Dr Deliang Long

  • Senior Research Fellow (Chemistry)

Research interests

Research Interests

Synthetic inorganic chemistry
Cluster materials

More details are available on the personal research pages

Research Topics

  • Polyoxometalates 
  • Ligand design and metal complexes 
  • Cluster synthesis and properties 
  • Chemical topology 
  • Chemical crystallography

Publication Highlights

Researcher ID button

  1. Assembly of molecular "layered" heteropolyoxometalate architectures. Jing Gao, Jun Yan, Sebastian Beeg, De-Liang Long, and Leory Cronin. Angew. Chem. Int. Ed. 2012, 51, 3373-3376. 
  2. Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties. Jing Gao, Jun Yan, Scott G. Mitchell, Haralampos N. Miras, Antony G. Boulay, De-Liang Long, and Leory Cronin. Chemical Science, 2011, 2, 1502-1508.
  3. Polyoxometalates: Building Blocks for Functional Nanoscale Systems. De-Liang Long, Ryo Tsunashima, Leroy Leroy Cronin, Angew. Chem. Int. Ed. 2010, 49, 1736-1758.
  4. Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel. Haralampos N. Miras, Geoffrey J. T. Cooper, De-Liang Long, Hartmut Bögge, Achim Müller, Carsten Streb, Leroy Cronin, Science 2010, 327, 72-74.
  5. Discovery of Heteroatom-"Embedded" Te subset of {W18O54} Nanofunctional Polyoxometalates by Use of Cryospray Mass Spectrometry. Jun Yan, De-Liang Long, Elizabeth F. Wilson, and Leroy Cronin, Angew. Chem. Int. Ed. 2009, 48, 4376-4380.
  6. Unravelling the Complexities of Polyoxometalates in Solution Using Mass Spectrometry: Protonation versus Heteroatom Inclusion. De-Liang Long, Carsten Streb, Yu-Fei Song, Scott Mitchell, Leroy Cronin. J. Am. Chem. Soc., 2008, 130, 1830-1832.
  7. Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices. De-Liang Long, Eric Burkholder, and Leroy Cronin. Chem. Soc. Rev., 2007, 36, 105-121.

Selected publications

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2013) One-pot versus sequential reactions in the self-assembly of gigantic nanoscale polyoxotungstates. Journal of the American Chemical Society, 135(5), pp. 1796-1805. (doi:10.1021/ja309237x)

Miras, H.N. , Cooper, G.J.T., Long, D.-L., Bogge, H., Muller, A., Streb, C. and Cronin, L. (2010) Unveiling the transient template in the self-assembly of a molecular oxide nanowheel. Science, 327(5961), pp. 72-74. (doi:10.1126/science.1181735)

Long, D.-L., Tsunashima, R. and Cronin, L. (2010) Polyoxometalates: building blocks for functional nanoscale systems. Angewandte Chemie (International Edition), 49(10), pp. 1736-1758. (doi:10.1002/anie.200902483)

Zhan, C.-H., Winter, R. S., Zheng, Q., Yan, J., Cameron, J. M., Long, D.-L. and Cronin, L. (2015) Assembly of tungsten-oxide-based pentagonal motifs in solution leads to nanoscale {W48}, {W56}, and {W92} polyoxometalate clusters. Angewandte Chemie (International Edition), 54(48), pp. 14308-14312. (doi:10.1002/anie.201506170) (PMID:26449850)

Gao, J., Yan, J., Mitchell, S.G., Miras, H.N. , Boulay, A.G., Long, D.L. and Cronin, L. (2011) Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties. Chemical Science, 2(8), pp. 1502-1508. (doi:10.1039/C1SC00150G)

Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi:10.1002/anie.200806343)

Xuan, W., Surman, A. J. , Zheng, Q., Long, D.-L. and Cronin, L. (2016) Self-templating and in situ assembly of a cubic cluster-of-clusters architecture based on a {Mo24Fe12} inorganic macrocycle. Angewandte Chemie (International Edition), 55(41), pp. 12703-12707. (doi:10.1002/anie.201603298) (PMID:27358195) (PMCID:PMC5396355)

Long, D.L. , Streb, C., Song, Y.-F., Mitchell, S. and Cronin, L. (2008) Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion. Journal of the American Chemical Society, 130(6), 1830-+. (doi:10.1021/ja075940z)

Zhan, C., Cameron, J. M., Gao, J., Purcell, J. W., Long, D. L. and Cronin, L. (2014) Time-resolved assembly of cluster-in-cluster {Ag12}-in-{W76} polyoxometalates under supramolecular control. Angewandte Chemie (International Edition), 53(39), pp. 10362-10366. (doi:10.1002/anie.201402932) (PMID:25087861)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2012) Assembly of molecular "layered" heteropolyoxometalate architectures. Angewandte Chemie (International Edition), 51(14), pp. 3373-3376. (doi:10.1002/anie.201108428)

Long, D.L. and Cronin, L. (2012) Pushing the frontiers in polyoxometalate and metal oxide cluster science. Dalton Transactions, 41(33), pp. 9815-9816. (doi:10.1039/c2dt90121h)

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi:10.1038/nature13951) (PMID:25409147)


Research datasets

Jump to: 2016 | 2014
Number of items: 3.

2016

Wiles, A. , Zhang, X., Fitzpatrick, B., Long, D. L. , Macgregor, S. A. and Cooke, G. (2016) Redox-mediated reactions of vinylferrocene: toward redox auxiliaries. [Data Collection]

Wiles, A. A., Fitzpatrick, B., McDonald, N. A., Westwater, M. M., Long, D.-L., Ebenhoch, B., Rotello, V. M., Samuel, I. D. W. and Cooke, G. (2016) Synthesis and properties of pteridine-2,4-dione-functionalised oligothiophenes. [Data Collection]

2014

Cogswell, T. J., Donald, C. S., Long, D. L. and Marquez, R. (2014) Short and efficient synthesis of fluorinated δ-lactams. [Data Collection]

This list was generated on Wed Jul 17 06:25:43 2019 BST.

Additional information

Awards

PhD (Nanjing)

Selected Recent Talks

  • Indaba7, Kruger National Park, South Africa, Sept. 2012
  • China National Inorganic Chemistry Meeting, Haerbin, China, July 2011
  • Scottish Dalton Meeting, Edinburgh, Scotland, June 2011
  • Frontiers in Metal oxide Cluster Sciences, Jerusalem, Israel, July 2010
  • China National Polyoxometalate Meeting, Fuzhou, China, Oct. 2009. 
  • 42nd IUPAC Congress, Glasgow, UK, Aug. 2009. 
  • Polyoxometalate Symposium, Bremen, Germany, July, 2009. 
  • European Cost D40 WG1 “Innovative Catalysis in Oxidation Reactions ", Tarragona, Spain. May, 2008. 
  • American Chemical Society 234th annual meeting, Boston, USA, Aug. 2007.

External Appointments & Positions

Member of RSC and IUCr


All publications

List by: Type | Date

Jump to: 2019 | 2018 | 2017 | 2016 | 2015 | 2014 | 2013 | 2012 | 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003
Number of items: 205.

2019

Xuan, W., Pow, R., Zheng, Q., Watfa, N., Long, D.-L. and Cronin, L. (2019) Ligand-directed template assembly for the construction of gigantic molybdenum blue wheels. Angewandte Chemie (International Edition), (doi:10.1002/anie.201901818) (PMID:31155800) (Early Online Publication)

Janusson, E. , de Kler, N., Vilà-Nadal, L. , Long, D.-L. and Cronin, L. (2019) Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection. Chemical Communications, 55(41), pp. 5797-5800. (doi:10.1039/C9CC02361E) (PMID:31041957)

Xuan, W., Pow, R., Watfa, N., Zheng, Q., Surman, A. J. , Long, D.-L. and Cronin, L. (2019) Stereoselective assembly of gigantic chiral molybdenum blue wheels using lanthanide ions and amino acids. Journal of the American Chemical Society, 141(3), pp. 1242-1250. (doi:10.1021/jacs.8b09750) (PMID:30495944)

2018

Lin, C.-G., Zhou, W., Xiong, X.-T., Xuan, W., Kitson, P. J., Long, D.-L. , Chen, W., Song, Y.-F. and Cronin, L. (2018) Digital control of multistep hydrothermal synthesis by using 3D printed reactionware for the synthesis of metal–organic frameworks. Angewandte Chemie (International Edition), 57(51), pp. 16716-16720. (doi:10.1002/anie.201810095) (PMID:30370977)

Granda, J. M., Donina, L., Dragone, V., Long, D.-L. and Cronin, L. (2018) Controlling an organic synthesis robot with machine learning to search for new reactivity. Nature, 559(7714), pp. 377-381. (doi:10.1038/s41586-018-0307-8) (PMID:30022133)

Purcell, J. W., Long, D.-L. , Lee, E. C. , Cronin, L. and Miras, H. N. (2018) Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates. Dalton Transactions, 47(18), pp. 6283-6287. (doi:10.1039/C8DT00832A)

Miras, H. N. , Sartzi, H., Long, D.-L. , Sproules, S. and Cronin, L. (2018) Directed self-assembly, symmetry breaking, and electronic modulation of metal oxide clusters by pyramidal heteroanions. Chemistry: A European Journal, 24(17), pp. 4399-4411. (doi:10.1002/chem.201705711) (PMID:29315925)

Martin-Sabi, M., Soriano-López, J., Winter, R. S., Chen, J.-J., Vilà-Nadal, L. , Long, D.-L. , Galán-Mascarós, J. R. and Cronin, L. (2018) Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction. Nature Catalysis, 1(3), pp. 208-213. (doi:10.1038/s41929-018-0037-1) (PMID:30079397) (PMCID:PMC6075698)

Zheng, Q., Vilà-Nadal, L. , Lang, Z., Chen, J.-j., Long, D.-L. , Mathieson, J. S., Poblet, J. M. and Cronin, L. (2018) Self-sorting of heteroanions in the assembly of cross-shaped polyoxometalate clusters. Journal of the American Chemical Society, 140(7), pp. 2595-2601. (doi:10.1021/jacs.7b11982) (PMID:29359931) (PMCID:PMC6075695)

Chen, J.-J., Ye, J.-C., Zhang, X.-G., Symes, M. D. , Fan, S.-C., Long, D.-L. , Zheng, M.-S., Wu, D.-Y., Cronin, L. and Dong, Q.-F. (2018) Design and performance of rechargeable sodium ion batteries, and symmetrical li-ion batteries with supercapacitor-like power density based upon polyoxovanadates. Advanced Energy Materials, 8(6), 1701021. (doi:10.1002/aenm.201701021)

2017

Yazigi, F.-J., Wilson, C. , Long, D.-L. and Forgan, R. S. (2017) Synthetic considerations in the self-assembly of coordination polymers of pyridine-functionalised hybrid Mn-Anderson polyoxometalates. Crystal Growth and Design, 17(9), pp. 4739-4748. (doi:10.1021/acs.cgd.7b00672)

Duros, V., Grizou, J., Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human versus robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie (International Edition), 56(36), pp. 10815-10820. (doi:10.1002/anie.201705721) (PMID:28649740) (PMCID:PMC5577512)

Duros, V., Grizou, J., Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human vs robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie, 129(36), pp. 10955-10960. (doi:10.1002/ange.201705721) (PMID:28649740)

Xuan, W., Pow, R., Long, D.-L. and Cronin, L. (2017) Exploring the molecular growth of two gigantic half-closed polyoxometalate clusters {Mo180} and {Mo130Ce6}. Angewandte Chemie (International Edition), 129(33), pp. 9859-9863. (doi:10.1002/ange.201702957) (PMID:28508585)

Zang, H.-Y., Purcell, J. W., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}. Chemical Communications, 53(61), pp. 8585-8587. (doi:10.1039/c7cc04398h) (PMID:28718479)

Purcell, J. W., Miras, H. , Long, D.-L. , Markopoulou, P. and Cronin, L. (2017) Tellurite-squarate driven assembly of a new family of nanoscale clusters based on (Mo2O2S2)2+. Chemistry: A European Journal, 23(40), pp. 9683-9689. (doi:10.1002/chem.201701920) (PMID:28548217)

Zhan, C., Busche, C., Long, D.-L. , Molina, P. I., Winter, R. S. and Cronin, L. (2017) Encapsulation of a {Cu16} cluster containing four [Cu4O4] cubanes within an isopolyoxometalate {W44} cluster. Chemical Communications, 53(52), pp. 7076-7079. (doi:10.1039/c7cc03544f) (PMID:28627534)

Ruiz de la Oliva, A., Sans, V., Miras, H. , Long, D. L. and Cronin, L. (2017) Coding the assembly of polyoxotungstates with a programmable reaction system. Inorganic Chemistry, 56(9), pp. 5089-5095. (doi:10.1021/acs.inorgchem.7b00206) (PMID:28414229) (PMCID:PMC5423703)

Boyd, T., Mitchell, S. G., Gabb, D., Long, D.-L. , Song, Y.-F. and Cronin, L. (2017) POMzites: a family of zeolitic polyoxometalate frameworks from a minimal building block library. Journal of the American Chemical Society, 139(16), pp. 5930-5938. (doi:10.1021/jacs.7b01807) (PMID:28368582) (PMCID:PMC5423706)

Zhan, C. et al. (2017) A metamorphic inorganic framework that can be switched between eight single-crystalline states. Nature Communications, 8, 14185. (doi:10.1038/ncomms14185) (PMID:28194009) (PMCID:PMC5316803)

Kulikov, V., Johnson, N. A.B., Surman, A. J. , Hutin, M., Kelly, S. K. , Hezwani, M., Long, D.-L. , Meyer, G. and Cronin, L. (2017) Spontaneous assembly of an organic-inorganic nucleic acid Z-DNA double-helix structure. Angewandte Chemie (International Edition), 56(4), pp. 1141-1145. (doi:10.1002/anie.201606658) (PMID:27900812) (PMCID:PMC6057607)

Miras, H.N. , Long, D.-L. and Cronin, L. (2017) Exploring self-assembly and the self-organization of nanoscale inorganic polyoxometalate clusters. In: van Eldik, R. and Cronin, L. (eds.) Polyoxometalate Chemistry. Series: Advances in inorganic chemistry, 69. Academic Press: Burlington, pp. 1-28. ISBN 9780128111055 (doi:10.1016/bs.adioch.2016.12.001)

2016

Christie, L. G. , Surman, A. J. , Scullion, R. A., Xu, F., Long, D.-L. and Cronin, L. (2016) Overcoming the crystallization bottleneck: a family of gigantic inorganic {Pdx}L(x=84, 72) palladium macrocycles discovered using solution techniques. Angewandte Chemie (International Edition), 55(41), pp. 12741-12745. (doi:10.1002/anie.201606005) (PMID:27634480) (PMCID:PMC5113701)

Xuan, W., Surman, A. J. , Zheng, Q., Long, D.-L. and Cronin, L. (2016) Self-templating and in situ assembly of a cubic cluster-of-clusters architecture based on a {Mo24Fe12} inorganic macrocycle. Angewandte Chemie (International Edition), 55(41), pp. 12703-12707. (doi:10.1002/anie.201603298) (PMID:27358195) (PMCID:PMC5396355)

Zhang, G., Liu, C., Long, D.-L. , Cronin, L. , Tung, C.-H. and Wang, Y. (2016) Water-soluble pentagonal-prismatic titanium-oxo clusters. Journal of the American Chemical Society, 138(35), pp. 11097-11100. (doi:10.1021/jacs.6b06290) (PMID:27525444)

Zang, H., Surman, A. , Long, D. L. , Cronin, L. and Miras, H. N. (2016) Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks. Chemical Communications, 52(58), pp. 9109-9112. (doi:10.1039/C6CC01041E) (PMID:26982102)

Porwol, L., Henson, A. , Kitson, P. J., Long, D. L. and Cronin, L. (2016) On the fly multi-modal observation of ligand synthesis and complexation of Cu complexes in flow with ‘benchtop’ NMR and mass spectrometry. Inorganic Chemistry Frontiers, 3(7), pp. 919-923. (doi:10.1039/C6QI00079G)

Zang, H.-Y., Chen, J.-J., Long, D. L. , Cronin, L. and Miras, H. N. (2016) Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters. Chemical Science, 7(6), pp. 3798-3804. (doi:10.1039/c5sc04944j)

Wiles, A. A. , Zhang, X., Fitzpatrick, B., Long, D.-L. , Macgregor, S. A. and Cooke, G. (2016) Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries. Dalton Transactions, 45(17), pp. 7220-7225. (doi:10.1039/C6DT00875E) (PMID:27063914)

