Pavel Kocowsky


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Number of items: 69.

2013

Malkov, A.V., Stončius, S., Bell, M., Castelluzzo, F., Ramírez-López, P., Biedermannová, L., Langer, V., Rulíšek, L., and Kočovský, P. (2013) Mechanistic dichotomy in the asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by chiral pyridine N-oxides. Chemistry: A European Journal, 19 (28). pp. 9167-9185. ISSN 0947-6539 (doi:10.1002/chem.201203817)

2012

Malkov, A.V., Stewart-Liddon, A.J.P., McGeoch, G.D., Ramirez-Lopez, P., and Kocovsky, P. (2012) Catalyst development for organocatalytic hydrosilylation of aromatic ketones and ketimines. Organic and Biomolecular Chemistry, 10 (25). pp. 4864-4877. ISSN 1477-0520 (doi:10.1039/C2OB25472G)

Malkov, A.V., Barłóg, M., Miller-Potucká, L., Kabeshov, M.A., Farrugia, L.J., and Kocovsky, P. (2012) Stereoselective palladium-catalyzed functionalization of homoallylic alcohols: a convenient synthesis of di- and trisubstituted isoxazolidines and β-amino-δ-hydroxy esters. Chemistry: A European Journal, 18 (22). pp. 6873-6884. ISSN 0947-6539 (doi:10.1002/chem.201102716)

2011

Štambaský, J., Kapras, V., Štefko, M., Kysilka, O., Hocek, M., Malkov, A.V., and Kocovsky, P. (2011) A modular approach to aryl-C-ribonucleosides via the allylic substitution and ring-closing metathesis sequence: a stereocontrolled synthesis of all four α-/β- andd-/l-C-nucleoside stereoisomers. Journal of Organic Chemistry, 76 (19). pp. 7781-7803. ISSN 0022-3263 (doi:10.1021/jo201110z)

Chelucci, G., Marchetti, M. , Malkov, A.V. , Friscourt, F. , Swarbrick, M.E. , and Kočovský, P. (2011) New monoterpene-derived phosphinopyridine ligands and their application in the enantioselective iridium-catalyzed hydrogenation. Tetrahedron, 67 (30). pp. 5421-5431. ISSN 0040-4020 (doi:10.1016/j.tet.2011.05.075)

Malkov, A.V., Kysilka, O., Edgar, M., Kadlčíková, A., Kotora, M., and Kocovsky, P. (2011) A novel bifunctional allyldisilane as a triple allylation reagent in the stereoselective synthesis of trisubstituted tetrahydrofurans. Chemistry: A European Journal, 17 (26). pp. 7162-7166. ISSN 0947-6539 (doi:10.1002/chem.201100513)

Malkov, A.V., Barłóg, M., Jewkes, Y., Mikušek, J., and Kocovsky, P. (2011) Enantioselective allylation of α,β-unsaturated aldehydes with allyltrichlorosilane catalyzed by METHOX. Journal of Organic Chemistry, 76 (11). pp. 4800-4804. ISSN 0022-3263 (doi:10.1021/jo200712p)

Cogdell, Richard J., Gardiner, Alastair T., Roszak, Aleksander W., Stončius, Sigitas, Kocovsky, Pavel, and Isaacs, Neil W. (2011) Mapping lipid and detergent molecules at the surface of membrane protein. Biochemical Society Transactions, 39 (3). pp. 775-779. ISSN 0300-5127 (doi:10.1042/BST0390775)

2010

Figlus, M., Caldwell, S.T., Walas, D., Yesilbag, G., Cooke, G., Kocovsky, P., Malkov, A.V., and Sanyal, A. (2010) Dendron-anchored organocatalysts: the asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron. Organic and Biomolecular Chemistry, 8 (1). pp. 137-141. ISSN 1477-0520 (doi:10.1039/b916601g)

Kocovsky, P., and Stoncius, S. (2010) Reduction of imines with trichlorosilane catalyzed by chiral lewis bases. In: Nugent, T.C. (ed.) Chiral Amine Synthesis: Methods, Developments and Applications. Wiley, Chichester, UK, pp. 131-156. ISBN 9783527325092

Malkov, A.V., MacDonald, C., and Kocovsky, P. (2010) Synthesis of γ-functionalized allyltrichlorosilanes and their application in the asymmetric allylation of aldehydes. Tetrahedron-Asymmetry, 21 (9-10). pp. 1173-1175. ISSN 0957-4166 (doi:10.1016/j.tetasy.2010.03.026)

2009

Farrugia, L.J., Kocovsky, P., Senn, H.M., and Vyskocil, S. (2009) Weak intra- and intermolecular interactions in a binaphthol imine: an experimental charge density study on (±)-8'benzhydrylideneamino-1,1'-binaphthyl-2-ol. Acta Crystallographica. Section B: Structural Science, B65 (6). pp. 757-769. ISSN 0108-7681 (doi:10.1107/S010876810903273X)

Malkov, Andrei V., Figlus, Marek, Prestly, Mark R., Rabani, Gouher, Cooke, Graeme, and Kocovsky, Pavel (2009) Soluble Polymer-Supported Organocatalysts: Asymmetric Reduction of Imines with Trichlorosilane Catalyzed by an Amino Acid Derived Formamide Anchored to a Soluble Polymer. Chemistry: A European Journal, 15 (38). pp. 9651-9654. ISSN 0947-6539 (doi:10.1002/chem.200901573)

Malkov, Andrei V., Vrankova, Kvetoslava, Stoncius, Sigitas , and Kocovsky, Pavel (2009) Asymmetric reduction of imines with trichlorosilane, catalyzed by sigamide, an amino acid-derived formamide: scope and limitations. Journal of Organic Chemistry, 74 (16). pp. 5839-5849. ISSN 0022-3263 (doi:10.1021/jo900561h)

