5495. (doi: 10.1039/C9DT00688E) (PMID:30892339)

Passadis, S. S., Hadjithoma, S., Kalampounias, A. G., Tsipis, A. C., Sproules, S. , Miras, H. N. , Keramidas, A. D. and Kabanos, T. A. (2019) Synthesis, structural and physicochemical characterization of a new type Ti6-oxo cluster protected by a cyclic imide dioxime ligand. Dalton Transactions, 48, pp. 5551-5559. (doi: 10.1039/C9DT00658C) (PMID:30785155)

2018

Papanikolaou, M. G., Hadjithoma, S., Chatzikypraiou, D. S., Papaioannou, D., Drouza, C., Tsipis, A. C., Miras, H. N. , Keramidas, A. D. and Kabanos, T. A. (2018) Investigation of dioxygen activation by copper(ii)-iminate/aminate complexes. Dalton Transactions, 47(45), pp. 16242-16254. (doi: 10.1039/c8dt03137a) (PMID:30398256)

McGuire, J., Miras, H. N. , Donahue, J. P., Richards, E. and Sproules, S. (2018) Ligand radicals as modular organic electron spin qubits. Chemistry: A European Journal, 24(66), pp. 17598-17605. (doi: 10.1002/chem.201804165) (PMID:30291646)

Li, T., Jin, L., Zhang, W., Miras, H. N. and Song, Y.-F. (2018) Robust and environmentally benign solid acid intercalation catalysts for the aminolysis of epoxides. ChemCatChem, 10(20), pp. 4699-4706. (doi: 10.1002/cctc.201801119)

Miras, H. N. , Vilà-Nadal, L. and Cronin, L. (2018) Correction: Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 47(17), p. 6890. (doi: 10.1039/c8cs90091d) (PMID:30067251)

Papanikolaou, M. G., Hadjithoma, S., Miras, H. N. , Keramidas, A. D. and Kabanos, T. A. (2018) Cobalt(II), nickel(II) and zinc(II) coordination chemistry of the N , N ′-disubstituted hydroxylamine-(diamido) ligand, 3,3′-(hydroxyazanediyl)dipropanamide. Polyhedron, 151, pp. 417-425. (doi: 10.1016/j.poly.2018.06.002)

Passadis, S., Kabanos, T., Song, Y.-F. and Miras, H. (2018) Self-assembly in polyoxometalate and metal coordination-based systems: synthetic approaches and developments. Inorganics, 6(3), 71. (doi: 10.3390/inorganics6030071)

McAllister, J. and Miras, H. N. (2018) Building block libraries and structural considerations in the self-assembly of polyoxometalate and polyoxothiometalate systems. Structure and Bonding, 176, pp. 1-29. (doi: 10.1007/430_2017_5)

Purcell, J. W., Long, D.-L. , Lee, E. C. , Cronin, L. and Miras, H. N. (2018) Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates. Dalton Transactions, 47(18), pp. 6283-6287. (doi: 10.1039/C8DT00832A) (PMID:29667663) (PMCID:PMC5944425)

Miras, H. N. , Sartzi, H., Long, D.-L. , Sproules, S. and Cronin, L. (2018) Directed self-assembly, symmetry breaking, and electronic modulation of metal oxide clusters by pyramidal heteroanions. Chemistry: A European Journal, 24(17), pp. 4399-4411. (doi: 10.1002/chem.201705711) (PMID:29315925)

Nicolaou, M., Papanikolaou, M., Tsipis, A., Kabanos, T., Keramidas, A., Sproules, S. and Miras, H. N. (2018) Design and assembly of covalently functionalised polyoxofluorovanadate molecular hybrids. Chemistry: A European Journal, 24(15), pp. 3836-3845. (doi: 10.1002/chem.201705730) (PMID:29319211)

Li, T., Zhang, W., Chen, W., Miras, H. N. and Song, Y.-F. (2018) Layered double hydroxide anchored ionic liquids as amphiphilic heterogeneous catalysts for the Knoevenagel condensation reaction. Dalton Transactions, 47(9), pp. 3059-3067. (doi: 10.1039/c7dt03665e) (PMID:29184948)

McGlynn, J. C., Cascallana-Matías, I., Fraser, J. P., Roger, I., McAllister, J. , Miras, H. N. , Symes, M. D. and Ganin, A. Y. (2018) Molybdenum ditelluride rendered into an efficient and stable electrocatalyst for the hydrogen evolution reaction by polymorphic control. Energy Technology, 6(2), pp. 345-350. (doi: 10.1002/ente.201700489)

Li, T., Zhang, W., Chen, W., Miras, H. N. and Song, Y.-F. (2018) Modular polyoxometalate-layered double hydroxides as efficient heterogeneous sulfoxidation and epoxidation catalysts. ChemCatChem, 10(1), pp. 188-197. (doi: 10.1002/cctc.201701056)