Martin-Sabi, M., Winter, R. S., Lydon, C., Cameron, J. M., Long, D.-L. and Cronin, L. (2016) Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters. Chemical Communications, 52(5), pp. 919-921. (doi:10.1039/C5CC08486E) (PMID:26581307)

Letort, A., Long, D.-L. and Prunet, J. (2016) Study of cascade ring-closing metathesis reactions en route to an advanced intermediate of Taxol. Journal of Organic Chemistry, 81(24), pp. 12318-12331. (doi:10.1021/acs.joc.6b02264) (PMID:27978745)

Wiles, A. A. , Fitzpatrick, B., McDonald, N. A., Westwater, M. M., Long, D. L. , Ebenhoch, B., Rotello, V. M., Samuel, I. D. W. and Cooke, G. (2016) Synthesis and properties of pteridine-2,4-dione-functionalised oligothiophenes. RSC Advances, 6(10), pp. 7999-8005. (doi:10.1039/c5ra22402k)

2015

Sartzi, H., Miras, H. N. , Vila-Nadal, L. , Long, D. L. and Cronin, L. (2015) Trapping the δ isomer of the polyoxometalate-based Keggin cluster with a tripodal ligand. Angewandte Chemie (International Edition), 54(51), pp. 15488-15492. (doi:10.1002/anie.201505377) (PMID:26511859)

Anamimoghadam, O., Symes, M. D. , Long, D. L. , Sproules, S. , Cronin, L. and Bucher, G. (2015) Electronically stabilized nonplanar phenalenyl radical and its planar isomer. Journal of the American Chemical Society, 137(47), pp. 14944-14951. (doi:10.1021/jacs.5b07959) (PMID:26526672)

Zhan, C.-H., Winter, R. S., Zheng, Q., Yan, J., Cameron, J. M., Long, D.-L. and Cronin, L. (2015) Assembly of tungsten-oxide-based pentagonal motifs in solution leads to nanoscale {W48}, {W56}, and {W92} polyoxometalate clusters. Angewandte Chemie (International Edition), 54(48), pp. 14308-14312. (doi:10.1002/anie.201506170) (PMID:26449850)

Zheng, Q., Vila-Nadal, L. , Busche, C., Mathieson, J. S., Long, D.-L. and Cronin, L. (2015) Following the reaction of heteroanions inside a {W18O56} polyoxometalate nanocage by NMR spectroscopy and mass spectrometry. Angewandte Chemie (International Edition), 127(27), pp. 8006-8010. (doi:10.1002/ange.201502295)

Wu, B., Li, S., Lei, Y., Hu, H., de Sousa Amadeu, N., Janiak, C., Mathieson, J. S., Long, D.-L. , Cronin, L. and Yang, X.-J. (2015) The effect of the spacer of Bis(biurea) ligands on the structure of A2L3-type (A=anion) phosphate complexes. Chemistry: A European Journal, 21(6), pp. 2588-2593. (doi:10.1002/chem.201405235) (PMID:25504744)

Cogswell, T. J., Donald, C. S., Long, D.-L. and Marquez, R. (2015) Short and efficient synthesis of fluorinated δ-lactams. Organic and Biomolecular Chemistry, 13(3), pp. 717-728. (doi:10.1039/c4ob01547a)

Forgan, R. S. , Marshall, R. J., Struckmann, M., Bleine, A., Long, D.-L. , Bernini, M. C. and Fairen-Jimenez, D. (2015) Structure-directing factors when introducing hydrogen bond functionality to metal-organic frameworks. CrystEngComm, 17(2), pp. 299-306. (doi:10.1039/C4CE01379D)

Winter, R. S., Long, D.-L. and Cronin, L. (2015) Synthesis and characterization of a series of [M2(β-SiW8O31)2]n− clusters and mechanistic insight into the reorganization of {β-SiW8O31} into {α-SiW9O34}. Inorganic Chemistry, 54(8), pp. 4151-4155. (doi:10.1021/acs.inorgchem.5b00405)

2014

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi:10.1038/nature13951) (PMID:25409147)

Kitson, P. J., Marshall, R. J., Long, D. , Forgan, R. S. and Cronin, L. (2014) 3D printed high-throughput hydrothermal reactionware for discovery, optimization, and scale-up. Angewandte Chemie (International Edition), 53(47), pp. 12723-12728. (doi:10.1002/anie.201402654)

Xuan, W., Surman, A. J. , Miras, H. N. , Long, D. L. and Cronin, L. (2014) Controlling the ring curvature, solution assembly, and reactivity of gigantic molybdenum blue wheels. Journal of the American Chemical Society, 136(40), pp. 14114-14120. (doi:10.1021/ja5062483)

Zhan, C., Cameron, J. M., Gao, J., Purcell, J. W., Long, D. L. and Cronin, L. (2014) Time-resolved assembly of cluster-in-cluster {Ag12}-in-{W76} polyoxometalates under supramolecular control. Angewandte Chemie (International Edition), 53(39), pp. 10362-10366. (doi:10.1002/anie.201402932) (PMID:25087861)

Scullion, R. A., Surman, A. J. , Xu, F., Mathieson, J. S., Long, D. L. , Haso, F., Liu, T. and Cronin, L. (2014) Exploring the symmetry, structure, and self-assembly mechanism of a gigantic seven-fold symmetric {Pd84} wheel. Angewandte Chemie (International Edition), 53(38), pp. 10032-10037. (doi:10.1002/anie.201404621) (PMID:25044792)

Lin, C.-G., Chen, W., Long, D. L. , Cronin, L. and Song, Y.-F. (2014) Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates. Dalton Transactions, 43(23), pp. 8587-8590. (doi:10.1039/c4dt00033a) (PMID:24695647)

Letort, A., Aouzal, R., Ma, C., Long, D.-L. and Prunet, J. (2014) Highly efficient synthesis of the tricyclic core of Taxol by cascade metathesis. Organic Letters, 16(12), pp. 3300-3303. (doi:10.1021/ol501304j)

Kitson, P. J., Macdonell, A., Tsuda, S., Zang, H., Long, D.-L. and Cronin, L. (2014) Bringing crystal structures to reality by three-dimensional printing. Crystal Growth and Design, 14(6), pp. 2720-2724. (doi:10.1021/cg5003012)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2014) Assembly and core transformation properties of two tetrahedral clusters:([FeIII13P8W60O227(OH)15(H2O)2]30− and [FeIII13P8W60O224(OH)12(PO4)4]33−. Dalton Transactions, 43(13), pp. 5190-5199. (doi:10.1039/c3dt53382d)

Yvon, C., Surman, A. J. , Hutin, M., Alex, J., Smith, B. O. , Long, D. L. and Cronin, L. (2014) Polyoxometalate clusters integrated into peptide chains and as inorganic amino acids: solution- and solid-phase approaches. Angewandte Chemie (International Edition), 53(13), pp. 3336-3341. (doi:10.1002/anie.201311135)

Takashima, Y., Long, D.-L. and Cronin, L. (2014) Towards imaging electron density inside metal–organic framework structures. Chemical Communications, 50(18), pp. 2271-2274. (doi:10.1039/c3cc48586b)

Cameron, J. M., Gao, J., Vila-Nadal, L. , Long, D.-L. and Cronin, L. (2014) Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles. Chemical Communications, 50(17), pp. 2155-2157. (doi:10.1039/C3CC49293A)

Cameron, J. M., Gao, J., Long, D. L. and Cronin, L. (2014) Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates. Inorganic Chemistry Frontiers, 1(2), pp. 178-185. (doi:10.1039/c3qi00075c)

Anamimoghadam, O., Long, D. L. and Bucher, G. (2014) 9-Iodophenalenone and 9-trifluoromethanesulfonyloxyphenalenone: convenient entry points to new phenalenones functionalised at the 9-position: iodine-carbonyl interaction studies by X-ray crystallography. RSC Advances, 4(100), pp. 56654-56657. (doi:10.1039/c4ra00178h)

Zang, H.-Y., Ruiz de la Oliva, A., Miras, H. N. , Long, D.-L. , McBurney, R. T. and Cronin, L. (2014) Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine. Nature Communications, 5(3715), pp. 1-8. (doi:10.1038/ncomms4715)

2013

Zang, H., Chen, J.-J., Long, D.-L. , Cronin, L. and Miras, H. N. (2013) Assembly of thiometalate-based [Mo16] and [Mo36] composite clusters combining [Mo2O2S2],2+ cations and selenite anions. Advanced Materials, 25(43), pp. 6245-6249. (doi:10.1002/adma.201302565)

Yvon, C., Macdonell, A., Buchwald, S., Surman, A. , Follet, N., Alex, J., Long, D.L. and Cronin, L. (2013) A collection of robust methodologies for the preparation of asymmetric hybrid Mn–Anderson polyoxometalates for multifunctional materials. Chemical Science, 4(10), pp. 3810-3817. (doi:10.1039/C3SC51618K)

Chen, W., Ma, D., Yan, J., Boyd, T., Cronin, L. , Long, D.-L. and Song, Y.-F. (2013) 0D to 1D switching of hybrid polyoxometalate assemblies at the nanoscale by using molecular control. ChemPlusChem, 78(10), pp. 1226-1229. (doi:10.1002/cplu.201300244)

Long, D.L. , Yan, J., Ruiz De La Oliva, A., Busche, C., Miras, H.N. , Errington, R.J. and Cronin, L. (2013) A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage. Chemical Communications, 49(84), pp. 9731-9733. (doi:10.1039/c3cc45659e)

Hansen, A.M., Sewell, A.L., Pedersen, R.H., Long, D.-L. , Gadegaard, N. and Marquez, R. (2013) Tunable BODIPY derivatives amenable to "click" and peptide chemistry. Tetrahedron, 69(39), pp. 8527-8533. (doi:10.1016/j.tet.2013.05.037)

Yin, P., Li, T., Forgan, R.S. , Lydon, C., Zuo, X., Zheng, Z.N., Lee, B., Long, D. , Cronin, L. and Liu, T. (2013) Exploring the programmable assembly of a polyoxometalate− organic hybrid via metal ion coordination. Journal of the American Chemical Society, 135(36), pp. 13425-13432. (doi:10.1021/ja404777g)

Vilà-Nadal, L. , Peuntinger, K., Busche, C., Yan, J., Lüders, D., Long, D. , Poblet, J.M., Guldi, D.M. and Cronin, L. (2013) Polyoxometalate {W18O56XO6} clusters with embedded redox-active main-group templates as localized inner-cluster radicals. Angewandte Chemie (International Edition), 52(37), pp. 9695-9699. (doi:10.1002/anie.201303126)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) Exploring time assembly of supramolecular polyoxometalate triangular morphologies with johnson solid cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19−. Inorganic Chemistry, 52(16), pp. 9284-9289. (doi:10.1021/ic400542x)

Kato, C., Nishihara, S., Tsunashima, R., Tatewaki, Y., Okada, S., Ren, X.M., Inoue, K., Long, D. and Cronin, L. (2013) Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents. Dalton Transactions, 42, pp. 11363-11366. (doi:10.1039/c3dt51120k)

Rosnes, M. H., Musumeci, C., Yvon, C., MacDonell, A., Pradeep, C. P., Sartorio, C., Long, D.-L. , Pignataro, B. and Cronin, L. (2013) Exploring the interplay between ligand derivatisation and cation type in the assembly of hybrid polyoxometalate Mn-Andersons. Small, 9(13), pp. 2316-2324. (doi:10.1002/smll.201202510)

Zang, H.-Y., Miras, H. N. , Long, D. L. , Rausch, B. and Cronin, L. (2013) Template-directed assembly of polyoxothiometalate scaffolds into nanomolecular architectures. Angewandte Chemie (International Edition), 52(27), pp. 6903-6906. (doi:10.1002/anie.201300578)

Anamimoghadam, O., Symes, M. D. , Busche, C., Long, D.-L. , Caldwell, S. T., Flors, C., Nonell, S., Cronin, L. and Bucher, G. (2013) Naphthoxanthenyl, a new stable phenalenyl type radical stabilized by electronic effects. Organic Letters, 15(12), pp. 2970-2973. (doi:10.1021/ol401117g)

Gabb, D., Pradeep, C. P., Boyd, T., Mitchell, S. G., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) A general route for the transfer of large, highly-charged polyoxometalates from aqueous to organic phase. Polyhedron, 52, pp. 159-164. (doi:10.1016/j.poly.2012.10.015)

Winter, R.S., Yan, J., Busche, C., Mathieson, J.S., Prescimone, A., Brechin, E.K., Long, D.L. and Cronin, L. (2013) Nanoscale control of polyoxometalate assembly: a {Mn8W4} cluster within a {W36Si4Mn10} cluster showing a new type of isomerism. Chemistry: A European Journal, 19(9), pp. 2976-2981. (doi:10.1002/chem.201204345)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2013) One-pot versus sequential reactions in the self-assembly of gigantic nanoscale polyoxotungstates. Journal of the American Chemical Society, 135(5), pp. 1796-1805. (doi:10.1021/ja309237x)

Cameron, J., Newton, G.N., Busche, C., Long, D.L. , Oshio, H. and Cronin, L. (2013) Synthesis and characterisation of a lanthanide-capped dodecavanadate cage. Chemical Communications, 49, pp. 3395-3397. (doi:10.1039/c3cc40912k)

Hutin, M., Yan, J., Yvon, C., MacDonell, A., Long, D.L. and Cronin, L. (2013) Programming the assembly of carboxylic acid-functionalised hybrid polyoxometalates. CrystEngComm, 15(22), pp. 4422-4430. (doi:10.1039/c3ce26816k)

Robbins, P.J., Surman, A.J. , Thiel, J., Long, D.L. and Cronin, L. (2013) Use of ion-mobility mass spectrometry (IMS-MS) to map polyoxometalate keplerate clusters and their supramolecular assemblies. Chemical Communications, 49, pp. 1909-1911. (doi:10.1039/c3cc38615e)

2012

Corella-Ochoa, M.N., Miras, N. , Long, D.L. and Cronin, L. (2012) Controlling the self-assembly of a mixed-metal Mo/V-selenite family of polyoxometalates. Chemistry: A European Journal, 18(43), pp. 13743-13754. (doi:10.1002/chem.201200912)

Xu, F., Miras, H.N. , Scullion, R.A., Long, D.L. , Thiel, J. and Cronin, L. (2012) Correlating the magic numbers of inorganic nanomolecular assemblies with a {Pd84} molecular-ring Rosetta Stone. Proceedings of the National Academy of Sciences of the United States of America, 109(29), pp. 11609-11612. (doi:10.1073/pnas.1202981109)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2012) Assembly of molecular "layered" heteropolyoxometalate architectures. Angewandte Chemie (International Edition), 51(14), pp. 3373-3376. (doi:10.1002/anie.201108428)

Lydon, C., Busche, C., Miras, H.N. , Delf, A., Long, D.-L. , Yellowlees, L. and Cronin, L. (2012) Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates. Angewandte Chemie (International Edition), 51(9), pp. 2115-2118. (doi:10.1002/anie.201105829)

Quesada Cabrera, R., Firth, S., Blackman, C.S., Long, D.L. , Cronin, L. and McMillan, P.F. (2012) Spectroscopic studies of sulfite-based polyoxometalates at high temperature and high pressure. Journal of Solid State Chemistry, 186, pp. 171-176. (doi:10.1016/j.jssc.2011.12.005)

Fielden, J., Long, D.-L. , Speldrich, M., Kögerler, P. and Cronin, L. (2012) [CoxCu1−x(DDOP)(OH2)(NO3)](NO3): hydrogen bond-driven distortion of cobalt(II) by solid solution ‘network mismatch’. Dalton Transactions, 41(16), pp. 4927-4934. (doi:10.1039/c2dt11055e)

Gabb, D., Pradeep, C.P., Miras, H.N. , Mitchell, S.G., Long, D.L. and Cronin, L. (2012) Organic-soluble lacunary {M-2(P2W15)(2)} polyoxometalate sandwiches showing a previously unseen alpha beta beta alpha isomerism. Dalton Transactions, 41(33), pp. 10000-10005. (doi:10.1039/C2DT30616F)

Li, F., Long, D.L. , Cameron, J.M., Miras, H.N. , Pradeep, C., Xu, L. and Cronin, L. (2012) Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV). Dalton Transactions, 41(33), pp. 9859-9862. (doi:10.1039/C2DT30627A)

Long, D.L. and Cronin, L. (2012) Pushing the frontiers in polyoxometalate and metal oxide cluster science. Dalton Transactions, 41(33), pp. 9815-9816. (doi:10.1039/c2dt90121h)

