Professor Graeme Cooke
- Head of School / Professor of Physical Organic Chemistry (Chemistry)
telephone: 01413305500
email: Graeme.Cooke@glasgow.ac.uk
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https://orcid.org/0000-0003-0890-5720Research interests
Research Interests
Research within the Cooke research group focuses upon the design, synthesis and characterisation of functional molecules, macromolecules and surfaces.
Research Topics
- Organic solar cells, dye-sensitized solar cells and perovskite solar cells
- Organic batteries
- Non-covalent modification of polymers, micelles and surfaces
- Biomimetic chemistry and supramolecular chemistry
Publication Highlights
- Spruell, J.M. et al. (2010) Highly stable tetrathiafulvalene radical dimers in [3]catenanes. Nature Chemistry, 2(10), pp. 870-879. (doi:10.1038/nchem.749)
- Hedley, G. J., Ward, A. J., Alekseev, A. , Howells, C. T., Martins, E. R., Serrano, L. A., Cooke, G., Ruseckas, A. and Samuel, I. D. W. (2013) Determining the optimum morphology in high-performance polymer-fullerene organic photovoltaic cells. Nature Communications, 4, 2867. (doi:10.1038/ncomms3867)
- Ward, A. J., Ruseckas, A., Kareem, M. M., Ebenhoch, B., Serrano, L. A., Al-Eid, M., Fitzpatrick, B., Rotello, V. M., Cooke, G. and Samuel, I. D.W. (2015) The impact of driving force on electron transfer rates in photovoltaic donor-acceptor blends. Advanced Materials, 27(15), pp. 2496-2500. (doi:10.1002/adma.201405623) (PMID:25759321)
- Karimullah, A. S. , Jack, C., Tullius, R., Rotello, V. M., Cooke, G., Gadegaard, N., Barron, L. D. and Kadodwala, M. (2015) Disposable plasmonics: plastic templated plasmonic metamaterials with tunable chirality. Advanced Materials, 27(37), pp. 5610-5616. (doi:10.1002/adma.201501816)
- Jack, C. et al. (2016) Spatial control of chemical processes on nanostructures through nano-localized water heating. Nature Communications, 7, 10946. (doi:10.1038/ncomms10946) (PMID:26961708) (PMCID:PMC4792951)
Teaching
Teaching
- Organic and Supramolecular and Materials Chemistry (Final year)
Research datasets
2018
Dos Santos, J. M., Jagadamma, L. K., Latif, N. M., Ruseckas, A., Samuel, I. D. W. and Cooke, G. (2018) New BODIPY derivatives with near infra-red absorption as small molecule donors for bulk heterojunction solar cells. [Data Collection]
Mica, N. A., Almahmoud, S. A. J., Jagadamma, L. K., Cooke, G. and Samuel, I. D. W. (2018) An investigation of the role acceptor side chains play in the processibility and efficiency of organic solar cells fabricated from small molecular donors featuring 3,4-ethylenedioxythiophene cores. [Data Collection]
2016
Abdalhadi, S. M., Connell, A., Zhang, X., Wiles, A. , Davies, M. L., Holliman, P. J. and Cooke, G. (2016) Convenient synthesis of EDOT-based dyes by CH-activation and their application as dyes in dye-sensitized solar cells. [Data Collection]
Wiles, A. , Zhang, X., Fitzpatrick, B., Long, D. L. , Macgregor, S. A. and Cooke, G. (2016) Redox-mediated reactions of vinylferrocene: toward redox auxiliaries. [Data Collection]
Cariello, M., Ahn, S., Park, K.-W., Chang, S.-K., Hong, J. and Cooke, G. (2016) An investigation of the role increasing p-conjugation has on the efficiency of dye-sensitized solar cells fabricated from ferrocene-based dyes. [Data Collection]
Wiles, A. A., Fitzpatrick, B., McDonald, N. A., Westwater, M. M., Long, D.-L., Ebenhoch, B., Rotello, V. M., Samuel, I. D. W. and Cooke, G. (2016) Synthesis and properties of pteridine-2,4-dione-functionalised oligothiophenes. [Data Collection]
Additional information
External Appointments & Positions
- Director of WestCHEM
- EPSRC College Member
- Fellow of the Higher Education Academy
- Fellow of the Royal Society of Chemistry
Publications
2019
Zhang, Y., Sajjad, M. T., Blaszczyk, O., Ruseckas, A., Serrano, L. A., Cooke, G. and Samuel, I. D.W. (2019) Enhanced exciton harvesting in a planar heterojunction organic photovoltaic device by solvent vapor annealing. Organic Electronics, 70, pp. 162-166. (doi:10.1016/j.orgel.2019.03.014)
Marques dos Santos, J., Jagadamma, L. K., Latif, N. M., Ruseckas, A., Samuel, I. D. W. and Cooke, G. (2019) BODIPY derivatives with near infra-red absorption as small molecule donors for bulk heterojunction solar cells. RSC Advances,
Connell, A. et al. (2019) Low cost triazatruxene hole transporting material for >20% efficient perovskite solar cells. Journal of Materials Chemistry C, 7, pp. 5235-5243. (doi:10.1039/C8TC04231D)
Zhang, Y., Sajjad, M. T., Blaszczyk, O., Parnell, A. J., Ruseckas, A., Serrano, L. A., Cooke, G. and Samuel, I. D.W. (2019) Large crystalline domains and enhanced exciton diffusion length enable efficient organic solar cells. Chemistry of Materials, (doi:10.1021/acs.chemmater.8b05293) (Early Online Publication)
Serrano, L. A., Park, K.-W., Ahn, S., Wiles, A. A. , Hong, J. and Cooke, G. (2019) Coplanar donor-π-acceptor dyes featuring a furylethynyl spacer for dye-sensitized solar cells. Materials, 12(5), 839. (doi:10.3390/ma12050839)
Cooke, G. , Evans, I. R. and Skabara, P. J. (2019) Functional organic materials for optoelectronic applications. Journal of Materials Chemistry C, 7, p. 6492. (doi:10.1039/c9tc90084e)
2018
Mica, N.A., Almahmoud, S.A.J., Krishnan Jagadamma, L., Cooke, G. and Samuel, I.D.W. (2018) An investigation of the role acceptor side chains play in the processibility and efficiency of organic solar cells fabricated from small molecular donors featuring 3,4-ethylenedioxythiophene cores. RSC Advances, 2018(8), pp. 39231-39240. (doi:10.1039/C8RA07034B)
Krishnan Jagadamma, L., McCarron, L. J., Wiles, A. A. , Savikhin, V., Sajjad, M., Yazdani, M., Rotello, V. M., Toney, M. F., Cooke, G. and Samuel, I. D. W. (2018) Triptycene as a supramolecular additive in PTB7:PCBM blends and its influence on photovoltaic properties. ACS Applied Materials and Interfaces, 10(29), pp. 24665-24678. (doi:10.1021/acsami.8b03114) (PMID:29932630)
Kelly, C., Tullius, R., Lapthorn, A. J. , Gadegaard, N. , Cooke, G. , Barron, L. D., Karimullah, A. S. , Rotello, V. M. and Kadodwala, M. (2018) Chiral plasmonic fields probe structural order of biointerfaces. Journal of the American Chemical Society, 140(27), pp. 8509-8517. (doi:10.1021/jacs.8b03634) (PMID:29909628)
Cariello, M., Abdalhadi, S. M., Yadav, P., Decoppet, J.-D., Zakeeruddin, S. M., Grätzel, M., Hagfeldt, A. and Cooke, G. (2018) An investigation of the roles furan versus thiophene π-bridges play in donor–π-acceptor porphyrin based DSSCs. Dalton Transactions, 47(18), pp. 6549-6556. (doi:10.1039/C8DT00413G) (PMID:29697124)
2017
Tullius, R. et al. (2017) Superchiral plasmonic phase sensitivity for fingerprinting of protein interface structure. ACS Nano, 11(12), pp. 12049-12056. (doi:10.1021/acsnano.7b04698) (PMID:29220155)
Fumagalli, M., Belal, K., Guo, H., Stoffelbach, F., Cooke, G. , Marcellan, A., Woisel, P. and Hourdet, D. (2017) Supramolecular polymer hydrogels induced by host-guest interactions with di-[cyclobis(paraquat-p-phenylene)] cross-linkers: from molecular complexation to viscoelastic properties. Soft Matter, 13(31), pp. 5269-5282. (doi:10.1039/C7SM01051F) (PMID:28676876)
Mohammed, N., Wiles, A. A. , Belsley, M., Fernandes, S. S.M., Cariello, M., Rotello, V. M., Raposo, M. M. M. and Cooke, G. (2017) Synthesis and characterisation of push-pull flavin dyes with efficient second harmonic generation (SHG) properties. RSC Advances, 7(39), pp. 24462-24469. (doi:10.1039/C7RA03400H)