2017

Fu, J., Meng, J.-L., Wei, M.-J., Zang, H.-Y., Tan, H.-Q., Wang, Y.-H., Miras, H. N. and Li, Y.-G. (2017) Cross-linked CoMoO4/rGO nanosheets as oxygen reduction catalyst. Catalysts, 7(12), 375. (doi: 10.3390/catal7120375)

Li, T., MIras, H. N. and Song, Y.-F. (2017) Polyoxometalate (POM)-layered double hydroxides (LDH) composite materials: design and catalytic applications. Catalysts, 7(9), 260. (doi: 10.3390/catal7090260)

Duros, V., Grizou, J. , Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human versus robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie (International Edition), 56(36), pp. 10815-10820. (doi: 10.1002/anie.201705721) (PMID:28649740) (PMCID:PMC5577512)

Zang, H.-Y., Purcell, J. W., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}. Chemical Communications, 53(61), pp. 8585-8587. (doi: 10.1039/c7cc04398h) (PMID:28718479)

Purcell, J. W., Miras, H. , Long, D.-L. , Markopoulou, P. and Cronin, L. (2017) Tellurite-squarate driven assembly of a new family of nanoscale clusters based on (Mo2O2S2)2+. Chemistry: A European Journal, 23(40), pp. 9683-9689. (doi: 10.1002/chem.201701920) (PMID:28548217) (PMCID:PMC5575479)

Ruiz de la Oliva, A., Sans, V., Miras, H. , Long, D. L. and Cronin, L. (2017) Coding the assembly of polyoxotungstates with a programmable reaction system. Inorganic Chemistry, 56(9), pp. 5089-5095. (doi: 10.1021/acs.inorgchem.7b00206) (PMID:28414229) (PMCID:PMC5423703)

Vantourout, J. C., Miras, H. N. , Isidro-Llobet, A., Sproules, S. and Watson, A. J.B. (2017) Spectroscopic studies of the Chan–Lam amination: a mechanism-inspired solution to boronic ester reactivity. Journal of the American Chemical Society, 139(13), pp. 4769-4779. (doi: 10.1021/jacs.6b12800) (PMID:28266843)

Roger, I., Moca, R., Miras, H. , Crawford, K. G., Moran, D. A.J. , Ganin, A. Y. and Symes, M. D. (2017) The direct hydrothermal deposition of cobalt-doped MoS2 onto fluorine-doped SnO2 substrates for catalysis of the electrochemical hydrogen evolution reaction. Journal of Materials Chemistry A, 5(4), pp. 1472-1480. (doi: 10.1039/C6TA08287D)

2016

Xu, Y., Xuan, W., Zhang, M., Miras, H. N. and Song, Y.-F. (2016) A multicomponent assembly approach for the design of deep desulfurization heterogeneous catalysts. Dalton Transactions, 45(48), pp. 19511-19518. (doi: 10.1039/C6DT03445D) (PMID:27896337)

Yao, Z., Miras, H. N. and Song, Y.-F. (2016) Efficient concurrent removal of sulfur and nitrogen contents from complex oil mixtures by using polyoxometalate-based composite materials. Inorganic Chemistry Frontiers, 3(8), pp. 1007-1013. (doi: 10.1039/C6QI00130K)

Zang, H., Surman, A. , Long, D. L. , Cronin, L. and Miras, H. N. (2016) Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks. Chemical Communications, 52(58), pp. 9109-9112. (doi: 10.1039/C6CC01041E) (PMID:26982102)

Hong, L., Win, P., Zhang, X., Chen, W., Miras, H. N. and Song, Y.-F. (2016) Covalent immobilization of polyoxotungstate on alumina and its catalytic generation of sulfoxides. Chemistry: A European Journal, 22(32), pp. 11232-11238. (doi: 10.1002/chem.201601864) (PMID:27400134)

Takashima, Y., Miras, H. N. , Glatzel, S. and Cronin, L. (2016) Shrink wrapping redox-active crystals of polyoxometalate open frameworks with organic polymers via crystal induced polymerisation. Chemical Communications, 52(50), pp. 7794-7797. (doi: 10.1039/C6CC03031A) (PMID:27203804) (PMCID:PMC6055993)

Liu, K., Xu, Y., Yao, Z., Miras, H.N. and Song, Y.-F. (2016) Polyoxometalate-intercalated layered double hydroxides as efficient and recyclable bi-functional catalysts for cascade reactions. ChemCatChem, 8(5), pp. 929-937. (doi: 10.1002/cctc.201501365)

Passadis, S. S., Tsiafoulis, C., Drouza, C., Tsipis, A. C., Miras, H. N. , Keramidas, A. D. and Kabanos, T. A. (2016) Synthesis, bonding, and reactivity of vanadium(IV) oxido–fluorido compounds with neutral chelate ligands of the general formula cis-[VIV(═O)(F)(LN–N)2]+. Inorganic Chemistry, 55(4), pp. 1364-1366. (doi: 10.1021/acs.inorgchem.5b02895) (PMID:26794835)