Lydon, C., Sabi, M.M., Symes, M.D. , Long, D.L. , Murrie, M. , Yoshii, S., Nojiri, H. and Cronin, L. (2012) Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates. Chemical Communications, 48(79), pp. 9819-9821. (doi:10.1039/c2cc34865a)

McGlone, T., Thiel, J., Streb, C., Long, D.L. and Cronin, L. (2012) An unprecedented silver-decavanadate dimer investigated using ion-mobility mass spectrometry. Chemical Communications, 48(3), pp. 359-361. (doi:10.1039/c1cc15879a)

Miras, H.N. , Richmond, C.J., Long, D.-L. and Cronin, L. (2012) Solution-phase monitoring of the structural evolution of a molybdenum blue nanoring. Journal of the American Chemical Society, 134(8), pp. 3816-3824. (doi:10.1021/ja210206z)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Engineering polyoxometalates with emergent properties. Chemical Society Reviews, 41(22), pp. 7403-7430. (doi:10.1039/C2CS35190K)

Pasqua, A.E., Crawford, J.J., Long, D.-L. and Marquez, R. (2012) Protecting group free, stereocontrolled synthesis of β-Halo-enamides. Journal of Organic Chemistry, 77(5), pp. 2149-2158. (doi:10.1021/jo202130e)

Richmond, C.J. et al. (2012) A flow-system array for the discovery and scale up of inorganic clusters. Nature Chemistry, 4(12), pp. 1038-1044. (doi:10.1038/nchem.1489)

Rosnes, M.H., Yvon, C., Long, D.L. and Cronin, L. (2012) Mapping the synthesis of low nuclearity polyoxometalates from octamolybdates to Mn-Anderson clusters. Dalton Transactions, 41, pp. 10071-10079. (doi:10.1039/c2dt31008b)

Vilá-Nadal, L. , Mitchell, S.G., Long, D.L. , Rodríguez-Fortea, A., López, X., Poblet, J.M. and Cronin, L. (2012) Exploring the rotational isomerism in non-classical Wells–Dawson anions {W18X}:: a combined theoretical and mass spectrometry study. Dalton Transactions, 41(8), pp. 2264-2271. (doi:10.1039/c2dt11919f)

Zang, H., Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Assembly and autochirogenesis of a chiral inorganic polythioanion Mobius strip via symmetry breaking. Journal of the American Chemical Society, 134(28), pp. 11376-11379. (doi:10.1021/ja304371j)

de la Oliva, A.R., Sans Sangorrin, V., Miras, H.N. , Yan, J., Zang, H., Richmond, C.J., Long, D.L. and Cronin, L. (2012) Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system. Angewandte Chemie (International Edition), 51(51), pp. 12759-12762. (doi:10.1002/anie.201206572)

2011

Miras, H.N. , Zang, H.Y., Long, D.L. and Cronin, L. (2011) Direct synthesis and mass spectroscopic observation of the {M40} polyoxothiometalate wheel. European Journal of Inorganic Chemistry, 2011(33), pp. 5105-5111. (doi:10.1002/ejic.201100833)

Cooper, G.J.T. , Kitson, P.J., Winter, R., Zagnoni, M., Long, D.L. and Cronin, L. (2011) Modular redox-active inorganic chemical cells: iCHELLs. Angewandte Chemie (International Edition), 50(44), pp. 10373-10376. (doi:10.1002/anie.201105068)

Boyd, T., Mitchell, S.G., Gabb, D., Long, D.L. and Cronin, L. (2011) Investigating cation binding in the polyoxometalate-super-crown [P8W48O184]40−. Chemistry: A European Journal, 17(43), pp. 12010-12014. (doi:10.1002/chem.201101666)

Mitchell, S. G. et al. (2011) A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands. Angewandte Chemie (International Edition), 50(39), pp. 9154-9157. (doi:10.1002/anie.201102727)

Corella-Ochoa, M.N., Miras, H.N. , Kidd, A., Long, D.L. and Cronin, L. (2011) Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}. Chemical Communications, 47(31), pp. 8799-8801. (doi:10.1002/chin.201143020)

Song, Y.-F., Long, D.-L. , Ritchie, C. and Cronin, L. (2011) Nanoscale polyoxometalate-based inorganic/organic hybrids. Chemical Record, 11(3), pp. 158-171. (doi:10.1002/tcr.201100002) (PMID:21594969)

Tsunashima, R., Long, D.L. , Noro, S., Akutagawa, T., Nakamura, T. and Quesada, R. (2011) Exploring the thermochromism of sulfite-embedded polyoxometalate capsules. Physical Chemistry Chemical Physics, 13(16), pp. 7295-7297. (doi:10.1039/C1CP20074G)

Walsh, J.J., Long, D.L. , Cronin, L. , Bond, A.M., Forster, R.J. and Keyes, T.E. (2011) Electronic and photophysical properties of adducts of [Ru(bpy)3]2+ and Dawson-type sulfite polyoxomolybdates α/β-[Mo18O54(SO3)2]4−. Dalton Transactions, 40(9), pp. 2038-2045. (doi:10.1039/C0DT01540G)

Mitchell, S.G., Boyd, T., Miras, H.N. , Long, D.L. and Cronin, L. (2011) Extended polyoxometalate framework solids: two MnII-linked {P8W48} network arrays. Inorganic Chemistry, 50(1), pp. 136-143. (doi:10.1021/ic101472s)

Cooper, G.T.J. , Boulay, A.G., Kitson, P.J., Ritchie, C., Richmond, C.J., Thiel, J., Gabb, D., Eadie, R., Long, D.L. and Cronin, L. (2011) Osmotically driven crystal morphogenesis: a general approach to the fabrication of micrometer-scale tubular architectures based on polyoxometalates. Journal of the American Chemical Society, 133(15), pp. 5947-5954. (doi:10.1021/ja111011j)

Gao, J., Yan, J., Mitchell, S.G., Miras, H.N. , Boulay, A.G., Long, D.L. and Cronin, L. (2011) Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties. Chemical Science, 2(8), pp. 1502-1508. (doi:10.1039/C1SC00150G)

Hutin, M., Long, D.L. and Cronin, L. (2011) Controlling the molecular assembly of polyoxometalates from the nano to the micron scale: molecules to materials. Israel Journal of Chemistry, 51(2), pp. 205-214. (doi:10.1002/ijch.201100008)

McGlone, T., Streb, C., Busquets-Fite, M., Yan, J., Gabb, D., Long, D.L. and Cronin, L. (2011) Silver linked polyoxometalate open frameworks (Ag-POMOFs) for the directed fabrication of silver nanomaterials. Crystal Growth and Design, 11(6), pp. 2471-2478. (doi:10.1021/cg2002496)

Miras, H.N. , Stone, D., Long, D.L. , McInnes, E.J.L., Kögerler, P. and Cronin, L. (2011) Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorganic Chemistry, 50(17), pp. 8384-8391. (doi:10.1021/ic200943s)

Musumeci, C., Luzio, A., Pradeep, C.P., Miras, H.N. , Rosnes, M.H., Song, Y.-F., Long, D.L. , Cronin, L. and Pignataro, B. (2011) Programmable surface architectures derived from hybrid polyoxometalate-based clusters. Journal of Physical Chemistry C, 115(11), pp. 4446-4455. (doi:10.1021/jp109916e)

Pradeep, C.P., Li, F.-Y., Lydon, C., Miras, H.N. , Long, D.L. , Xu, L. and Cronin, L. (2011) Design and synthesis of "dumb-bell" and "triangular" inorganic-organic hybrid nanopolyoxometalate clusters and their characterisation through ESI-MS analyses. Chemistry: A European Journal, 17(27), pp. 7472-7479. (doi:10.1002/chem.201100257)

Thiel, J., Yang, D., Rosnes, M.H., Liu, X., Yvon, C., Kelly, S.E., Song, Y.F., Long, D.L. and Cronin, L. (2011) Observing the hierarchical self-assembly and architectural bistability of hybrid molecular metal oxides using ion-mobility mass spectrometry. Angewandte Chemie (International Edition), 50(38), pp. 8871-8875. (doi:10.1002/anie.201102340)

Xu, F., Scullion, R.A., Yan, J., Miras, H.N. , Busche, C., Scandurra, A., Pignataro, B., Long, D.-L. and Cronin, L. (2011) A supramolecular heteropolyoxopalladate {Pd15} cluster host encapsulating a {Pd2} dinuclear guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−. Journal of the American Chemical Society, 133(13), pp. 4684-4686. (doi:10.1021/ja1105514)

2010

Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core. Inorganica Chimica Acta, 363(15), pp. 4240-4246. (doi:10.1016/j.ica.2010.07.020)

Pradeep, C. P., Long, D.-L. and Cronin, L. (2010) Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly. Dalton Transactions, 39(40), p. 9443. (doi:10.1039/C0DT00325E) (PMID:20721370)

Rosnes, M.H., Musumeci, C., Pradeep, C.P., Mathieson, J.S., Long, D.L. , Song, Y.-F., Pignataro, B., Cogdell, R.J. and Cronin, L. (2010) Assembly of modular asymmetric organic-inorganic polyoxometalate hybrids into anisotropic nanostructures. Journal of the American Chemical Society, 132(44), pp. 15490-15492. (doi:10.1021/ja1066338)

Long, D.-L., Tsunashima, R. and Cronin, L. (2010) Polyoxometalates: building blocks for functional nanoscale systems. Angewandte Chemie (International Edition), 49(10), pp. 1736-1758. (doi:10.1002/anie.200902483)

Miras, H.N. , Cooper, G.J.T., Long, D.-L., Bogge, H., Muller, A., Streb, C. and Cronin, L. (2010) Unveiling the transient template in the self-assembly of a molecular oxide nanowheel. Science, 327(5961), pp. 72-74. (doi:10.1126/science.1181735)

Boyd, T., Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) Understanding and mapping the assembly of a family of trimeric polyoxometalates: transition metal mediated Wells-Dawson (M-18)-trimers. Dalton Transactions, 39(28), pp. 6460-6465. (doi:10.1039/C002633F)

Cabrera, R.Q., Long, D.-L. , Cronin, L. and McMillan, P.F. (2010) In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions. CrystEngComm, 12(9), pp. 2568-2572. (doi:10.1039/C003388J)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2010) Assembly of Pure Silver-Tungsten-Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component. Advanced Materials, 22(38), pp. 4275-4279. (doi:10.1002/adma.201001398)

McGlone, T., Vilà-Nadal, L. , Miras, H.N. , Long, D.L. , Poblet, J.M. and Cronin, L. (2010) Assembly of titanium embedded polyoxometalates with unprecedented structural features. Dalton Transactions, 39(48), pp. 11599-11604. (doi:10.1039/c0dt01327g)

Miras, H.N. , Ochoa, M.N.C., Long, D.L. and Cronin, L. (2010) Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}. Chemical Communications, 46(43), pp. 8148-8150. (doi:10.1039/C0CC02849E)

Mitchell, S.G., Streb, C., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2010) Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture. Nature Chemistry, 2(4), pp. 308-312. (doi:10.1038/NCHEM.581)

Ochoa, M.N.C., Cooper, G.J.T. , Newton, G.N., Long, D.L. , Seeber, G. and Cronin, L. (2010) Supramolecular Architectures of Copper(II) Perchlorate Complexes of cis,trans-1,3,5-Triaminocyclohexane Assembled Exploiting the Delicate Balance Between Weak and Strong Interactions. Zeitschrift für Naturforschung B - A Journal of Chemical Sciences, 65(3), pp. 304-310.

Seeber, G., Cooper, G. J. T. , Newton, G. N., Rosnes, M. H., Long, D. L. , Kariuki, B. M., Kogerler, P. and Cronin, L. (2010) Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry. Chemical Science, 1(1), pp. 62-67. (doi:10.1039/c0sc00264j)

Song, Y. -F., Long, D. L. and Cronin, L. (2010) Hybrid polyoxometalate clusters with appended aromatic platforms. CrystEngComm, 12(1), pp. 109-115. (doi:10.1039/b910434h)

Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi:10.1002/anie.201002672)

Tsunashima, R., Long, D.L. , Miras, H.N. , Gabb, D., Pradeep, C.P. and Cronin, L. (2010) The construction of high-nuclearity isopolyoxoniobates with pentagonal building blocks: [HNb27O76](16-) and [H10Nb31O93(CO3)](23-). Angewandte Chemie (International Edition), 49(1), pp. 113-116. (doi:10.1002/anie.200903970)

Yan, J., Gao, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Self-assembly of a nanosized, saddle-shaped, solution-stable polyoxometalate anion built from pentagonal building blocks: [H34W119Se8Fe2O420](54-). Journal of the American Chemical Society, 132(33), pp. 11410-11411. (doi:10.1021/ja104043s)

Yan, J., Long, D. L. and Cronin, L. (2010) Development of a Building Block Strategy To Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO32- as a Template Linker. Angewandte Chemie (International Edition), 49(24), pp. 4117-4120. (doi:10.1002/anie.201000076)

Yan, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Cation controlled assembly and transformation of mono- and bi-sulfite templated dawson-type polyoxotungstates. Inorganic Chemistry, 49(4), pp. 1819-1825. (doi:10.1021/ic9021646)

2009

Pradeep, P.C., Misdrahi, M.F., Li, F.Y., Zhang, J., Xu, L., Long, D.L. , Liu, T. and Cronin, L. (2009) Synthesis of modular “inorganic-organic-inorganic” polyoxometalates and their assembly into vesicles. Angewandte Chemie (International Edition), 48(44), pp. 8309-8313. (doi:10.1002/anie.200903070)

Kitson, P. J., Parenty, A. D. C., Richmond, C. J., Long, D. L. and Cronin, L. (2009) A new C-C bond forming annulation reaction leading to pH switchable heterocycles. Chemical Communications(27), pp. 4067-4069. (doi:10.1039/b905383b)

Mitchell, S.G., Khanra, S., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2009) The trinity of polyoxometalates: connecting {M-12} Keggin and {M-18} Dawson clusters to triangles. Chemical Communications(19), pp. 2712-2714. (doi:10.1039/b903206a)

Thiel, J., Ritchie, C., Streb, C., Long, D. L. and Cronin, L. (2009) Heteroatom-controlled kinetics of switchable polyoxometalate frameworks. Journal of the American Chemical Society, 131(12), pp. 4180-4181. (doi:10.1021/ja809422k)

Cooper, G. J.T. , Newton, G. N., Long, D.-L. , Kogerler, P., Rosnes, M. H., Keller, M. and Cronin, L. (2009) Exploring a series of isostructural dodecanuclear mixed ni:co clusters: toward the control of elemental composition using ph and stoichiometry. Inorganic Chemistry, 48(3), pp. 1097-1104. (doi:10.1021/ic802197u)

Fielden, J., Long, D. L. , Cronin, L. and Kogerler, P. (2009) Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. Polyhedron, 28(13), pp. 2803-2807. (doi:10.1016/j.poly.2009.05.058)

Goral, M., McCormac, T., Dempsey, E., Long, D. L. , Cronin, L. and Bond, A. M. (2009) Voltammetry of [R4N](4)[M18O54(SO3)(2)] and [Ru(bpy)(3)](2)[M18O54(SO3)(2)] (M = Mo, W) as microcrystals adhered to a glassy carbon electrode surface in contact with ionic liquid media. Dalton Transactions(34), pp. 6727-6735. (doi:10.1039/b822167g)

Mathieson, J.S., Cooper, G.J.T. , Pickering, A.L., Keller, M., Long, D.L. , Newton, G.N. and Cronin, L. (2009) Monitoring the Formation of Coordination Complexes Using Electrospray Mass Spectrometry. Chemistry: An Asian Journal, 4(5), pp. 681-687. (doi:10.1002/asia.200900007)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2009) Guest-Directed Supramolecular Architectures of {W-36} Polyoxometalate Crowns. Chemistry: An Asian Journal, 4(10), pp. 1612-1618. (doi:10.1002/asia.200900242)

Mitchell, S. G., Gabb, D., Ritchie, C., Hazel, N., Long, D. L. and Cronin, L. (2009) Controlling nucleation of the cyclic heteropolyanion {P8W48}: a cobalt-substituted phosphotungstate chain and network. CrystEngComm, 11(1), pp. 36-39. (doi:10.1039/b813066c)

Newton, G. N., Cooper, G. J. T. , Schuch, D., Shiga, T., Khanra, S., Long, D. L. , Oshio, H. and Cronin, L. (2009) cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe-III and Pd-II coordination clusters. Dalton Transactions(9), pp. 1549-1553. (doi:10.1039/b815200d)