Malkov, Andrei V., Kabeshov, Mikhail A., Barlog, Maciej, and Kocovsky, Pavel (2009) Enantioselective and catalytic method for α-crotylation of aldehydes with a kinetic self-refinement of stereochemistry. Chemistry: A European Journal, 15 (7). pp. 1570-1573. ISSN 0947-6539 (doi:10.1002/chem.200802224)

Malkov, A. V., Figlus, M., Cooke, G., Caldwell, S.T., Rabani, G., Prestly, M. R., and Kocovsky, P. (2009) Organocatalysts immobilised onto gold nanoparticles: application in the asymmetric reduction of imines with trichlorosilane. Organic and Biomolecular Chemistry, 7 (9). pp. 1878-1883. ISSN 1477-0520 (doi:10.1039/b821391g)

Malkov, A. V., Gordon, M. R., Stoncius, S., Hussain, J., and Kocovsky, P. (2009) Desymmetrization of Cyclic meso-Epoxides with Silicon Tetrachloride Catalyzed by PINDOX, a Chiral Bipyridine Mono-N-oxide. Organic Letters, 11 (23). pp. 5390-5393. ISSN 1523-7060 (doi:10.1021/ol902148s)

Malkov, A. V., Vrankova, K., Cerny, M., and Kocovsky, P. (2009) On the Selective N-Methylation of BOC-Protected Amino Acids. Journal of Organic Chemistry, 74 (21). pp. 8425-8427. ISSN 0022-3263 (doi:10.1021/jo9016293)

Malkov, A. V., Vrankova, K., Sigerson, R. C., Stoncius, S., and Kocovsky, P. (2009) New organocatalysts for the asymmetric reduction of imines with trichlorosilane. Tetrahedron, 65 (45). pp. 9481-9486. ISSN 0040-4020 (doi:10.1016/j.tet.2009.08.048)

Stambasky, J., Hocek, M., and Kocovsky, P. (2009) C-nucleosides: synthetic strategies and biological applications. Chemical Reviews, 109 (12). pp. 6729-6764. ISSN 0009-2665 (doi:10.1021/cr9002165)

2008

Kocovsky, Pavel, and Malkov, Andrei V. (2008) Asymmetric synthesis: From transition metals to organocatalysis. Pure and Applied Chemistry, 80 (5). pp. 953-966. ISSN 0033-4545 (doi:10.1351/pac200880050953)

Drabina, P., Sedlak, M., Ruzicka, A., Malkov, A. V., and Kocovsky, P. (2008) Synthesis of (R)- and (S)-2-N-methylamino-2,3-dimethylbutanamides and (R)- and (S)-(5-isopropyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridine s. Tetrahedron-Asymmetry, 19 (3). pp. 384-390. ISSN 0957-4166 (doi:10.1016/j.tetasy.2008.01.016)

Malkov, A. V., Figlus, M., and Kocovsky, P. (2008) Polymer-supported organocatalysts: Asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid-derived formamide anchored to a polymer. Journal of Organic Chemistry, 73 (11). pp. 3985-3995. ISSN 0022-3263 (doi:10.1021/jo800094q)

Malkov, A. V., Friscourt, F., Bell, M., Swarbrick, M. E., and Kocovsky, P. (2008) Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands. Journal of Organic Chemistry, 73 (11). pp. 3996-4003. ISSN 0022-3263 (doi:10.1021/jo800246g)

Malkov, A. V., Ramirez-Lopez, P., Biedermannova, L., Rulisek, L., Dufkova, L., Kotora, M., Zhu, F. J., and Kocovsky, P. (2008) On the mechanism of asymmetric allylation of aldehydes with allyltrichlorosi lanes catalyzed by QUINOX, a chiral lsoquinoline N-oxide. Journal of the American Chemical Society, 130 (15). pp. 5341-5348. ISSN 0002-7863 (doi:10.1021/ja711338ci)

Malkov, A. V., Stewart-Liddon, A. J. P., Teply, F., Kobr, L., Muir, K. W., Haigh, D., and Kocovsky, P. (2008) New pinene-derived pyridines as bidentate chiral ligands. Tetrahedron, 64 (18). pp. 4011-4025. ISSN 0040-4020 (doi:10.1016/j.tet.2008.02.045)

Malkov, A. V., Westwater, M. M., Gutnov, A., Ramirez-Lopez, P., Friscourt, F., Kadlcikova, A., Hodacova, J., Rankovic, Z., Kotora, M., and Kocovsky, P. (2008) New pyridine N-oxides as chiral organocatalysts in the asymmetric allylation of aromatic aldehydes. Tetrahedron, 64 (49). pp. 11335-11348. ISSN 0040-4020 (doi:10.1016/j.tet.2008.08.084)

Malkov, A.V., Ramírez-López, P., Biedermannová, L., Rulíšek, L., Dufková, L., Kotora, M., Zhu, F., and Kocovsky, P. (2008) On the mechanism of asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by QUINOX, a chiral isoquinoline N-Oxide. Journal of the American Chemical Society, 130 (15). pp. 5341-5348. ISSN 0002-7863 (doi:10.1021/ja711338q)

Malkov, A.V., Stoncius, S., Vrankova, K., Arndt, M., and Kocovsky, P. (2008) Dynamic kinetic resolution in the asymmetric synthesis of beta-amino acids by organocatalytic reduction of enamines with trichlorosilane. Chemistry: A European Journal, 14 (27). pp. 8082-8085. ISSN 0947-6539 (doi:10.1002/chem.200801244)

Stambasky, J., Malkov, A. V., and Kocovsky, P. (2008) Preparation of Boc-protected cinnamyl-type alcohols: A comparison of the Suzuki-Miyaura coupling, cross-metathesis, and Horner-Wadsworth-Emmons approaches and their merit in parallel synthesis. Collection of Czechoslovak Chemical Communications, 73 (5). pp. 705-732. ISSN 0010-0765 (doi:10.1135/cccc20080705)