Long, Y., Hedley, G. , Ruseckas, A., Chowdhury, M., Roland, T., Serrano, L. A., Cooke, G. and Samuel, I. D.W. (2017) Effect of annealing on exciton diffusion in a high performance small molecule organic photovoltaic material. ACS Applied Materials and Interfaces, 9(17), pp. 14945-14952. (doi:10.1021/acsami.6b16487) (PMID:28358189) (PMCID:PMC5423077)
Park, K.-W., Serrano, L. A., Ahn, S., Baek, M. H., Wiles, A. A. , Cooke, G. and Hong, J. (2017) An investigation of the role the donor moiety plays in modulating the efficiency of ‘donor-π-acceptor-π-acceptor’ organic DSSCs. Tetrahedron, 73(8), pp. 1098-1104. (doi:10.1016/j.tet.2016.12.061)
2016
Belal, K. et al. (2016) Recognition-mediated hydrogel swelling controlled by interaction with a negative thermoresponsive LCST polymer. Angewandte Chemie (International Edition), 55(45), pp. 13974-13978. (doi:10.1002/anie.201605630) (PMID:27730718)
Abdalhadi, S.M., Connell, A., Zhang, X., Wiles, A.A. , Davies, M.L., Holliman, P.J. and Cooke, G. (2016) Convenient synthesis of EDOT-based dyes by CH-activation and their application as dyes in dye-sensitized solar cells. Journal of Materials Chemistry A, 40(4), pp. 15655-15661. (doi:10.1039/C6TA04483B)
Jack, C., Karimullah, A. S. , Leyman, R., Tullius, R., Rotello, V. M., Cooke, G. , Gadegaard, N. , Barron, L. D. and Kadodwala, M. (2016) Biomacromolecular stereostructure mediates mode hybridization in chiral plasmonic nanostructures. Nano Letters, 16(9), pp. 5806-5814. (doi:10.1021/acs.nanolett.6b02549) (PMID:27547978)
Yeniad, B., Ryskulova, K., Fournier, D., Lyskawa, J., Cooke, G. , Woisel, P. and Hoogenboom, R. (2016) Complexation of thermoresponsive dialkoxynaphthalene end-functionalized poly(oligoethylene glycol acrylate)s with CBPQT4+in water. Polymer Chemistry, 7(22), pp. 3681-3690. (doi:10.1039/c6py00303f)
Wiles, A. A. , Zhang, X., Fitzpatrick, B., Long, D.-L. , Macgregor, S. A. and Cooke, G. (2016) Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries. Dalton Transactions, 45(17), pp. 7220-7225. (doi:10.1039/C6DT00875E) (PMID:27063914)
Jack, C. et al. (2016) Spatial control of chemical processes on nanostructures through nano-localized water heating. Nature Communications, 7, 10946. (doi:10.1038/ncomms10946) (PMID:26961708) (PMCID:PMC4792951)
Belal, K., Poitras-Jolicoeur, S., Lyskawa, J., Pembouong, G., Cooke, G. , Woisel, P. and Stoffelbach, F. (2016) A triple carboxylic acid-functionalized RAFT agent platform for the elaboration of well-defined telechelic 3-arm star PDMAc. Chemical Communications, 52(9), pp. 1847-1850. (doi:10.1039/c5cc09684g) (PMID:26670290)
Cariello, M., Ahn, S., Park, K.-W., Chang, S.-K., Hong, J. and Cooke, G. (2016) An investigation of the role increasing π-conjugation has on the efficiency of dye-sensitized solar cells fabricated from ferrocene-based dyes. RSC Advances, 6, pp. 9132-9138. (doi:10.1039/C5RA21565J)
Wiles, A. A. , Fitzpatrick, B., McDonald, N. A., Westwater, M. M., Long, D. L. , Ebenhoch, B., Rotello, V. M., Samuel, I. D. W. and Cooke, G. (2016) Synthesis and properties of pteridine-2,4-dione-functionalised oligothiophenes. RSC Advances, 6(10), pp. 7999-8005. (doi:10.1039/c5ra22402k)
2015
Laggoune, N., Delattre, F., Lyskawa, J., Stoffelbach, F., Guigner, J.-M., Ruellan, S., Cooke, G. and Woisel, P. (2015) Synthesis, binding and self-assembly properties of a well-defined pillar[5]arene end functionalised polydimethylacrylamide. Polymer Chemistry, 6(42), pp. 7389-7394. (doi:10.1039/C5PY01186H)
Karimullah, A. S. , Jack, C., Tullius, R., Rotello, V. M., Cooke, G. , Gadegaard, N. , Barron, L. D. and Kadodwala, M. (2015) Disposable plasmonics: plastic templated plasmonic metamaterials with tunable chirality. Advanced Materials, 27(37), pp. 5610-5616. (doi:10.1002/adma.201501816)
Malfait, A., Coumes, F., Fournier, D., Cooke, G. and Woisel, P. (2015) A water-soluble supramolecular polymeric dual sensor for temperature and pH with an associated direct visible readout. European Polymer Journal, 69, pp. 552-558. (doi:10.1016/j.eurpolymj.2015.02.033)
Tullius, R., Karimullah, A. S. , Rodier, M., Fitzpatrick, B., Gadegaard, N. , Barron, L. D., Rotello, V. M., Cooke, G. , Lapthorn, A. and Kadodwala, M. (2015) "Superchiral” spectroscopy: detection of protein higher order hierarchical structure with chiral plasmonic nanostructures. Journal of the American Chemical Society, 137(26), pp. 8380-8383. (doi:10.1021/jacs.5b04806) (PMID:26102606)
Ward, A. J., Ruseckas, A., Kareem, M. M., Ebenhoch, B., Serrano, L. A., Al-Eid, M., Fitzpatrick, B., Rotello, V. M., Cooke, G. and Samuel, I. D.W. (2015) The impact of driving force on electron transfer rates in photovoltaic donor-acceptor blends. Advanced Materials, 27(15), pp. 2496-2500. (doi:10.1002/adma.201405623) (PMID:25759321)
Ebenhoch, B., Prasetya, N. B.A., Rotello, V. M., Cooke, G. and Samuel, I. D.W. (2015) Solution-processed boron subphthalocyanine derivatives as acceptors for organic bulk-heterojunction solar cells. Journal of Materials Chemistry A, 3(14), pp. 7345-7352. (doi:10.1039/C5TA00715A)
Connell, A., Holliman, P. J., Jones, E. W., Furnell, L., Kershaw, C., Davies, M. L., Gwenin, C. D., Pitak, M. B., Coles, S. J. and Cooke, G. (2015) Multiple linker half-squarylium dyes for dye-sensitized solar cells; are two linkers better than one? Journal of Materials Chemistry A, 3(6), pp. 2883-2894. (doi:10.1039/c4ta06896c)
2014
Sambe, L., de La Rosa, V. R., Belal, K., Stoffelbach, F., Lyskawa, J., Delattre, F., Bria, M., Cooke, G. , Hoogenboom, R. and Woisel, P. (2014) Programmable polymer-based supramolecular temperature sensor with a memory function. Angewandte Chemie (International Edition), 53(20), pp. 5044-5048. (doi:10.1002/anie.201402108)
Landis, R. F., Yazdani, M., Creran, B., Yu, X., Nandwana, V., Cooke, G. and Rotello, V. M. (2014) Solvatochromic probes for detecting hydrogen-bond-donating solvents. Chemical Communications, 50(35), p. 4579. (doi:10.1039/C4CC00805G)
Al-Eid, M., Lim, S., Park, K.-W., Fitzpatrick, B., Han, C.-H., Kwak, K., Hong, J. and Cooke, G. (2014) Facile synthesis of metal-free organic dyes featuring a thienylethynyl spacer for dye sensitized solar cells. Dyes and Pigments, 104, pp. 197-203. (doi:10.1016/j.dyepig.2014.01.004)
Sambe, L., Stoffelbach, F., Poltorak, K., Lyskawa, J., Malfait, A., Bria, M., Cooke, G. and Woisel, P. (2014) Elaboration of Thermoresponsive Supramolecular DiBlock Copolymers in Water from Complementary CBPQT4+ and TTF End-functionalized Polymers. Macromolecular Rapid Communications, 35(4), pp. 498-504. (doi:10.1002/marc.201300729)
Caldwell, S.T. et al. (2014) Protein-mediated dethreading of a biotin-functionalised pseudorotaxane. Organic and Biomolecular Chemistry, 12(3), pp. 511-516. (doi:10.1039/C3OB41612G)
Connell, A., Holliman, P.J., Davies, M.L., Gwenin, C.D., Weiss, S., Pitak, M.B., Horton, P.N., Coles, S.J. and Cooke, G. (2014) A study of dye anchoring points in half-squarylium dyes for dye-sensitized solar cells. Journal of Materials Chemistry A, 2, pp. 4055-4066. (doi:10.1039/C3TA15278B)
Sambe, L. et al. (2014) Multi stimuli responsive suprmolecular diblock copolymers. Polymer Chemistry, 5(3), pp. 1031-1036. (doi:10.1039/C3PY01093G)
2013
Hedley, G. J. , Ward, A. J., Alekseev, A. , Howells, C. T., Martins, E. R., Serrano, L. A., Cooke, G. , Ruseckas, A. and Samuel, I. D.W. (2013) Determining the optimum morphology in high-performance polymer-fullerene organic photovoltaic cells. Nature Communications, 4, 2867. (doi:10.1038/ncomms3867) (PMID:24343223) (PMCID:PMC3905772)