Ritchie, C., Boyd, T., Long, D. L. , Ditzel, E. and Cronin, L. (2009) Grafting ligands to direct the self-assembly of Co/Ni2+ substituted polyoxometalate clusters. Dalton Transactions(9), pp. 1587-1592. (doi:10.1039/b814076f)

Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L. , Xu, L. and Cronin, L. (2009) A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)(2)Co2Na2(H2O)(2)](18-). Dalton Transactions(33), pp. 6483-6486. (doi:10.1039/b907410d)

Song, Y.F., McMillan, N., Long, D.L. , Kane, S., Malm, J., Riehle, M. , Pradeep, C.P., Gadegaard, N. and Cronin, L. (2009) Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-Hybrid Clusters Lead to Selective Cell Adhesion. Journal of the American Chemical Society, 131(4), pp. 1340-1341. (doi:10.1021/ja807091v)

Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi:10.1002/anie.200806343)

Yang, X. S., Long, D. L. , Li, H. M. and Lu, Z. L. (2009) Synthesis, structures and catalytic properties of palladacycles derived from N,N-dimethylaminomethylferrocene. Inorganic Chemistry Communications, 12(6), pp. 572-575. (doi:10.1016/j.inoche.2009.04.027)

2008

Fleming, C., Long, D. L. , McMillan, N., Johnston, J., Bovet, N., Dhanak, V., Gadegaard, N. , Kogerler, P., Cronin, L. and Kadodwala, M. (2008) Reversible electron-transfer reactions within a nanoscale metal oxide cage mediated by metallic substrates. Nature Nanotechnology, 3(4), pp. 229-233. (doi:10.1038/nnano.2008.66)

Song, Y.-F., McMillan, N., Long, D.-L. , Thiel, J., Ding, Y., Chen, H., Gadegaard, N. and Cronin, L. (2008) Design of hydrophobic polyoxometalate hybrid assemblies beyond surfactant encapsulation. Chemistry: A European Journal, 14(8), pp. 2349-2354. (doi:10.1002/chem.200701629)

Abbas, H., Streb, C., Pickering, A. L., Neil, A. R., Long, D. L. and Cronin, L. (2008) Molecular growth of polyoxometalate Architectures based on [-Ag{Mo-8}Ag-] synthons: Toward designed cluster assemblies. Crystal Growth and Design, 8(2), pp. 635-642. (doi:10.1021/cg700736v)

Caldwell, S. T., Cooke, G. , Fitzpatrick, B., Long, D.L. , Rabani, G. and Rotello, V. M. (2008) A flavin-based [2]catenane. Chemical Communications(45), pp. 5912-5914. (doi:10.1039/b813779j)

Kitson, P. J., Song, Y. -F., Gamez, P., de Hoog, P., Long, D. L. , Parenty, A. D. C., Reedijk, J. and Cronin, L. (2008) Metal-mediated transformation of a triazinephenanthridinium ligand leading to a {Pd-5} coordination complex observed crystallographically and by cryospray mass Spectrometry. Inorganic Chemistry, 47(6), pp. 1883-1885. (doi:10.1021/ic7022192)

Long, D.L. , Song, Y.-F., Wilson, E.F., Kogerler, P., Guo, S.X., Bond, A.M., Hargreaves, J.S.J. and Cronin, L. (2008) Capture of periodate in a {W18O54} cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)](6-) embedded with high-valent iodine. Angewandte Chemie (International Edition), 47(23), pp. 4384-4387. (doi:10.1002/anie.200800041)

Long, D.L. , Streb, C., Song, Y.-F., Mitchell, S. and Cronin, L. (2008) Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion. Journal of the American Chemical Society, 130(6), 1830-+. (doi:10.1021/ja075940z)

Miras, H.N. , Long, D.L. , Kogerler, P. and Cronin, L. (2008) Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties. Dalton Transactions(2), pp. 214-221. (doi:10.1039/b714285d)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2008) Structural evolution of "S"-shaped [H4W22O74](12-) and ""-shaped [H10W34O116](18-) isopolyoxotungstate clusters. Angewandte Chemie (International Edition), 47(44), pp. 8420-8423. (doi:10.1002/anie.200802109)

Mitchell, S. G., Ritchie, C., Long, D.L. and Cronin, L. (2008) Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control. Dalton Transactions(11), pp. 1415-1417. (doi:10.1039/b715885h)

Newton, G.N., Cooper, G.J.T. , Kogerler, P., Long, D.L. and Cronin, L. (2008) Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters. Journal of the American Chemical Society, 130(3), pp. 790-791. (doi:10.1021/ja0768183)

Pradeep, C. P., Long, D. L. , Newton, G. N., Song, Y. -F. and Cronin, L. (2008) Supramolecular metal oxides: Programmed hierarchical assembly of a protein-sized 21 kDa [(C16H36N)(19){H2NC(CH2O)(3)P2V3W15O59}(4)](5-) polyoxometalate assembly. Angewandte Chemie (International Edition), 47(23), pp. 4388-4391. (doi:10.1002/anie.200800431)

Pradeep, C. P., Long, D. L. , Streb, C. and Cronin, L. (2008) "Bottom-Up" Meets "Top-Down" Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P4W52O178](24-) and Disassembly to [P3W39O134](19-). Journal of the American Chemical Society, 130(45), p. 14946. (doi:10.1021/ja806596j)

Ritchie, C. et al. (2008) Polyoxometalate-mediated self-assembly of single-molecule magnets: {[XW9O34](2)[(Mn4Mn2O4)-Mn-III-O-II(H2O)(4)]}(12-). Angewandte Chemie (International Edition), 47(30), pp. 5609-5612. (doi:10.1002/anie.200801281)

Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N. , Long, D.L. , Boyd, T., Peacock, R.D., McGlone, T. and Cronin, L. (2008) Reversible redox reactions in an extended polyoxometalate framework solid. Angewandte Chemie (International Edition), 47(36), pp. 6881-6884. (doi:10.1002/anie.200802594)

Song, Y. -F., Long, D. L. , Kelly, S. E. and Cronin, L. (2008) Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry. Inorganic Chemistry, 47(20), pp. 9137-9139. (doi:10.1021/ic801366r)

Song, Y.F., Kitson, P.J., Long, D.L. , Parenty, A.D.C., Thatcher, R.J. and Cronin, L. (2008) Supramolecular self-assembly and anion-dependence of copper(II) complexes with cationic dihydro-imidazo phenanthridinium (DIP)-containing ligands. CrystEngComm, 10(9), pp. 1243-1251. (doi:10.1039/b802541j)

Streb, C., McGlone, T., Brucher, O., Long, D. L. and Cronin, L. (2008) Hybrid Host-Guest Complexes: Directing the Supramolecular Structure through Secondary Host-Guest Interactions. Chemistry: A European Journal, 14(29), pp. 8861-8868. (doi:10.1002/chem.200801247)

Wilson, E. F., Abbas, H., Duncombe, B. J., Streb, C., Long, D. L. and Cronin, L. (2008) Probing the self-assembly of inorganic cluster architectures in solution with cryospray mass spectrometry: Growth of polyoxomolybdate clusters and polymers mediated by silver(I) ions. Journal of the American Chemical Society, 130(42), pp. 13876-13884. (doi:10.1021/ja802514q)

2007

Streb, C., Ritchie, C., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported AgIAgI interactions. Angewandte Chemie (International Edition), 46(40), pp. 7579-7582. (doi:10.1002/anie.200702698)

Long, D.L. , Burkholder, E. and Cronin, L. (2007) Polyoxometalate clusters, nanostructures and materials: from self-assembly to designer materials and devices. ChemInform, 38(15), (doi:10.1002/chin.200715223)

Song, Y.F., Long, D.L. and Cronin, L. (2007) Noncovalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate-pyrene hybrid. Angewandte Chemie (International Edition), 46(21), pp. 3900-3904. (doi:10.1002/anie.200604734)

Fay, N., Bond, A.M., Baffert, C., Boas, J.F., Pilbrow, J.R., Long, D.-L. and Cronin, L. (2007) Structural, electrochemical, and spectroscopic characterization of a redox pair of sulfite-based polyoxotungstates: α-[W18O54(SO3)2]4- and α-[W18O54(SO3)2]5-. Inorganic Chemistry, 46(9), pp. 3502-3510. (doi:10.1021/ic062067e)

Baffert, C., Feldberg, S.W., Bond, A.M., Long, D.L. and Cronin, L. (2007) pH-Dependence of the aqueous electrochemistry of the two-electron reduced alpha-[Mo18O54(SO3)] sulfite Dawson-like polyoxometalate anion derived from its triethanolammonium salt. Dalton Transactions, pp. 4599-4607. (doi:10.1039/b705991d)

Cooper, G.J.T. , Newton, G.N., Kogerler, P., Long, D.L. , Engelhardt, L., Luban, M. and Cronin, L. (2007) Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry. Angewandte Chemie (International Edition), 46(8), pp. 1340-1344. (doi:10.1002/anie.200603870)

Fielden, J., Long, D.L. , Slawin, A.M.Z., Kogerler, P. and Cronin, L. (2007) Ligand and counterion control of Ag(I) architectures: Assembly of a {Ag-8} ring cluster mediated by hydrophobic and Ag center dot center dot center dot Ag interactions. Inorganic Chemistry, 46, pp. 9090-9097. (doi:10.1021/ic700872b)

Pradeep, C.P., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Controlled assembly and solution observation of a 2.6 nm polyoxometalate super tetrahedron cluster: [KFe12(OH)18(-1,2,3-P2W15O56)4]29–. Chemical Communications, 41, pp. 4254-4256. (doi:10.1039/b707202c)

Ritchie, C., Burkholder, E.M., Long, D.-L. , Adam, D., Kögerler, P. and Cronin, L. (2007) Exploiting the multifunctionality of organocations in the assembly of hybrid polyoxometalate clusters and networks. Chemical Communications, 38(17), pp. 468-470. (doi:10.1039/b612741j)

Song, Y.-F., Abbas, H., Ritchie, C., McMillian, N., Long, D.-L. , Gadegaard, N. and Cronin, L. (2007) From polyoxometalate building blocks to polymers and materials: the silver connection. Journal of Materials Chemistry, 17, pp. 1903-1908. (doi:10.1039/b617830h)

Streb, C., Ritchie, C., Long, D.L. , Kogerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported Ag-I center dot center dot center dot Ag-I interactions". Angewandte Chemie (International Edition), 46, pp. 7579-7582. (doi:10.1002/anie.200702698)

Streb, C., Long, D. L. and Cronin, L. (2007) Engineering porosity in a chiral heteropolyoxometalate-based framework: the supramolecular effect of benzenetricarboxylic acid. Chemical Communications, pp. 471-473. (doi:10.1039/b613808j)

2006

Fielden, J., Gunning, P.T., Long, D.-L. , Nutley, M., Ellern, A., Kögerler, P. and Cronin, L. (2006) Anion control of isomerism, crystal packing and binding properties in a mononuclear zinc complex. Polyhedron, 25(18), pp. 3474-3480. (doi:10.1016/j.poly.2006.06.044)

Baffert, C., Boas, J.F., Bond, A.M., Kögerler, P., Long, D.-L. , Pilbrow, J.R. and Cronin, L. (2006) Experimental and theoretical investigations of the sulfite-based polyoxometalate cluster redox series: α - and β-[Mo18O54(SO3)2]4-/5-/6-. Chemistry: A European Journal, 12(33), pp. 8472-8483. (doi:10.1002/chem.200501450)

Newton, G. N., Cooper, G. J.T. , Long, D.-L. , Kogerler, P. and Cronin, L. (2006) Synthetic, structural and magnetic characterisation of a one-dimensional nickel chain constructed using cis,trans-1,3,5-triaminocyclohexane as a building block. Journal of Molecular Structure, 796, pp. 23-27. (doi:10.1016/j.molstruc.2006.03.087)

Fielden, J., Long, D.L. , Evans, C. and Cronin, L. (2006) Metal-dependent formation of mononuclear complexes and M2L2 mesocates with Schiff-base ligands. European Journal of Inorganic Chemistry, 2006(19), pp. 3930-3935. (doi:10.1002/ejic.200600367)

Long, D.L. , Kögerler, P., Farrugia, L.J. and Cronin, L. (2006) Linking chiral clusters with molybdate building blocks: from homochiral helical supramolecular arrays to coordination helices. Chemistry: An Asian Journal, 1(3), pp. 352-357. (doi:10.1002/asia.200600069)

Long, D.L. , Kogerler, P., Parenty, A.D.C., Fielden, J. and Cronin, L. (2006) Discovery of a family of isopolyoxotungstates [H4W19O62]6- encapsulating a {WO6} moiety within a {W18} Dawson-like cluster cage. Angewandte Chemie (International Edition), 45(29), pp. 4798-4803. (doi:10.1002/anie.200504600)

Long, D.-L. , Streb, C., Kögerler, P. and Cronin, L. (2006) Observation and theoretical analysis of the “sensitive coordination sites” in the isopolyoxomolybdate cluster [Mo36O112(H2O)14]8-. Journal of Cluster Science, 17(2), pp. 257-266. (doi:10.1007/s10876-006-0058-9)

Long, D.-L. and Cronin, L. (2006) Towards polyoxometalate-integrated nanosystems. Chemistry: A European Journal, 12(14), pp. 3698-3706. (doi:10.1002/chem.200501002)

Fielden, J., Sprott, J., Long, D.-L. , Kögerler, P. and Cronin, L. (2006) Controlling aggregation of copper(II)-based coordination compounds: from mononuclear to dinuclear, tetranuclear, and polymeric copper complexes. Inorganic Chemistry, 45(7), pp. 2886-2895. (doi:10.1021/ic051647t)

Long, D.-L. , Brücher, O., Streb, C. and Cronin, L. (2006) Inorganic crown: the host–guest chemistry of a high nuclearity 'Celtic-ring' isopolyoxotungstate [H12W36O120]12–. Dalton Transactions(23), pp. 2852-2860. (doi:10.1039/b515935k)

Streb, C., Long, D.-L. and Cronin, L. (2006) Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks. CrystEngComm, 8, pp. 629-634. (doi:10.1039/b605285a)

2005

Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2005) A novel copper (II) metallacycle as a building block for the assembly of an extended supramolecular array containing channels and helical chains. Inorganic Chemistry Communications, 8(8), pp. 737-739. (doi:10.1016/j.inoche.2005.05.005)

Parenty, A.D.C., Smith, L.V., Guthrie, K.M., Long, D.-L. , Plumb, J., Brown, R. and Cronin, L. (2005) Highly stable phenanthridinium frameworks as a new class of tunable DNA binding agents with cytotoxic properties. Journal of Medicinal Chemistry, 48(14), pp. 4504-4506. (doi:10.1021/jm050320z)

Long, D.-L. , Abbas, H., Kogerler, P. and Cronin, L. (2005) Confined electron-transfer reactions within a molecular metal oxide "Trojan horse". Angewandte Chemie (International Edition), 44(22), pp. 3415-3419. (doi:10.1002/anie.200500541)

Abbas, H., Pickering, A.L., Long, D.-L. , Kögerler, P. and Cronin, L. (2005) Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers. Chemistry: A European Journal, 11(4), pp. 1071-1078. (doi:10.1002/chem.200401088)

Long, D.L. , Kogerler, P., Farrugia, L.J. and Cronin, L. (2005) Reactions of a {Mo-16}-type polyoxometalate cluster with electrophiles: a synthetic, theoretical and magnetic investigation. Dalton Transactions, pp. 1372-1380. (doi:10.1039/b419301f)

Pickering, A.L., Seeber, G., Long, D.L. and Cronin, L. (2005) The importance of pi-pi, pi-CH and N-CH interactions in the crystal packing of Schiff-base derivatives of cis,cis- and cis,trans-1,3,5-triaminocyclohexane. CrystEngComm, 7, pp. 504-510. (doi:10.1039/b506718a)

2004

Cooper, G.J.T. , Abbas, H., Kögerler, P., Long, D.-L. and Cronin, L. (2004) Pentadecadentate chelating ligands as building blocks for a {Fe6} cage with 12 exo-coordinated sodium cations. Inorganic Chemistry, 43(23), pp. 7266-7268. (doi:10.1021/ic049068w)

Parenty, A.D.C., Smith, L.V., Pickering, A.L., Long, D.-L. and Cronin, L. (2004) General one-pot, three-step methodology leading to an extended class of N-heterocyclic cations: spontaneous nucleophilic addition, cyclization, and hydride loss. Journal of Organic Chemistry, 69(18), pp. 5934-5946. (doi:10.1021/jo0495440)