2015

Liu, K., Yao, Z., Miras, H. N. and Song, Y.-F. (2015) Facile immobilization of a Lewis acid polyoxometalate onto layered double hydroxides for highly efficient N-oxidation of pyridine based derivatives and denitrogenation. ChemCatChem, 7(23), pp. 3903-3910. (doi: 10.1002/cctc.201500594)

Jia, Y., Fang, Y., Zhang, Y., Miras, H. N. and Song, Y.-F. (2015) Classical Keggin intercalated into layered double hydroxides: facile preparation and catalytic efficiency in Knoevenagel condensation reaction. Chemistry: A European Journal, 21(42), pp. 14862-14870. (doi: 10.1002/chem.201501953) (PMID:26337902)

Chen, J.-J., Symes, M. D. , Fan, S.-C., Zheng, M.-S., Miras, H. N. , Dong, Q.-F. and Cronin, L. (2015) High performance polyoxometalate-based cathode materials for rechargeable lithium ion batteries. Advanced Materials, 27(31), pp. 4649-4654. (doi: 10.1002/adma.201501088) (PMID:26177828)

Chen, Y., Yao, Z., Miras, H. N. and Song, Y.-F. (2015) Modular polyoxometalate-layered double hydroxide composites as efficient oxidative catalysts. Chemistry: A European Journal, 21(30), pp. 10812-10820. (doi: 10.1002/chem.201501214) (PMID:26176975)

Nakamura, I., Miras, H. N. , Fujiwara, A., Fujibayashi, M., Song, Y.-F., Cronin, L. and Tsunashima, R. (2015) Investigating the formation of 'Molybdenum Blues' with gel electrophoresis and mass spectrometry. Journal of the American Chemical Society, 137(20), pp. 6524-6530. (doi: 10.1021/ja512758j) (PMID:25897816)

2014

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi: 10.1038/nature13951) (PMID:25409147)

Xuan, W., Surman, A. J. , Miras, H. N., Long, D. L. and Cronin, L. (2014) Controlling the ring curvature, solution assembly, and reactivity of gigantic molybdenum blue wheels. Journal of the American Chemical Society, 136(40), pp. 14114-14120. (doi: 10.1021/ja5062483)

Miras, H. N. , Vilà-Nadal, L. and Cronin, L. (2014) Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 43(16), pp. 5679-5699. (doi: 10.1039/c4cs00097h) (PMID:25005364)

Miras, H. N. (2014) Molecular chalcoxides (ChalcoPolyoxometalates):a family of functional materials with emergent properties. Chemistry: A European Journal, 20(34), pp. 10554-10560. (doi: 10.1002/chem.201402407)

Miras, H. (2014) Molecular metal oxides: toward a directed and functional future. In: Pignataro, B. (ed.) Discovering the Future of Molecular Sciences. Wiley-VCH Verlag: Weinheim, Germany, pp. 191-215. ISBN 9783527335442

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2014) Assembly and core transformation properties of two tetrahedral clusters:([FeIII13P8W60O227(OH)15(H2O)2]30− and [FeIII13P8W60O224(OH)12(PO4)4]33−. Dalton Transactions, 43(13), pp. 5190-5199. (doi: 10.1039/c3dt53382d)

Tziouris, P. A., Tsiafoulis, C. G., Vlasiou, M., Miras, H. N. , Sigalas, M. P., Keramidas, A. D. and Kabanos, T. A. (2014) Interaction of chromium(III) with aN,N′-disubstituted hydroxylamine-(diamido) ligand: a combined experimental and theoretical study. Inorganic Chemistry, 53(21), pp. 11404-11414. (doi: 10.1021/ic501778d)

Zang, H.-Y., Ruiz de la Oliva, A., Miras, H. N. , Long, D.-L. , McBurney, R. T. and Cronin, L. (2014) Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine. Nature Communications, 5, pp. 1-8. (doi: 10.1038/ncomms4715)

2013

Zang, H., Chen, J.-J., Long, D.-L. , Cronin, L. and Miras, H. N. (2013) Assembly of thiometalate-based [Mo₁₆] and [Mo₃₆] composite clusters combining [Mo₂O₂S₂],²⁺ cations and selenite anions. Advanced Materials, 25(43), pp. 6245-6249. (doi: 10.1002/adma.201302565)

Long, D.L. , Yan, J., Ruiz De La Oliva, A., Busche, C. , Miras, H.N. , Errington, R.J. and Cronin, L. (2013) A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage. Chemical Communications, 49(84), pp. 9731-9733. (doi: 10.1039/c3cc45659e)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) Exploring time assembly of supramolecular polyoxometalate triangular morphologies with johnson solid cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19−. Inorganic Chemistry, 52(16), pp. 9284-9289. (doi: 10.1021/ic400542x)