Nandwana, V., Serrano Gonzalez, L. A., Solntsev, K. M., Ebenhoch, B., Liu, Q., Tonga, G. Y., Samuel, I. D.W., Cooke, G. and Rotello, V. M. (2013) Engineering the nanoscale morphology of quantum dot-fullerene assembly via complementary hydrogen bonding interactions. Langmuir, 29(24), pp. 7534-7537. (doi:10.1021/la4007372)
Pauszek, R. F., Kodali, G., Caldwell, S. T., Fitzpatrick, B., Zainalabdeen, N. Y., Cooke, G. , Rotello, V. M. and Stanley, R. J. (2013) Excited state charge redistribution and dynamics in the donor-π-acceptor flavin derivative ABFL. Journal of Physical Chemistry B, 117(49), pp. 15684-15694. (doi:10.1021/jp406420h)
Zainalabdeen, N., Fitzpatrick, B., Kareem, M. M., Nandwana, V., Cooke, G. and Rotello, V. M. (2013) Synthesis and Xharacterization of naphthalenediimide-functionalized flavin derivatives. International Journal of Molecular Sciences, 14(4), pp. 7468-7479. (doi:10.3390/ijms14047468)
2012
Fitzpatrick, B., Creran, B., Cooke, G. and Rotello, V.M. (2012) Flavin-functionalized amphiphilic block copolymer gela. Macromolecular Chemistry and Physics, 213(17), pp. 1758-1767. (doi:10.1002/macp.201200225)
Maclean, C.E., Parkinson, C.L., Davis, P.J., Davis, M.J. and Cooke, G. (2012) A dual-responsive ferrocene-functionalized PDA liposome. Tetrahedron Letters, 53(24), pp. 2948-2950. (doi:10.1016/j.tetlet.2012.03.064)
Nandwana, V., Fitzpatrick, B., Liu, Q., Solntsev, K.M., Yu, X., Tonga, G.Y., Eymur, S., Tonga, M., Cooke, G. and Rotello, V.M. (2012) Fluorescence resonance energy transfer in recognition-mediated polymer-quantum dot assemblies. Polymer Chemistry, 3(11), pp. 3072-3076. (doi:10.1039/C2PY20353G)
Nandwana, V., Samuel, I., Cooke, G. and Rotello, V. M. (2012) Aromatic stacking interactions in flavin model systems. Accounts of Chemical Research, 46(4), pp. 1000-1009. (doi:10.1021/ar300132r)
Xi, Y. et al. (2012) Flavin as a photo-active acceptor for efficient energy and charge transfer in a model donor-acceptor system. Physical Chemistry Chemical Physics, 14(19), pp. 6749-6754. (doi:10.1039/C2CP40073A)
2011
Sambe, L., Stoffelba, F., Lyskawa, J., Delattre, F., Fournier, D., Bouteiller, L., Charleux, B., Cooke, G. and Woisel, P. (2011) Host–guest modulation of the micellization of a tetrathiafulvalene-functionalized poly(N-isopropylacrylamid). Macromolecules, 44(16), pp. 6532-6538. (doi:10.1021/ma2009854)
McDonald, N.A., Subramani, C., Caldwell, S.T., Zainalabdeen, N.Y., Cooke, G. and Rotello, V.M. (2011) Simultaneous hydrogen bonding and π-stacking interactions between flavin/porphyrin host–guest syst. Tetrahedron Letters, 52(17), pp. 2107-2110. (doi:10.1016/j.tetlet.2010.11.004)
Barka-Bouaifel, F. et al. (2011) Optical and electrochemical properties of tunable host–guest complexes linked to plasmonic interfaces. Journal of Materials Chemistry, 21(9), pp. 3006-3013. (doi:10.1039/C0JM03293J)
Louisy, J., Delattre, F., Lyskawa, J., Malfait, A., Maclean, C.E., Sambe, L., Zhu, N., Cooke, G. and Woisel, P. (2011) Surfactant-mediated control of CBPQT4+–dialkoxynaphthalene complexation. Chemical Communications, 47(24), pp. 6819-6821. (doi:10.1039/C1CC10571J)
Nandwana, V. et al. (2011) Recognition-mediated assembly of quantum dot polymer conjugates with controlled morphology. International Journal of Molecular Sciences, 12(9), pp. 6357-6366. (doi:10.3390/ijms12096357)
2010
Bigot, J., Charleux, B., Cooke, G. , Delattre, F., Fournier, D., Lyskawa, J., Sambe, L., Stoffelbach, F. and Woisel, P. (2010) Tetrathiafulvalene end-functionalized poly(N-isopropylacrylamide): a new class of amphiphilic polymer for the creation of multistimuli responsive micelles. Journal of the American Chemical Society, 132(31), pp. 10796-10801. (doi:10.1021/ja1027452)
Bigot, J., Charleux, B., Cooke, G. , Delattre, F., Fournier, D., Lyskawa, J., Stoffelbach, F. and Woisel, P. (2010) Synthesis and properties of tetrathiafulvalene end-functionalized polymers prepared via RAFT polymerization. Macromolecules, 43(1), pp. 82-90. (doi:10.1021/ma901809a)
Figlus, M., Caldwell, S.T., Walas, D., Yesilbag, G., Cooke, G. , Kocovsky, P., Malkov, A.V. and Sanyal, A. (2010) Dendron-anchored organocatalysts: the asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron. Organic and Biomolecular Chemistry, 8(1), pp. 137-141. (doi:10.1039/b916601g)
Nakade, H., Jordan, B., Srivastava, S., Xu, H., Yu, X., Pollier, M., Cooke, G. and Rotello, V. (2010) Molecular recognition-induced liquid crystals from complementary diaminopyridine and flavin dyads. Supramolecular Chemistry, 22(11), pp. 691-696. (doi:10.1080/10610278.2010.506540)
Siddle, J. S., Batsanov, A. S., Caldwell, S. T., Cooke, G. and Bryce, M. R. (2010) Divergent synthesis of arylated pyridin-2(1H)-one derivatives via metal-catalysed cross-coupling processes. Tetrahedron, 66(32), pp. 6138-6149. (doi:10.1016/j.tet.2010.05.108)
Spreull, J.M. et al. (2010) Highly stable tetrathiafulvalene radical dimers in [3]catenanes. Nature Chemistry, 2(10), pp. 870-879. (doi:10.1038/nchem.749)
Subramani, C., Yesilbag, G., Jordan, B. J., Li, X. N., Khorasani, A., Cooke, G. , Sanyal, A. and Rotello, V. M. (2010) Recognition mediated encapsulation and isolation of flavin-polymer conjugates using dendritic guest moieties. Chemical Communications, 46(12), pp. 2067-2069. (doi:10.1039/b926746h)
2009
Malkov, A. V., Figlus, M., Prestly, M. R., Rabani, G., Cooke, G. and Kocovsky, P. (2009) Soluble Polymer-Supported Organocatalysts: Asymmetric Reduction of Imines with Trichlorosilane Catalyzed by an Amino Acid Derived Formamide Anchored to a Soluble Polymer. Chemistry: A European Journal, 15(38), pp. 9651-9654. (doi:10.1002/chem.200901573)
Bigot, J. et al. (2009) LCST: a powerful tool to control complexation between a dialkoxynaphthalene-functionalised poly(N-isopropylacrylamide) and CBPQT(4+) in water. Chemical Communications(35), pp. 5266-5268. (doi:10.1039/b910856d)
Bria, M., Bigot, J., Cooke, G. , Lyskawa, J., Rabani, G., Rotello, V. M. and Woisel, P. (2009) Synthesis of a polypseudorotaxane, polyrotaxane, and polycatenane using 'click' chemistry. Tetrahedron, 65(1), pp. 400-407. (doi:10.1016/j.tet.2008.10.005)
Caldwell, S. T., Farrugia, L. J., Hewage, S. G., Kryvokhyzha, N., Rotello, V. M. and Cooke, G. (2009) Model systems for flavoenzyme activity: an investigation of the role functionality attached to the C(7) position of the flavin unit has on redox and molecular recognition properties. Chemical Communications(11), pp. 1350-1352. (doi:10.1039/b900269n)
Malkov, A. V., Figlus, M., Cooke, G. , Caldwell, S.T., Rabani, G., Prestly, M. R. and Kocovsky, P. (2009) Organocatalysts immobilised onto gold nanoparticles: application in the asymmetric reduction of imines with trichlorosilane. Organic and Biomolecular Chemistry, 7(9), pp. 1878-1883. (doi:10.1039/b821391g)
Patra, D., Pagliuca, C., Subramani, C., Samanta, B., Agasti, S. S., Zainalabdeen, N., Caldwell, S. T., Cooke, G. and Rotello, V. M. (2009) Molecular recognition at the liquid-liquid interface of colloidal microcapsules. Chemical Communications(28), pp. 4248-4250. (doi:10.1039/b906458c)
2008
Jordan, B.J. et al. (2008) 'Lock and key' control of optical properties in a push-pull system. Chemical Communications(14), pp. 1653-1655. (doi:10.1039/b718015b)
Agasti, S. S., Caldwell, S. T., Cooke, G. , Jordan, B. J., Kennedy, A., Kryvokhyzha, N., Rabani, G., Rana, S., Sanyal, A. and Rotello, V. M. (2008) Dendron-based model systems for flavoenzyme activity: towards a new class of synthetic flavoenzyme. Chemical Communications(35), pp. 4123-4125. (doi:10.1039/b809568j)