Pickering, A.L., Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2004) Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers. Polyhedron, 23(12), pp. 2075-2079. (doi:10.1016/j.poly.2004.06.002)

Pickering, A.L., Long, D.-L. and Cronin, L. (2004) Coordination networks through the dimensions: from discrete clusters to 1D, 2D, and 3D silver(I) coordination polymers with rigid aliphatic amino ligands. Inorganic Chemistry, 43(16), pp. 4953-4961. (doi:10.1021/ic049786i)

Long, D.-L. , Kögerler, P. and Cronin, L. (2004) Old clusters with new tricks: engineering S...S interactions and novel physical properties in sulfite-based Dawson clusters. Angewandte Chemie (International Edition), 43(14), pp. 1817-1820. (doi:10.1002/anie.200352896)

Fielden, J., Long, D.-L. and Cronin, L. (2004) Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes. Chemical Communications(19), pp. 2156-2157. (doi:10.1039/b407229d)

Long, D.L. , Abbas, H., Kogerler, P. and Cronin, L. (2004) A high-nuclearity "Celtic-Ring" isopolyoxotungstate, [H12W36O120] that captures trace potassium ions. Journal of the American Chemical Society, 126, pp. 13880-13881. (doi:10.1021/ja046410v)

Pickering, A.L., Seeber, G., Long, D.-L. and Cronin, L. (2004) Polymeric silver(I) coordination tubes. Chemical Communications, 2004, pp. 136-137. (doi:10.1039/b312876h)

2003

Long, D.-L. , Kögerler, P., Farrugia, L. and Cronin, L. (2003) Restraining symmetry in the formation of small polyoxomolybdates: building blocks of unprecedented topology resulting from "shrink-wrapping" [H2Mo16O52]10--type clusters. Angewandte Chemie (International Edition), 42(35), pp. 4180-4183. (doi:10.1002/anie.200351615)

Long, D.-L. , Orr, D., Seeber, G., Kögerler, P., Farrugia, L.J. and Cronin, L. (2003) The missing link in low nuclearity pure polyoxovanadate clusters: preliminary synthesis and structural analysis of a new {V16} cluster and related products: dedicated to professor Achim Müller. Journal of Cluster Science, 14(3), pp. 313-324. (doi:10.1023/B:JOCL.0000005066.92182.90)

Seeber, G., Long, D.L. , Kariuki, B.M. and Cronin, L. (2003) Palladium(II)-based cis,trans-1,3,5-triaminocyclohexane complexes demonstrating a variety of coordination modes and architectures. Dalton Transactions, pp. 4498-4504. (doi:10.1039/b307616d)

Seeber, G., Pickering, A.L., Long, D.L. and Cronin, L. (2003) Controlling dimensionality of silver(I) coordination networks with rigid aliphatic amino ligands: from a 2D to a 3D network of unprecedented topology comprising helical channels. Chemical Communications, pp. 2002-2003. (doi:10.1039/b305188a)

This list was generated on Wed Jul 17 06:25:45 2019 BST.
Number of items: 205.

Articles

Xuan, W., Pow, R., Zheng, Q., Watfa, N., Long, D.-L. and Cronin, L. (2019) Ligand-directed template assembly for the construction of gigantic molybdenum blue wheels. Angewandte Chemie (International Edition), (doi:10.1002/anie.201901818) (PMID:31155800) (Early Online Publication)

Janusson, E. , de Kler, N., Vilà-Nadal, L. , Long, D.-L. and Cronin, L. (2019) Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection. Chemical Communications, 55(41), pp. 5797-5800. (doi:10.1039/C9CC02361E) (PMID:31041957)

Xuan, W., Pow, R., Watfa, N., Zheng, Q., Surman, A. J. , Long, D.-L. and Cronin, L. (2019) Stereoselective assembly of gigantic chiral molybdenum blue wheels using lanthanide ions and amino acids. Journal of the American Chemical Society, 141(3), pp. 1242-1250. (doi:10.1021/jacs.8b09750) (PMID:30495944)

Lin, C.-G., Zhou, W., Xiong, X.-T., Xuan, W., Kitson, P. J., Long, D.-L. , Chen, W., Song, Y.-F. and Cronin, L. (2018) Digital control of multistep hydrothermal synthesis by using 3D printed reactionware for the synthesis of metal–organic frameworks. Angewandte Chemie (International Edition), 57(51), pp. 16716-16720. (doi:10.1002/anie.201810095) (PMID:30370977)

Granda, J. M., Donina, L., Dragone, V., Long, D.-L. and Cronin, L. (2018) Controlling an organic synthesis robot with machine learning to search for new reactivity. Nature, 559(7714), pp. 377-381. (doi:10.1038/s41586-018-0307-8) (PMID:30022133)

Purcell, J. W., Long, D.-L. , Lee, E. C. , Cronin, L. and Miras, H. N. (2018) Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates. Dalton Transactions, 47(18), pp. 6283-6287. (doi:10.1039/C8DT00832A)

Miras, H. N. , Sartzi, H., Long, D.-L. , Sproules, S. and Cronin, L. (2018) Directed self-assembly, symmetry breaking, and electronic modulation of metal oxide clusters by pyramidal heteroanions. Chemistry: A European Journal, 24(17), pp. 4399-4411. (doi:10.1002/chem.201705711) (PMID:29315925)

Martin-Sabi, M., Soriano-López, J., Winter, R. S., Chen, J.-J., Vilà-Nadal, L. , Long, D.-L. , Galán-Mascarós, J. R. and Cronin, L. (2018) Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction. Nature Catalysis, 1(3), pp. 208-213. (doi:10.1038/s41929-018-0037-1) (PMID:30079397) (PMCID:PMC6075698)

Zheng, Q., Vilà-Nadal, L. , Lang, Z., Chen, J.-j., Long, D.-L. , Mathieson, J. S., Poblet, J. M. and Cronin, L. (2018) Self-sorting of heteroanions in the assembly of cross-shaped polyoxometalate clusters. Journal of the American Chemical Society, 140(7), pp. 2595-2601. (doi:10.1021/jacs.7b11982) (PMID:29359931) (PMCID:PMC6075695)

Chen, J.-J., Ye, J.-C., Zhang, X.-G., Symes, M. D. , Fan, S.-C., Long, D.-L. , Zheng, M.-S., Wu, D.-Y., Cronin, L. and Dong, Q.-F. (2018) Design and performance of rechargeable sodium ion batteries, and symmetrical li-ion batteries with supercapacitor-like power density based upon polyoxovanadates. Advanced Energy Materials, 8(6), 1701021. (doi:10.1002/aenm.201701021)

Yazigi, F.-J., Wilson, C. , Long, D.-L. and Forgan, R. S. (2017) Synthetic considerations in the self-assembly of coordination polymers of pyridine-functionalised hybrid Mn-Anderson polyoxometalates. Crystal Growth and Design, 17(9), pp. 4739-4748. (doi:10.1021/acs.cgd.7b00672)

Duros, V., Grizou, J., Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human versus robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie (International Edition), 56(36), pp. 10815-10820. (doi:10.1002/anie.201705721) (PMID:28649740) (PMCID:PMC5577512)

Duros, V., Grizou, J., Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human vs robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie, 129(36), pp. 10955-10960. (doi:10.1002/ange.201705721) (PMID:28649740)

Xuan, W., Pow, R., Long, D.-L. and Cronin, L. (2017) Exploring the molecular growth of two gigantic half-closed polyoxometalate clusters {Mo180} and {Mo130Ce6}. Angewandte Chemie (International Edition), 129(33), pp. 9859-9863. (doi:10.1002/ange.201702957) (PMID:28508585)

Zang, H.-Y., Purcell, J. W., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}. Chemical Communications, 53(61), pp. 8585-8587. (doi:10.1039/c7cc04398h) (PMID:28718479)

Purcell, J. W., Miras, H. , Long, D.-L. , Markopoulou, P. and Cronin, L. (2017) Tellurite-squarate driven assembly of a new family of nanoscale clusters based on (Mo2O2S2)2+. Chemistry: A European Journal, 23(40), pp. 9683-9689. (doi:10.1002/chem.201701920) (PMID:28548217)

Zhan, C., Busche, C., Long, D.-L. , Molina, P. I., Winter, R. S. and Cronin, L. (2017) Encapsulation of a {Cu16} cluster containing four [Cu4O4] cubanes within an isopolyoxometalate {W44} cluster. Chemical Communications, 53(52), pp. 7076-7079. (doi:10.1039/c7cc03544f) (PMID:28627534)

Ruiz de la Oliva, A., Sans, V., Miras, H. , Long, D. L. and Cronin, L. (2017) Coding the assembly of polyoxotungstates with a programmable reaction system. Inorganic Chemistry, 56(9), pp. 5089-5095. (doi:10.1021/acs.inorgchem.7b00206) (PMID:28414229) (PMCID:PMC5423703)

Boyd, T., Mitchell, S. G., Gabb, D., Long, D.-L. , Song, Y.-F. and Cronin, L. (2017) POMzites: a family of zeolitic polyoxometalate frameworks from a minimal building block library. Journal of the American Chemical Society, 139(16), pp. 5930-5938. (doi:10.1021/jacs.7b01807) (PMID:28368582) (PMCID:PMC5423706)

Zhan, C. et al. (2017) A metamorphic inorganic framework that can be switched between eight single-crystalline states. Nature Communications, 8, 14185. (doi:10.1038/ncomms14185) (PMID:28194009) (PMCID:PMC5316803)

Kulikov, V., Johnson, N. A.B., Surman, A. J. , Hutin, M., Kelly, S. K. , Hezwani, M., Long, D.-L. , Meyer, G. and Cronin, L. (2017) Spontaneous assembly of an organic-inorganic nucleic acid Z-DNA double-helix structure. Angewandte Chemie (International Edition), 56(4), pp. 1141-1145. (doi:10.1002/anie.201606658) (PMID:27900812) (PMCID:PMC6057607)

Christie, L. G. , Surman, A. J. , Scullion, R. A., Xu, F., Long, D.-L. and Cronin, L. (2016) Overcoming the crystallization bottleneck: a family of gigantic inorganic {Pdx}L(x=84, 72) palladium macrocycles discovered using solution techniques. Angewandte Chemie (International Edition), 55(41), pp. 12741-12745. (doi:10.1002/anie.201606005) (PMID:27634480) (PMCID:PMC5113701)

Xuan, W., Surman, A. J. , Zheng, Q., Long, D.-L. and Cronin, L. (2016) Self-templating and in situ assembly of a cubic cluster-of-clusters architecture based on a {Mo24Fe12} inorganic macrocycle. Angewandte Chemie (International Edition), 55(41), pp. 12703-12707. (doi:10.1002/anie.201603298) (PMID:27358195) (PMCID:PMC5396355)

Zhang, G., Liu, C., Long, D.-L. , Cronin, L. , Tung, C.-H. and Wang, Y. (2016) Water-soluble pentagonal-prismatic titanium-oxo clusters. Journal of the American Chemical Society, 138(35), pp. 11097-11100. (doi:10.1021/jacs.6b06290) (PMID:27525444)

Zang, H., Surman, A. , Long, D. L. , Cronin, L. and Miras, H. N. (2016) Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks. Chemical Communications, 52(58), pp. 9109-9112. (doi:10.1039/C6CC01041E) (PMID:26982102)

Porwol, L., Henson, A. , Kitson, P. J., Long, D. L. and Cronin, L. (2016) On the fly multi-modal observation of ligand synthesis and complexation of Cu complexes in flow with ‘benchtop’ NMR and mass spectrometry. Inorganic Chemistry Frontiers, 3(7), pp. 919-923. (doi:10.1039/C6QI00079G)

Zang, H.-Y., Chen, J.-J., Long, D. L. , Cronin, L. and Miras, H. N. (2016) Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters. Chemical Science, 7(6), pp. 3798-3804. (doi:10.1039/c5sc04944j)

Wiles, A. A. , Zhang, X., Fitzpatrick, B., Long, D.-L. , Macgregor, S. A. and Cooke, G. (2016) Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries. Dalton Transactions, 45(17), pp. 7220-7225. (doi:10.1039/C6DT00875E) (PMID:27063914)

Martin-Sabi, M., Winter, R. S., Lydon, C., Cameron, J. M., Long, D.-L. and Cronin, L. (2016) Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters. Chemical Communications, 52(5), pp. 919-921. (doi:10.1039/C5CC08486E) (PMID:26581307)

Letort, A., Long, D.-L. and Prunet, J. (2016) Study of cascade ring-closing metathesis reactions en route to an advanced intermediate of Taxol. Journal of Organic Chemistry, 81(24), pp. 12318-12331. (doi:10.1021/acs.joc.6b02264) (PMID:27978745)

Wiles, A. A. , Fitzpatrick, B., McDonald, N. A., Westwater, M. M., Long, D. L. , Ebenhoch, B., Rotello, V. M., Samuel, I. D. W. and Cooke, G. (2016) Synthesis and properties of pteridine-2,4-dione-functionalised oligothiophenes. RSC Advances, 6(10), pp. 7999-8005. (doi:10.1039/c5ra22402k)

Sartzi, H., Miras, H. N. , Vila-Nadal, L. , Long, D. L. and Cronin, L. (2015) Trapping the δ isomer of the polyoxometalate-based Keggin cluster with a tripodal ligand. Angewandte Chemie (International Edition), 54(51), pp. 15488-15492. (doi:10.1002/anie.201505377) (PMID:26511859)

Anamimoghadam, O., Symes, M. D. , Long, D. L. , Sproules, S. , Cronin, L. and Bucher, G. (2015) Electronically stabilized nonplanar phenalenyl radical and its planar isomer. Journal of the American Chemical Society, 137(47), pp. 14944-14951. (doi:10.1021/jacs.5b07959) (PMID:26526672)

Zhan, C.-H., Winter, R. S., Zheng, Q., Yan, J., Cameron, J. M., Long, D.-L. and Cronin, L. (2015) Assembly of tungsten-oxide-based pentagonal motifs in solution leads to nanoscale {W48}, {W56}, and {W92} polyoxometalate clusters. Angewandte Chemie (International Edition), 54(48), pp. 14308-14312. (doi:10.1002/anie.201506170) (PMID:26449850)

Zheng, Q., Vila-Nadal, L. , Busche, C., Mathieson, J. S., Long, D.-L. and Cronin, L. (2015) Following the reaction of heteroanions inside a {W18O56} polyoxometalate nanocage by NMR spectroscopy and mass spectrometry. Angewandte Chemie (International Edition), 127(27), pp. 8006-8010. (doi:10.1002/ange.201502295)

Wu, B., Li, S., Lei, Y., Hu, H., de Sousa Amadeu, N., Janiak, C., Mathieson, J. S., Long, D.-L. , Cronin, L. and Yang, X.-J. (2015) The effect of the spacer of Bis(biurea) ligands on the structure of A2L3-type (A=anion) phosphate complexes. Chemistry: A European Journal, 21(6), pp. 2588-2593. (doi:10.1002/chem.201405235) (PMID:25504744)

Cogswell, T. J., Donald, C. S., Long, D.-L. and Marquez, R. (2015) Short and efficient synthesis of fluorinated δ-lactams. Organic and Biomolecular Chemistry, 13(3), pp. 717-728. (doi:10.1039/c4ob01547a)

Forgan, R. S. , Marshall, R. J., Struckmann, M., Bleine, A., Long, D.-L. , Bernini, M. C. and Fairen-Jimenez, D. (2015) Structure-directing factors when introducing hydrogen bond functionality to metal-organic frameworks. CrystEngComm, 17(2), pp. 299-306. (doi:10.1039/C4CE01379D)

Winter, R. S., Long, D.-L. and Cronin, L. (2015) Synthesis and characterization of a series of [M2(β-SiW8O31)2]n− clusters and mechanistic insight into the reorganization of {β-SiW8O31} into {α-SiW9O34}. Inorganic Chemistry, 54(8), pp. 4151-4155. (doi:10.1021/acs.inorgchem.5b00405)

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi:10.1038/nature13951) (PMID:25409147)

Kitson, P. J., Marshall, R. J., Long, D. , Forgan, R. S. and Cronin, L. (2014) 3D printed high-throughput hydrothermal reactionware for discovery, optimization, and scale-up. Angewandte Chemie (International Edition), 53(47), pp. 12723-12728. (doi:10.1002/anie.201402654)