Stambasky, J., Malkov, A. V., and Kocovsky, P. (2008) Synthesis of Enantiopure 1-Arylprop-2-en-1-ols and Their tert-Butyl Carbonates. Journal of Organic Chemistry, 73 (22). pp. 9148-9150. ISSN 0022-3263 (doi:10.1021/jo801874r)

2007

Kocovsky, P., and Malkov, A.V. (2007) Chiral lewis bases as catalysts. In: Dalko, P.I. (ed.) Enantioselective Organocatalysis: Reactions and Experimental Procedures. Wiley-VCH, Weinheim, Germany, pp. 255-286. ISBN 9783527315222

Malkov, Andrei V., Figlus, Marek, Stoncius, Sigitas, and Kocovsky, Pavel . (2007) Organocatalysis with a fluorous tag: Asymmetric reduction of imines with trichlorosilane catalyzed by amino acid-derived formamides. Journal of Organic Chemistry, 72 (4). pp. 1315-1325. ISSN 0022-3263 (doi:10.1021/jo062215i)

Malkov, A. V., Kabeshov, M. A., Bella, M., Kysilka, O., Malyshev, D. A., Pluhackova, K., and Kocovsky, P. (2007) Vicinal amino alcohols as organocatalysts in asymmetric cross-aldol reaction of ketones: Application in the synthesis of convolutamydine a. Organic Letters, 9 (26). pp. 5473-5476. ISSN 1523-7060 (doi:10.1021/ol7023983)

Malkov, A.V., Stoncius, S, and Kocovsky, P. (2007) Enantioselective synthesis of 1,2-diarylaziridines by the organocatalytic reductive amination of alpha-chloroketones. Angewandte Chemie (International Edition), 46 (20). pp. 3722-3724. ISSN 1433-7851 (doi:10.1002/anie.200700165)

Malkov, AV, and Kocovsky, P (2007) Chiral N-oxides in asymmetric catalysis. European Journal of Organic Chemistry . pp. 29-36. (doi:10.1002/ejoc.200600474)

2006

Malkov, Andrei V., Stoncius, Sigitas, MacDougall, Kenneth N., Mariani, Andrea, McGeoch, Grant D., and Kocovsky, Pavel (2006) Formamides derived from N-methyl amino acids serve as new chiral organocatalysts in the enantioselective reduction of aromatic ketimines with trichlorosilane. Tetrahedron, 62 (2-3). pp. 264-284. ISSN 0040-4020 (doi:10.1016/j.tet.2005.08.117)

Malkov, A.V., Gouriou, L., Lloyd-Jones, G.C., Stary, I., Langer, V., Spoor, P., Vinader, V., and Kocovsky, P. (2006) Asymmetric allylic substitution catalyzed by C-1-symmetrical complexes of molybdenum: Structural requirements of the ligand and the stereochemical course of the reaction. Chemistry: A European Journal, 12 . pp. 6910-6929. ISSN 0947-6539 (doi:10.1002/chem.200501574)

Malkov, AV, Liddon, AJPS, Ramirez-Lopez, P, Bendova, L, Haigh, D, and Kocovsky, P (2006) Remote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines. Angewandte Chemie (International Edition), 45 . pp. 1432-1435. ISSN 1433-7851 (doi:10.1002/anie.200503941)

2005

Malkov, AV, Bell, M, Castelluzzo, F, and Kocovsky, P (2005) METHOX: A new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes. Organic Letters, 7 . pp. 3219-3222. (doi:10.1021/ol050972h)

Malkov, AV, Bourhani, Z, and Kocovsky, P (2005) Amino acid-derived hydroxamic acids as chiral ligands in the vanadium catalysed epoxidation. Organic and Biomolecular Chemistry, 3 . pp. 3194-3200. (doi:10.1039/b505324b)

2004

Kocovsky, P, and Malkov, AV (2004) From transition metals to organocatalysis. Russian Chemical Bulletin, 53 . pp. 1806-1812.

Malkov, AV, Mariani, A, MacDougall, KN, and Kocovsky, P (2004) Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane. Organic Letters, 6 . pp. 2253-2256. (doi:10.1021/ol049213+)

Seymour, JL, Turecek, F, Malkov, AV, and Kocovsky, P (2004) Chiral recognition in solution and the gas phase. Experimental and theoretical studies of aromatic D- and L-amino acid-Cu(II)-chiragen complexes. Journal of Mass Spectrometry, 39 . pp. 1044-1052. (doi:10.1002/jms.675)

2003

Abbott, AP, Barker, GW, Walter, AJ, and Kocovsky, P (2003) Electrochemical recognition of analytes using quaternary ammonium binaphthyl salts. Analyst, 128 . pp. 245-248. (doi:10.1039/b209478a)

Belokon, YN et al. (2003) Synthesis of alpha-amino acids via asymmetric phase transfer-catalyzed alkylation of achiral nickel(II) complexes of glycine-derived Schiff bases. Journal of the American Chemical Society, 125 . pp. 12860-12871. (doi:10.1021/ja035465e)

Gouriou, L, Lloyd-Jones, GC, Vyskocil, S, and Kocovsky, P (2003) H-2-quadrupolar coupling-based analysis of stereochemical and regiochemical memory in the Pd-catalysed allylic alkylation of iso-cinnamyl type substrates employing the chiral monophosphine ligands 'MOP' and 'MAP'. Journal of Organometallic Chemistry, 687 . pp. 525-537. (doi:10.1016/j.jorganchem.2003.09.015)

Kocovsky, P (2003) Reactivity control in palladium-catalyzed reactions: a personal account. Journal of Organometallic Chemistry, 687 . pp. 256-268. (doi:10.1016/jorganchem.2003.07.008)

Kocovsky, P, Vyskocil, S, and Smrcina, M (2003) Non-symmetrically substituted 1,1 '-binaphthyls in enantioselective catalysis. Chemical Reviews, 103 . pp. 3213-3245. (doi:10.1021/cr9900230)

Malkov, A.V., Bell, M., Vassieu, M., Bugatti, V., and Kocovsky, P. (2003) New pyridine-derived N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes. Journal of Molecular Catalysis A: Chemical, 196 . pp. 179-186. ISSN 1381-1169