Zang, H.-Y., Miras, H. N. , Long, D. L. , Rausch, B. and Cronin, L. (2013) Template-directed assembly of polyoxothiometalate scaffolds into nanomolecular architectures. Angewandte Chemie (International Edition), 52(27), pp. 6903-6906. (doi: 10.1002/anie.201300578)

Miras, H. N. , Chilas, G. I., Cronin, L. and Kabanos, T. A. (2013) Sulfite anions as structure-directing templates for the engineering of modular polyoxometalates. European Journal of Inorganic Chemistry, 2013(10-11), pp. 1620-1630. (doi: 10.1002/ejic.201201065)

Gabb, D., Pradeep, C. P., Boyd, T., Mitchell, S. G., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) A general route for the transfer of large, highly-charged polyoxometalates from aqueous to organic phase. Polyhedron, 52, pp. 159-164. (doi: 10.1016/j.poly.2012.10.015)

2012

Corella-Ochoa, M.N., Miras, N., Long, D.L. and Cronin, L. (2012) Controlling the self-assembly of a mixed-metal Mo/V-selenite family of polyoxometalates. Chemistry: A European Journal, 18(43), pp. 13743-13754. (doi: 10.1002/chem.201200912)

Xu, F., Miras, H.N. , Scullion, R.A., Long, D.L. , Thiel, J. and Cronin, L. (2012) Correlating the magic numbers of inorganic nanomolecular assemblies with a {Pd₈₄} molecular-ring Rosetta Stone. Proceedings of the National Academy of Sciences of the United States of America, 109(29), pp. 11609-11612. (doi: 10.1073/pnas.1202981109)

Miras, H. and Cronin, L. (2012) Electrospray and cryospray mass spectrometry: from serendipity to designed synthesis of supramolecular coordination and polyoxometalate clusters. In: Pignataro, B. (ed.) New Strategies in Chemical Synthesis and Catalysis. Wiley-VCH Verlag: Weinheim, pp. 3-32. ISBN 9783527330904

Lydon, C., Busche, C. , Miras, H.N. , Delf, A., Long, D.-L. , Yellowlees, L. and Cronin, L. (2012) Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates. Angewandte Chemie (International Edition), 51(9), pp. 2115-2118. (doi: 10.1002/anie.201105829)

de la Oliva, A.R., Sans Sangorrin, V., Miras, H.N. , Yan, J., Zang, H., Richmond, C.J., Long, D.L. and Cronin, L. (2012) Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system. Angewandte Chemie (International Edition), 51(51), pp. 12759-12762. (doi: 10.1002/anie.201206572)

Gabb, D., Pradeep, C.P., Miras, H.N. , Mitchell, S.G., Long, D.L. and Cronin, L. (2012) Organic-soluble lacunary {M-2(P2W15)(2)} polyoxometalate sandwiches showing a previously unseen alpha beta beta alpha isomerism. Dalton Transactions, 41(33), pp. 10000-10005. (doi: 10.1039/C2DT30616F)

Li, F., Long, D.L. , Cameron, J.M., Miras, H.N. , Pradeep, C., Xu, L. and Cronin, L. (2012) Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV). Dalton Transactions, 41(33), pp. 9859-9862. (doi: 10.1039/C2DT30627A)

Miras, H.N. , Richmond, C.J., Long, D.-L. and Cronin, L. (2012) Solution-phase monitoring of the structural evolution of a molybdenum blue nanoring. Journal of the American Chemical Society, 134(8), pp. 3816-3824. (doi: 10.1021/ja210206z)

Miras, H.N. , Sorus, M., Hawkett, J., Sells, D.O., McInnes, E.L. and Cronin, L. (2012) Oscillatory template exchange in polyoxometalate capsules: a ligand-triggered, redox-powered, chemically damped oscillation. Journal of the American Chemical Society, 134(16), pp. 6980-6983. (doi: 10.1021/ja302861z)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Engineering polyoxometalates with emergent properties. Chemical Society Reviews, 41(22), pp. 7403-7430. (doi: 10.1039/C2CS35190K)

Richmond, C.J. et al. (2012) A flow-system array for the discovery and scale up of inorganic clusters. Nature Chemistry, 4(12), pp. 1038-1044. (doi: 10.1038/nchem.1489)

Zang, H., Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Assembly and autochirogenesis of a chiral inorganic polythioanion Mobius strip via symmetry breaking. Journal of the American Chemical Society, 134(28), pp. 11376-11379. (doi: 10.1021/ja304371j)

2011

Miras, H.N. , Zang, H.Y., Long, D.L. and Cronin, L. (2011) Direct synthesis and mass spectroscopic observation of the {M40} polyoxothiometalate wheel. European Journal of Inorganic Chemistry, 2011(33), pp. 5105-5111. (doi: 10.1002/ejic.201100833)

Mitchell, S. G. et al. (2011) A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands. Angewandte Chemie (International Edition), 50(39), pp. 9154-9157. (doi: 10.1002/anie.201102727)