Caldwell, S. T., Cooke, G. , Cooper, A., Nutley, M., Rabani, G., Rotello, V., Smith, B. O. and Woisel, P. (2008) Tuneable pseudorotaxane formation between a biotin-avidin bioconjugate and CBPQT(4+). Chemical Communications(23), pp. 2650-2652. (doi:10.1039/b803856b)
Caldwell, S. T., Cooke, G. , Fitzpatrick, B., Long, D.L. , Rabani, G. and Rotello, V. M. (2008) A flavin-based [2]catenane. Chemical Communications(45), pp. 5912-5914. (doi:10.1039/b813779j)
Caldwell, S. T., Cooke, G. , Hewage, S. G., Mabruk, S., Rabani, G., Rotello, V., Smith, B.O. , Subramani, C. and Woisel, P. (2008) Model systems for flavoenzyme activity: intramolecular self-assembly of a flavin derivative via hydrogen bonding and aromatic interactions. Chemical Communications(35), pp. 4126-4128. (doi:10.1039/b809762c)
Jordan, B. J., Ofir, Y., Patra, D., Caldwell, S. T., Kennedy, A., Joubanian, S., Rabani, G., Cooke, G. and Rotello, V. M. (2008) Controlled Self-Assembly of Organic Nanowires and Platelets Using Dipolar and Hydrogen-Bonding Interactions. Small, 4(11), pp. 2074-2078. (doi:10.1002/smll.200800811)
Richmond, C. J., Parenty, A. D. C., Song, Y. -F., Cooke, G. and Cronin, L. (2008) Realization of a "Lockable" molecular switch via pH- and redox-modulated cyclization. Journal of the American Chemical Society, 130(39), pp. 13059-13065. (doi:10.1021/ja803338m)
2007
Jordan, B. J., Cooke, G. , Garety, J. F., Pollier, M. A., Kryvokhyzha, N., Bayir, A., Rabani, G. and Rotello, V. M. (2007) Polymeric model systems for flavoenzyme activity: towards synthetic flavoenzymes. Chemical Communications, 12, pp. 1248-1250. (doi:10.1039/b616159f)
Cooke, G. , Garety, J. F., Hewage, S. G., Jordan, B. J., Rabani, G., Rotello, V. M. and Woisel, P. (2007) Tuneable side-chain supramolecular polymer. Organic Letters, 9(3), pp. 481-484. (doi:10.1021/ol062846z)
Bria, M., Cooke, G. , Cooper, A., Garety, J., Hewage, S., Nutley, M., Rabani, G. and Woisel, P. (2007) An investigation of the complexation properties of cyclobis(paraquat-p-phenylene) in water. Tetrahedron Letters, 48, pp. 301-304. (doi:10.1016/j.tetlet.2006.11.003)
Bria, M., Cooke, G. , Cooper, A., Delattre, F., Hewage, S. G., Rabani, G., Nutley, M. and Woisel, P. (2007) An investigation of the complexation of a TTF derivative with alpha-, beta- and gamma-cyclodextrins in aqueous media. Tetrahedron Letters, 48(48), pp. 8430-8433. (doi:10.1016/j.tetlet.2007.09.167)
Cooke, G. , Daniels, L. M., Cazier, F., Garety, J. F., Hewage, S. G., Parkin, A., Rabani, G., Rotello, V. M., Wilson, C. C. and Woisel, P. (2007) The synthesis of a pyrrole-functionalized cyclobis( paraquat-p-phenylene) derivative and its corresponding [2]rotaxane and [2]catenane and their subsequent deposition onto an electrode surface. Tetrahedron, 63(45), pp. 11114-11121. (doi:10.1016/j.tet.2007.08.027)
2006
Cooke, G. , Garety, J. F., Jordan, B., Kryvokhyzha, N., Parkin, A., Rabani, G. and Rotello, V. M. (2006) Flavin-based [2]rotaxanes. Organic Letters, 8(11), pp. 2297-2300. (doi:10.1021/ol060620q)
Cooke, G. , Woisel, P., Bria, M., Delattre, F., Garety, J. F., Hewage, S. G., Rabani, G. and Rosair, G. M. (2006) A tuneable self-complexing molecular switch. Organic Letters, 8(7), pp. 1423-1426. (doi:10.1021/ol0602553)
Bayir, A., Jordan, B. J., Verma, A., Pollier, M. A., Cooke, G. and Rotello, V. M. (2006) Model systems for flavoenzyme activity: Recognition and redox modulation of flavin mononucleotide in water using nanoparticles. Chemical Communications, 38, pp. 4033-4035. (doi:10.1039/b608928c)
Cooke, G. , Couet, J., Garety, J., Ma, C., Mabruk, S., Rabani, G., Rotello, V., Sindelar, V. and Woisel, P. (2006) The electrochemically tuneable hydrogen bonding interactions between a phenanthrenequinone-functionalized self-assembled monolayer and a phenyl-urea terminated dendrimer. Tetrahedron Letters, 47, pp. 3763-3766. (doi:10.1016/j.tetlet.2006.03.117)
Cooke, G. , Garety, J., Mabruk, S., Rabani, G., Rotello, V., Surpateanu, G. and Woisel, P. (2006) The electrochemical polymerisation of a [2]rotaxane. Tetrahedron Letters, 47, pp. 783-786. (doi:10.1016/j.tetlet.2005.11.106)
Cooke, G. , Woisel, P., Delattre, F., Bria, M., Garety, J., Hewage, S. and Rabani, G. (2006) An electrochemically tuneable cyclodextrin-based molecular adapter. Tetrahedron Letters, 47, pp. 6449-6452. (doi:10.1016/j.tetlet.2006.06.116)
Cooke, G. , Garety, J. F., Hewage, S. G., Rabani, G., Rotello, V. M. and Woisel, P. (2006) The tuneable complexation of gold nanoparticles. Chemical Communications, 39, pp. 4119-4121. (doi:10.1039/b608543a)
Nakade, H., Jordan, B., Xu, H., Han, G., Srivastava, S., Arvizo, R., Cooke, G. and Rotello, V. (2006) Chiral translation and cooperative self-assembly of discrete helical structures using molecular recognition dyads. Journal of the American Chemical Society, 128, pp. 14924-14929. (doi:10.1021/ja064554z)
2005
Cooke, G. (2005) Model systems for flavoenzyme activity: Site-isolated redox behavior in flavin-functionalized random polystyrene copolymers. Organic Letters, 7(13), pp. 2551-2554.
Cooke, G. (2005) Model systems for flavoenzyme activity: a tuneable intramolecularly hydrogen bonded flavin-diamidopyridine complex. Chemical Communications(19), pp. 2468-2470.
Cooke, G. (2005) The electrochemically-tuneable interactions between flavin-functionalised C-60 derivatives and 2,6-diethylamidopyridine. Chemical Communications(30), pp. 3838-3840.
2004
Cooke, G. (2004) Model systems for flavoenzyme activity: Interplay of hydrogen bonding and aromatic stacking in cofactor redox modulation. Organic Letters, 6(3), pp. 385-388.
Cooke, G. (2004) Model systems for flavoenzyme activity: an electrochemically tuneable model of roseoflavin. Chemical Communications(9), pp. 1088-1089.
Cooke, G. (2004) Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine. Tetrahedron Letters, 45(3), pp. 557-560.
Cooke, G. (2004) Proton transfer versus redox modulation in thiourea-phenanthrenequinone molecular and polymeric complexes. Chemical Communications(4), pp. 442-443.
Cooke, G. (2004) The electrochemically tuneable recognition properties of an electropolymerised flavin derivative. Chemical Communications(23), pp. 2722-2723.
2003
Cooke, G. (2003) Electrochemical and photochemical control of host-guest complexation at surfaces. Angewandte Chemie (International Edition), 42(40), pp. 4860-4870.
Cooke, G. (2003) Electrochemically tuneable hydrogen bonding interactions between a phenyl-urea terminated dendrimer and phenanthrenequinone. Chemical Communications(6), pp. 752-753.
Cooke, G. (2003) Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties. Tetrahedron, 59(18), pp. 3341-3347.
Cooke, G. (2003) Hydrogen bonding in redox-modulated molecular recognition. An experimental and theoretical investigation. Journal of the American Chemical Society, 125(26), pp. 7882-7888.
Cooke, G. (2003) Model systems for flavoenzyme activity: Relationships between cofactor structure, binding and redox properties. Journal of the American Chemical Society, 125(51), pp. 15789-15795.
Cooke, G. (2003) Model systems for flavoenzyme activity: flavin-functionalised SAMs as models for probing redox modulation through hydrogen bonding. Chemical Communications(19), pp. 2468-2469.
Cooke, G. (2003) Surface confined pseudorotaxanes with electrochemically controllable complexation properties. Journal of Materials Chemistry, 13(9), pp. 2111-2117.