Malkov, AV, Bell, M, Orsini, M, Pernazza, D, Massa, A, Herrmann, P, Meghani, P, and Kocovsky, P (2003) New Lewis-basic N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes. Journal of Organic Chemistry, 68 . pp. 9659-9668. (doi:10.1021/jo035074i)

Malkov, AV, Dufkova, L, Farrugia, L, and Kocovsky, P (2003) Quinox, a quinoline-type N-oxide, as organocatalyst in the asymmetric allylation of aromatic aldehydes with allyltrichlorosilanes: The role of arene-arene interactions. Angewandte Chemie (International Edition), 42 . pp. 3674-3677. ISSN 1433-7851 (doi:10.1002/anie.200351737)

Malkov, AV, Hand, JB, and Kocovsky, P (2003) A long-range chiral relay via tertiary amide group in asymmetric catalysis: new amino acid-derived N,P-ligands for copper-catalysed conjugate addition. Chemical Communications . pp. 1948-1949. (doi:10.1039/b304131j)

Malkov, AV, and Kocovsky, P (2003) Chiral bipyridine derivatives in asymmetric catalysis. Current Organic Chemistry, 7 . pp. 1737-1757.

Malkov, AV, Pernazza, D, Bell, M, Bella, M, Massa, A, Teply, F, Meghani, P, and Kocovsky, P (2003) Synthesis of new chiral 2,2 '-bipyridine ligands and their application in copper-catalyzed asymmetric allylic oxidation and cyclopropanation. Journal of Organic Chemistry, 68 . pp. 4727-4742. (doi:10.1021/jo034179i)

Massa, A, Malkov, AV, Kocovsky, P, and Scettri, A (2003) Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides. Tetrahedron Letters, 44 . pp. 7179-7181. (doi:10.1016/S0040-4039(03)01801-X)

Vyskocil, S, Lockhart, SC, Mitchell, WL, and Kocovsky, P (2003) Synthesis of 2-hydroxy-8 '-(hydroxymethyl)-1,1 '-binaphthalene (iso-homo-binol). A new structural pattern in the binaphthyl realm. Collection of Czechoslovak Chemical Communications, 68 . pp. 907-916. (doi:10.1135/cccc20030907)

2002

Abbott, AP, Barker, GW, Davies, DL, Griffiths, GA, Walter, AJ, and Kocovsky, P (2002) Electrochemical recognition of chiral species using quaternary ammonium binaphthyl salts. Analytical Chemistry, 74 . pp. 4002-4006. (doi:10.1021/ac025635q)

Fairlamb, I.J.S., Lloyd-Jones, G.C., Stepan, V., and Kocovsky, P. (2002) Analysis of stereochemical convergence in asymmetric Pd-catalysed allylic alkylation reactions complicated by halide and memory effects. Chemistry: A European Journal, 8 . pp. 4443-4453. ISSN 0947-6539

Malkov, AV, Orsini, M, Pernazza, D, Muir, KW, Langer, V, Meghani, P, and Kocovsky, P (2002) Chiral 2,2 '-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane. Organic Letters, 4 . pp. 1047-1049. (doi:10.1021/ol025654m)

Vyskocil, S. et al. (2002) 2,8 '-disubstituted-1,1 '-binaphthyls: A new pattern in chiral ligands. Chemistry: A European Journal, 8 . pp. 4633-4648. ISSN 0947-6539

2001

Abbott, AP, Barker, GW, Lonergan, GR, Walter, AJ, and Kocovsky, P (2001) Electrochemical recognition of charged species using quaternary ammonium binaphthyl salts. Analyst, 126 . pp. 1892-1896.

Malkov, A.V., Baxendale, I.R., Mansfield, D.J., and Kocovsky, P. (2001) Molybdenum(0) and tungsten(0) catalysts with enhanced reactivity for allylic substitution: regioselectivity and solvent effects. Journal of the Chemical Society: Perkin Transactions 1 . pp. 1234-1240. (doi:10.1039/b100903f)

Malkov, AV, Baxendale, IR, Bella, M, Langer, V, Fawcett, J, Russell, DR, Mansfield, DJ, Valko, M, and Kocovsky, P (2001) Synthesis of new chiral 2,2 '-bipyridyl-type ligands, their coordination to molybdenum(0), copper(II), and palladium(II), and application in asymmetric allylic substitution, allylic oxidation, and cyclopropanation. Organometallics, 20 . pp. 673-690. (doi:10.1021/om000850m)

Malkov, AV, Bella, M, Stara, IG, and Kocovsky, P (2001) Modular pyridine-type P,N-ligands derived from monoterpenes: application in asymmetric Heck addition. Tetrahedron Letters, 42 . pp. 3045-3048.

Malkov, AV, Farn, BP, Hussain, N, and Kocovsky, P (2001) Molybdenum-catalyzed allylic substitution in glycals: A C-C bond-forming Ferrier-type reaction. Collection of Czechoslovak Chemical Communications, 66 . pp. 1735-1745.

Malkov, AV, and Kocovsky, P (2001) Tetrahydrocannabinol revisited: Synthetic approaches utilizing molybdenum catalysts. Collection of Czechoslovak Chemical Communications, 66 . pp. 1257-1268.

Malkov, AV, Spoor, P, Vinader, V, and Kocovsky, P (2001) Asymmetric molybdenum(0)-catalyzed allylic substitution. Tetrahedron Letters, 42 . pp. 509-512.

Vyskocil, S, Smrcina, M, Lorenc, M, Tislerova, I, Brooks, RD, Kulagowski, JJ, Langer, V, Farrugia, LJ, and Kocovsky, P (2001) Copper(II)-mediated oxidative coupling of 2-aminonaphthalene homologues. Competition between the straight dimerization and the formation of carbazoles. Journal of Organic Chemistry, 66 . pp. 1359-1365.