Corella-Ochoa, M.N., Miras, H.N. , Kidd, A., Long, D.L. and Cronin, L. (2011) Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO₃^2-: {Mo₁₂V₁₂Te₃}, {Mo₁₂V₁₂Te₂} and {Mo₁₇V₈Te}. Chemical Communications, 47(31), pp. 8799-8801. (doi: 10.1002/chin.201143020)

Mitchell, S.G., Boyd, T., Miras, H.N. , Long, D.L. and Cronin, L. (2011) Extended polyoxometalate framework solids: two Mn^II-linked {P₈W₄₈} network arrays. Inorganic Chemistry, 50(1), pp. 136-143. (doi: 10.1021/ic101472s)

Cronin, L. , Molina, P.I. and Miras, H.N. (2011) Polyoxometalate-based solar cells for water splitting. Proceedings of the SPIE: The International Society for Optical Engineering, 8109, 81090C. (doi: 10.1117/12.895296)

Gao, J., Yan, J., Mitchell, S.G., Miras, H.N. , Boulay, A.G., Long, D.L. and Cronin, L. (2011) Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties. Chemical Science, 2(8), pp. 1502-1508. (doi: 10.1039/C1SC00150G)

Miras, H.N. , Stone, D., Long, D.L. , McInnes, E.J.L., Kögerler, P. and Cronin, L. (2011) Exploring the structure and properties of transition metal templated {VM₁₇(VO₄)₂} Dawson-like capsules. Inorganic Chemistry, 50(17), pp. 8384-8391. (doi: 10.1021/ic200943s)

Musumeci, C., Luzio, A., Pradeep, C.P., Miras, H.N. , Rosnes, M.H., Song, Y.-F., Long, D.L. , Cronin, L. and Pignataro, B. (2011) Programmable surface architectures derived from hybrid polyoxometalate-based clusters. Journal of Physical Chemistry C, 115(11), pp. 4446-4455. (doi: 10.1021/jp109916e)

Pradeep, C.P., Li, F.-Y., Lydon, C., Miras, H.N. , Long, D.L. , Xu, L. and Cronin, L. (2011) Design and synthesis of "dumb-bell" and "triangular" inorganic-organic hybrid nanopolyoxometalate clusters and their characterisation through ESI-MS analyses. Chemistry: A European Journal, 17(27), pp. 7472-7479. (doi: 10.1002/chem.201100257)

Vila-Nadal, L. , Wilson, E.F., Miras, H.N. , Rodriguez-Fortea, A., Cronin, L. and Poblet, J.M. (2011) Combined theoretical and mass spectrometry study of the formation-fragmentation of small polyoxomolybdates. Inorganic Chemistry, 50(16), pp. 7811-7819. (doi: 10.1021/ic200969h)

Vilà-Nadal, L. , Mitchell, S.G., Rodríguez-Fortea, A., Miras, H.N. , Cronin, L. and Poblet, J.M. (2011) Connecting theory with experiment to understand the initial nucleation steps of heteropolyoxometalate clusters. Physical Chemistry Chemical Physics, 13(45), pp. 20136-20145. (doi: 10.1039/c1cp21209e)

Xu, F., Scullion, R.A., Yan, J., Miras, H.N. , Busche, C. , Scandurra, A., Pignataro, B., Long, D.-L. and Cronin, L. (2011) A supramolecular heteropolyoxopalladate {Pd₁₅} cluster host encapsulating a {Pd₂} dinuclear guest: [Pd^II_2⊂{H₇Pd^II₁₅O₁₀(PO₄)₁₀}]⁹⁻. Journal of the American Chemical Society, 133(13), pp. 4684-4686. (doi: 10.1021/ja1105514)

2010

Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core. Inorganica Chimica Acta, 363(15), pp. 4240-4246. (doi: 10.1016/j.ica.2010.07.020)

Boyd, T., Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) Understanding and mapping the assembly of a family of trimeric polyoxometalates: transition metal mediated Wells-Dawson (M-18)-trimers. Dalton Transactions, 39(28), pp. 6460-6465. (doi: 10.1039/C002633F)

McGlone, T., Vilà-Nadal, L. , Miras, H.N. , Long, D.L. , Poblet, J.M. and Cronin, L. (2010) Assembly of titanium embedded polyoxometalates with unprecedented structural features. Dalton Transactions, 39(48), pp. 11599-11604. (doi: 10.1039/c0dt01327g)

Miras, H.N. , Chakraborty, I. and Raptis, R.G. (2010) Tri-, deca- and dodecanuclear Co(III)-pyrazolate metallacycles. Chemical Communications, 46(15), pp. 2569-2571. (doi: 10.1039/B920486E)

Miras, H.N. , Ochoa, M.N.C., Long, D.L. and Cronin, L. (2010) Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}. Chemical Communications, 46(43), pp. 8148-8150. (doi: 10.1039/C0CC02849E)

Mitchell, S.G., Streb, C., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2010) Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture. Nature Chemistry, 2(4), pp. 308-312. (doi: 10.1038/NCHEM.581)

Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi: 10.1002/anie.201002672)

Tsunashima, R., Long, D.L. , Miras, H.N. , Gabb, D., Pradeep, C.P. and Cronin, L. (2010) The construction of high-nuclearity isopolyoxoniobates with pentagonal building blocks: [HNb27O76](16-) and [H10Nb31O93(CO3)](23-). Angewandte Chemie (International Edition), 49(1), pp. 113-116. (doi: 10.1002/anie.200903970)

Yan, J., Gao, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Self-assembly of a nanosized, saddle-shaped, solution-stable polyoxometalate anion built from pentagonal building blocks: [H34W119Se8Fe2O420](54-). Journal of the American Chemical Society, 132(33), pp. 11410-11411. (doi: 10.1021/ja104043s)

Yan, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Cation controlled assembly and transformation of mono- and bi-sulfite templated dawson-type polyoxotungstates. Inorganic Chemistry, 49(4), pp. 1819-1825. (doi: 10.1021/ic9021646)

2009

Mitchell, S.G., Khanra, S., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2009) The trinity of polyoxometalates: connecting {M-12} Keggin and {M-18} Dawson clusters to triangles. Chemical Communications(19), pp. 2712-2714. (doi: 10.1039/b903206a)

Miras, H.N. , Wilson, E.F. and Cronin, L. (2009) Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry. Chemical Communications(11), pp. 1297-1311. (doi: 10.1039/b819534j)

2008

Miras, H. and Cronin, L. (2008) Polyoxometalate nanocapsules: from structure to function. In: Atwood, J. L. and Steed, J. W. (eds.) Organic Nanostructures. Wiley-VCH Verlag: Weinheim, pp. 277-291. ISBN 9783527318360

Miras, H.N. , Long, D.L. , Kogerler, P. and Cronin, L. (2008) Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties. Dalton Transactions(2), pp. 214-221. (doi: 10.1039/b714285d)

Miras, H.N. , Stone, D.J., McInnes, E.J.L., Raptis, R.G., Baran, P., Chilas, G.I., Sigalas, M.P., Kabanos, T.A. and Cronin, L. (2008) Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-). Chemical Communications(39), pp. 4703-4705. (doi: 10.1039/B811279G)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2008) Structural evolution of "S"-shaped [H4W22O74](12-) and ""-shaped [H10W34O116](18-) isopolyoxotungstate clusters. Angewandte Chemie (International Edition), 47(44), pp. 8420-8423. (doi: 10.1002/anie.200802109)

Miras, H.N. , Zhao, H., Herchel, R., Rinaldi, C., Perez, S. and Raptis, R.G. (2008) Synthesis and characterization of linear trinuclear Pd, Co, and Pd/Co pyrazolate complexes. European Journal of Inorganic Chemistry(30), pp. 4745-4755. (doi: 10.1002/ejic.200800349)

Ritchie, C. et al. (2008) Polyoxometalate-mediated self-assembly of single-molecule magnets: {[XW9O34](2)[(Mn4Mn2O4)-Mn-III-O-II(H2O)(4)]}(12-). Angewandte Chemie (International Edition), 47(30), pp. 5609-5612. (doi: 10.1002/anie.200801281)

Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N. , Long, D.L. , Boyd, T., Peacock, R.D., McGlone, T. and Cronin, L. (2008) Reversible redox reactions in an extended polyoxometalate framework solid. Angewandte Chemie (International Edition), 47(36), pp. 6881-6884. (doi: 10.1002/anie.200802594)

2005

Chilas, G.I., Miras, H.N. , Manos, M.J., Woollins, J.D., Slawin, A.M.Z., Stylianou, M., Keramidas, A.D. and Kabanos, T.A. (2005) Oxovanadium(IV)-sulfite compounds: Synthesis and structural and physical studies. Pure and Applied Chemistry, 77(9), pp. 1529-1538. (doi: 10.1351/pac200577091529)

Miras, H.N. , Raptis, R., Baran, P., Lalioti, N., Harrison, A. and Kabanos, T.A. (2005) Novel compound with a 1D network structure constructed by ((VO)-O-IV)(6)(mu(4)-O)(2)(mu(3)-OH)(2)(mu(3)-SO3)(4)](2-)/SO32- and 4,4 `-bipyridine components: its synthesis, characterization, and magnetic behavior. Comptes Rendus Chimie, 8(6-7), pp. 957-962. (doi: 10.1016/j.crci.2004.12.010)

Miras, H.N. , Raptis, R.G., Lalioti, N., Sigalas, M.P., Baran, P. and Kabanos, T.A. (2005) A novel series of vanadium-sulfite polyoxometalates: synthesis, structural, and physical studies. Chemistry: A European Journal, 11(8), pp. 2295-2306. (doi: 10.1002/chem.200400203)

2003

Manos, M.J., Miras, H.N. , Tangoulis, V., Woollins, J.D., Slawin, A.M.Z. and Kabanos, T.A. (2003) Polyoxovanadium(IV) sulfite compounds: Synthesis, structural, and physical studies. Angewandte Chemie (International Edition), 42(4), pp. 425-427. (doi: 10.1002/anie.200390129)

Miras, H.N. , Woollins, J.D., Slawin, A.M., Raptis, R., Baran, P. and Kabanos, T.A. (2003) A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {Mo-2(V)(mu-S)(2)O-2](6)(mu(3)-SO3)(4)(mu-SO3)(12)}(20-)anion. Dalton Transactions(19), pp. 3668-3670. (doi: 10.1039/B309473C)

This list was generated on Tue Oct 3 20:07:02 2023 BST.