Cooke, G. (2003) An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution. Tetrahedron Letters, 44(2), pp. 303-306.
Manickam, M., Cooke, G. , Kumar, S., Ashton, P.R., Preece, J.A. and Spencer, N. (2003) Triphenylene/carbazole mesogens and their electrochemistry. Molecular Crystals and Liquid Crystals, 397, pp. 399-416. (doi:10.1080/15421400390214059)
2002
Beeby, A., Bryce, M., Christensen, C., Cooke, G. , Duclairoir, F. and Rotello, V. (2002) Electrochemically controlled interactions between TTF-based dendrimers and an electron-rich oligomer. Chemical Communications, pp. 2950-2951. (doi:10.1039/b209765f)
Cooke, G. (2002) Methods of modulating hydrogen bonded interactions in synthetic host-guest systems. Chemical Society Reviews, 31(5), pp. 275-286.
2001
Bryce, M., Cooke, G. , Devonport, W., Duclairoir, F. and Rotello, V. (2001) A stopperless tetrathiafulvalene based [2]pseudorotaxane molecular shuttle. Tetrahedron Letters, 42, pp. 4223-4226.
Bryce, M., Cooke, G. , Duclairoir, F. and Rotello, V. (2001) An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene). Tetrahedron Letters, 42, pp. 1143-1145.
Cooke, G. (2001) Control of host dimerization and flavin recognition via intramolecular receptor self-assembly. Tetrahedron Letters, 42(42), pp. 7357-7359.
Cooke, G. (2001) Synthesis of 6-aryl-2,4-diamino-pyrimidines and triazines using palladium catalysed Suzuki cross-coupling reactions. Tetrahedron, 57(14), pp. 2787-2789.
Cooke, G. (2001) Tuneable electrochemical interactions between polystyrenes with anthracenyl and tetrathiafulvalenyl sidechains. Chemical Communications(21), pp. 2232-2233.
Cooke, G. (2001) The charge-transfer complexation of tetrathiafulvalene with paraquat and its oligomeric derivatives. Tetrahedron Letters, 42(30), pp. 5089-5091.
Cooke, G. (2001) The first redox controlled hydrogen bonded three-pole switch. Chemical Communications(19), pp. 1954-1955.
Articles
Zhang, Y., Sajjad, M. T., Blaszczyk, O., Ruseckas, A., Serrano, L. A., Cooke, G. and Samuel, I. D.W. (2019) Enhanced exciton harvesting in a planar heterojunction organic photovoltaic device by solvent vapor annealing. Organic Electronics, 70, pp. 162-166. (doi:10.1016/j.orgel.2019.03.014)
Marques dos Santos, J., Jagadamma, L. K., Latif, N. M., Ruseckas, A., Samuel, I. D. W. and Cooke, G. (2019) BODIPY derivatives with near infra-red absorption as small molecule donors for bulk heterojunction solar cells. RSC Advances,
Connell, A. et al. (2019) Low cost triazatruxene hole transporting material for >20% efficient perovskite solar cells. Journal of Materials Chemistry C, 7, pp. 5235-5243. (doi:10.1039/C8TC04231D)
Zhang, Y., Sajjad, M. T., Blaszczyk, O., Parnell, A. J., Ruseckas, A., Serrano, L. A., Cooke, G. and Samuel, I. D.W. (2019) Large crystalline domains and enhanced exciton diffusion length enable efficient organic solar cells. Chemistry of Materials, (doi:10.1021/acs.chemmater.8b05293) (Early Online Publication)
Serrano, L. A., Park, K.-W., Ahn, S., Wiles, A. A. , Hong, J. and Cooke, G. (2019) Coplanar donor-π-acceptor dyes featuring a furylethynyl spacer for dye-sensitized solar cells. Materials, 12(5), 839. (doi:10.3390/ma12050839)
Cooke, G. , Evans, I. R. and Skabara, P. J. (2019) Functional organic materials for optoelectronic applications. Journal of Materials Chemistry C, 7, p. 6492. (doi:10.1039/c9tc90084e)
Mica, N.A., Almahmoud, S.A.J., Krishnan Jagadamma, L., Cooke, G. and Samuel, I.D.W. (2018) An investigation of the role acceptor side chains play in the processibility and efficiency of organic solar cells fabricated from small molecular donors featuring 3,4-ethylenedioxythiophene cores. RSC Advances, 2018(8), pp. 39231-39240. (doi:10.1039/C8RA07034B)
Krishnan Jagadamma, L., McCarron, L. J., Wiles, A. A. , Savikhin, V., Sajjad, M., Yazdani, M., Rotello, V. M., Toney, M. F., Cooke, G. and Samuel, I. D. W. (2018) Triptycene as a supramolecular additive in PTB7:PCBM blends and its influence on photovoltaic properties. ACS Applied Materials and Interfaces, 10(29), pp. 24665-24678. (doi:10.1021/acsami.8b03114) (PMID:29932630)
Kelly, C., Tullius, R., Lapthorn, A. J. , Gadegaard, N. , Cooke, G. , Barron, L. D., Karimullah, A. S. , Rotello, V. M. and Kadodwala, M. (2018) Chiral plasmonic fields probe structural order of biointerfaces. Journal of the American Chemical Society, 140(27), pp. 8509-8517. (doi:10.1021/jacs.8b03634) (PMID:29909628)
Cariello, M., Abdalhadi, S. M., Yadav, P., Decoppet, J.-D., Zakeeruddin, S. M., Grätzel, M., Hagfeldt, A. and Cooke, G. (2018) An investigation of the roles furan versus thiophene π-bridges play in donor–π-acceptor porphyrin based DSSCs. Dalton Transactions, 47(18), pp. 6549-6556. (doi:10.1039/C8DT00413G) (PMID:29697124)
Tullius, R. et al. (2017) Superchiral plasmonic phase sensitivity for fingerprinting of protein interface structure. ACS Nano, 11(12), pp. 12049-12056. (doi:10.1021/acsnano.7b04698) (PMID:29220155)
Fumagalli, M., Belal, K., Guo, H., Stoffelbach, F., Cooke, G. , Marcellan, A., Woisel, P. and Hourdet, D. (2017) Supramolecular polymer hydrogels induced by host-guest interactions with di-[cyclobis(paraquat-p-phenylene)] cross-linkers: from molecular complexation to viscoelastic properties. Soft Matter, 13(31), pp. 5269-5282. (doi:10.1039/C7SM01051F) (PMID:28676876)
Mohammed, N., Wiles, A. A. , Belsley, M., Fernandes, S. S.M., Cariello, M., Rotello, V. M., Raposo, M. M. M. and Cooke, G. (2017) Synthesis and characterisation of push-pull flavin dyes with efficient second harmonic generation (SHG) properties. RSC Advances, 7(39), pp. 24462-24469. (doi:10.1039/C7RA03400H)
Long, Y., Hedley, G. , Ruseckas, A., Chowdhury, M., Roland, T., Serrano, L. A., Cooke, G. and Samuel, I. D.W. (2017) Effect of annealing on exciton diffusion in a high performance small molecule organic photovoltaic material. ACS Applied Materials and Interfaces, 9(17), pp. 14945-14952. (doi:10.1021/acsami.6b16487) (PMID:28358189) (PMCID:PMC5423077)
Park, K.-W., Serrano, L. A., Ahn, S., Baek, M. H., Wiles, A. A. , Cooke, G. and Hong, J. (2017) An investigation of the role the donor moiety plays in modulating the efficiency of ‘donor-π-acceptor-π-acceptor’ organic DSSCs. Tetrahedron, 73(8), pp. 1098-1104. (doi:10.1016/j.tet.2016.12.061)
Belal, K. et al. (2016) Recognition-mediated hydrogel swelling controlled by interaction with a negative thermoresponsive LCST polymer. Angewandte Chemie (International Edition), 55(45), pp. 13974-13978. (doi:10.1002/anie.201605630) (PMID:27730718)
Abdalhadi, S.M., Connell, A., Zhang, X., Wiles, A.A. , Davies, M.L., Holliman, P.J. and Cooke, G. (2016) Convenient synthesis of EDOT-based dyes by CH-activation and their application as dyes in dye-sensitized solar cells. Journal of Materials Chemistry A, 40(4), pp. 15655-15661. (doi:10.1039/C6TA04483B)
Jack, C., Karimullah, A. S. , Leyman, R., Tullius, R., Rotello, V. M., Cooke, G. , Gadegaard, N. , Barron, L. D. and Kadodwala, M. (2016) Biomacromolecular stereostructure mediates mode hybridization in chiral plasmonic nanostructures. Nano Letters, 16(9), pp. 5806-5814. (doi:10.1021/acs.nanolett.6b02549) (PMID:27547978)
Yeniad, B., Ryskulova, K., Fournier, D., Lyskawa, J., Cooke, G. , Woisel, P. and Hoogenboom, R. (2016) Complexation of thermoresponsive dialkoxynaphthalene end-functionalized poly(oligoethylene glycol acrylate)s with CBPQT4+in water. Polymer Chemistry, 7(22), pp. 3681-3690. (doi:10.1039/c6py00303f)