This list was generated on Sun Apr 20 05:51:27 2014 BST.
Number of items: 69.

Article

Malkov, A.V., Stončius, S., Bell, M., Castelluzzo, F., Ramírez-López, P., Biedermannová, L., Langer, V., Rulíšek, L., and Kočovský, P. (2013) Mechanistic dichotomy in the asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by chiral pyridine N-oxides. Chemistry: A European Journal, 19 (28). pp. 9167-9185. ISSN 0947-6539 (doi:10.1002/chem.201203817)

Malkov, A.V., Stewart-Liddon, A.J.P., McGeoch, G.D., Ramirez-Lopez, P., and Kocovsky, P. (2012) Catalyst development for organocatalytic hydrosilylation of aromatic ketones and ketimines. Organic and Biomolecular Chemistry, 10 (25). pp. 4864-4877. ISSN 1477-0520 (doi:10.1039/C2OB25472G)

Malkov, A.V., Barłóg, M., Miller-Potucká, L., Kabeshov, M.A., Farrugia, L.J., and Kocovsky, P. (2012) Stereoselective palladium-catalyzed functionalization of homoallylic alcohols: a convenient synthesis of di- and trisubstituted isoxazolidines and β-amino-δ-hydroxy esters. Chemistry: A European Journal, 18 (22). pp. 6873-6884. ISSN 0947-6539 (doi:10.1002/chem.201102716)

Štambaský, J., Kapras, V., Štefko, M., Kysilka, O., Hocek, M., Malkov, A.V., and Kocovsky, P. (2011) A modular approach to aryl-C-ribonucleosides via the allylic substitution and ring-closing metathesis sequence: a stereocontrolled synthesis of all four α-/β- andd-/l-C-nucleoside stereoisomers. Journal of Organic Chemistry, 76 (19). pp. 7781-7803. ISSN 0022-3263 (doi:10.1021/jo201110z)

Chelucci, G., Marchetti, M. , Malkov, A.V. , Friscourt, F. , Swarbrick, M.E. , and Kočovský, P. (2011) New monoterpene-derived phosphinopyridine ligands and their application in the enantioselective iridium-catalyzed hydrogenation. Tetrahedron, 67 (30). pp. 5421-5431. ISSN 0040-4020 (doi:10.1016/j.tet.2011.05.075)

Malkov, A.V., Kysilka, O., Edgar, M., Kadlčíková, A., Kotora, M., and Kocovsky, P. (2011) A novel bifunctional allyldisilane as a triple allylation reagent in the stereoselective synthesis of trisubstituted tetrahydrofurans. Chemistry: A European Journal, 17 (26). pp. 7162-7166. ISSN 0947-6539 (doi:10.1002/chem.201100513)

Malkov, A.V., Barłóg, M., Jewkes, Y., Mikušek, J., and Kocovsky, P. (2011) Enantioselective allylation of α,β-unsaturated aldehydes with allyltrichlorosilane catalyzed by METHOX. Journal of Organic Chemistry, 76 (11). pp. 4800-4804. ISSN 0022-3263 (doi:10.1021/jo200712p)

Cogdell, Richard J., Gardiner, Alastair T., Roszak, Aleksander W., Stončius, Sigitas, Kocovsky, Pavel, and Isaacs, Neil W. (2011) Mapping lipid and detergent molecules at the surface of membrane protein. Biochemical Society Transactions, 39 (3). pp. 775-779. ISSN 0300-5127 (doi:10.1042/BST0390775)

Figlus, M., Caldwell, S.T., Walas, D., Yesilbag, G., Cooke, G., Kocovsky, P., Malkov, A.V., and Sanyal, A. (2010) Dendron-anchored organocatalysts: the asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron. Organic and Biomolecular Chemistry, 8 (1). pp. 137-141. ISSN 1477-0520 (doi:10.1039/b916601g)

Malkov, A.V., MacDonald, C., and Kocovsky, P. (2010) Synthesis of γ-functionalized allyltrichlorosilanes and their application in the asymmetric allylation of aldehydes. Tetrahedron-Asymmetry, 21 (9-10). pp. 1173-1175. ISSN 0957-4166 (doi:10.1016/j.tetasy.2010.03.026)

Farrugia, L.J., Kocovsky, P., Senn, H.M., and Vyskocil, S. (2009) Weak intra- and intermolecular interactions in a binaphthol imine: an experimental charge density study on (±)-8'benzhydrylideneamino-1,1'-binaphthyl-2-ol. Acta Crystallographica. Section B: Structural Science, B65 (6). pp. 757-769. ISSN 0108-7681 (doi:10.1107/S010876810903273X)

Malkov, Andrei V., Figlus, Marek, Prestly, Mark R., Rabani, Gouher, Cooke, Graeme, and Kocovsky, Pavel (2009) Soluble Polymer-Supported Organocatalysts: Asymmetric Reduction of Imines with Trichlorosilane Catalyzed by an Amino Acid Derived Formamide Anchored to a Soluble Polymer. Chemistry: A European Journal, 15 (38). pp. 9651-9654. ISSN 0947-6539 (doi:10.1002/chem.200901573)

Malkov, Andrei V., Vrankova, Kvetoslava, Stoncius, Sigitas , and Kocovsky, Pavel (2009) Asymmetric reduction of imines with trichlorosilane, catalyzed by sigamide, an amino acid-derived formamide: scope and limitations. Journal of Organic Chemistry, 74 (16). pp. 5839-5849. ISSN 0022-3263 (doi:10.1021/jo900561h)

Malkov, Andrei V., Kabeshov, Mikhail A., Barlog, Maciej, and Kocovsky, Pavel (2009) Enantioselective and catalytic method for α-crotylation of aldehydes with a kinetic self-refinement of stereochemistry. Chemistry: A European Journal, 15 (7). pp. 1570-1573. ISSN 0947-6539 (doi:10.1002/chem.200802224)