Jump to: Articles | Book Sections

Number of items: 136.

Articles

Elliott, A. and Miras, H.N. (2022) Recent advances in polyoxothiometalate chemistry. Journal of Coordination Chemistry, 75(11-14), pp. 1467-1493. (doi: 10.1080/00958972.2022.2086049)

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi: 10.1038/nature13951) (PMID:25409147)

Miras, H. N. , Vilà-Nadal, L. and Cronin, L. (2014) Polyoxometalate based open-frameworks (POM-OFs). Chemical Society Reviews, 43(16), pp. 5679-5699. (doi: 10.1039/c4cs00097h) (PMID:25005364)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Engineering polyoxometalates with emergent properties. Chemical Society Reviews, 41(22), pp. 7403-7430. (doi: 10.1039/C2CS35190K)

Richmond, C.J. et al. (2012) A flow-system array for the discovery and scale up of inorganic clusters. Nature Chemistry, 4(12), pp. 1038-1044. (doi: 10.1038/nchem.1489)

Miras, H.N. , Chakraborty, I. and Raptis, R.G. (2010) Tri-, deca- and dodecanuclear Co(III)-pyrazolate metallacycles. Chemical Communications, 46(15), pp. 2569-2571. (doi: 10.1039/B920486E)

Book Sections

This list was generated on Tue Oct 3 20:07:02 2023 BST.

Grants

Research Grant Income

2019-2023, EPSRC (£999 K)

"3DSynth: Design and fabrication of cartridges for digital chemical synthesis"H. N. Miras (Co-I), L. Cronin (PI)

2018-2023, EPSRC (£1.6 M)

"Complex Chemical Systems Platform Exploring Inorganic Intelligence" H. N. Miras (Co-I), C. Busche (Co-I), D.-L. Long (Co-I), L. Cronin (PI)

2014-2020, EPSRC (£3.6 M)

"Programmable 'Digital' Synthesis for Discovery & Scale-up of Molecules, Clusters & Nanomaterials" H. N. Miras (Co-I), M. Symes (Co-I), M. Padget (Co-I), L. Cronin (PI)

2012-2017, EPSRC (£1.4 M)

"Programmable Molecular Metal Oxides (PMMOs): From Fundamentals to Application" H. N. Miras (Co-I),D.-L. Long (Co-I), L. Cronin (PI)

2010-2015, Royal Society of Edinburgh co-funded by Marie Curie actions (£528 K)

"Non equilibrium engineering methods for the assembly of functional metal oxides" H. N. Miras (PI)

2013-2015, University of Glasgow Leadership Research Fellow award (£125 K) H. N. Miras (PI)

Supervision

Neus Corella Ochoa, PhD graduated 2008-2012
Pedro Molina Sanchez, PhD graduated 2009-2013
Hongying Zhang, PhD graduated 2009-2013
Merce Martin, PhD graduated 2013-2017
Charikleia Sartzi, PhD graduated 2013-2017
Jamie Purcell, PhD graduated 2013-2017
Vasilios Douros, PhD graduated 2014-2018
James McAllister, PhD graduated 2016-2020
Alexander Elliot, PhD graduated 2018-2022
Mark Gray, PhD student since October 2021
Giulia Pellegrino, PhD student since October 2022
Project students
- Final year / MSci project
- Arcadia project
- EPSRC vacation scholarship placement

Teaching

Teaching & Admin

Director of Learning & Teaching (School of Chemistry)
Level-4 Inorganic Mechanisms
Interactive Teaching Units (ITU 1 and ITU 2)
Lever-3
- Inorganic tutorials coordinator

Spectroscopy workshop
Level-1: Quantitative 1
Level-1: Synthesis Lab 1
Level-3: Inorganic Lab

Adviser of Studies
International Association for the Exchange of Students for Technical Experience (IASTE) Coordinator
Member of Senate
First aider

Professional activities & recognition

Prizes, awards & distinctions

2016: Invited contribution to the “Emerging Investigators 2016” volume of Chemical Communications (Royal Society of Chemisrty)

Research fellowships

2010 - 2015: Royal Society of Edinburgh / Scottish Executive Personal Research Fellowship