Wiles, A. A. , Zhang, X., Fitzpatrick, B., Long, D.-L. , Macgregor, S. A. and Cooke, G. (2016) Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries. Dalton Transactions, 45(17), pp. 7220-7225. (doi:10.1039/C6DT00875E) (PMID:27063914)
Jack, C. et al. (2016) Spatial control of chemical processes on nanostructures through nano-localized water heating. Nature Communications, 7, 10946. (doi:10.1038/ncomms10946) (PMID:26961708) (PMCID:PMC4792951)
Belal, K., Poitras-Jolicoeur, S., Lyskawa, J., Pembouong, G., Cooke, G. , Woisel, P. and Stoffelbach, F. (2016) A triple carboxylic acid-functionalized RAFT agent platform for the elaboration of well-defined telechelic 3-arm star PDMAc. Chemical Communications, 52(9), pp. 1847-1850. (doi:10.1039/c5cc09684g) (PMID:26670290)
Cariello, M., Ahn, S., Park, K.-W., Chang, S.-K., Hong, J. and Cooke, G. (2016) An investigation of the role increasing π-conjugation has on the efficiency of dye-sensitized solar cells fabricated from ferrocene-based dyes. RSC Advances, 6, pp. 9132-9138. (doi:10.1039/C5RA21565J)
Wiles, A. A. , Fitzpatrick, B., McDonald, N. A., Westwater, M. M., Long, D. L. , Ebenhoch, B., Rotello, V. M., Samuel, I. D. W. and Cooke, G. (2016) Synthesis and properties of pteridine-2,4-dione-functionalised oligothiophenes. RSC Advances, 6(10), pp. 7999-8005. (doi:10.1039/c5ra22402k)
Laggoune, N., Delattre, F., Lyskawa, J., Stoffelbach, F., Guigner, J.-M., Ruellan, S., Cooke, G. and Woisel, P. (2015) Synthesis, binding and self-assembly properties of a well-defined pillar[5]arene end functionalised polydimethylacrylamide. Polymer Chemistry, 6(42), pp. 7389-7394. (doi:10.1039/C5PY01186H)
Karimullah, A. S. , Jack, C., Tullius, R., Rotello, V. M., Cooke, G. , Gadegaard, N. , Barron, L. D. and Kadodwala, M. (2015) Disposable plasmonics: plastic templated plasmonic metamaterials with tunable chirality. Advanced Materials, 27(37), pp. 5610-5616. (doi:10.1002/adma.201501816)
Malfait, A., Coumes, F., Fournier, D., Cooke, G. and Woisel, P. (2015) A water-soluble supramolecular polymeric dual sensor for temperature and pH with an associated direct visible readout. European Polymer Journal, 69, pp. 552-558. (doi:10.1016/j.eurpolymj.2015.02.033)
Tullius, R., Karimullah, A. S. , Rodier, M., Fitzpatrick, B., Gadegaard, N. , Barron, L. D., Rotello, V. M., Cooke, G. , Lapthorn, A. and Kadodwala, M. (2015) "Superchiral” spectroscopy: detection of protein higher order hierarchical structure with chiral plasmonic nanostructures. Journal of the American Chemical Society, 137(26), pp. 8380-8383. (doi:10.1021/jacs.5b04806) (PMID:26102606)
Ward, A. J., Ruseckas, A., Kareem, M. M., Ebenhoch, B., Serrano, L. A., Al-Eid, M., Fitzpatrick, B., Rotello, V. M., Cooke, G. and Samuel, I. D.W. (2015) The impact of driving force on electron transfer rates in photovoltaic donor-acceptor blends. Advanced Materials, 27(15), pp. 2496-2500. (doi:10.1002/adma.201405623) (PMID:25759321)
Ebenhoch, B., Prasetya, N. B.A., Rotello, V. M., Cooke, G. and Samuel, I. D.W. (2015) Solution-processed boron subphthalocyanine derivatives as acceptors for organic bulk-heterojunction solar cells. Journal of Materials Chemistry A, 3(14), pp. 7345-7352. (doi:10.1039/C5TA00715A)
Connell, A., Holliman, P. J., Jones, E. W., Furnell, L., Kershaw, C., Davies, M. L., Gwenin, C. D., Pitak, M. B., Coles, S. J. and Cooke, G. (2015) Multiple linker half-squarylium dyes for dye-sensitized solar cells; are two linkers better than one? Journal of Materials Chemistry A, 3(6), pp. 2883-2894. (doi:10.1039/c4ta06896c)
Sambe, L., de La Rosa, V. R., Belal, K., Stoffelbach, F., Lyskawa, J., Delattre, F., Bria, M., Cooke, G. , Hoogenboom, R. and Woisel, P. (2014) Programmable polymer-based supramolecular temperature sensor with a memory function. Angewandte Chemie (International Edition), 53(20), pp. 5044-5048. (doi:10.1002/anie.201402108)
Landis, R. F., Yazdani, M., Creran, B., Yu, X., Nandwana, V., Cooke, G. and Rotello, V. M. (2014) Solvatochromic probes for detecting hydrogen-bond-donating solvents. Chemical Communications, 50(35), p. 4579. (doi:10.1039/C4CC00805G)
Al-Eid, M., Lim, S., Park, K.-W., Fitzpatrick, B., Han, C.-H., Kwak, K., Hong, J. and Cooke, G. (2014) Facile synthesis of metal-free organic dyes featuring a thienylethynyl spacer for dye sensitized solar cells. Dyes and Pigments, 104, pp. 197-203. (doi:10.1016/j.dyepig.2014.01.004)
Sambe, L., Stoffelbach, F., Poltorak, K., Lyskawa, J., Malfait, A., Bria, M., Cooke, G. and Woisel, P. (2014) Elaboration of Thermoresponsive Supramolecular DiBlock Copolymers in Water from Complementary CBPQT4+ and TTF End-functionalized Polymers. Macromolecular Rapid Communications, 35(4), pp. 498-504. (doi:10.1002/marc.201300729)
Caldwell, S.T. et al. (2014) Protein-mediated dethreading of a biotin-functionalised pseudorotaxane. Organic and Biomolecular Chemistry, 12(3), pp. 511-516. (doi:10.1039/C3OB41612G)
Connell, A., Holliman, P.J., Davies, M.L., Gwenin, C.D., Weiss, S., Pitak, M.B., Horton, P.N., Coles, S.J. and Cooke, G. (2014) A study of dye anchoring points in half-squarylium dyes for dye-sensitized solar cells. Journal of Materials Chemistry A, 2, pp. 4055-4066. (doi:10.1039/C3TA15278B)
Sambe, L. et al. (2014) Multi stimuli responsive suprmolecular diblock copolymers. Polymer Chemistry, 5(3), pp. 1031-1036. (doi:10.1039/C3PY01093G)
Hedley, G. J. , Ward, A. J., Alekseev, A. , Howells, C. T., Martins, E. R., Serrano, L. A., Cooke, G. , Ruseckas, A. and Samuel, I. D.W. (2013) Determining the optimum morphology in high-performance polymer-fullerene organic photovoltaic cells. Nature Communications, 4, 2867. (doi:10.1038/ncomms3867) (PMID:24343223) (PMCID:PMC3905772)
Nandwana, V., Serrano Gonzalez, L. A., Solntsev, K. M., Ebenhoch, B., Liu, Q., Tonga, G. Y., Samuel, I. D.W., Cooke, G. and Rotello, V. M. (2013) Engineering the nanoscale morphology of quantum dot-fullerene assembly via complementary hydrogen bonding interactions. Langmuir, 29(24), pp. 7534-7537. (doi:10.1021/la4007372)
Pauszek, R. F., Kodali, G., Caldwell, S. T., Fitzpatrick, B., Zainalabdeen, N. Y., Cooke, G. , Rotello, V. M. and Stanley, R. J. (2013) Excited state charge redistribution and dynamics in the donor-π-acceptor flavin derivative ABFL. Journal of Physical Chemistry B, 117(49), pp. 15684-15694. (doi:10.1021/jp406420h)
Zainalabdeen, N., Fitzpatrick, B., Kareem, M. M., Nandwana, V., Cooke, G. and Rotello, V. M. (2013) Synthesis and Xharacterization of naphthalenediimide-functionalized flavin derivatives. International Journal of Molecular Sciences, 14(4), pp. 7468-7479. (doi:10.3390/ijms14047468)
Fitzpatrick, B., Creran, B., Cooke, G. and Rotello, V.M. (2012) Flavin-functionalized amphiphilic block copolymer gela. Macromolecular Chemistry and Physics, 213(17), pp. 1758-1767. (doi:10.1002/macp.201200225)
Maclean, C.E., Parkinson, C.L., Davis, P.J., Davis, M.J. and Cooke, G. (2012) A dual-responsive ferrocene-functionalized PDA liposome. Tetrahedron Letters, 53(24), pp. 2948-2950. (doi:10.1016/j.tetlet.2012.03.064)
Nandwana, V., Fitzpatrick, B., Liu, Q., Solntsev, K.M., Yu, X., Tonga, G.Y., Eymur, S., Tonga, M., Cooke, G. and Rotello, V.M. (2012) Fluorescence resonance energy transfer in recognition-mediated polymer-quantum dot assemblies. Polymer Chemistry, 3(11), pp. 3072-3076. (doi:10.1039/C2PY20353G)
Nandwana, V., Samuel, I., Cooke, G. and Rotello, V. M. (2012) Aromatic stacking interactions in flavin model systems. Accounts of Chemical Research, 46(4), pp. 1000-1009. (doi:10.1021/ar300132r)