Malkov, A. V., Figlus, M., Cooke, G., Caldwell, S.T., Rabani, G., Prestly, M. R., and Kocovsky, P. (2009) Organocatalysts immobilised onto gold nanoparticles: application in the asymmetric reduction of imines with trichlorosilane. Organic and Biomolecular Chemistry, 7 (9). pp. 1878-1883. ISSN 1477-0520 (doi:10.1039/b821391g)

Malkov, A. V., Gordon, M. R., Stoncius, S., Hussain, J., and Kocovsky, P. (2009) Desymmetrization of Cyclic meso-Epoxides with Silicon Tetrachloride Catalyzed by PINDOX, a Chiral Bipyridine Mono-N-oxide. Organic Letters, 11 (23). pp. 5390-5393. ISSN 1523-7060 (doi:10.1021/ol902148s)

Malkov, A. V., Vrankova, K., Cerny, M., and Kocovsky, P. (2009) On the Selective N-Methylation of BOC-Protected Amino Acids. Journal of Organic Chemistry, 74 (21). pp. 8425-8427. ISSN 0022-3263 (doi:10.1021/jo9016293)

Malkov, A. V., Vrankova, K., Sigerson, R. C., Stoncius, S., and Kocovsky, P. (2009) New organocatalysts for the asymmetric reduction of imines with trichlorosilane. Tetrahedron, 65 (45). pp. 9481-9486. ISSN 0040-4020 (doi:10.1016/j.tet.2009.08.048)

Stambasky, J., Hocek, M., and Kocovsky, P. (2009) C-nucleosides: synthetic strategies and biological applications. Chemical Reviews, 109 (12). pp. 6729-6764. ISSN 0009-2665 (doi:10.1021/cr9002165)

Kocovsky, Pavel, and Malkov, Andrei V. (2008) Asymmetric synthesis: From transition metals to organocatalysis. Pure and Applied Chemistry, 80 (5). pp. 953-966. ISSN 0033-4545 (doi:10.1351/pac200880050953)

Drabina, P., Sedlak, M., Ruzicka, A., Malkov, A. V., and Kocovsky, P. (2008) Synthesis of (R)- and (S)-2-N-methylamino-2,3-dimethylbutanamides and (R)- and (S)-(5-isopropyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridine s. Tetrahedron-Asymmetry, 19 (3). pp. 384-390. ISSN 0957-4166 (doi:10.1016/j.tetasy.2008.01.016)

Malkov, A. V., Figlus, M., and Kocovsky, P. (2008) Polymer-supported organocatalysts: Asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid-derived formamide anchored to a polymer. Journal of Organic Chemistry, 73 (11). pp. 3985-3995. ISSN 0022-3263 (doi:10.1021/jo800094q)

Malkov, A. V., Friscourt, F., Bell, M., Swarbrick, M. E., and Kocovsky, P. (2008) Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands. Journal of Organic Chemistry, 73 (11). pp. 3996-4003. ISSN 0022-3263 (doi:10.1021/jo800246g)

Malkov, A. V., Ramirez-Lopez, P., Biedermannova, L., Rulisek, L., Dufkova, L., Kotora, M., Zhu, F. J., and Kocovsky, P. (2008) On the mechanism of asymmetric allylation of aldehydes with allyltrichlorosi lanes catalyzed by QUINOX, a chiral lsoquinoline N-oxide. Journal of the American Chemical Society, 130 (15). pp. 5341-5348. ISSN 0002-7863 (doi:10.1021/ja711338ci)

Malkov, A. V., Stewart-Liddon, A. J. P., Teply, F., Kobr, L., Muir, K. W., Haigh, D., and Kocovsky, P. (2008) New pinene-derived pyridines as bidentate chiral ligands. Tetrahedron, 64 (18). pp. 4011-4025. ISSN 0040-4020 (doi:10.1016/j.tet.2008.02.045)

Malkov, A. V., Westwater, M. M., Gutnov, A., Ramirez-Lopez, P., Friscourt, F., Kadlcikova, A., Hodacova, J., Rankovic, Z., Kotora, M., and Kocovsky, P. (2008) New pyridine N-oxides as chiral organocatalysts in the asymmetric allylation of aromatic aldehydes. Tetrahedron, 64 (49). pp. 11335-11348. ISSN 0040-4020 (doi:10.1016/j.tet.2008.08.084)

Malkov, A.V., Ramírez-López, P., Biedermannová, L., Rulíšek, L., Dufková, L., Kotora, M., Zhu, F., and Kocovsky, P. (2008) On the mechanism of asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by QUINOX, a chiral isoquinoline N-Oxide. Journal of the American Chemical Society, 130 (15). pp. 5341-5348. ISSN 0002-7863 (doi:10.1021/ja711338q)

Malkov, A.V., Stoncius, S., Vrankova, K., Arndt, M., and Kocovsky, P. (2008) Dynamic kinetic resolution in the asymmetric synthesis of beta-amino acids by organocatalytic reduction of enamines with trichlorosilane. Chemistry: A European Journal, 14 (27). pp. 8082-8085. ISSN 0947-6539 (doi:10.1002/chem.200801244)

Stambasky, J., Malkov, A. V., and Kocovsky, P. (2008) Preparation of Boc-protected cinnamyl-type alcohols: A comparison of the Suzuki-Miyaura coupling, cross-metathesis, and Horner-Wadsworth-Emmons approaches and their merit in parallel synthesis. Collection of Czechoslovak Chemical Communications, 73 (5). pp. 705-732. ISSN 0010-0765 (doi:10.1135/cccc20080705)

Stambasky, J., Malkov, A. V., and Kocovsky, P. (2008) Synthesis of Enantiopure 1-Arylprop-2-en-1-ols and Their tert-Butyl Carbonates. Journal of Organic Chemistry, 73 (22). pp. 9148-9150. ISSN 0022-3263 (doi:10.1021/jo801874r)