Xuan, W., Surman, A. J. , Miras, H. N. , Long, D. L. and Cronin, L. (2014) Controlling the ring curvature, solution assembly, and reactivity of gigantic molybdenum blue wheels. Journal of the American Chemical Society, 136(40), pp. 14114-14120. (doi:10.1021/ja5062483)

Zhan, C., Cameron, J. M., Gao, J., Purcell, J. W., Long, D. L. and Cronin, L. (2014) Time-resolved assembly of cluster-in-cluster {Ag12}-in-{W76} polyoxometalates under supramolecular control. Angewandte Chemie (International Edition), 53(39), pp. 10362-10366. (doi:10.1002/anie.201402932) (PMID:25087861)

Scullion, R. A., Surman, A. J. , Xu, F., Mathieson, J. S., Long, D. L. , Haso, F., Liu, T. and Cronin, L. (2014) Exploring the symmetry, structure, and self-assembly mechanism of a gigantic seven-fold symmetric {Pd84} wheel. Angewandte Chemie (International Edition), 53(38), pp. 10032-10037. (doi:10.1002/anie.201404621) (PMID:25044792)

Lin, C.-G., Chen, W., Long, D. L. , Cronin, L. and Song, Y.-F. (2014) Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates. Dalton Transactions, 43(23), pp. 8587-8590. (doi:10.1039/c4dt00033a) (PMID:24695647)

Letort, A., Aouzal, R., Ma, C., Long, D.-L. and Prunet, J. (2014) Highly efficient synthesis of the tricyclic core of Taxol by cascade metathesis. Organic Letters, 16(12), pp. 3300-3303. (doi:10.1021/ol501304j)

Kitson, P. J., Macdonell, A., Tsuda, S., Zang, H., Long, D.-L. and Cronin, L. (2014) Bringing crystal structures to reality by three-dimensional printing. Crystal Growth and Design, 14(6), pp. 2720-2724. (doi:10.1021/cg5003012)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2014) Assembly and core transformation properties of two tetrahedral clusters:([FeIII13P8W60O227(OH)15(H2O)2]30− and [FeIII13P8W60O224(OH)12(PO4)4]33−. Dalton Transactions, 43(13), pp. 5190-5199. (doi:10.1039/c3dt53382d)

Yvon, C., Surman, A. J. , Hutin, M., Alex, J., Smith, B. O. , Long, D. L. and Cronin, L. (2014) Polyoxometalate clusters integrated into peptide chains and as inorganic amino acids: solution- and solid-phase approaches. Angewandte Chemie (International Edition), 53(13), pp. 3336-3341. (doi:10.1002/anie.201311135)

Takashima, Y., Long, D.-L. and Cronin, L. (2014) Towards imaging electron density inside metal–organic framework structures. Chemical Communications, 50(18), pp. 2271-2274. (doi:10.1039/c3cc48586b)

Cameron, J. M., Gao, J., Vila-Nadal, L. , Long, D.-L. and Cronin, L. (2014) Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles. Chemical Communications, 50(17), pp. 2155-2157. (doi:10.1039/C3CC49293A)

Cameron, J. M., Gao, J., Long, D. L. and Cronin, L. (2014) Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates. Inorganic Chemistry Frontiers, 1(2), pp. 178-185. (doi:10.1039/c3qi00075c)

Anamimoghadam, O., Long, D. L. and Bucher, G. (2014) 9-Iodophenalenone and 9-trifluoromethanesulfonyloxyphenalenone: convenient entry points to new phenalenones functionalised at the 9-position: iodine-carbonyl interaction studies by X-ray crystallography. RSC Advances, 4(100), pp. 56654-56657. (doi:10.1039/c4ra00178h)

Zang, H.-Y., Ruiz de la Oliva, A., Miras, H. N. , Long, D.-L. , McBurney, R. T. and Cronin, L. (2014) Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine. Nature Communications, 5(3715), pp. 1-8. (doi:10.1038/ncomms4715)

Zang, H., Chen, J.-J., Long, D.-L. , Cronin, L. and Miras, H. N. (2013) Assembly of thiometalate-based [Mo16] and [Mo36] composite clusters combining [Mo2O2S2],2+ cations and selenite anions. Advanced Materials, 25(43), pp. 6245-6249. (doi:10.1002/adma.201302565)

Yvon, C., Macdonell, A., Buchwald, S., Surman, A. , Follet, N., Alex, J., Long, D.L. and Cronin, L. (2013) A collection of robust methodologies for the preparation of asymmetric hybrid Mn–Anderson polyoxometalates for multifunctional materials. Chemical Science, 4(10), pp. 3810-3817. (doi:10.1039/C3SC51618K)

Chen, W., Ma, D., Yan, J., Boyd, T., Cronin, L. , Long, D.-L. and Song, Y.-F. (2013) 0D to 1D switching of hybrid polyoxometalate assemblies at the nanoscale by using molecular control. ChemPlusChem, 78(10), pp. 1226-1229. (doi:10.1002/cplu.201300244)

Long, D.L. , Yan, J., Ruiz De La Oliva, A., Busche, C., Miras, H.N. , Errington, R.J. and Cronin, L. (2013) A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage. Chemical Communications, 49(84), pp. 9731-9733. (doi:10.1039/c3cc45659e)

Hansen, A.M., Sewell, A.L., Pedersen, R.H., Long, D.-L. , Gadegaard, N. and Marquez, R. (2013) Tunable BODIPY derivatives amenable to "click" and peptide chemistry. Tetrahedron, 69(39), pp. 8527-8533. (doi:10.1016/j.tet.2013.05.037)

Yin, P., Li, T., Forgan, R.S. , Lydon, C., Zuo, X., Zheng, Z.N., Lee, B., Long, D. , Cronin, L. and Liu, T. (2013) Exploring the programmable assembly of a polyoxometalate− organic hybrid via metal ion coordination. Journal of the American Chemical Society, 135(36), pp. 13425-13432. (doi:10.1021/ja404777g)

Vilà-Nadal, L. , Peuntinger, K., Busche, C., Yan, J., Lüders, D., Long, D. , Poblet, J.M., Guldi, D.M. and Cronin, L. (2013) Polyoxometalate {W18O56XO6} clusters with embedded redox-active main-group templates as localized inner-cluster radicals. Angewandte Chemie (International Edition), 52(37), pp. 9695-9699. (doi:10.1002/anie.201303126)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) Exploring time assembly of supramolecular polyoxometalate triangular morphologies with johnson solid cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19−. Inorganic Chemistry, 52(16), pp. 9284-9289. (doi:10.1021/ic400542x)

Kato, C., Nishihara, S., Tsunashima, R., Tatewaki, Y., Okada, S., Ren, X.M., Inoue, K., Long, D. and Cronin, L. (2013) Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents. Dalton Transactions, 42, pp. 11363-11366. (doi:10.1039/c3dt51120k)

Rosnes, M. H., Musumeci, C., Yvon, C., MacDonell, A., Pradeep, C. P., Sartorio, C., Long, D.-L. , Pignataro, B. and Cronin, L. (2013) Exploring the interplay between ligand derivatisation and cation type in the assembly of hybrid polyoxometalate Mn-Andersons. Small, 9(13), pp. 2316-2324. (doi:10.1002/smll.201202510)

Zang, H.-Y., Miras, H. N. , Long, D. L. , Rausch, B. and Cronin, L. (2013) Template-directed assembly of polyoxothiometalate scaffolds into nanomolecular architectures. Angewandte Chemie (International Edition), 52(27), pp. 6903-6906. (doi:10.1002/anie.201300578)

Anamimoghadam, O., Symes, M. D. , Busche, C., Long, D.-L. , Caldwell, S. T., Flors, C., Nonell, S., Cronin, L. and Bucher, G. (2013) Naphthoxanthenyl, a new stable phenalenyl type radical stabilized by electronic effects. Organic Letters, 15(12), pp. 2970-2973. (doi:10.1021/ol401117g)

Gabb, D., Pradeep, C. P., Boyd, T., Mitchell, S. G., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) A general route for the transfer of large, highly-charged polyoxometalates from aqueous to organic phase. Polyhedron, 52, pp. 159-164. (doi:10.1016/j.poly.2012.10.015)

Winter, R.S., Yan, J., Busche, C., Mathieson, J.S., Prescimone, A., Brechin, E.K., Long, D.L. and Cronin, L. (2013) Nanoscale control of polyoxometalate assembly: a {Mn8W4} cluster within a {W36Si4Mn10} cluster showing a new type of isomerism. Chemistry: A European Journal, 19(9), pp. 2976-2981. (doi:10.1002/chem.201204345)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2013) One-pot versus sequential reactions in the self-assembly of gigantic nanoscale polyoxotungstates. Journal of the American Chemical Society, 135(5), pp. 1796-1805. (doi:10.1021/ja309237x)

Cameron, J., Newton, G.N., Busche, C., Long, D.L. , Oshio, H. and Cronin, L. (2013) Synthesis and characterisation of a lanthanide-capped dodecavanadate cage. Chemical Communications, 49, pp. 3395-3397. (doi:10.1039/c3cc40912k)

Hutin, M., Yan, J., Yvon, C., MacDonell, A., Long, D.L. and Cronin, L. (2013) Programming the assembly of carboxylic acid-functionalised hybrid polyoxometalates. CrystEngComm, 15(22), pp. 4422-4430. (doi:10.1039/c3ce26816k)

Robbins, P.J., Surman, A.J. , Thiel, J., Long, D.L. and Cronin, L. (2013) Use of ion-mobility mass spectrometry (IMS-MS) to map polyoxometalate keplerate clusters and their supramolecular assemblies. Chemical Communications, 49, pp. 1909-1911. (doi:10.1039/c3cc38615e)

Corella-Ochoa, M.N., Miras, N. , Long, D.L. and Cronin, L. (2012) Controlling the self-assembly of a mixed-metal Mo/V-selenite family of polyoxometalates. Chemistry: A European Journal, 18(43), pp. 13743-13754. (doi:10.1002/chem.201200912)

Xu, F., Miras, H.N. , Scullion, R.A., Long, D.L. , Thiel, J. and Cronin, L. (2012) Correlating the magic numbers of inorganic nanomolecular assemblies with a {Pd84} molecular-ring Rosetta Stone. Proceedings of the National Academy of Sciences of the United States of America, 109(29), pp. 11609-11612. (doi:10.1073/pnas.1202981109)

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2012) Assembly of molecular "layered" heteropolyoxometalate architectures. Angewandte Chemie (International Edition), 51(14), pp. 3373-3376. (doi:10.1002/anie.201108428)

Lydon, C., Busche, C., Miras, H.N. , Delf, A., Long, D.-L. , Yellowlees, L. and Cronin, L. (2012) Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates. Angewandte Chemie (International Edition), 51(9), pp. 2115-2118. (doi:10.1002/anie.201105829)

Quesada Cabrera, R., Firth, S., Blackman, C.S., Long, D.L. , Cronin, L. and McMillan, P.F. (2012) Spectroscopic studies of sulfite-based polyoxometalates at high temperature and high pressure. Journal of Solid State Chemistry, 186, pp. 171-176. (doi:10.1016/j.jssc.2011.12.005)

Fielden, J., Long, D.-L. , Speldrich, M., Kögerler, P. and Cronin, L. (2012) [CoxCu1−x(DDOP)(OH2)(NO3)](NO3): hydrogen bond-driven distortion of cobalt(II) by solid solution ‘network mismatch’. Dalton Transactions, 41(16), pp. 4927-4934. (doi:10.1039/c2dt11055e)

Gabb, D., Pradeep, C.P., Miras, H.N. , Mitchell, S.G., Long, D.L. and Cronin, L. (2012) Organic-soluble lacunary {M-2(P2W15)(2)} polyoxometalate sandwiches showing a previously unseen alpha beta beta alpha isomerism. Dalton Transactions, 41(33), pp. 10000-10005. (doi:10.1039/C2DT30616F)

Li, F., Long, D.L. , Cameron, J.M., Miras, H.N. , Pradeep, C., Xu, L. and Cronin, L. (2012) Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV). Dalton Transactions, 41(33), pp. 9859-9862. (doi:10.1039/C2DT30627A)

Long, D.L. and Cronin, L. (2012) Pushing the frontiers in polyoxometalate and metal oxide cluster science. Dalton Transactions, 41(33), pp. 9815-9816. (doi:10.1039/c2dt90121h)

Lydon, C., Sabi, M.M., Symes, M.D. , Long, D.L. , Murrie, M. , Yoshii, S., Nojiri, H. and Cronin, L. (2012) Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates. Chemical Communications, 48(79), pp. 9819-9821. (doi:10.1039/c2cc34865a)

McGlone, T., Thiel, J., Streb, C., Long, D.L. and Cronin, L. (2012) An unprecedented silver-decavanadate dimer investigated using ion-mobility mass spectrometry. Chemical Communications, 48(3), pp. 359-361. (doi:10.1039/c1cc15879a)

Miras, H.N. , Richmond, C.J., Long, D.-L. and Cronin, L. (2012) Solution-phase monitoring of the structural evolution of a molybdenum blue nanoring. Journal of the American Chemical Society, 134(8), pp. 3816-3824. (doi:10.1021/ja210206z)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Engineering polyoxometalates with emergent properties. Chemical Society Reviews, 41(22), pp. 7403-7430. (doi:10.1039/C2CS35190K)

Pasqua, A.E., Crawford, J.J., Long, D.-L. and Marquez, R. (2012) Protecting group free, stereocontrolled synthesis of β-Halo-enamides. Journal of Organic Chemistry, 77(5), pp. 2149-2158. (doi:10.1021/jo202130e)

Richmond, C.J. et al. (2012) A flow-system array for the discovery and scale up of inorganic clusters. Nature Chemistry, 4(12), pp. 1038-1044. (doi:10.1038/nchem.1489)

Rosnes, M.H., Yvon, C., Long, D.L. and Cronin, L. (2012) Mapping the synthesis of low nuclearity polyoxometalates from octamolybdates to Mn-Anderson clusters. Dalton Transactions, 41, pp. 10071-10079. (doi:10.1039/c2dt31008b)

Vilá-Nadal, L. , Mitchell, S.G., Long, D.L. , Rodríguez-Fortea, A., López, X., Poblet, J.M. and Cronin, L. (2012) Exploring the rotational isomerism in non-classical Wells–Dawson anions {W18X}:: a combined theoretical and mass spectrometry study. Dalton Transactions, 41(8), pp. 2264-2271. (doi:10.1039/c2dt11919f)

Zang, H., Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2012) Assembly and autochirogenesis of a chiral inorganic polythioanion Mobius strip via symmetry breaking. Journal of the American Chemical Society, 134(28), pp. 11376-11379. (doi:10.1021/ja304371j)

de la Oliva, A.R., Sans Sangorrin, V., Miras, H.N. , Yan, J., Zang, H., Richmond, C.J., Long, D.L. and Cronin, L. (2012) Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system. Angewandte Chemie (International Edition), 51(51), pp. 12759-12762. (doi:10.1002/anie.201206572)

Miras, H.N. , Zang, H.Y., Long, D.L. and Cronin, L. (2011) Direct synthesis and mass spectroscopic observation of the {M40} polyoxothiometalate wheel. European Journal of Inorganic Chemistry, 2011(33), pp. 5105-5111. (doi:10.1002/ejic.201100833)

Cooper, G.J.T. , Kitson, P.J., Winter, R., Zagnoni, M., Long, D.L. and Cronin, L. (2011) Modular redox-active inorganic chemical cells: iCHELLs. Angewandte Chemie (International Edition), 50(44), pp. 10373-10376. (doi:10.1002/anie.201105068)

Boyd, T., Mitchell, S.G., Gabb, D., Long, D.L. and Cronin, L. (2011) Investigating cation binding in the polyoxometalate-super-crown [P8W48O184]40−. Chemistry: A European Journal, 17(43), pp. 12010-12014. (doi:10.1002/chem.201101666)

Mitchell, S. G. et al. (2011) A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands. Angewandte Chemie (International Edition), 50(39), pp. 9154-9157. (doi:10.1002/anie.201102727)

Corella-Ochoa, M.N., Miras, H.N. , Kidd, A., Long, D.L. and Cronin, L. (2011) Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}. Chemical Communications, 47(31), pp. 8799-8801. (doi:10.1002/chin.201143020)

Song, Y.-F., Long, D.-L. , Ritchie, C. and Cronin, L. (2011) Nanoscale polyoxometalate-based inorganic/organic hybrids. Chemical Record, 11(3), pp. 158-171. (doi:10.1002/tcr.201100002) (PMID:21594969)