Xi, Y. et al. (2012) Flavin as a photo-active acceptor for efficient energy and charge transfer in a model donor-acceptor system. Physical Chemistry Chemical Physics, 14(19), pp. 6749-6754. (doi:10.1039/C2CP40073A)
Sambe, L., Stoffelba, F., Lyskawa, J., Delattre, F., Fournier, D., Bouteiller, L., Charleux, B., Cooke, G. and Woisel, P. (2011) Host–guest modulation of the micellization of a tetrathiafulvalene-functionalized poly(N-isopropylacrylamid). Macromolecules, 44(16), pp. 6532-6538. (doi:10.1021/ma2009854)
McDonald, N.A., Subramani, C., Caldwell, S.T., Zainalabdeen, N.Y., Cooke, G. and Rotello, V.M. (2011) Simultaneous hydrogen bonding and π-stacking interactions between flavin/porphyrin host–guest syst. Tetrahedron Letters, 52(17), pp. 2107-2110. (doi:10.1016/j.tetlet.2010.11.004)
Barka-Bouaifel, F. et al. (2011) Optical and electrochemical properties of tunable host–guest complexes linked to plasmonic interfaces. Journal of Materials Chemistry, 21(9), pp. 3006-3013. (doi:10.1039/C0JM03293J)
Louisy, J., Delattre, F., Lyskawa, J., Malfait, A., Maclean, C.E., Sambe, L., Zhu, N., Cooke, G. and Woisel, P. (2011) Surfactant-mediated control of CBPQT4+–dialkoxynaphthalene complexation. Chemical Communications, 47(24), pp. 6819-6821. (doi:10.1039/C1CC10571J)
Nandwana, V. et al. (2011) Recognition-mediated assembly of quantum dot polymer conjugates with controlled morphology. International Journal of Molecular Sciences, 12(9), pp. 6357-6366. (doi:10.3390/ijms12096357)
Bigot, J., Charleux, B., Cooke, G. , Delattre, F., Fournier, D., Lyskawa, J., Sambe, L., Stoffelbach, F. and Woisel, P. (2010) Tetrathiafulvalene end-functionalized poly(N-isopropylacrylamide): a new class of amphiphilic polymer for the creation of multistimuli responsive micelles. Journal of the American Chemical Society, 132(31), pp. 10796-10801. (doi:10.1021/ja1027452)
Bigot, J., Charleux, B., Cooke, G. , Delattre, F., Fournier, D., Lyskawa, J., Stoffelbach, F. and Woisel, P. (2010) Synthesis and properties of tetrathiafulvalene end-functionalized polymers prepared via RAFT polymerization. Macromolecules, 43(1), pp. 82-90. (doi:10.1021/ma901809a)
Figlus, M., Caldwell, S.T., Walas, D., Yesilbag, G., Cooke, G. , Kocovsky, P., Malkov, A.V. and Sanyal, A. (2010) Dendron-anchored organocatalysts: the asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron. Organic and Biomolecular Chemistry, 8(1), pp. 137-141. (doi:10.1039/b916601g)
Nakade, H., Jordan, B., Srivastava, S., Xu, H., Yu, X., Pollier, M., Cooke, G. and Rotello, V. (2010) Molecular recognition-induced liquid crystals from complementary diaminopyridine and flavin dyads. Supramolecular Chemistry, 22(11), pp. 691-696. (doi:10.1080/10610278.2010.506540)
Siddle, J. S., Batsanov, A. S., Caldwell, S. T., Cooke, G. and Bryce, M. R. (2010) Divergent synthesis of arylated pyridin-2(1H)-one derivatives via metal-catalysed cross-coupling processes. Tetrahedron, 66(32), pp. 6138-6149. (doi:10.1016/j.tet.2010.05.108)
Spreull, J.M. et al. (2010) Highly stable tetrathiafulvalene radical dimers in [3]catenanes. Nature Chemistry, 2(10), pp. 870-879. (doi:10.1038/nchem.749)
Subramani, C., Yesilbag, G., Jordan, B. J., Li, X. N., Khorasani, A., Cooke, G. , Sanyal, A. and Rotello, V. M. (2010) Recognition mediated encapsulation and isolation of flavin-polymer conjugates using dendritic guest moieties. Chemical Communications, 46(12), pp. 2067-2069. (doi:10.1039/b926746h)
Malkov, A. V., Figlus, M., Prestly, M. R., Rabani, G., Cooke, G. and Kocovsky, P. (2009) Soluble Polymer-Supported Organocatalysts: Asymmetric Reduction of Imines with Trichlorosilane Catalyzed by an Amino Acid Derived Formamide Anchored to a Soluble Polymer. Chemistry: A European Journal, 15(38), pp. 9651-9654. (doi:10.1002/chem.200901573)
Bigot, J. et al. (2009) LCST: a powerful tool to control complexation between a dialkoxynaphthalene-functionalised poly(N-isopropylacrylamide) and CBPQT(4+) in water. Chemical Communications(35), pp. 5266-5268. (doi:10.1039/b910856d)
Bria, M., Bigot, J., Cooke, G. , Lyskawa, J., Rabani, G., Rotello, V. M. and Woisel, P. (2009) Synthesis of a polypseudorotaxane, polyrotaxane, and polycatenane using 'click' chemistry. Tetrahedron, 65(1), pp. 400-407. (doi:10.1016/j.tet.2008.10.005)
Caldwell, S. T., Farrugia, L. J., Hewage, S. G., Kryvokhyzha, N., Rotello, V. M. and Cooke, G. (2009) Model systems for flavoenzyme activity: an investigation of the role functionality attached to the C(7) position of the flavin unit has on redox and molecular recognition properties. Chemical Communications(11), pp. 1350-1352. (doi:10.1039/b900269n)
Malkov, A. V., Figlus, M., Cooke, G. , Caldwell, S.T., Rabani, G., Prestly, M. R. and Kocovsky, P. (2009) Organocatalysts immobilised onto gold nanoparticles: application in the asymmetric reduction of imines with trichlorosilane. Organic and Biomolecular Chemistry, 7(9), pp. 1878-1883. (doi:10.1039/b821391g)
Patra, D., Pagliuca, C., Subramani, C., Samanta, B., Agasti, S. S., Zainalabdeen, N., Caldwell, S. T., Cooke, G. and Rotello, V. M. (2009) Molecular recognition at the liquid-liquid interface of colloidal microcapsules. Chemical Communications(28), pp. 4248-4250. (doi:10.1039/b906458c)
Jordan, B.J. et al. (2008) 'Lock and key' control of optical properties in a push-pull system. Chemical Communications(14), pp. 1653-1655. (doi:10.1039/b718015b)
Agasti, S. S., Caldwell, S. T., Cooke, G. , Jordan, B. J., Kennedy, A., Kryvokhyzha, N., Rabani, G., Rana, S., Sanyal, A. and Rotello, V. M. (2008) Dendron-based model systems for flavoenzyme activity: towards a new class of synthetic flavoenzyme. Chemical Communications(35), pp. 4123-4125. (doi:10.1039/b809568j)
Caldwell, S. T., Cooke, G. , Cooper, A., Nutley, M., Rabani, G., Rotello, V., Smith, B. O. and Woisel, P. (2008) Tuneable pseudorotaxane formation between a biotin-avidin bioconjugate and CBPQT(4+). Chemical Communications(23), pp. 2650-2652. (doi:10.1039/b803856b)
Caldwell, S. T., Cooke, G. , Fitzpatrick, B., Long, D.L. , Rabani, G. and Rotello, V. M. (2008) A flavin-based [2]catenane. Chemical Communications(45), pp. 5912-5914. (doi:10.1039/b813779j)
Caldwell, S. T., Cooke, G. , Hewage, S. G., Mabruk, S., Rabani, G., Rotello, V., Smith, B.O. , Subramani, C. and Woisel, P. (2008) Model systems for flavoenzyme activity: intramolecular self-assembly of a flavin derivative via hydrogen bonding and aromatic interactions. Chemical Communications(35), pp. 4126-4128. (doi:10.1039/b809762c)
Jordan, B. J., Ofir, Y., Patra, D., Caldwell, S. T., Kennedy, A., Joubanian, S., Rabani, G., Cooke, G. and Rotello, V. M. (2008) Controlled Self-Assembly of Organic Nanowires and Platelets Using Dipolar and Hydrogen-Bonding Interactions. Small, 4(11), pp. 2074-2078. (doi:10.1002/smll.200800811)
Richmond, C. J., Parenty, A. D. C., Song, Y. -F., Cooke, G. and Cronin, L. (2008) Realization of a "Lockable" molecular switch via pH- and redox-modulated cyclization. Journal of the American Chemical Society, 130(39), pp. 13059-13065. (doi:10.1021/ja803338m)
Jordan, B. J., Cooke, G. , Garety, J. F., Pollier, M. A., Kryvokhyzha, N., Bayir, A., Rabani, G. and Rotello, V. M. (2007) Polymeric model systems for flavoenzyme activity: towards synthetic flavoenzymes. Chemical Communications, 12, pp. 1248-1250. (doi:10.1039/b616159f)
Cooke, G. , Garety, J. F., Hewage, S. G., Jordan, B. J., Rabani, G., Rotello, V. M. and Woisel, P. (2007) Tuneable side-chain supramolecular polymer. Organic Letters, 9(3), pp. 481-484. (doi:10.1021/ol062846z)