Malkov, Andrei V., Figlus, Marek, Stoncius, Sigitas, and Kocovsky, Pavel . (2007) Organocatalysis with a fluorous tag: Asymmetric reduction of imines with trichlorosilane catalyzed by amino acid-derived formamides. Journal of Organic Chemistry, 72 (4). pp. 1315-1325. ISSN 0022-3263 (doi:10.1021/jo062215i)

Malkov, A. V., Kabeshov, M. A., Bella, M., Kysilka, O., Malyshev, D. A., Pluhackova, K., and Kocovsky, P. (2007) Vicinal amino alcohols as organocatalysts in asymmetric cross-aldol reaction of ketones: Application in the synthesis of convolutamydine a. Organic Letters, 9 (26). pp. 5473-5476. ISSN 1523-7060 (doi:10.1021/ol7023983)

Malkov, A.V., Stoncius, S, and Kocovsky, P. (2007) Enantioselective synthesis of 1,2-diarylaziridines by the organocatalytic reductive amination of alpha-chloroketones. Angewandte Chemie (International Edition), 46 (20). pp. 3722-3724. ISSN 1433-7851 (doi:10.1002/anie.200700165)

Malkov, AV, and Kocovsky, P (2007) Chiral N-oxides in asymmetric catalysis. European Journal of Organic Chemistry . pp. 29-36. (doi:10.1002/ejoc.200600474)

Malkov, Andrei V., Stoncius, Sigitas, MacDougall, Kenneth N., Mariani, Andrea, McGeoch, Grant D., and Kocovsky, Pavel (2006) Formamides derived from N-methyl amino acids serve as new chiral organocatalysts in the enantioselective reduction of aromatic ketimines with trichlorosilane. Tetrahedron, 62 (2-3). pp. 264-284. ISSN 0040-4020 (doi:10.1016/j.tet.2005.08.117)

Malkov, A.V., Gouriou, L., Lloyd-Jones, G.C., Stary, I., Langer, V., Spoor, P., Vinader, V., and Kocovsky, P. (2006) Asymmetric allylic substitution catalyzed by C-1-symmetrical complexes of molybdenum: Structural requirements of the ligand and the stereochemical course of the reaction. Chemistry: A European Journal, 12 . pp. 6910-6929. ISSN 0947-6539 (doi:10.1002/chem.200501574)

Malkov, AV, Liddon, AJPS, Ramirez-Lopez, P, Bendova, L, Haigh, D, and Kocovsky, P (2006) Remote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines. Angewandte Chemie (International Edition), 45 . pp. 1432-1435. ISSN 1433-7851 (doi:10.1002/anie.200503941)

Malkov, AV, Bell, M, Castelluzzo, F, and Kocovsky, P (2005) METHOX: A new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes. Organic Letters, 7 . pp. 3219-3222. (doi:10.1021/ol050972h)

Malkov, AV, Bourhani, Z, and Kocovsky, P (2005) Amino acid-derived hydroxamic acids as chiral ligands in the vanadium catalysed epoxidation. Organic and Biomolecular Chemistry, 3 . pp. 3194-3200. (doi:10.1039/b505324b)

Kocovsky, P, and Malkov, AV (2004) From transition metals to organocatalysis. Russian Chemical Bulletin, 53 . pp. 1806-1812.

Malkov, AV, Mariani, A, MacDougall, KN, and Kocovsky, P (2004) Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane. Organic Letters, 6 . pp. 2253-2256. (doi:10.1021/ol049213+)

Seymour, JL, Turecek, F, Malkov, AV, and Kocovsky, P (2004) Chiral recognition in solution and the gas phase. Experimental and theoretical studies of aromatic D- and L-amino acid-Cu(II)-chiragen complexes. Journal of Mass Spectrometry, 39 . pp. 1044-1052. (doi:10.1002/jms.675)

Abbott, AP, Barker, GW, Walter, AJ, and Kocovsky, P (2003) Electrochemical recognition of analytes using quaternary ammonium binaphthyl salts. Analyst, 128 . pp. 245-248. (doi:10.1039/b209478a)

Belokon, YN et al. (2003) Synthesis of alpha-amino acids via asymmetric phase transfer-catalyzed alkylation of achiral nickel(II) complexes of glycine-derived Schiff bases. Journal of the American Chemical Society, 125 . pp. 12860-12871. (doi:10.1021/ja035465e)

Gouriou, L, Lloyd-Jones, GC, Vyskocil, S, and Kocovsky, P (2003) H-2-quadrupolar coupling-based analysis of stereochemical and regiochemical memory in the Pd-catalysed allylic alkylation of iso-cinnamyl type substrates employing the chiral monophosphine ligands 'MOP' and 'MAP'. Journal of Organometallic Chemistry, 687 . pp. 525-537. (doi:10.1016/j.jorganchem.2003.09.015)

Kocovsky, P (2003) Reactivity control in palladium-catalyzed reactions: a personal account. Journal of Organometallic Chemistry, 687 . pp. 256-268. (doi:10.1016/jorganchem.2003.07.008)

Kocovsky, P, Vyskocil, S, and Smrcina, M (2003) Non-symmetrically substituted 1,1 '-binaphthyls in enantioselective catalysis. Chemical Reviews, 103 . pp. 3213-3245. (doi:10.1021/cr9900230)

Malkov, A.V., Bell, M., Vassieu, M., Bugatti, V., and Kocovsky, P. (2003) New pyridine-derived N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes. Journal of Molecular Catalysis A: Chemical, 196 . pp. 179-186. ISSN 1381-1169

Malkov, AV, Bell, M, Orsini, M, Pernazza, D, Massa, A, Herrmann, P, Meghani, P, and Kocovsky, P (2003) New Lewis-basic N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes. Journal of Organic Chemistry, 68 . pp. 9659-9668. (doi:10.1021/jo035074i)

Malkov, AV, Dufkova, L, Farrugia, L, and Kocovsky, P (2003) Quinox, a quinoline-type N-oxide, as organocatalyst in the asymmetric allylation of aromatic aldehydes with allyltrichlorosilanes: The role of arene-arene interactions. Angewandte Chemie (International Edition), 42 . pp. 3674-3677. ISSN 1433-7851 (doi:10.1002/anie.200351737)

Malkov, AV, Hand, JB, and Kocovsky, P (2003) A long-range chiral relay via tertiary amide group in asymmetric catalysis: new amino acid-derived N,P-ligands for copper-catalysed conjugate addition. Chemical Communications . pp. 1948-1949. (doi:10.1039/b304131j)

Malkov, AV, and Kocovsky, P (2003) Chiral bipyridine derivatives in asymmetric catalysis. Current Organic Chemistry, 7 . pp. 1737-1757.