Tsunashima, R., Long, D.L. , Noro, S., Akutagawa, T., Nakamura, T. and Quesada, R. (2011) Exploring the thermochromism of sulfite-embedded polyoxometalate capsules. Physical Chemistry Chemical Physics, 13(16), pp. 7295-7297. (doi:10.1039/C1CP20074G)

Walsh, J.J., Long, D.L. , Cronin, L. , Bond, A.M., Forster, R.J. and Keyes, T.E. (2011) Electronic and photophysical properties of adducts of [Ru(bpy)3]2+ and Dawson-type sulfite polyoxomolybdates α/β-[Mo18O54(SO3)2]4−. Dalton Transactions, 40(9), pp. 2038-2045. (doi:10.1039/C0DT01540G)

Mitchell, S.G., Boyd, T., Miras, H.N. , Long, D.L. and Cronin, L. (2011) Extended polyoxometalate framework solids: two MnII-linked {P8W48} network arrays. Inorganic Chemistry, 50(1), pp. 136-143. (doi:10.1021/ic101472s)

Cooper, G.T.J. , Boulay, A.G., Kitson, P.J., Ritchie, C., Richmond, C.J., Thiel, J., Gabb, D., Eadie, R., Long, D.L. and Cronin, L. (2011) Osmotically driven crystal morphogenesis: a general approach to the fabrication of micrometer-scale tubular architectures based on polyoxometalates. Journal of the American Chemical Society, 133(15), pp. 5947-5954. (doi:10.1021/ja111011j)

Gao, J., Yan, J., Mitchell, S.G., Miras, H.N. , Boulay, A.G., Long, D.L. and Cronin, L. (2011) Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties. Chemical Science, 2(8), pp. 1502-1508. (doi:10.1039/C1SC00150G)

Hutin, M., Long, D.L. and Cronin, L. (2011) Controlling the molecular assembly of polyoxometalates from the nano to the micron scale: molecules to materials. Israel Journal of Chemistry, 51(2), pp. 205-214. (doi:10.1002/ijch.201100008)

McGlone, T., Streb, C., Busquets-Fite, M., Yan, J., Gabb, D., Long, D.L. and Cronin, L. (2011) Silver linked polyoxometalate open frameworks (Ag-POMOFs) for the directed fabrication of silver nanomaterials. Crystal Growth and Design, 11(6), pp. 2471-2478. (doi:10.1021/cg2002496)

Miras, H.N. , Stone, D., Long, D.L. , McInnes, E.J.L., Kögerler, P. and Cronin, L. (2011) Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorganic Chemistry, 50(17), pp. 8384-8391. (doi:10.1021/ic200943s)

Musumeci, C., Luzio, A., Pradeep, C.P., Miras, H.N. , Rosnes, M.H., Song, Y.-F., Long, D.L. , Cronin, L. and Pignataro, B. (2011) Programmable surface architectures derived from hybrid polyoxometalate-based clusters. Journal of Physical Chemistry C, 115(11), pp. 4446-4455. (doi:10.1021/jp109916e)

Pradeep, C.P., Li, F.-Y., Lydon, C., Miras, H.N. , Long, D.L. , Xu, L. and Cronin, L. (2011) Design and synthesis of "dumb-bell" and "triangular" inorganic-organic hybrid nanopolyoxometalate clusters and their characterisation through ESI-MS analyses. Chemistry: A European Journal, 17(27), pp. 7472-7479. (doi:10.1002/chem.201100257)

Thiel, J., Yang, D., Rosnes, M.H., Liu, X., Yvon, C., Kelly, S.E., Song, Y.F., Long, D.L. and Cronin, L. (2011) Observing the hierarchical self-assembly and architectural bistability of hybrid molecular metal oxides using ion-mobility mass spectrometry. Angewandte Chemie (International Edition), 50(38), pp. 8871-8875. (doi:10.1002/anie.201102340)

Xu, F., Scullion, R.A., Yan, J., Miras, H.N. , Busche, C., Scandurra, A., Pignataro, B., Long, D.-L. and Cronin, L. (2011) A supramolecular heteropolyoxopalladate {Pd15} cluster host encapsulating a {Pd2} dinuclear guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−. Journal of the American Chemical Society, 133(13), pp. 4684-4686. (doi:10.1021/ja1105514)

Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core. Inorganica Chimica Acta, 363(15), pp. 4240-4246. (doi:10.1016/j.ica.2010.07.020)

Pradeep, C. P., Long, D.-L. and Cronin, L. (2010) Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly. Dalton Transactions, 39(40), p. 9443. (doi:10.1039/C0DT00325E) (PMID:20721370)

Rosnes, M.H., Musumeci, C., Pradeep, C.P., Mathieson, J.S., Long, D.L. , Song, Y.-F., Pignataro, B., Cogdell, R.J. and Cronin, L. (2010) Assembly of modular asymmetric organic-inorganic polyoxometalate hybrids into anisotropic nanostructures. Journal of the American Chemical Society, 132(44), pp. 15490-15492. (doi:10.1021/ja1066338)

Long, D.-L., Tsunashima, R. and Cronin, L. (2010) Polyoxometalates: building blocks for functional nanoscale systems. Angewandte Chemie (International Edition), 49(10), pp. 1736-1758. (doi:10.1002/anie.200902483)

Miras, H.N. , Cooper, G.J.T., Long, D.-L., Bogge, H., Muller, A., Streb, C. and Cronin, L. (2010) Unveiling the transient template in the self-assembly of a molecular oxide nanowheel. Science, 327(5961), pp. 72-74. (doi:10.1126/science.1181735)

Boyd, T., Mitchell, S.G., Miras, H.N. , Long, D.L. and Cronin, L. (2010) Understanding and mapping the assembly of a family of trimeric polyoxometalates: transition metal mediated Wells-Dawson (M-18)-trimers. Dalton Transactions, 39(28), pp. 6460-6465. (doi:10.1039/C002633F)

Cabrera, R.Q., Long, D.-L. , Cronin, L. and McMillan, P.F. (2010) In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions. CrystEngComm, 12(9), pp. 2568-2572. (doi:10.1039/C003388J)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2010) Assembly of Pure Silver-Tungsten-Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component. Advanced Materials, 22(38), pp. 4275-4279. (doi:10.1002/adma.201001398)

McGlone, T., Vilà-Nadal, L. , Miras, H.N. , Long, D.L. , Poblet, J.M. and Cronin, L. (2010) Assembly of titanium embedded polyoxometalates with unprecedented structural features. Dalton Transactions, 39(48), pp. 11599-11604. (doi:10.1039/c0dt01327g)

Miras, H.N. , Ochoa, M.N.C., Long, D.L. and Cronin, L. (2010) Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}. Chemical Communications, 46(43), pp. 8148-8150. (doi:10.1039/C0CC02849E)

Mitchell, S.G., Streb, C., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2010) Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture. Nature Chemistry, 2(4), pp. 308-312. (doi:10.1038/NCHEM.581)

Ochoa, M.N.C., Cooper, G.J.T. , Newton, G.N., Long, D.L. , Seeber, G. and Cronin, L. (2010) Supramolecular Architectures of Copper(II) Perchlorate Complexes of cis,trans-1,3,5-Triaminocyclohexane Assembled Exploiting the Delicate Balance Between Weak and Strong Interactions. Zeitschrift für Naturforschung B - A Journal of Chemical Sciences, 65(3), pp. 304-310.

Seeber, G., Cooper, G. J. T. , Newton, G. N., Rosnes, M. H., Long, D. L. , Kariuki, B. M., Kogerler, P. and Cronin, L. (2010) Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry. Chemical Science, 1(1), pp. 62-67. (doi:10.1039/c0sc00264j)

Song, Y. -F., Long, D. L. and Cronin, L. (2010) Hybrid polyoxometalate clusters with appended aromatic platforms. CrystEngComm, 12(1), pp. 109-115. (doi:10.1039/b910434h)

Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi:10.1002/anie.201002672)

Tsunashima, R., Long, D.L. , Miras, H.N. , Gabb, D., Pradeep, C.P. and Cronin, L. (2010) The construction of high-nuclearity isopolyoxoniobates with pentagonal building blocks: [HNb27O76](16-) and [H10Nb31O93(CO3)](23-). Angewandte Chemie (International Edition), 49(1), pp. 113-116. (doi:10.1002/anie.200903970)

Yan, J., Gao, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Self-assembly of a nanosized, saddle-shaped, solution-stable polyoxometalate anion built from pentagonal building blocks: [H34W119Se8Fe2O420](54-). Journal of the American Chemical Society, 132(33), pp. 11410-11411. (doi:10.1021/ja104043s)

Yan, J., Long, D. L. and Cronin, L. (2010) Development of a Building Block Strategy To Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO32- as a Template Linker. Angewandte Chemie (International Edition), 49(24), pp. 4117-4120. (doi:10.1002/anie.201000076)

Yan, J., Long, D.L. , Miras, H.N. and Cronin, L. (2010) Cation controlled assembly and transformation of mono- and bi-sulfite templated dawson-type polyoxotungstates. Inorganic Chemistry, 49(4), pp. 1819-1825. (doi:10.1021/ic9021646)

Pradeep, P.C., Misdrahi, M.F., Li, F.Y., Zhang, J., Xu, L., Long, D.L. , Liu, T. and Cronin, L. (2009) Synthesis of modular “inorganic-organic-inorganic” polyoxometalates and their assembly into vesicles. Angewandte Chemie (International Edition), 48(44), pp. 8309-8313. (doi:10.1002/anie.200903070)

Kitson, P. J., Parenty, A. D. C., Richmond, C. J., Long, D. L. and Cronin, L. (2009) A new C-C bond forming annulation reaction leading to pH switchable heterocycles. Chemical Communications(27), pp. 4067-4069. (doi:10.1039/b905383b)

Mitchell, S.G., Khanra, S., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2009) The trinity of polyoxometalates: connecting {M-12} Keggin and {M-18} Dawson clusters to triangles. Chemical Communications(19), pp. 2712-2714. (doi:10.1039/b903206a)

Thiel, J., Ritchie, C., Streb, C., Long, D. L. and Cronin, L. (2009) Heteroatom-controlled kinetics of switchable polyoxometalate frameworks. Journal of the American Chemical Society, 131(12), pp. 4180-4181. (doi:10.1021/ja809422k)

Cooper, G. J.T. , Newton, G. N., Long, D.-L. , Kogerler, P., Rosnes, M. H., Keller, M. and Cronin, L. (2009) Exploring a series of isostructural dodecanuclear mixed ni:co clusters: toward the control of elemental composition using ph and stoichiometry. Inorganic Chemistry, 48(3), pp. 1097-1104. (doi:10.1021/ic802197u)

Fielden, J., Long, D. L. , Cronin, L. and Kogerler, P. (2009) Synthesis of Cu(I) octamolybdates using tetrakis-acetonitrilecopper(I) hexafluorophosphate. Polyhedron, 28(13), pp. 2803-2807. (doi:10.1016/j.poly.2009.05.058)

Goral, M., McCormac, T., Dempsey, E., Long, D. L. , Cronin, L. and Bond, A. M. (2009) Voltammetry of [R4N](4)[M18O54(SO3)(2)] and [Ru(bpy)(3)](2)[M18O54(SO3)(2)] (M = Mo, W) as microcrystals adhered to a glassy carbon electrode surface in contact with ionic liquid media. Dalton Transactions(34), pp. 6727-6735. (doi:10.1039/b822167g)

Mathieson, J.S., Cooper, G.J.T. , Pickering, A.L., Keller, M., Long, D.L. , Newton, G.N. and Cronin, L. (2009) Monitoring the Formation of Coordination Complexes Using Electrospray Mass Spectrometry. Chemistry: An Asian Journal, 4(5), pp. 681-687. (doi:10.1002/asia.200900007)

McGlone, T., Streb, C., Long, D.L. and Cronin, L. (2009) Guest-Directed Supramolecular Architectures of {W-36} Polyoxometalate Crowns. Chemistry: An Asian Journal, 4(10), pp. 1612-1618. (doi:10.1002/asia.200900242)

Mitchell, S. G., Gabb, D., Ritchie, C., Hazel, N., Long, D. L. and Cronin, L. (2009) Controlling nucleation of the cyclic heteropolyanion {P8W48}: a cobalt-substituted phosphotungstate chain and network. CrystEngComm, 11(1), pp. 36-39. (doi:10.1039/b813066c)

Newton, G. N., Cooper, G. J. T. , Schuch, D., Shiga, T., Khanra, S., Long, D. L. , Oshio, H. and Cronin, L. (2009) cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe-III and Pd-II coordination clusters. Dalton Transactions(9), pp. 1549-1553. (doi:10.1039/b815200d)

Ritchie, C., Boyd, T., Long, D. L. , Ditzel, E. and Cronin, L. (2009) Grafting ligands to direct the self-assembly of Co/Ni2+ substituted polyoxometalate clusters. Dalton Transactions(9), pp. 1587-1592. (doi:10.1039/b814076f)

Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L. , Xu, L. and Cronin, L. (2009) A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)(2)Co2Na2(H2O)(2)](18-). Dalton Transactions(33), pp. 6483-6486. (doi:10.1039/b907410d)

Song, Y.F., McMillan, N., Long, D.L. , Kane, S., Malm, J., Riehle, M. , Pradeep, C.P., Gadegaard, N. and Cronin, L. (2009) Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-Hybrid Clusters Lead to Selective Cell Adhesion. Journal of the American Chemical Society, 131(4), pp. 1340-1341. (doi:10.1021/ja807091v)

Yan, J., Long, D.-L. , Wilson, E.F. and Cronin, L. (2009) Discovery of heteroatom "embedded" Te⊂{W18O54} nanofunctional polyoxometalates using cryospray mass spectrometry. Angewandte Chemie (International Edition), 48(24), pp. 4376-4380. (doi:10.1002/anie.200806343)

Yang, X. S., Long, D. L. , Li, H. M. and Lu, Z. L. (2009) Synthesis, structures and catalytic properties of palladacycles derived from N,N-dimethylaminomethylferrocene. Inorganic Chemistry Communications, 12(6), pp. 572-575. (doi:10.1016/j.inoche.2009.04.027)

Fleming, C., Long, D. L. , McMillan, N., Johnston, J., Bovet, N., Dhanak, V., Gadegaard, N. , Kogerler, P., Cronin, L. and Kadodwala, M. (2008) Reversible electron-transfer reactions within a nanoscale metal oxide cage mediated by metallic substrates. Nature Nanotechnology, 3(4), pp. 229-233. (doi:10.1038/nnano.2008.66)

Song, Y.-F., McMillan, N., Long, D.-L. , Thiel, J., Ding, Y., Chen, H., Gadegaard, N. and Cronin, L. (2008) Design of hydrophobic polyoxometalate hybrid assemblies beyond surfactant encapsulation. Chemistry: A European Journal, 14(8), pp. 2349-2354. (doi:10.1002/chem.200701629)

Abbas, H., Streb, C., Pickering, A. L., Neil, A. R., Long, D. L. and Cronin, L. (2008) Molecular growth of polyoxometalate Architectures based on [-Ag{Mo-8}Ag-] synthons: Toward designed cluster assemblies. Crystal Growth and Design, 8(2), pp. 635-642. (doi:10.1021/cg700736v)

Caldwell, S. T., Cooke, G. , Fitzpatrick, B., Long, D.L. , Rabani, G. and Rotello, V. M. (2008) A flavin-based [2]catenane. Chemical Communications(45), pp. 5912-5914. (doi:10.1039/b813779j)

Kitson, P. J., Song, Y. -F., Gamez, P., de Hoog, P., Long, D. L. , Parenty, A. D. C., Reedijk, J. and Cronin, L. (2008) Metal-mediated transformation of a triazinephenanthridinium ligand leading to a {Pd-5} coordination complex observed crystallographically and by cryospray mass Spectrometry. Inorganic Chemistry, 47(6), pp. 1883-1885. (doi:10.1021/ic7022192)

Long, D.L. , Song, Y.-F., Wilson, E.F., Kogerler, P., Guo, S.X., Bond, A.M., Hargreaves, J.S.J. and Cronin, L. (2008) Capture of periodate in a {W18O54} cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)](6-) embedded with high-valent iodine. Angewandte Chemie (International Edition), 47(23), pp. 4384-4387. (doi:10.1002/anie.200800041)

Long, D.L. , Streb, C., Song, Y.-F., Mitchell, S. and Cronin, L. (2008) Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion. Journal of the American Chemical Society, 130(6), 1830-+. (doi:10.1021/ja075940z)

Miras, H.N. , Long, D.L. , Kogerler, P. and Cronin, L. (2008) Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties. Dalton Transactions(2), pp. 214-221. (doi:10.1039/b714285d)

Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2008) Structural evolution of "S"-shaped [H4W22O74](12-) and ""-shaped [H10W34O116](18-) isopolyoxotungstate clusters. Angewandte Chemie (International Edition), 47(44), pp. 8420-8423. (doi:10.1002/anie.200802109)

Mitchell, S. G., Ritchie, C., Long, D.L. and Cronin, L. (2008) Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control. Dalton Transactions(11), pp. 1415-1417. (doi:10.1039/b715885h)

Newton, G.N., Cooper, G.J.T. , Kogerler, P., Long, D.L. and Cronin, L. (2008) Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters. Journal of the American Chemical Society, 130(3), pp. 790-791. (doi:10.1021/ja0768183)

Pradeep, C. P., Long, D. L. , Newton, G. N., Song, Y. -F. and Cronin, L. (2008) Supramolecular metal oxides: Programmed hierarchical assembly of a protein-sized 21 kDa [(C16H36N)(19){H2NC(CH2O)(3)P2V3W15O59}(4)](5-) polyoxometalate assembly. Angewandte Chemie (International Edition), 47(23), pp. 4388-4391. (doi:10.1002/anie.200800431)

Pradeep, C. P., Long, D. L. , Streb, C. and Cronin, L. (2008) "Bottom-Up" Meets "Top-Down" Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P4W52O178](24-) and Disassembly to [P3W39O134](19-). Journal of the American Chemical Society, 130(45), p. 14946. (doi:10.1021/ja806596j)

Ritchie, C. et al. (2008) Polyoxometalate-mediated self-assembly of single-molecule magnets: {[XW9O34](2)[(Mn4Mn2O4)-Mn-III-O-II(H2O)(4)]}(12-). Angewandte Chemie (International Edition), 47(30), pp. 5609-5612. (doi:10.1002/anie.200801281)

Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N. , Long, D.L. , Boyd, T., Peacock, R.D., McGlone, T. and Cronin, L. (2008) Reversible redox reactions in an extended polyoxometalate framework solid. Angewandte Chemie (International Edition), 47(36), pp. 6881-6884. (doi:10.1002/anie.200802594)

Song, Y. -F., Long, D. L. , Kelly, S. E. and Cronin, L. (2008) Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry. Inorganic Chemistry, 47(20), pp. 9137-9139. (doi:10.1021/ic801366r)

Song, Y.F., Kitson, P.J., Long, D.L. , Parenty, A.D.C., Thatcher, R.J. and Cronin, L. (2008) Supramolecular self-assembly and anion-dependence of copper(II) complexes with cationic dihydro-imidazo phenanthridinium (DIP)-containing ligands. CrystEngComm, 10(9), pp. 1243-1251. (doi:10.1039/b802541j)

Streb, C., McGlone, T., Brucher, O., Long, D. L. and Cronin, L. (2008) Hybrid Host-Guest Complexes: Directing the Supramolecular Structure through Secondary Host-Guest Interactions. Chemistry: A European Journal, 14(29), pp. 8861-8868. (doi:10.1002/chem.200801247)

Wilson, E. F., Abbas, H., Duncombe, B. J., Streb, C., Long, D. L. and Cronin, L. (2008) Probing the self-assembly of inorganic cluster architectures in solution with cryospray mass spectrometry: Growth of polyoxomolybdate clusters and polymers mediated by silver(I) ions. Journal of the American Chemical Society, 130(42), pp. 13876-13884. (doi:10.1021/ja802514q)

Streb, C., Ritchie, C., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported AgIAgI interactions. Angewandte Chemie (International Edition), 46(40), pp. 7579-7582. (doi:10.1002/anie.200702698)

Long, D.L. , Burkholder, E. and Cronin, L. (2007) Polyoxometalate clusters, nanostructures and materials: from self-assembly to designer materials and devices. ChemInform, 38(15), (doi:10.1002/chin.200715223)

Song, Y.F., Long, D.L. and Cronin, L. (2007) Noncovalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate-pyrene hybrid. Angewandte Chemie (International Edition), 46(21), pp. 3900-3904. (doi:10.1002/anie.200604734)

Fay, N., Bond, A.M., Baffert, C., Boas, J.F., Pilbrow, J.R., Long, D.-L. and Cronin, L. (2007) Structural, electrochemical, and spectroscopic characterization of a redox pair of sulfite-based polyoxotungstates: α-[W18O54(SO3)2]4- and α-[W18O54(SO3)2]5-. Inorganic Chemistry, 46(9), pp. 3502-3510. (doi:10.1021/ic062067e)

Baffert, C., Feldberg, S.W., Bond, A.M., Long, D.L. and Cronin, L. (2007) pH-Dependence of the aqueous electrochemistry of the two-electron reduced alpha-[Mo18O54(SO3)] sulfite Dawson-like polyoxometalate anion derived from its triethanolammonium salt. Dalton Transactions, pp. 4599-4607. (doi:10.1039/b705991d)

Cooper, G.J.T. , Newton, G.N., Kogerler, P., Long, D.L. , Engelhardt, L., Luban, M. and Cronin, L. (2007) Structural and compositional control in {M-12} cobalt and nickel coordination clusters detected magnetochemically and with cryospray mass spectrometry. Angewandte Chemie (International Edition), 46(8), pp. 1340-1344. (doi:10.1002/anie.200603870)

Fielden, J., Long, D.L. , Slawin, A.M.Z., Kogerler, P. and Cronin, L. (2007) Ligand and counterion control of Ag(I) architectures: Assembly of a {Ag-8} ring cluster mediated by hydrophobic and Ag center dot center dot center dot Ag interactions. Inorganic Chemistry, 46, pp. 9090-9097. (doi:10.1021/ic700872b)

Pradeep, C.P., Long, D.-L. , Kögerler, P. and Cronin, L. (2007) Controlled assembly and solution observation of a 2.6 nm polyoxometalate super tetrahedron cluster: [KFe12(OH)18(-1,2,3-P2W15O56)4]29–. Chemical Communications, 41, pp. 4254-4256. (doi:10.1039/b707202c)

Ritchie, C., Burkholder, E.M., Long, D.-L. , Adam, D., Kögerler, P. and Cronin, L. (2007) Exploiting the multifunctionality of organocations in the assembly of hybrid polyoxometalate clusters and networks. Chemical Communications, 38(17), pp. 468-470. (doi:10.1039/b612741j)

Song, Y.-F., Abbas, H., Ritchie, C., McMillian, N., Long, D.-L. , Gadegaard, N. and Cronin, L. (2007) From polyoxometalate building blocks to polymers and materials: the silver connection. Journal of Materials Chemistry, 17, pp. 1903-1908. (doi:10.1039/b617830h)

Streb, C., Ritchie, C., Long, D.L. , Kogerler, P. and Cronin, L. (2007) Modular assembly of a functional polyoxometalate-based open framework constructed from unsupported Ag-I center dot center dot center dot Ag-I interactions". Angewandte Chemie (International Edition), 46, pp. 7579-7582. (doi:10.1002/anie.200702698)

Streb, C., Long, D. L. and Cronin, L. (2007) Engineering porosity in a chiral heteropolyoxometalate-based framework: the supramolecular effect of benzenetricarboxylic acid. Chemical Communications, pp. 471-473. (doi:10.1039/b613808j)

Fielden, J., Gunning, P.T., Long, D.-L. , Nutley, M., Ellern, A., Kögerler, P. and Cronin, L. (2006) Anion control of isomerism, crystal packing and binding properties in a mononuclear zinc complex. Polyhedron, 25(18), pp. 3474-3480. (doi:10.1016/j.poly.2006.06.044)

Baffert, C., Boas, J.F., Bond, A.M., Kögerler, P., Long, D.-L. , Pilbrow, J.R. and Cronin, L. (2006) Experimental and theoretical investigations of the sulfite-based polyoxometalate cluster redox series: α - and β-[Mo18O54(SO3)2]4-/5-/6-. Chemistry: A European Journal, 12(33), pp. 8472-8483. (doi:10.1002/chem.200501450)

Newton, G. N., Cooper, G. J.T. , Long, D.-L. , Kogerler, P. and Cronin, L. (2006) Synthetic, structural and magnetic characterisation of a one-dimensional nickel chain constructed using cis,trans-1,3,5-triaminocyclohexane as a building block. Journal of Molecular Structure, 796, pp. 23-27. (doi:10.1016/j.molstruc.2006.03.087)

Fielden, J., Long, D.L. , Evans, C. and Cronin, L. (2006) Metal-dependent formation of mononuclear complexes and M2L2 mesocates with Schiff-base ligands. European Journal of Inorganic Chemistry, 2006(19), pp. 3930-3935. (doi:10.1002/ejic.200600367)

Long, D.L. , Kögerler, P., Farrugia, L.J. and Cronin, L. (2006) Linking chiral clusters with molybdate building blocks: from homochiral helical supramolecular arrays to coordination helices. Chemistry: An Asian Journal, 1(3), pp. 352-357. (doi:10.1002/asia.200600069)

Long, D.L. , Kogerler, P., Parenty, A.D.C., Fielden, J. and Cronin, L. (2006) Discovery of a family of isopolyoxotungstates [H4W19O62]6- encapsulating a {WO6} moiety within a {W18} Dawson-like cluster cage. Angewandte Chemie (International Edition), 45(29), pp. 4798-4803. (doi:10.1002/anie.200504600)

Long, D.-L. , Streb, C., Kögerler, P. and Cronin, L. (2006) Observation and theoretical analysis of the “sensitive coordination sites” in the isopolyoxomolybdate cluster [Mo36O112(H2O)14]8-. Journal of Cluster Science, 17(2), pp. 257-266. (doi:10.1007/s10876-006-0058-9)

Long, D.-L. and Cronin, L. (2006) Towards polyoxometalate-integrated nanosystems. Chemistry: A European Journal, 12(14), pp. 3698-3706. (doi:10.1002/chem.200501002)

Fielden, J., Sprott, J., Long, D.-L. , Kögerler, P. and Cronin, L. (2006) Controlling aggregation of copper(II)-based coordination compounds: from mononuclear to dinuclear, tetranuclear, and polymeric copper complexes. Inorganic Chemistry, 45(7), pp. 2886-2895. (doi:10.1021/ic051647t)

Long, D.-L. , Brücher, O., Streb, C. and Cronin, L. (2006) Inorganic crown: the host–guest chemistry of a high nuclearity 'Celtic-ring' isopolyoxotungstate [H12W36O120]12–. Dalton Transactions(23), pp. 2852-2860. (doi:10.1039/b515935k)

Streb, C., Long, D.-L. and Cronin, L. (2006) Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks. CrystEngComm, 8, pp. 629-634. (doi:10.1039/b605285a)

Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2005) A novel copper (II) metallacycle as a building block for the assembly of an extended supramolecular array containing channels and helical chains. Inorganic Chemistry Communications, 8(8), pp. 737-739. (doi:10.1016/j.inoche.2005.05.005)

Parenty, A.D.C., Smith, L.V., Guthrie, K.M., Long, D.-L. , Plumb, J., Brown, R. and Cronin, L. (2005) Highly stable phenanthridinium frameworks as a new class of tunable DNA binding agents with cytotoxic properties. Journal of Medicinal Chemistry, 48(14), pp. 4504-4506. (doi:10.1021/jm050320z)

Long, D.-L. , Abbas, H., Kogerler, P. and Cronin, L. (2005) Confined electron-transfer reactions within a molecular metal oxide "Trojan horse". Angewandte Chemie (International Edition), 44(22), pp. 3415-3419. (doi:10.1002/anie.200500541)

Abbas, H., Pickering, A.L., Long, D.-L. , Kögerler, P. and Cronin, L. (2005) Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers. Chemistry: A European Journal, 11(4), pp. 1071-1078. (doi:10.1002/chem.200401088)

Long, D.L. , Kogerler, P., Farrugia, L.J. and Cronin, L. (2005) Reactions of a {Mo-16}-type polyoxometalate cluster with electrophiles: a synthetic, theoretical and magnetic investigation. Dalton Transactions, pp. 1372-1380. (doi:10.1039/b419301f)

Pickering, A.L., Seeber, G., Long, D.L. and Cronin, L. (2005) The importance of pi-pi, pi-CH and N-CH interactions in the crystal packing of Schiff-base derivatives of cis,cis- and cis,trans-1,3,5-triaminocyclohexane. CrystEngComm, 7, pp. 504-510. (doi:10.1039/b506718a)

Cooper, G.J.T. , Abbas, H., Kögerler, P., Long, D.-L. and Cronin, L. (2004) Pentadecadentate chelating ligands as building blocks for a {Fe6} cage with 12 exo-coordinated sodium cations. Inorganic Chemistry, 43(23), pp. 7266-7268. (doi:10.1021/ic049068w)

Parenty, A.D.C., Smith, L.V., Pickering, A.L., Long, D.-L. and Cronin, L. (2004) General one-pot, three-step methodology leading to an extended class of N-heterocyclic cations: spontaneous nucleophilic addition, cyclization, and hydride loss. Journal of Organic Chemistry, 69(18), pp. 5934-5946. (doi:10.1021/jo0495440)

Pickering, A.L., Cooper, G.J.T. , Long, D.-L. and Cronin, L. (2004) Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers. Polyhedron, 23(12), pp. 2075-2079. (doi:10.1016/j.poly.2004.06.002)

Pickering, A.L., Long, D.-L. and Cronin, L. (2004) Coordination networks through the dimensions: from discrete clusters to 1D, 2D, and 3D silver(I) coordination polymers with rigid aliphatic amino ligands. Inorganic Chemistry, 43(16), pp. 4953-4961. (doi:10.1021/ic049786i)

Long, D.-L. , Kögerler, P. and Cronin, L. (2004) Old clusters with new tricks: engineering S...S interactions and novel physical properties in sulfite-based Dawson clusters. Angewandte Chemie (International Edition), 43(14), pp. 1817-1820. (doi:10.1002/anie.200352896)

Fielden, J., Long, D.-L. and Cronin, L. (2004) Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes. Chemical Communications(19), pp. 2156-2157. (doi:10.1039/b407229d)

Long, D.L. , Abbas, H., Kogerler, P. and Cronin, L. (2004) A high-nuclearity "Celtic-Ring" isopolyoxotungstate, [H12W36O120] that captures trace potassium ions. Journal of the American Chemical Society, 126, pp. 13880-13881. (doi:10.1021/ja046410v)

Pickering, A.L., Seeber, G., Long, D.-L. and Cronin, L. (2004) Polymeric silver(I) coordination tubes. Chemical Communications, 2004, pp. 136-137. (doi:10.1039/b312876h)

Long, D.-L. , Kögerler, P., Farrugia, L. and Cronin, L. (2003) Restraining symmetry in the formation of small polyoxomolybdates: building blocks of unprecedented topology resulting from "shrink-wrapping" [H2Mo16O52]10--type clusters. Angewandte Chemie (International Edition), 42(35), pp. 4180-4183. (doi:10.1002/anie.200351615)

Long, D.-L. , Orr, D., Seeber, G., Kögerler, P., Farrugia, L.J. and Cronin, L. (2003) The missing link in low nuclearity pure polyoxovanadate clusters: preliminary synthesis and structural analysis of a new {V16} cluster and related products: dedicated to professor Achim Müller. Journal of Cluster Science, 14(3), pp. 313-324. (doi:10.1023/B:JOCL.0000005066.92182.90)

Seeber, G., Long, D.L. , Kariuki, B.M. and Cronin, L. (2003) Palladium(II)-based cis,trans-1,3,5-triaminocyclohexane complexes demonstrating a variety of coordination modes and architectures. Dalton Transactions, pp. 4498-4504. (doi:10.1039/b307616d)

Seeber, G., Pickering, A.L., Long, D.L. and Cronin, L. (2003) Controlling dimensionality of silver(I) coordination networks with rigid aliphatic amino ligands: from a 2D to a 3D network of unprecedented topology comprising helical channels. Chemical Communications, pp. 2002-2003. (doi:10.1039/b305188a)

Book Sections

Miras, H.N. , Long, D.-L. and Cronin, L. (2017) Exploring self-assembly and the self-organization of nanoscale inorganic polyoxometalate clusters. In: van Eldik, R. and Cronin, L. (eds.) Polyoxometalate Chemistry. Series: Advances in inorganic chemistry, 69. Academic Press: Burlington, pp. 1-28. ISBN 9780128111055 (doi:10.1016/bs.adioch.2016.12.001)

This list was generated on Wed Jul 17 06:25:45 2019 BST.