Bria, M., Cooke, G. , Cooper, A., Garety, J., Hewage, S., Nutley, M., Rabani, G. and Woisel, P. (2007) An investigation of the complexation properties of cyclobis(paraquat-p-phenylene) in water. Tetrahedron Letters, 48, pp. 301-304. (doi:10.1016/j.tetlet.2006.11.003)
Bria, M., Cooke, G. , Cooper, A., Delattre, F., Hewage, S. G., Rabani, G., Nutley, M. and Woisel, P. (2007) An investigation of the complexation of a TTF derivative with alpha-, beta- and gamma-cyclodextrins in aqueous media. Tetrahedron Letters, 48(48), pp. 8430-8433. (doi:10.1016/j.tetlet.2007.09.167)
Cooke, G. , Daniels, L. M., Cazier, F., Garety, J. F., Hewage, S. G., Parkin, A., Rabani, G., Rotello, V. M., Wilson, C. C. and Woisel, P. (2007) The synthesis of a pyrrole-functionalized cyclobis( paraquat-p-phenylene) derivative and its corresponding [2]rotaxane and [2]catenane and their subsequent deposition onto an electrode surface. Tetrahedron, 63(45), pp. 11114-11121. (doi:10.1016/j.tet.2007.08.027)
Cooke, G. , Garety, J. F., Jordan, B., Kryvokhyzha, N., Parkin, A., Rabani, G. and Rotello, V. M. (2006) Flavin-based [2]rotaxanes. Organic Letters, 8(11), pp. 2297-2300. (doi:10.1021/ol060620q)
Cooke, G. , Woisel, P., Bria, M., Delattre, F., Garety, J. F., Hewage, S. G., Rabani, G. and Rosair, G. M. (2006) A tuneable self-complexing molecular switch. Organic Letters, 8(7), pp. 1423-1426. (doi:10.1021/ol0602553)
Bayir, A., Jordan, B. J., Verma, A., Pollier, M. A., Cooke, G. and Rotello, V. M. (2006) Model systems for flavoenzyme activity: Recognition and redox modulation of flavin mononucleotide in water using nanoparticles. Chemical Communications, 38, pp. 4033-4035. (doi:10.1039/b608928c)
Cooke, G. , Couet, J., Garety, J., Ma, C., Mabruk, S., Rabani, G., Rotello, V., Sindelar, V. and Woisel, P. (2006) The electrochemically tuneable hydrogen bonding interactions between a phenanthrenequinone-functionalized self-assembled monolayer and a phenyl-urea terminated dendrimer. Tetrahedron Letters, 47, pp. 3763-3766. (doi:10.1016/j.tetlet.2006.03.117)
Cooke, G. , Garety, J., Mabruk, S., Rabani, G., Rotello, V., Surpateanu, G. and Woisel, P. (2006) The electrochemical polymerisation of a [2]rotaxane. Tetrahedron Letters, 47, pp. 783-786. (doi:10.1016/j.tetlet.2005.11.106)
Cooke, G. , Woisel, P., Delattre, F., Bria, M., Garety, J., Hewage, S. and Rabani, G. (2006) An electrochemically tuneable cyclodextrin-based molecular adapter. Tetrahedron Letters, 47, pp. 6449-6452. (doi:10.1016/j.tetlet.2006.06.116)
Cooke, G. , Garety, J. F., Hewage, S. G., Rabani, G., Rotello, V. M. and Woisel, P. (2006) The tuneable complexation of gold nanoparticles. Chemical Communications, 39, pp. 4119-4121. (doi:10.1039/b608543a)
Nakade, H., Jordan, B., Xu, H., Han, G., Srivastava, S., Arvizo, R., Cooke, G. and Rotello, V. (2006) Chiral translation and cooperative self-assembly of discrete helical structures using molecular recognition dyads. Journal of the American Chemical Society, 128, pp. 14924-14929. (doi:10.1021/ja064554z)
Cooke, G. (2005) Model systems for flavoenzyme activity: Site-isolated redox behavior in flavin-functionalized random polystyrene copolymers. Organic Letters, 7(13), pp. 2551-2554.
Cooke, G. (2005) Model systems for flavoenzyme activity: a tuneable intramolecularly hydrogen bonded flavin-diamidopyridine complex. Chemical Communications(19), pp. 2468-2470.
Cooke, G. (2005) The electrochemically-tuneable interactions between flavin-functionalised C-60 derivatives and 2,6-diethylamidopyridine. Chemical Communications(30), pp. 3838-3840.
Cooke, G. (2004) Model systems for flavoenzyme activity: Interplay of hydrogen bonding and aromatic stacking in cofactor redox modulation. Organic Letters, 6(3), pp. 385-388.
Cooke, G. (2004) Model systems for flavoenzyme activity: an electrochemically tuneable model of roseoflavin. Chemical Communications(9), pp. 1088-1089.
Cooke, G. (2004) Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine. Tetrahedron Letters, 45(3), pp. 557-560.
Cooke, G. (2004) Proton transfer versus redox modulation in thiourea-phenanthrenequinone molecular and polymeric complexes. Chemical Communications(4), pp. 442-443.
Cooke, G. (2004) The electrochemically tuneable recognition properties of an electropolymerised flavin derivative. Chemical Communications(23), pp. 2722-2723.
Cooke, G. (2003) Electrochemical and photochemical control of host-guest complexation at surfaces. Angewandte Chemie (International Edition), 42(40), pp. 4860-4870.
Cooke, G. (2003) Electrochemically tuneable hydrogen bonding interactions between a phenyl-urea terminated dendrimer and phenanthrenequinone. Chemical Communications(6), pp. 752-753.
Cooke, G. (2003) Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties. Tetrahedron, 59(18), pp. 3341-3347.
Cooke, G. (2003) Hydrogen bonding in redox-modulated molecular recognition. An experimental and theoretical investigation. Journal of the American Chemical Society, 125(26), pp. 7882-7888.
Cooke, G. (2003) Model systems for flavoenzyme activity: Relationships between cofactor structure, binding and redox properties. Journal of the American Chemical Society, 125(51), pp. 15789-15795.
Cooke, G. (2003) Model systems for flavoenzyme activity: flavin-functionalised SAMs as models for probing redox modulation through hydrogen bonding. Chemical Communications(19), pp. 2468-2469.
Cooke, G. (2003) Surface confined pseudorotaxanes with electrochemically controllable complexation properties. Journal of Materials Chemistry, 13(9), pp. 2111-2117.
Cooke, G. (2003) An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution. Tetrahedron Letters, 44(2), pp. 303-306.
Manickam, M., Cooke, G. , Kumar, S., Ashton, P.R., Preece, J.A. and Spencer, N. (2003) Triphenylene/carbazole mesogens and their electrochemistry. Molecular Crystals and Liquid Crystals, 397, pp. 399-416. (doi:10.1080/15421400390214059)
Beeby, A., Bryce, M., Christensen, C., Cooke, G. , Duclairoir, F. and Rotello, V. (2002) Electrochemically controlled interactions between TTF-based dendrimers and an electron-rich oligomer. Chemical Communications, pp. 2950-2951. (doi:10.1039/b209765f)
Cooke, G. (2002) Methods of modulating hydrogen bonded interactions in synthetic host-guest systems. Chemical Society Reviews, 31(5), pp. 275-286.
Bryce, M., Cooke, G. , Devonport, W., Duclairoir, F. and Rotello, V. (2001) A stopperless tetrathiafulvalene based [2]pseudorotaxane molecular shuttle. Tetrahedron Letters, 42, pp. 4223-4226.
Bryce, M., Cooke, G. , Duclairoir, F. and Rotello, V. (2001) An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene). Tetrahedron Letters, 42, pp. 1143-1145.
Cooke, G. (2001) Control of host dimerization and flavin recognition via intramolecular receptor self-assembly. Tetrahedron Letters, 42(42), pp. 7357-7359.
Cooke, G. (2001) Synthesis of 6-aryl-2,4-diamino-pyrimidines and triazines using palladium catalysed Suzuki cross-coupling reactions. Tetrahedron, 57(14), pp. 2787-2789.
Cooke, G. (2001) Tuneable electrochemical interactions between polystyrenes with anthracenyl and tetrathiafulvalenyl sidechains. Chemical Communications(21), pp. 2232-2233.
Cooke, G. (2001) The charge-transfer complexation of tetrathiafulvalene with paraquat and its oligomeric derivatives. Tetrahedron Letters, 42(30), pp. 5089-5091.
Cooke, G. (2001) The first redox controlled hydrogen bonded three-pole switch. Chemical Communications(19), pp. 1954-1955.
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