Malkov, AV, Pernazza, D, Bell, M, Bella, M, Massa, A, Teply, F, Meghani, P, and Kocovsky, P (2003) Synthesis of new chiral 2,2 '-bipyridine ligands and their application in copper-catalyzed asymmetric allylic oxidation and cyclopropanation. Journal of Organic Chemistry, 68 . pp. 4727-4742. (doi:10.1021/jo034179i)

Massa, A, Malkov, AV, Kocovsky, P, and Scettri, A (2003) Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides. Tetrahedron Letters, 44 . pp. 7179-7181. (doi:10.1016/S0040-4039(03)01801-X)

Vyskocil, S, Lockhart, SC, Mitchell, WL, and Kocovsky, P (2003) Synthesis of 2-hydroxy-8 '-(hydroxymethyl)-1,1 '-binaphthalene (iso-homo-binol). A new structural pattern in the binaphthyl realm. Collection of Czechoslovak Chemical Communications, 68 . pp. 907-916. (doi:10.1135/cccc20030907)

Abbott, AP, Barker, GW, Davies, DL, Griffiths, GA, Walter, AJ, and Kocovsky, P (2002) Electrochemical recognition of chiral species using quaternary ammonium binaphthyl salts. Analytical Chemistry, 74 . pp. 4002-4006. (doi:10.1021/ac025635q)

Fairlamb, I.J.S., Lloyd-Jones, G.C., Stepan, V., and Kocovsky, P. (2002) Analysis of stereochemical convergence in asymmetric Pd-catalysed allylic alkylation reactions complicated by halide and memory effects. Chemistry: A European Journal, 8 . pp. 4443-4453. ISSN 0947-6539

Malkov, AV, Orsini, M, Pernazza, D, Muir, KW, Langer, V, Meghani, P, and Kocovsky, P (2002) Chiral 2,2 '-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane. Organic Letters, 4 . pp. 1047-1049. (doi:10.1021/ol025654m)

Vyskocil, S. et al. (2002) 2,8 '-disubstituted-1,1 '-binaphthyls: A new pattern in chiral ligands. Chemistry: A European Journal, 8 . pp. 4633-4648. ISSN 0947-6539

Abbott, AP, Barker, GW, Lonergan, GR, Walter, AJ, and Kocovsky, P (2001) Electrochemical recognition of charged species using quaternary ammonium binaphthyl salts. Analyst, 126 . pp. 1892-1896.

Malkov, A.V., Baxendale, I.R., Mansfield, D.J., and Kocovsky, P. (2001) Molybdenum(0) and tungsten(0) catalysts with enhanced reactivity for allylic substitution: regioselectivity and solvent effects. Journal of the Chemical Society: Perkin Transactions 1 . pp. 1234-1240. (doi:10.1039/b100903f)

Malkov, AV, Baxendale, IR, Bella, M, Langer, V, Fawcett, J, Russell, DR, Mansfield, DJ, Valko, M, and Kocovsky, P (2001) Synthesis of new chiral 2,2 '-bipyridyl-type ligands, their coordination to molybdenum(0), copper(II), and palladium(II), and application in asymmetric allylic substitution, allylic oxidation, and cyclopropanation. Organometallics, 20 . pp. 673-690. (doi:10.1021/om000850m)

Malkov, AV, Bella, M, Stara, IG, and Kocovsky, P (2001) Modular pyridine-type P,N-ligands derived from monoterpenes: application in asymmetric Heck addition. Tetrahedron Letters, 42 . pp. 3045-3048.

Malkov, AV, Farn, BP, Hussain, N, and Kocovsky, P (2001) Molybdenum-catalyzed allylic substitution in glycals: A C-C bond-forming Ferrier-type reaction. Collection of Czechoslovak Chemical Communications, 66 . pp. 1735-1745.

Malkov, AV, and Kocovsky, P (2001) Tetrahydrocannabinol revisited: Synthetic approaches utilizing molybdenum catalysts. Collection of Czechoslovak Chemical Communications, 66 . pp. 1257-1268.

Malkov, AV, Spoor, P, Vinader, V, and Kocovsky, P (2001) Asymmetric molybdenum(0)-catalyzed allylic substitution. Tetrahedron Letters, 42 . pp. 509-512.

Vyskocil, S, Smrcina, M, Lorenc, M, Tislerova, I, Brooks, RD, Kulagowski, JJ, Langer, V, Farrugia, LJ, and Kocovsky, P (2001) Copper(II)-mediated oxidative coupling of 2-aminonaphthalene homologues. Competition between the straight dimerization and the formation of carbazoles. Journal of Organic Chemistry, 66 . pp. 1359-1365.

Book Section

Kocovsky, P., and Stoncius, S. (2010) Reduction of imines with trichlorosilane catalyzed by chiral lewis bases. In: Nugent, T.C. (ed.) Chiral Amine Synthesis: Methods, Developments and Applications. Wiley, Chichester, UK, pp. 131-156. ISBN 9783527325092

Kocovsky, P., and Malkov, A.V. (2007) Chiral lewis bases as catalysts. In: Dalko, P.I. (ed.) Enantioselective Organocatalysis: Reactions and Experimental Procedures. Wiley-VCH, Weinheim, Germany, pp. 255-286. ISBN 9783527315222

This list was generated on Sun Apr 20 05:51:27 2014 BST.