Grant committees & research advisory boards

2015 - -: EPSRC, Associate Peer Review College

Editorial boards

2015 - -: Materials editorial board
2015 - -: Molecules editorial board

Professional & learned societies

2013 - -: Member, Higher Education Academy
2007 - -: Member, Royal Society of Chemistry

Selected international presentations

2019: EICC-5 (Moscow, Russia)
2019: Core-to-Core Japan-UK (Hiroshima, Japan)
2018: International Conference on Advanced Complex Inorganic Nanomaterials (Namur, Belgium)
2018: 7th EuCheMS (Liverpool, UK)
2017: 4th EuCheMS Inorganic Chemistry (Copenhagen, Denmark)
2017: 13th International Conference on Materials Chemistry (MC13) (Liverpool, UK)
2016: 4th “Frontiers in Metal Oxide Cluster Science” symposia (Newcastle, UK)

Research datasets

Jump to: 2016

Number of items: 1.

2016

Roger, I., Moca, R., Moiras, H., Crawford, K. G., Moran, D., Ganin, A. and Symes, M. (2016) The Direct Hydrothermal Deposition of Cobalt-Doped MoS2 onto Fluorine-Doped SnO2 Substrates for Catalysis of the Electrochemical Hydrogen Evolution Reaction. [Data Collection] (Unpublished)

This list was generated on Tue Oct 3 20:07:04 2023 BST.

Additional information

Awards

PhD (Ioannina, Greece)

External Appointments & Positions

Member of the EPSRC Associate Peer Review College
Fellow of the Higher Education Academy
Editorial Board Member of Materials (2017- present)
Editorial Board Member of Molecules (electrochemistry section) (2017- present)
Guest Editor for the Theamed Issue on "Self-Assembly of Supramolecualr Coordination Compounds" in Inorganics (http://www.mdpi.com/journal/inorganics /special_issues/supramolecular_coordination_compounds)
Guest Editor for the Theamed Issue on "REcent Advances in Polyoxometalate-Catalyzed Reactions" in Catalysts (https://www.mdpi.com/journal/catalysts/special_issues/Recent_Advances_in_Polyoxometalate)
Member of the Royal Society of Chemistry
Member of Senate

Selected Recent Talks

“Bottom-up design approach for the preparation of H₂ evolution catalysts” International Symposium on Advanced Complex Inorganic Nanomaterials (ACIN 2018), 12-17 July, 2018, Namur, Belgium (Invited Oral Presentation)
"Modulating the Complexity of Chalcoxide Chemical Systems and Discovery of a Nanosized {(Mo₂O₂S₂)_a(OH)_b(SeO₃)_c(C₄O₄)_d(Mo₂O₇)_e}^n- family" EICC-4 July 2-5, 2017, Copenhagen, Denmark (Oral presentation)
"Directed Self-Assembly, Electronic Modulation and Isomer “locking” in POM systems" FMOCS IV-PoCheMoN 2016, July 10 – 14, 2016, Newcastle, UK. (Invited Oral Presentation)
“ChalcoPOMs: A family of materials with emergent properties” 12th International Conference on Materials Chemistry (MC12), 20-23 July, 2015, York, UK
‘Molecular Chalcoxide-based Materials (ChalcoPOMs): Design Approach and Emergence of Functionality’ 5th EuCheMS Chemistry Congress 2014, 30 August 2014, Istanbul, Turkey (Oral presentation)
"Building blocks for the Engineering of Modular Polyoxometalates" International Symposium on Advanced Complex Inorganic Nanomaterials (ACIN), July 15-19, 2013, Namur, Belgium (Oral presentation)
‘Chemical Oscillations in POM Chemistry” 4th EuCheMS Chemistry Congress 2012, 26 – 30 August in Prague, Czech Republic (Young Chemist Award finalist talk)
‘Controlling the Evolution of Molecules: Towards the Engineering of Tomorrow’s Molecular Devices’ SET for BRITAIN 2012, March 12, 2012, House of Commons, London, UK. (Invited science communication)
“Non Equilibrium Structured Nanomolecular Assemblies” International Symposium on Advanced Complex Inorganic Nanomaterials (ACIN), September 11-14, 2011, Namur, Belgium (Invited oral presentation)
“Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel” ACS 239th National Meeting, March 21 – 25, 2010, San Francisco, California, USA, Division of Inorganic Chemistry, General Inorganic Chemistry Session, paper number 1331 (Oral presentation)

Recent Outreach

“Making food from ....air”,Glasgow Science Festival, June 2014 (public lecture and question-and-answer session)
“Self-assembled chemical systems”, Glasgow, April 2014 (lecture and question-and-answer session to student representatives from Utrecht University )
University Open Day, Glasgow, Annually since 2010 (Studies and opportunities in Glasgow University: Information for prospective students)
Salter's Festival, Glasgow, Annually since 2010
Chemistry at Work, Glasgow, Anually since 2010

Harry Miras square photo

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Professor Haralampos Moiras

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Teaching & Admin

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Selected international presentations

Research datasets

2016

Additional information